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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesis.

manufacturer of 4-Chlorophenylboronic acid

Cas:1679-18-1

Min.Order:100 Gram

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem supply this product at best price in China, We had exported chemicals to many countries and regions. If you are looking for the product’s supplier in China, Dayangchem is your best choice. Pls contact with us freely for getting d

4-Chlorophenylboronic acid supplier in China CAS NO.1679-18-1

Cas:1679-18-1

Min.Order:100 Gram

FOB Price: $50.0 / 100.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

4-Chlorophenylboronic acid

Cas:1679-18-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/62.html Product Name 4-Chlorophenylboronic acid CAS No. 1679-18-1

4-Chlorophenylboronic acid

Cas:1679-18-1

Min.Order:1 Gram

FOB Price: $5.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Chlorophenylboronic Acid supplier in China

Cas:1679-18-1

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

High quality 4-Chlorophenylboronic acid CAS 1679-18-1 with factory price Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/F

High quality 4-Chlorophenylboronic acid CAS 1679-18-1 with factory price

Cas:1679-18-1

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Hangzhou Think Chemical Co. Ltd

4-Chlorophenylboronic acid CAS No.:1679-18-1 Name: 4-Chlorophenylboronic acid Molecular Structure Molecular Formula: C

High purity 4-Chlorophenylboronic acid CAS No.:1679-18-1

Cas:1679-18-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

4-Chlorophenylboronic acid

Cas:1679-18-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply (p-chlorophenyl)metaboric acid

Cas:1679-18-1

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 1679-18-1 4-chlorophenylboronicacid Manufacturer

Cas:1679-18-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis 1. Beijing High-Tech Enterprises 2. Strong R&D Team 3. 8 years of experiences in R & D of high-tech Catalyst; 4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sal

4-Chlorophenylboronic acid

Cas:1679-18-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Chlorobenzeneboronic acid

Cas:1679-18-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

4-Chlorophenylboronic acid

Cas:1679-18-1

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Product Name: 4-Chlorophenylboronic acid Synonyms: 4-Chlorophenylbronic Acid;4-Chlorophenylboronic acid 95%;The effects of boric acid;AC 34441;Benzeneboronic acid, p-chloro-;WLN: QBQR DG;B-(4-Chlorophenyl)boronic acid;BORONIC ACID, (4-CHLOROPHENYL

4-Chlorophenylboronic acid 1679-18-1

Cas:1679-18-1

Min.Order:1 Kilogram

FOB Price: $500.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

4-Chlorophenylboronic acid

Cas:1679-18-1

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 1679-18-1 with competitive price

Cas:1679-18-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS1679-18-1 4-Chlorophenylboronic acid

Cas:1679-18-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name 4-Chlorophenylboronic acid Synonyms 4-Chlorophenylboronic acid;4-Chlorophenylboronic acid CAS: 1679-18-1 MF: C6H6BClO2 MW: -

4-Chlorophenylboronic Acid 1679-18-1

Cas:1679-18-1

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

Our Adwantage: 1.We have stock so we can delivery quickly at the very day when receive the payment. 2.Best price, first class service, high successful delivery rate. A discount would be given when you make a large order. 3.High quality gua

4-Chlorophenylboronic acid CAS 1679-18-1 Intermediates C6H6BClO2

Cas:1679-18-1

Min.Order:10 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

4-Chlorophenylboronic acid 1679-18-1

Cas:1679-18-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Melting point 284-289 °C(lit.) Boiling point 295.4±42.0 °C(Predicted) density 1.32±0.1 g/cm3(Predicted) storage temp. Refrigerator (+4°C) pka 8.39±0.10(Predicted) form Crystalline Powder color

4-Chlorophenylboronic acid

Cas:1679-18-1

Min.Order:100 Kilogram

FOB Price: $66.0

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Agrochemical Intermediates, 4-Chlorophenylboronic acid CAS:1679-18-1

