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Hebei yanxi chemical co.,LTD.

chengdu and import and export trade co., LTD., who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do res

Di-tert-butylchlorophosphane

Cas:13716-10-4

Min.Order:10 Kilogram

FOB Price: $1000.0

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

Di-t-butylchlorophosphine

Cas:13716-10-4

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 13716-10-4 di-tert-butylchlorophosphine Manufacturer

Cas:13716-10-4

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesi

High purity and quality Di-tert-butylchlorophosphane

Cas:13716-10-4

Min.Order:100 Gram

Negotiable

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

Di-tert-butylchlorophosphane

Cas:13716-10-4

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Chlorodi-tert-butylphosphine

Cas:13716-10-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.

13716-10-4 Di-tert-butylchlorophosphane

Cas:13716-10-4

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 13716-10-4 with best quality

Cas:13716-10-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Di-tert-butylchlorophosphane/CAS 13716-10-4 factory

Cas:13716-10-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

CAS No.: 13716-10-4 Molecular formula: C8H18ClP Molecular weight: 180.66 EINECS number: Related Categories: Chlorophosphines; Ligand; Catalysis and Inorganic Chemistry; Phosphorus Compounds; Phosphorus Precursors; Phosphines; Phosphine Compou

Di-t-butylchlorophosphine

Cas:13716-10-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Phosphinous chloride,P,P-bis(1,1-dimethylethyl)-

Cas:13716-10-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Di-tert-butylchlorophosphine

Cas:13716-10-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Di-tert-butylchlorophosphane

Cas:13716-10-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Di-tert-butylchlorophosphine

Cas:13716-10-4

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products Di-tert-butylchlorophosphane

Cas:13716-10-4

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Di-tert-butylchlorophosphane/13716-10-4 factory

Cas:13716-10-4

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Colorless to light yellow liquid Storage:In Room Temperature Package:25kg/drum, or as per your request. Application:For medicine , pesticide intermediates Transportation:as per y

Di-tert-butylchlorophosphane

Cas:13716-10-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply Di-tert-butylchlorophosphine

Cas:13716-10-4

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

Best Quality CAS 13716-10-4CAS NO.: 13716-10-4

Cas:13716-10-4

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

roduct Name: Di-tert-butylchlorophosphane CAS: 13716-10-4 MF: C8H18ClP MW: 180.66 EINECS: Mol File: 13716-10-4.mol Di-tert-butylchlorophosphane Structure Di-tert-butylchlorophosphane Chemical Properties Melting point 2-3°

Di-tert-butylchlorophosphane

Cas:13716-10-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Di-tert-butylchlorophosphane/13716-10-4 factory

Cas:13716-10-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

Di-tert-butylchlorophosphane

Cas:13716-10-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Di-tert-butylchlorophosphane/13716-10-4 factory

Cas:13716-10-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Di-tert-butylchlorophosphane/13716-10-4 factory

Cas:13716-10-4

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Di-tert-butylchlorophosphane

Cas:13716-10-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

Di-tert-butylchlorophosphane

Cas:13716-10-4

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Di-tert-butylchlorophosphane/13716-10-4 factory

Cas:13716-10-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratoryAppearance:Colorless liquid Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Di-tert-butylchlorophosphane cas no. 13716-10-4 96%

Cas:13716-10-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Vanz Pharm Co.,Ltd

ISO/factory/goodqualityAppearance:off white Storage:Dry,cool place Package:drum Application:active pharmaceutical ingredients Transportation:by air/sea/express Port:shenzhen/shanghai

Di-tert-butylchlorophosphine

Cas:13716-10-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

di-tert-Butylchlorophosphine

Cas:13716-10-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

tetra-tert-butyldiphosphane
5995-06-2

tetra-tert-butyldiphosphane

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

Conditions
ConditionsYield
With Dichlorophenylphosphine for 2h;83%
di-tert-butylphosphine
819-19-2

di-tert-butylphosphine

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

Conditions
ConditionsYield
With n-octyl trichloroacetate at 70 - 84℃; for 0.666667h; Product distribution / selectivity;78.2%
With tetrachloromethane at 20℃; for 48h; also at 100 deg C, 30 min.; Yield given;
tert-butylmagnesium chloride
677-22-5

tert-butylmagnesium chloride

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

Conditions
ConditionsYield
With phosphorus trichloride In diethyl ether for 0.5h; Heating;60%
With phosphorus trichloride In diethyl ether
With phosphorus trichloride In diethyl ether at 20℃; Inert atmosphere; Schlenk technique;
tertiary butyl chloride
507-20-0

