A new phase transition in the title compound is observed at 260 K by DSC and NMR. Furthermore, the phase stable between 260 K and 280 K is found to be triclinic and not monoclinic as believed earlier. The structure is determined from single crystal X-ray data, and the molecules are found to be i...

Bulk crystals of the charge-transfer complex, ethylenediamine-4-nitrophenolate monohydrate, were grown by slow solvent evaporation method from aqueous solution at room temperature. The X-ray diffraction measurements showed that the crystal belongs to centrosymmetric space group C2/c of monoclini...

As a part of the Japanese Center for the Validation of Alternative Methods (JaCVAM)-initiative international validation study of the in vivo alkaline comet assay (comet assay), we examined DNA damage in the liver, stomach, and bone marrow of rats dosed orally three times with up to 2000 mg/kg of...

A new tris(ethylenediamine)nickel(II) complex [Ni(en)3]GeS2(OH)2·H2O containing a zero-dimensional thiohydroxogermanate [GeS2(OH)2]2− anion was synthesized using a solvothermal reaction. The compound crystallizes in monoclinic space group P21/n with cell parameters a = 8.676(3) Å, b = 13.574(4)...

As a continuation to our research, a series of novel Bcr-Abl inhibitors incorporated with 6-phenyl-1H-indazol-3-amine as hinge binding moiety (HBM) were developed based on confirmation analysis. Biological results indicated that these compounds exhibited an enhanced inhibition against Bcr-AblWT ...

Dyes have been used for more than twenty thousand years in textile, pharmaceutical, food, cosmetic, and photographic industries, among others. Despite their importance in these applications, dyes can be toxic and resistant to many degradation processes used in wastewater treatment plants. Althou...

Bioremediation of textile dyes adsorbed on agricultural solid wastes under solid state fermentation (SSF) using rhizospheric plant growth promoting microorganisms pose an ecofriendly, economically feasible and promising treatment approach. The purpose of this study was to adsorb azo dye Disperse...

The solubilities of disperse dyes and their mixture in supercritical carbon dioxide are important to the fundamental research and development of supercritical fluid dyeing (SFD). The solubilities of Disperse Red 73, Disperse Yellow 119 and their mixture in supercritical carbon dioxide were measu...

Single crystals of C.I. Disperse Red 65 and C.I. Disperse Red 73 were grown from ethyl acetate and acetonitrile/toluene solutions, respectively, and their crystal structures were determined using single-crystal X-ray diffraction analysis. In each dye molecule, the aminoazobenzene framework is al...

Star polymers (CD-POEGMAs and CD-PNIPAMs), and pseudo-graft polymer (PADMA-(CD-POEGMAs)x) formed from PADMA with adamantyl(Ad) pendants and CD-POEGMAs by host–guest inclusion complexation were prepared and characterized. This work compared the thermoresponsive and self-assembly mechanisms of th...

Acid-cleavable branched polymers composed of a methacrylate and two acrylates were prepared through reversible addition-fragmentation chain transfer (RAFT) polymerization. The molecular weight of primary chains and the degree of branching of the polymers were controlled by the feed ratio of mono...

In order to prevent freshwater biofouling glass and metal surfaces were coated with novel transparent methacrylate-based copolymers. The multifunctionality of the copolymers, such as adhesion to the substrate, surface polarity, mechanical long-term stability in water, and ability to form metal c...

Three 4-(1-adamantyl)phenyl methacrylate monomers were synthesized from 4-(1-adamantyl)phenol derivatives which were obtained by Friedel–Crafts alkylation of phenol, 2-methylphenol and 2,6-dimethylphenol with 1-bromoadamantane. Characterization of the monomers by IR, 1H and 13C NMR, GC and elem...

This paper aimed to evaluate the effect of electrochemical chloride removal (ECR) on the stability of bound chlorides in ground granulated blast furnace slag (GGBS) blended cement pastes subjected to NaCl and Na2SO4 attack. Two chloride attack conditions (pure chlorides, 5%NaCl + 0%Na2SO4, and t...

A novel isotope dilution method for the analysis of inorganic chloride in fuel oil matrix is presented. The samples were diluted by isopropyl alcohol:toluene, mixed with 37Cl− internal standard and reacted with triethyloxonium tetrafluoroborate at room temperature. This reagent promoted conversi...

One of the principal reasons for premature deterioration in reinforced concrete is chloride-induced corrosion. In materials such as stone, or earthen materials, salt crystallization plays a significant damaging role, and chloride distribution is an important factor. The reliable quantification o...

In this work, we investigated the self-reaction of allyl radicals and its cross-reaction with hydroxyl radical by employing shock tube and laser absorption techniques. We carried out the experiments behind reflected shock waves over the temperature range of 800–1200 K and pressures of 1.1–2.5 ...

Sodium carbonate peroxyhydrate (SCP) is a granular algaecide containing H2O2 as an active ingredient to control growth of noxious algae. Measurements of sensitivities of target and non-target species to hydrogen peroxide are necessary for water resource managers to make informed decisions and mi...

A one-pot three-component process for the synthesis of highly functionalized 2,3-dihydrofurans from 1,3-dicarbonyl compounds, aromatic aldehydes, and N-phenacylpyridinium bromides has been developed. Benzylidene 1,3-dicarbonyl compounds could be generated in situ from aromatic aldehydes and 1,3-...

Reaction of 2-chloro-1-phenacylpyridinium bromide 1a with KSCN led to 2-amino-thiazolo[3,2-a]pyridinium salts 4a,b thus opening a novel route to fused thiazoles. In reaction with KSCN oxazolo[3,2-a]pyridinium perchlorate 2a was converted to thiocyanate 2b. Crystal structures of thiocyanates 2b a...