Cas:1679-18-1

Min.Order:1 Kilogram

FOB Price: $19.4 / 24.8

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

4-Chlorophenylboronic acid CAS:1679-18-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

4-Chlorophenylboronic acid CAS:1679-18-1

Cas:1679-18-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

4-Chlorophenylboronic acid

Cas:1679-18-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

4-Chlorophenylboronic acid/ LIDE PHARMA- Factory supply / Best price

Cas:1679-18-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,

4-Chlorophenylboronic acid supplier in China CAS NO.1679-18-1

Cas:1679-18-1

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Lonwin Chemical Group Limited

4-Chlorophenylboronic Acid 1679-18-1 CAS: 1679-18-1 Specification Item Specification Specific rotation +39.5 to +41.5° State of solution(transmittance) Clear 98

Factory supply 4-Chlorophenylboronic Acid 1679-18-1

Cas:1679-18-1

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Chlorophenylboronic acid

Cas:1679-18-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Leader Biochemical Group

PRODUCT DETAILS 4-Chlorophenylboronic aci

China Largest Factory Manufacturer sales 4-Chlorophenylboronic acid CAS 1679-18-1

Cas:1679-18-1

Min.Order:500 Kilogram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

4-Chlorophenylboronic acid

Cas:1679-18-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

4-chlorophenyl trifluoromethanesulfonate
29540-84-9

4-chlorophenyl trifluoromethanesulfonate

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-chlorophenyl trifluoromethanesulfonate With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; diisopropopylaminoborane; triethylamine; triphenylphosphine In tetrahydrofuran at 65℃; for 12h; Alcaraz-Vaultier borylation; Inert atmosphere;
Stage #2: With methanol In tetrahydrofuran at 0℃; Inert atmosphere; Further stages;
97%
para-dichlorobenzene
106-46-7

para-dichlorobenzene

Trimethyl borate
121-43-7

Trimethyl borate

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: para-dichlorobenzene With iodine; magnesium In tetrahydrofuran; toluene at 60 - 65℃; for 2h; Grignard Reaction; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran; toluene at -20 - -15℃; for 2h; Solvent; Reagent/catalyst; Temperature;
96.2%
para-dichlorobenzene
106-46-7

para-dichlorobenzene

boric acid tributyl ester
688-74-4

boric acid tributyl ester

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: para-dichlorobenzene With iodine; magnesium In tetrahydrofuran; toluene at 60 - 65℃; for 0.5h; Grignard Reaction; Inert atmosphere;
Stage #2: boric acid tributyl ester In tetrahydrofuran; toluene at -20 - -15℃; for 2h;
95.1%
bromochlorobenzene
106-39-8

bromochlorobenzene

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: bromochlorobenzene With n-butyllithium In tetrahydrofuran; hexane Inert atmosphere;
Stage #2: With Trimethyl borate In tetrahydrofuran; hexane Inert atmosphere;
90%
Stage #1: bromochlorobenzene With diisobutylaluminium hydride; magnesium; lithium chloride In tetrahydrofuran; toluene at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: With Trimethyl borate In tetrahydrofuran; toluene at 0℃; Inert atmosphere;
Stage #3: With hydrogenchloride; water In tetrahydrofuran; toluene at 0℃; Inert atmosphere;
81%
Stage #1: bromochlorobenzene With tert.-butyl lithium In tetrahydrofuran at -78℃;
Stage #2: With Trimethyl borate In tetrahydrofuran at -78 - 20℃; Further stages.;
74%
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