tertiary butyl chloride

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

Conditions
ConditionsYield
Stage #1: tertiary butyl chloride With magnesium In diethyl ether at 20℃; Inert atmosphere; Schlenk technique;
Stage #2: With phosphorus trichloride In diethyl ether at -40℃; Inert atmosphere; Schlenk technique;
50%
Stage #1: tertiary butyl chloride With magnesium In diethyl ether at 20℃; Inert atmosphere; Schlenk technique;
Stage #2: With phosphorus trichloride In diethyl ether at -40℃; Inert atmosphere; Schlenk technique;
50%
(i) Mg, Et2O, (ii) PCl3; Multistep reaction;
tetrachloromethane
56-23-5

tetrachloromethane

2-Methyl-1-(1,2,2-tri-tert-butyl-diphosphanyl)-propan-1-one
131551-72-9

2-Methyl-1-(1,2,2-tri-tert-butyl-diphosphanyl)-propan-1-one

A

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

B

tert-butylpivaloylphosphinic acid chloride
131551-83-2

tert-butylpivaloylphosphinic acid chloride

C

tert-butylpivaloylphosphinic acid chloride
131551-82-1

tert-butylpivaloylphosphinic acid chloride

D

1-(tert-Butyl-trichloromethyl-phosphanyl)-2-methyl-propan-1-one
131551-85-4

1-(tert-Butyl-trichloromethyl-phosphanyl)-2-methyl-propan-1-one

Conditions
ConditionsYield
at 20℃; for 48h;
tetrachloromethane
56-23-5

tetrachloromethane

2-Methyl-1-(1,2,2-tri-tert-butyl-diphosphanyl)-propan-1-one
131551-72-9

2-Methyl-1-(1,2,2-tri-tert-butyl-diphosphanyl)-propan-1-one

A

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

B

tert-butylpivaloylphosphinic acid chloride
131551-82-1

tert-butylpivaloylphosphinic acid chloride

C

1-(tert-Butyl-trichloromethyl-phosphanyl)-2-methyl-propan-1-one
131551-85-4

1-(tert-Butyl-trichloromethyl-phosphanyl)-2-methyl-propan-1-one

D

Di-tert-butyl(trichloromethyl)phosphine
125325-14-6

Di-tert-butyl(trichloromethyl)phosphine

Conditions
ConditionsYield
at 20℃; for 48h;
Di-tert-butylphosphine
119522-06-4

Di-tert-butylphosphine

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

C

N,N,N',N'-Tetramethylformamidinium chloride
1071-38-1

N,N,N',N'-Tetramethylformamidinium chloride

Conditions
ConditionsYield
With tetrachloromethane In diethyl ether at 20℃; for 48h;
pivaloyl chloride
3282-30-2

pivaloyl chloride

2-Methyl-1-(1,2,2-tri-tert-butyl-diphosphanyl)-propan-1-one
131551-72-9

2-Methyl-1-(1,2,2-tri-tert-butyl-diphosphanyl)-propan-1-one

A

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

B

tert-butylpivaloylphosphinic acid chloride
131551-83-2

tert-butylpivaloylphosphinic acid chloride

C

di-tert-butylpivaloylphosphine
66199-86-8

di-tert-butylpivaloylphosphine

D

1-(tert-Butyl-isobutyryl-phosphanyl)-2,2-dimethyl-propan-1-one
131551-84-3

1-(tert-Butyl-isobutyryl-phosphanyl)-2,2-dimethyl-propan-1-one

Conditions
ConditionsYield
at 20℃; for 48h;
<(di-tert-butylphosphino)(trimethylsilyl)amino>lithium
92387-43-4

<(di-tert-butylphosphino)(trimethylsilyl)amino>lithium

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

Conditions
ConditionsYield
With phosphorus trichloride In diethyl ether; hexane at 20℃;
2-Methyl-1-(1,2,2-tri-tert-butyl-diphosphanyl)-propan-1-one
131551-72-9

2-Methyl-1-(1,2,2-tri-tert-butyl-diphosphanyl)-propan-1-one

A

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

B

tert-butylpivaloylphosphinic acid chloride
131551-83-2

tert-butylpivaloylphosphinic acid chloride

C

di-tert-butylpivaloylphosphine
66199-86-8

di-tert-butylpivaloylphosphine

D

1-(tert-Butyl-isobutyryl-phosphanyl)-2,2-dimethyl-propan-1-one
131551-84-3

1-(tert-Butyl-isobutyryl-phosphanyl)-2,2-dimethyl-propan-1-one

Conditions
ConditionsYield
With pivaloyl chloride at 20℃; for 48h;
2-Methyl-1-(1,2,2-tri-tert-butyl-diphosphanyl)-propan-1-one
131551-72-9

