The monometallic single crystal of zinc iodate [Zn(IO3)2] was grown by slow cooling technique with the dimension up to 14 × 4 × 3 mm3 in the period of 35–45 days. Single crystal X-ray diffraction (XRD) analysis shows that the zinc iodate (ZI) crystal crystallizes in monoclinic crystal system ...

Background: Iodate is a strong oxidant, and some animal studies indicate that iodate intake may cause adverse effects. A key focus of the safety assessment of potassium iodate as a salt additive is determining whether iodate is safely reduced to iodide in food. Objective: To study the reduction ...

Studies that deal with iodine mobility in uncontaminated agricultural soils are scarce and unique. Therefore, in this article, we have evaluated the sorption behavior of two most abundant naturally occurring inorganic iodine species – iodide and iodate – in several soil types. Our results show...

The new inorganic-organic iodate hybrid compound N-(3-ammonium propyl)-1, 3 diaminopropane tris iodate dehydrate [(C6H20N3) (IO3)3·2H2O] denoted as BATID was synthesized and characterized by single X-ray diffraction. This iodate salt crystallizes in the orthorhombic system with acentric space g...

Four new transition metal fluorosulfates NH4MSO4F (M = Mn, 1; Fe, 2; Co, 3; Ni, 4) were solvothermally synthesized in the solvent of N,N-dimethylacetamide (DMA) with HF as the mineralization agent. The X-ray single crystal diffraction analyses revealed that 1–4 are isomorphous, and possess a th...

A simple, practical and gram-scale process for direct transformation of primary alcohols or silyl ethers to ammonium salts was developed. This method has the feathers of easy work-up (a simple filtration), mild condition, high yield, great practicality and robustness. And the application of the ...

New chiral porphyrins bearing glycosyl substituents (glucose, maltose or lactose) at ortho or meta positions of the meso-phenyl groups have been synthesized. Their manganese complexes, associated with hydrogen monopersulfate, lithium hypochlorite, hydrogen peroxide, or iodosylbenzene, have been ...

Palladium(II) and platinum(II) thiosaccharinate complexes [M(κ1-tsac)2{κ2-Ph2P(CH2)nPPh2}] (M = Pd, Pt; n = 1–4) have been prepared, palladium complexes from reaction of [Pd(tsac)2]·H2O with diphosphanes and platinum complexes from addition of thiosaccharin to [PtCl2{κ2-Ph2P(CH2)nPPh2}] in ...

Reaction of two equivalents of lithium hypersilylphosphanide (hypersilyl, Hyp = tris(trimethylsilyl)silyl) with dichlorotetramethyldisilane at low temperatures gives [HypPH–SiMe2–]2 1, a compound with high steric protection on both phosphane functionalities. Dehydrogenation reaction of 1 with ...

Three silver(I) complexes bearing different combinations of diphosphanes and N-heterocyclic thioamides or thioamidates as ligands have been synthesized and structurally characterized: the ionic, homoleptic compound [Ag(xantphos)2][BF4] (1), where xantphos = 4,5-bis(diphenylphosphano)-9,9-dimethy...

Electrolyzed sulfuric acid is a new chemical reagent prepared by electrolysis of aqueous sulfuric acid. In the present work, the concentrations of the oxidizing species (S2O82–, HSO5−, and H2O2) present in electrolyzed sulfuric acid were quantified, and photochemical decomposition of trifluoroa...

Peroxydisulfuric acid oxidant (H2S2O8) was electro-generated using boron doped diamond (BDD) anode in an undivided electrolytic cell under the optimized conditions and used for the oxidative removal of gaseous SO2. The influence of the nature of cathode material on the formation yield of H2S2O8 ...

Steroidal Pd (II) metal complexes were synthesized by the reaction of steroidal thiosemicarbazones with [Pd (DMSO)2 Cl2]. The steroidal thiosemicarbazones coordinate to palladium through the azomethine nitrogen and thionic sulfur. The thiosemicarbazone derivatives were obtained by the reaction o...

The reaction of multi-walled carbon nanotubes (MWCNT) with xenon difluoride has been studied and compared with the results from experiments with elemental fluorine. A low level fluorination of MWCNTs was achieved at ambient temperature under the influence of light. The outer shells of the nanotu...

Porous palladium (Pd) nanoparticles have garnered great research attention due to their potential anticancer activity and photothermal effect. In this study, a transferrin-conjugated pH-sensitive platform (Tf-PPP), comprising porous Pd nanoparticles (PdNPs) and paclitaxel (PTX), was successfully...

Reaction of aryltrimethylsilanes with xenon difluoride in C6F6/Pyrex® at room temperature gives aryl fluorides in good yield. The reaction is inhibited when acetonitrile is used as solvent but proceeds well in CFCl3/Pyrex® or CH2Cl2/Pyrex®. Pyrex® appears to be a very effective heterogeneous cat...

As the speciation of metal species, especially the noble metals, are crucial for recovery and separation purposes, the complex formation of Pd(II), with chloride and bromide respectively, has been investigated employing spectrophotometry at 25 °C and an ionic strength of 1.0 M Hyperquad Simulat...

The spectroscopy, electrochemistry and electrogenerated chemiluminescence (ECL) of four osmium(II) phenanthroline carbonyl chloride complexes are reported. Three of these compounds also contain diphosphine chelating ligands. ECL is generated in acetonitrile solutions with tri-n-propylamine (TPrA...

Osmium and iridium metal nanoparticles were supported on a fluorous organic-inorganic hybrid material prepared by the sol-gel process. Moreover, we also found that the thermolysis of the Ir4(CO)12 cluster in simply diphenylether also gave Ir(0) nanoparticles. All the materials were studied as ca...

The 12.6 µm region of nitryl chloride (ClNO2) has been recorded at high resolution (0.00102 cm−1) using a Fourier transform spectrometer and the SOLEIL synchrotron light source. ClNO2 was found during our studies of chlorine nitrate and, after fractional distillations it was introduced into a m...