1-Chloro-4-iodobenzene
637-87-6

1-Chloro-4-iodobenzene

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
In methanol at 15℃; for 3h; Microwave irradiation;87%
With bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II); tetramethyl ammonium acetate In 2-methyltetrahydrofuran; methanol; water at 40℃; for 6h; Schlenk technique; Inert atmosphere;67%
With bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II); N-ethyl-N,N-diisopropylamine In 2-methyltetrahydrofuran; methanol at 50 - 55℃; Inert atmosphere;85 %Chromat.
With [{Pd(μ-Cl){κ2-P,C-P(iPr)2(OC6H3-2-Ph)}}2]; sodium acetate In dichloromethane; water at 40℃; for 6h; Inert atmosphere;
water
7732-18-5

water

boron trichloride
10294-34-5

boron trichloride

chlorobenzene
108-90-7

chlorobenzene

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: boron trichloride; chlorobenzene With aluminum (III) chloride at 110℃; for 10h; Inert atmosphere;
Stage #2: water at 0 - 5℃; pH=1 - 2; Temperature;
86.6%
water
7732-18-5

water

potassium (4-chlorophenyl)trifluoroborate

potassium (4-chlorophenyl)trifluoroborate

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
With 1H-imidazole; iron(III) chloride at 20℃; for 0.25h; Inert atmosphere;85%
methanol
67-56-1

methanol

bromochlorobenzene
106-39-8

bromochlorobenzene

diisopropylamine borane
55124-35-1

diisopropylamine borane

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: diisopropylamine borane With magnesium; phenylmagnesium bromide In tetrahydrofuran at 20℃; for 0.166667h;
Stage #2: bromochlorobenzene In tetrahydrofuran at 70℃;
Stage #3: methanol Further stages;
84%
borane
13283-31-3

borane

(4-chlorphenyl)magnesium bromide
873-77-8

(4-chlorphenyl)magnesium bromide

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
With water In tetrahydrofuran slow addn. of 10 mmol of the Grignard reagent to a stirred soln. of borane in THF (40 mmol); the mixt. was poured into ice-water and acidified with 10% HCl;; extn. into ether three-times; the combined extracts were dried over NaSO4; removal of solvent under reduced pressure; trituration with petroleum ether; recrystn. from H2O;;81%
bromochlorobenzene
106-39-8

bromochlorobenzene

tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
In methanol at 15℃; for 4h; Microwave irradiation;78%
With bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II); N-ethyl-N,N-diisopropylamine In 2-methyltetrahydrofuran; methanol at 50 - 55℃; Inert atmosphere;78 %Chromat.
4-chloro-aniline
106-47-8

4-chloro-aniline

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-chloro-aniline With hydrogenchloride; sodium nitrite In methanol; water at 0 - 5℃; for 0.5h;
Stage #2: With tetrahydroxydiboron In methanol; water at 20℃; for 1h;
73%
Multi-step reaction with 2 steps
1.1: water / 0.03 h / 20 °C
1.2: 0.25 h / 0 °C
2.1: N,N-dimethyl-formamide / 0.25 h / 20 °C
View Scheme
bromochlorobenzene
106-39-8

bromochlorobenzene

tri-n-propyl borate
688-71-1

tri-n-propyl borate

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: bromochlorobenzene With iodine; magnesium In tetrahydrofuran for 2h; Inert atmosphere; Reflux;
Stage #2: tri-n-propyl borate In tetrahydrofuran at -78 - 20℃; Inert atmosphere;
Stage #3: With hydrogenchloride In water
63%
potassium (4-chlorophenyl)trifluoroborate

potassium (4-chlorophenyl)trifluoroborate

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
With water; silica gel at 20℃; for 1h; Inert atmosphere;60%
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

p-chlorobenzenediazonium tetrafluoroborate
673-41-6

p-chlorobenzenediazonium tetrafluoroborate

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; for 0.25h;60%
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