2-Methyl-1-(1,2,2-tri-tert-butyl-diphosphanyl)-propan-1-one

A

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

B

tert-butylpivaloylphosphinic acid chloride
131551-83-2

tert-butylpivaloylphosphinic acid chloride

C

1-(tert-Butyl-trichloromethyl-phosphanyl)-2-methyl-propan-1-one
131551-85-4

1-(tert-Butyl-trichloromethyl-phosphanyl)-2-methyl-propan-1-one

D

Di-tert-butyl(trichloromethyl)phosphine
125325-14-6

Di-tert-butyl(trichloromethyl)phosphine

Conditions
ConditionsYield
With tetrachloromethane at 20℃; for 48h;
1,1-Di-tert-butyl-2-diphosphan
81979-49-9

1,1-Di-tert-butyl-2-diphosphan

A

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

Conditions
ConditionsYield
With hexachloroethane Product distribution;
[Li+*3DME][Cl((2,6-iPr2C6H3)N)2W(η2-t-Bu2PP)-]

[Li+*3DME][Cl((2,6-iPr2C6H3)N)2W(η2-t-Bu2PP)-]

chloro-diphenylphosphine
1079-66-9

chloro-diphenylphosphine

A

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

B

di-tert-butylphosphine
819-19-2

di-tert-butylphosphine

C

(1,2-η-t-Bu2PPP-t-Bu2)W(2,6-i-Pr2C6H3N)2Cl

(1,2-η-t-Bu2PPP-t-Bu2)W(2,6-i-Pr2C6H3N)2Cl

D

1.1-Diisobutyl-2.2-diphenyldiphosphin
67857-60-7

1.1-Diisobutyl-2.2-diphenyldiphosphin

E

Tetraphenyldiphosphin
1101-41-3

Tetraphenyldiphosphin

Conditions
ConditionsYield
In 1,2-dimethoxyethane at -40 - 20℃; for 24h; Schlenk technique;A n/a
B 8 %Spectr.
C 9 %Spectr.
D 17 %Spectr.
E 41 %Spectr.
tert-butylmagnesium chloride
677-22-5

tert-butylmagnesium chloride

A

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

B

tert-butyldichlorophosphine
25979-07-1

tert-butyldichlorophosphine

Conditions
ConditionsYield
With phosphorus trichloride In diethyl ether at 20℃;
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

di-tert-butylphosphine oxide
684-19-5

di-tert-butylphosphine oxide

Conditions
ConditionsYield
In dichloromethane at 20℃; Inert atmosphere; Glovebox;100%
With water; triethylamine In tetrahydrofuran for 0.666667h;89%
With ethylene glycol; triethylamine In tetrahydrofuran at 0 - 130℃;31%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

1-(4-fluorophenyl)ethylamine
403-40-7

1-(4-fluorophenyl)ethylamine

C16H27FNP
183797-20-8

C16H27FNP

Conditions
ConditionsYield
100%
(RC,SFc,SP)-1-[2-(1-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-bromoferrocene

(RC,SFc,SP)-1-[2-(1-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-bromoferrocene

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

(RC,SFc,SP)-1-[2-(1-N,N-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-di-tert-butylphosphinoferrocene

(RC,SFc,SP)-1-[2-(1-N,N-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-di-tert-butylphosphinoferrocene

Conditions
ConditionsYield
Stage #1: (RC,SFc,SP)-1-[2-(1-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-bromoferrocene With n-butyllithium In hexane; tert-butyl methyl ether at -5 - 0℃;
Stage #2: di(tert-butyl)chlorophosphine In hexane; tert-butyl methyl ether at 0 - 20℃;
100%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

trans-1,3-cyclohexanediol
5515-64-0

trans-1,3-cyclohexanediol

trans-1,3-bis-(di-tert-butylphosphinito-cyclohexane)

trans-1,3-bis-(di-tert-butylphosphinito-cyclohexane)

Conditions
ConditionsYield
With sodium hydride In paraffin oil Inert atmosphere; Schlenk technique; Glovebox;100%
2,2-dimethyl-1,2,3,4-tetrahydroquinoline
20364-30-1

