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3-chloroperoxybenzoic acid CAS No. 937-14-4 m-Chloroperoxybenzoic
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3-chloroperoxybenzoic acid is white powdery crystals. Melting point is 92-94°C (decomposed). It is almost insoluble in water, but soluble in ethanol, ethers, chloroform, and dichloroethane. It is thermally stable and has an annual decomposition rate of less than 1% at room temperature. The decomposition rate is accelerated in the liquid state. 3-Chloroperbenzoic acid is sensitive to heat and shock, and pure solid. 3-Chloroperbenzoic acid is flammable and potentially explosive. It contains a weak –O–O– bond and a nucleophilic OH group, that makes it versatile oxidative and easily breakable.
3-Chloroperoxybenzoic acid is commonly used in double bond epoxidation, nitridation, cyclization, Baeyer-Villiger oxidation, and N-oxidation. It can also be used as an oxidant for fine chemicals such as synthetic medicine and pesticides. It is also sometimes used as a bleaching agent.
• Used in cyclization reaction, Baeyer-Villiger reaction, N-oxidation reaction and S-oxidation reaction.
• Used as an oxidant for fine chemical products such as synthetic medicine and pesticides.
• Used as oxidant and bleach.
• As a good electrophilic reagent, it can react with many functional groups and can oxidize olefins, enol silyl ethers, furans, sulfides, selenides and amino compounds.
3-Chloroperoxybenzoic acid is a strong oxidizing agent used in the oxidation reactions such as aldehydes and ketones to esters (Bayer-Villiger-Oxidation), olefines to epoxides, sulfides to sulfoxides and sulfones, and amines to nitroalkanes, N-oxides.
Product Name: |
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Synonyms: |
3-CHLOROPEROXYBENZOIC ACID, 50-55%; |
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CAS: |
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MF: |
C7H5ClO3 |
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MW: |
172.57 |
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EINECS: |
213-322-3 |
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3-Chloroperoxybenzoic acid Chemical Properties |
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Melting point |
69-71 °C(lit.) |
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Boiling point |
244.67°C (rough estimate) |
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Density |
0.56 |
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refractive index |
1.4580 (estimate) |
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storage temp. |
2-8°C |
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form |
Moist Powder |
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pka |
7.57 (in water @ 25 °C) |
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color |
White |
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Odor |
slight pungent odor |
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PH |
4.5@25 °C (saturated aq. sol) |
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Water Solubility |
insoluble |
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Decomposition |
>88 °C |
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Stability: |
Strong oxidizing agent - contact with combustible material may cause fire. May be shock or heat sensitive. Incompatible with organic materials, strong reducing agents. |
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Safety Information |
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Hazard Codes |
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Risk Statements |
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Safety Statements |
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RIDADR |
UN 3106 5.2 |
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HazardClass |
5.2 |
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PackingGroup |
II |
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HS Code |
29163990 |
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