4-chloro-aniline
106-47-8

4-chloro-aniline

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: 4-chloro-aniline With hydrogenchloride; sodium nitrite In water at 0℃; for 0.25h;
Stage #2: tetrahydroxydiboron With sodium acetate In water at 20℃; for 0.333333h;
53%
Stage #1: 4-chloro-aniline With hydrogenchloride; sodium nitrite In water at 0℃; for 0.25h;
Stage #2: tetrahydroxydiboron With potassium carbonate In water at 20℃; for 0.333333h;
bromochlorobenzene
106-39-8

bromochlorobenzene

Triisopropyl borate
5419-55-6

Triisopropyl borate

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
Stage #1: bromochlorobenzene With n-butyllithium In tetrahydrofuran; hexane at -78 - -10℃;
Stage #2: Triisopropyl borate In tetrahydrofuran; hexane at -78 - 20℃;
34%
di-(p-chlorophenyl)borinic acid
89566-59-6

di-(p-chlorophenyl)borinic acid

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
With water; bromine
With water; chlorine
(4-chlorphenyl)magnesium bromide
873-77-8

(4-chlorphenyl)magnesium bromide

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
With diethyl ether; boron trifluoride Zersetzen des Reaktionsprodukts mit Salzsaeure und nachfolgendes Einleiten von Wasserdampf in das entstehendene 4-Chlor-phenylbordifluorid;
1-Chloro-4-iodobenzene
637-87-6

1-Chloro-4-iodobenzene

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
(i) (UV-irradiation), BBr3, (ii) aq. NaOH; Multistep reaction;
tris(4-chlorophenyl)boroxine
7519-91-7

tris(4-chlorophenyl)boroxine

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
With water In chloroform-d1 at 25℃; Equilibrium constant; Thermodynamic data;
bromochlorobenzene
106-39-8

bromochlorobenzene

borane
13283-31-3

borane

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
With water; magnesium In tetrahydrofuran a 2.0 M soln. of borane (40 mmol) in THF was added to flame dried Mg turnings (12 mmol) at 0°C; slow addn. of the aryl bromide (10 mmol)in THF; stirring at room temp. for 12-16 h; the mixt. was poured into ice-water and acidified with 10% HCl;; extn. into ether three-times; the combined extracts were dried over NaSO4; removal of solvent under reduced pressure; trituration with petroleum ether; recrystn. from H2O;;
boron trifluoride
7637-07-2

boron trifluoride

(4-chlorphenyl)magnesium bromide
873-77-8

(4-chlorphenyl)magnesium bromide

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
With H2=
With H2=
borane
13283-31-3

borane

tetra(p-chlorophenyl)tin
15799-48-1

tetra(p-chlorophenyl)tin

ethanolamine
141-43-5

ethanolamine

A

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

B

di(p-chlorophenyl)borinic acid ethanolamine complex

di(p-chlorophenyl)borinic acid ethanolamine complex

Conditions
ConditionsYield
With water In tetrahydrofuran; diethyl ether; ethanol to THF soln. of Sn compd. added BH3 (N2, room temp.),refluxed (1 h), added H2O,stirred (30 min),extd. (Et2O), dried (MgSO4),evapd. in vac.,heated with pentane,filtered ArB(OH)2,filtrate evapd.,added Et2O,EtOH soln. of HOCH2CH2NH2 added,refluxed (30 min); filtered hot, complex pptd. by cooling, filtered; ArB(OH)2 recrystd. from H2O; compds. identified by m. p., IR, NMR;
Trimethyl borate
121-43-7

Trimethyl borate

(4-chlorphenyl)magnesium bromide
873-77-8

(4-chlorphenyl)magnesium bromide

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
In tetrahydrofuran dropwise addn. of p-ClC6H4MgBr to borane at -70°C; stirred below -60°C for 1 h; hydrolyzed (sulfuric acid); filtration; sepn. of org. layer; extn. of aq. layer (ether); combined org. layer washed (H2O); dried (Na2SO4); concn. of soln.; crystn.; washed (hexane, H2O); IR; NMR; mass spectra;
1,2-bis(p-chlorophenyl)diborane(6)
120208-73-3

1,2-bis(p-chlorophenyl)diborane(6)

water
7732-18-5

water

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

1,2-bis(p-chlorophenyl)diborane(6)
120208-73-3

1,2-bis(p-chlorophenyl)diborane(6)