2,2-dimethyl-1,2,3,4-tetrahydroquinoline

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

1-(Di-tert-butyl-phosphanyl)-2,2-dimethyl-1,2,3,4-tetrahydro-quinoline
183797-19-5

1-(Di-tert-butyl-phosphanyl)-2,2-dimethyl-1,2,3,4-tetrahydro-quinoline

Conditions
ConditionsYield
99%
indole
120-72-9

indole

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

1-(di-tert-butylphosphino)-1H-indole

1-(di-tert-butylphosphino)-1H-indole

Conditions
ConditionsYield
Stage #1: indole With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 0.25h; Inert atmosphere;
Stage #2: di(tert-butyl)chlorophosphine In tetrahydrofuran; hexane at 0 - 20℃; Inert atmosphere;
99%
Stage #1: indole With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 0.25h; Schlenk technique; Inert atmosphere; Sealed tube;
Stage #2: di(tert-butyl)chlorophosphine In tetrahydrofuran; hexane at 0 - 20℃; Schlenk technique; Inert atmosphere; Sealed tube;
99%
Stage #1: indole With n-butyllithium In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere; Schlenk technique;
Stage #2: di(tert-butyl)chlorophosphine In tetrahydrofuran at 0 - 25℃; for 12h;
95%
With n-butyllithium In tetrahydrofuran; hexane at 0 - 20℃;
Stage #1: indole With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube;
Stage #2: di(tert-butyl)chlorophosphine In tetrahydrofuran; hexane at 0 - 20℃; Inert atmosphere; Schlenk technique; Sealed tube;
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

P,P-bis(1,1-dimethylethyl)phosphinoselenoic chloride
882000-55-7

P,P-bis(1,1-dimethylethyl)phosphinoselenoic chloride

Conditions
ConditionsYield
With selenium In toluene for 0.25h; Heating;99%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

(8S)-8-hydroxy-5,6,7,8-tetrahydroquinoline
451466-79-8

(8S)-8-hydroxy-5,6,7,8-tetrahydroquinoline

(S)-5,6,7,8-tetrahydroquinolin-8-yl di-tert-butylphosphinite
912277-33-9

(S)-5,6,7,8-tetrahydroquinolin-8-yl di-tert-butylphosphinite

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran; N,N-dimethyl-formamide at 0 - 20℃; for 96h;99%
2,5-(Ph2P=NTMS)2thiophene

2,5-(Ph2P=NTMS)2thiophene

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

2,5-(Ph2P=NP(Bu-t)2)2thiophene

2,5-(Ph2P=NP(Bu-t)2)2thiophene

Conditions
ConditionsYield
In toluene for 25h; Heating / reflux; Under Ar or N2;99%
lithium aluminium tetrahydride
16853-85-3

lithium aluminium tetrahydride

borane-THF
14044-65-6

borane-THF

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

di-tert-butylphosphine borane
128363-76-8

di-tert-butylphosphine borane

Conditions
ConditionsYield
In tetrahydrofuran for 60h; Cooling with ice; Schlenk technique;99%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

3,5-dihydroxy-N,N-(dimethylamino)benzene
40248-00-8

3,5-dihydroxy-N,N-(dimethylamino)benzene

C24H45NO2P2

C24H45NO2P2

Conditions
ConditionsYield
With sodium hydride Inert atmosphere;99%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

5-diethylene glycol monomethyl ether resorcinol

5-diethylene glycol monomethyl ether resorcinol

C27H50O5P2

C27H50O5P2

Conditions
ConditionsYield
With sodium hydride Inert atmosphere;99%
gallium(III) trichloride

gallium(III) trichloride

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

t-Bu2PCl(GaCl3)
126047-05-0

t-Bu2PCl(GaCl3)

Conditions
ConditionsYield
In dichloromethane at -30 - 20℃; for 0.25h; Inert atmosphere;99%
In dichloromethane at -35℃; for 0.25h; Inert atmosphere;99%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