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
hydrolysis;;
hydrolysis;;
2-(4-chlorophenyloxy)-2-(4-chlorophenyl)-5-methyl-3,3-tetramethylen-1-oxa-3-azonia-2-boratacyclopentane
95890-68-9

2-(4-chlorophenyloxy)-2-(4-chlorophenyl)-5-methyl-3,3-tetramethylen-1-oxa-3-azonia-2-boratacyclopentane

A

2-monochlorophenol
95-57-8

2-monochlorophenol

B

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
With water In methanol; water byproducts: 4-chlorophenol, 1-pyrrilidino-2-propanol; borate was suspended in boiling water, dild. with methanol until dissolution of the ppt.; cooled, mixt. was analyzed by TLC (SiO2, dioxane-benzene-AcOH);A 0%
B n/a
4-chlorophenylboronic dimethyl ester

4-chlorophenylboronic dimethyl ester

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
With sodium hydrogencarbonate at 20℃; pH=6.5;
With hydrogenchloride; water Inert atmosphere;2.07 g
With hydrogenchloride In water at 20℃; Inert atmosphere; Schlenk technique;
bromochlorobenzene
106-39-8

bromochlorobenzene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Conditions
ConditionsYield
With Co(1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene)2Cl2; potassium methanolate In tert-butyl methyl ether at 70℃; for 8h;62 %Spectr.
4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

(7-bromo-2,3-dimethoxy-quinoxalin-5-ylmethyl)-phosphonic acid diethyl ester
187479-58-9

(7-bromo-2,3-dimethoxy-quinoxalin-5-ylmethyl)-phosphonic acid diethyl ester

[7-(4-chloro-phenyl)-2,3-dimethoxy-quinoxalin-5-ylmethyl]-phosphonic acid diethyl ester

[7-(4-chloro-phenyl)-2,3-dimethoxy-quinoxalin-5-ylmethyl]-phosphonic acid diethyl ester

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane for 24h; Suzuki cpupling; Heating;100%
4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

methyl vinyl ketone
78-94-4

methyl vinyl ketone

4-(4-chlorophenyl)butan-2-one
3506-75-0

4-(4-chlorophenyl)butan-2-one

Conditions
ConditionsYield
With potassium phosphate; chloro(1,5-cyclooctadiene)rhodium(I) dimer In 1,4-dioxane; water at 60℃; Glovebox;100%
With cyclo-octa-1,5-diene In methanol at 65℃; for 8h; Inert atmosphere;89%
polystyrene In water at 25℃; for 24h; Michael reaction;79%
iodobenzene
591-50-4

iodobenzene

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

4'-biphenyl chloride
2051-62-9

4'-biphenyl chloride

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; potassium carbonate; palladium diacetate In acetone at 110℃; for 2h; Suzuki-Miyaura cross-coupling reaction;100%
With potassium carbonate In ethanol at 80℃; for 12h; Reagent/catalyst; Suzuki-Miyaura Coupling;100%
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;99%
4-bromobenzenecarbonitrile
623-00-7

4-bromobenzenecarbonitrile

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

4-(4'-chlorophenyl)benzonitrile
57774-36-4

4-(4'-chlorophenyl)benzonitrile

Conditions
ConditionsYield
With [(PdCl2)Fe{C5H4P-(OC6H3(OMe-o)(C3H5-p))2}2]; potassium carbonate In methanol at 60℃; for 3.5h; Catalytic behavior; Inert atmosphere; Schlenk technique;100%
Stage #1: 4-bromobenzenecarbonitrile In N,N-dimethyl-formamide at 90℃; for 0.833333h; Microwave irradiation;
Stage #2: 4-Chlorophenylboronic acid With potassium carbonate In N,N-dimethyl-formamide at 102℃; for 1h; Suzuki-Miyaura Coupling; Microwave irradiation;
99%
With dichloro bis(acetonitrile) palladium(II); C95H120N20O10(10+)*10F6P(1-); potassium carbonate In ethanol at 50℃; for 1.5h; Suzuki-Miyaura Coupling;96%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