3,5-dimethylaminoaniline
108-69-0

3,5-dimethylaminoaniline

1,1-di-tert-butyl-N-(3,5-dimethylphenyl)phosphanamine

1,1-di-tert-butyl-N-(3,5-dimethylphenyl)phosphanamine

Conditions
ConditionsYield
Stage #1: 3,5-dimethylaminoaniline With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: di(tert-butyl)chlorophosphine In tetrahydrofuran; hexane at -78 - 20℃; for 18h; Schlenk technique; Inert atmosphere;
99%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

palladium
7440-05-3

palladium

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

bis(di-tert-butylphenylphosphine)palladium(II) dichloride
34409-44-4

bis(di-tert-butylphenylphosphine)palladium(II) dichloride

Conditions
ConditionsYield
Stage #1: palladium With hydrogenchloride; nitric acid; cyclo-octa-1,5-diene In ethanol; water at 50℃;
Stage #2: di(tert-butyl)chlorophosphine; phenylmagnesium bromide In tetrahydrofuran; ethanol; water at 50 - 70℃; Temperature;
98.8%
C6H5B(OH)2

C6H5B(OH)2

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

2-Chloroanisole
766-51-8

2-Chloroanisole

2-methoxy-1,1'-biphenyl
86-26-0

2-methoxy-1,1'-biphenyl

Conditions
ConditionsYield
With cesium fluoride; palladium diacetate In 1,4-dioxane; dichloromethane; water98%
ferrocene
102-54-5

ferrocene

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

(ferrocenyl)di(tert-butyl)phosphine
223655-16-1

(ferrocenyl)di(tert-butyl)phosphine

Conditions
ConditionsYield
With aluminum (III) chloride In hexane at 0℃; for 3h; Temperature; Inert atmosphere;98%
Stage #1: ferrocene With potassium tert-butylate; tert.-butyl lithium In diethyl ether at -78 - -70℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: di(tert-butyl)chlorophosphine In diethyl ether at 0℃; Inert atmosphere; Schlenk technique;
71%
With tert.-butyl lithium In not given addn. of excess chlorophosphine to lithioferrocene (prepd. from t-BuLi and ferrocene); repeated sublimation (85°C, 0.01 mmHg); elem. anal.;27%
Stage #1: ferrocene With potassium tert-butylate; tert.-butyl lithium In tetrahydrofuran; pentane at -73 - 0℃; Inert atmosphere;
Stage #2: di(tert-butyl)chlorophosphine In tetrahydrofuran; pentane at 0 - 20℃; for 12h; Inert atmosphere;
Li(1+)*{(C5H5)2NbH2}(1-)=Li{(C5H5)2NbH2}

Li(1+)*{(C5H5)2NbH2}(1-)=Li{(C5H5)2NbH2}

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

(C5H5)2NbH(PH(C(CH3)3)2)
201869-99-0

(C5H5)2NbH(PH(C(CH3)3)2)

Conditions
ConditionsYield
In tetrahydrofuran byproducts: LiCl; absence of air and moisture; stirring Nb-complex soln. with phosphine (-78°C, 15 min), warming to room temp.; decantation, drying (vac.), extn. into ether, filtration, solvent removal; elem. anal.;98%
propan-1-ol
71-23-8

propan-1-ol

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

propyl di-tert-butylphosphinite

propyl di-tert-butylphosphinite

Conditions
ConditionsYield
Stage #1: propan-1-ol; di(tert-butyl)chlorophosphine With sodium In diethyl ether at 20℃; for 16h; Inert atmosphere;
Stage #2: With water In diethyl ether Inert atmosphere;
98%
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20℃; for 5h; Schlenk technique; Inert atmosphere;96%
propylamine
107-10-8

propylamine

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

propyl di-tert-butylphosphinite

propyl di-tert-butylphosphinite

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 0 - 20℃; for 36h; Inert atmosphere;98%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

Trimethylenediamine
109-76-2

Trimethylenediamine

CH2(CH2NHPtBu2)2

CH2(CH2NHPtBu2)2

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran Inert atmosphere;97%
In toluene Heating;
(R)-5H,6H,7H-cyclopenta[b]pyridin-7-ol
912277-45-3

(R)-5H,6H,7H-cyclopenta[b]pyridin-7-ol

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

(R)-6,7-dihydro-5H-[1]pyrindin-7-yl di-tert-butylphosphinite
912277-29-3

(R)-6,7-dihydro-5H-[1]pyrindin-7-yl di-tert-butylphosphinite

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran; N,N-dimethyl-formamide at 0 - 20℃; for 39h;97%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

(E)-6-(1-((2,6-dimethylphenyl)imino)ethyl)pyridin-2(1H)-one
1510817-50-1

(E)-6-(1-((2,6-dimethylphenyl)imino)ethyl)pyridin-2(1H)-one

(E)-N-(1-(6-((di-tert-butylphosphino)oxy)-pyridin-2-yl)ethylidene)-2,6-dimethylaniline
1510817-54-5

(E)-N-(1-(6-((di-tert-butylphosphino)oxy)-pyridin-2-yl)ethylidene)-2,6-dimethylaniline

Conditions
ConditionsYield
Stage #1: (E)-6-(1-((2,6-dimethylphenyl)imino)ethyl)pyridin-2(1H)-one With sodium hydride In tetrahydrofuran at 20℃; for 0.166667h; Inert atmosphere; Schlenk technique;
Stage #2: di(tert-butyl)chlorophosphine In tetrahydrofuran for 3h; Inert atmosphere; Schlenk technique;
97%
6-methyl-2-phenylpyridine
46181-30-0

6-methyl-2-phenylpyridine

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

2-((di-tert-butylphosphino)methyl)-6-phenylpyridine

2-((di-tert-butylphosphino)methyl)-6-phenylpyridine

Conditions
ConditionsYield
Stage #1: 6-methyl-2-phenylpyridine With tert.-butyl lithium In tetrahydrofuran; pentane at -78℃; for 2h; Inert atmosphere; Schlenk technique;
Stage #2: di(tert-butyl)chlorophosphine In tetrahydrofuran; pentane at -78 - 20℃; Inert atmosphere; Schlenk technique;
97%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

C19H17N5

C19H17N5

C27H34N5P

C27H34N5P

Conditions
ConditionsYield
Stage #1: C19H17N5 With n-butyllithium In tetrahydrofuran at -80 - 0℃; for 1h; Inert atmosphere;
Stage #2: di(tert-butyl)chlorophosphine at -80 - 20℃; Inert atmosphere;
96.36%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

methyllithium
917-54-4

methyllithium

methyldi-t-butylphosphine
6002-40-0

methyldi-t-butylphosphine

Conditions
ConditionsYield
In diethyl ether; pentane at -78 - 20℃;96%
In pentane 1) - 80 deg C, 2) -20 to 20 deg C, 15 min, 3) 20 deg C, 30 min;87%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

benzyl(di-tert-butyl)phosphane
27286-19-7

benzyl(di-tert-butyl)phosphane

Conditions
ConditionsYield
Stage #1: di(tert-butyl)chlorophosphine; benzylmagnesium chloride In tetrahydrofuran for 48h; Heating / reflux;
Stage #2: With water; ammonium chloride In tetrahydrofuran at 20℃;
96%
In tetrahydrofuran for 48h; Heating / reflux;96%
Stage #1: di(tert-butyl)chlorophosphine; benzylmagnesium chloride In tetrahydrofuran for 48h; Heating / reflux;
Stage #2: With ammonium chloride In tetrahydrofuran; water at 20℃;
96%
copper(ll) bromide In tetrahydrofuran at 40 - 45℃; for 4h;88.3%
1H-imidazole
288-32-4

1H-imidazole

di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

1-(di-tert-butylphosphino)imidazole
1416734-56-9

1-(di-tert-butylphosphino)imidazole

Conditions
ConditionsYield
With triethylamine In diethyl ether at 20℃; for 24h; Inert atmosphere; Schlenk technique;96%
With triethylamine In diethyl ether at 20℃; Inert atmosphere;95%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

2'-bromo-1,1':3',1'-terphenyl

2'-bromo-1,1':3',1'-terphenyl

2,6-diphenyl-1-(di-t-butylphosphino)benzene

2,6-diphenyl-1-(di-t-butylphosphino)benzene

Conditions
ConditionsYield
Stage #1: 2'-bromo-1,1':3',1'-terphenyl With magnesium In tetrahydrofuran for 4h; Inert atmosphere; Reflux;
Stage #2: di(tert-butyl)chlorophosphine With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; for 6h; Reflux; Inert atmosphere;
96%
di(tert-butyl)chlorophosphine
13716-10-4

di(tert-butyl)chlorophosphine

3-methyl-4-bromo-N,N-dimethylaniline
50638-50-1

3-methyl-4-bromo-N,N-dimethylaniline

2-methyl-4-(N,N-dimethylamino)-1-di-tert-butylphosphinobenzene

2-methyl-4-(N,N-dimethylamino)-1-di-tert-butylphosphinobenzene

Conditions
ConditionsYield
Stage #1: 3-methyl-4-bromo-N,N-dimethylaniline With magnesium In tetrahydrofuran for 2h; Inert atmosphere; Reflux;
Stage #2: di(tert-butyl)chlorophosphine With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; for 6h; Reflux; Inert atmosphere;
96%

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