2-(4-chlorophenyl)pyridine
5969-83-5

2-(4-chlorophenyl)pyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 18h; Inert atmosphere; Reflux;100%
With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate In 1,4-dioxane; water at 120℃; Inert atmosphere;99%
With sodium phosphate; palladium on activated charcoal In isopropyl alcohol at 80℃; for 24h; Suzuki-Miyaura coupling reaction;95%
4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

4-chlorobenzonitrile
100-00-5

4-chlorobenzonitrile

4-(4-nitrophenyl)chlorobenzene
6242-97-3

4-(4-nitrophenyl)chlorobenzene

Conditions
ConditionsYield
With potassium carbonate; Pd(OAc)2*(1,1,3,3-tetramethyl-2-n-butylguanidine)2 In ethanol; water at 20℃; for 20h; Suzuki cross-coupling;100%
With C20H16Cl2N2Pd; potassium carbonate In N,N-dimethyl-formamide at 100℃; for 6h; Suzuki-Miyaura Coupling;91%
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 5h; Catalytic behavior; Suzuki-Miyaura Coupling;89%
(S)-2-((5-bromopyridin-3-yloxy)methyl)pyrrolidine-1-carboxylic acid tert-butyl ester
191162-30-8

(S)-2-((5-bromopyridin-3-yloxy)methyl)pyrrolidine-1-carboxylic acid tert-butyl ester

Pd(0)

Pd(0)

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

5-(4-chlorophenyl)-3-(2-(R)-pyrrolidinylmethoxy)pyridine

5-(4-chlorophenyl)-3-(2-(R)-pyrrolidinylmethoxy)pyridine

Conditions
ConditionsYield
With sodium carbonate In toluene100%
(S)-2-((5-bromopyridin-3-yloxy)methyl)pyrrolidine-1-carboxylic acid tert-butyl ester
191162-30-8

(S)-2-((5-bromopyridin-3-yloxy)methyl)pyrrolidine-1-carboxylic acid tert-butyl ester

Pd(0)

Pd(0)

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

3-(1-BOC-2-(R)-Pyrrolidinylmethoxy)-5-(4-chlorophenyl)pyridine
299893-21-3

3-(1-BOC-2-(R)-Pyrrolidinylmethoxy)-5-(4-chlorophenyl)pyridine

Conditions
ConditionsYield
With sodium carbonate In toluene100%
(S)-2-((5-bromopyridin-3-yloxy)methyl)pyrrolidine-1-carboxylic acid tert-butyl ester
191162-30-8

(S)-2-((5-bromopyridin-3-yloxy)methyl)pyrrolidine-1-carboxylic acid tert-butyl ester

Pd(0)

Pd(0)

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

sodium carbonate
497-19-8

sodium carbonate

5-(4-chlorophenyl)-3-(2-(R)-pyrrolidinylmethoxy)pyridine

5-(4-chlorophenyl)-3-(2-(R)-pyrrolidinylmethoxy)pyridine

Conditions
ConditionsYield
In toluene100%
In toluene100%
(S)-2-((5-bromopyridin-3-yloxy)methyl)pyrrolidine-1-carboxylic acid tert-butyl ester
191162-30-8

(S)-2-((5-bromopyridin-3-yloxy)methyl)pyrrolidine-1-carboxylic acid tert-butyl ester

Pd(0)

Pd(0)

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

sodium carbonate
497-19-8

sodium carbonate

3-(1-BOC-2-(R)-Pyrrolidinylmethoxy)-5-(4-chlorophenyl)pyridine
299893-21-3

3-(1-BOC-2-(R)-Pyrrolidinylmethoxy)-5-(4-chlorophenyl)pyridine

Conditions
ConditionsYield
In toluene100%
2-(5-amino-2-oxobenzo[d]oxazol-3(2H)-yl)-N-methyl-N-phenylacetamide

2-(5-amino-2-oxobenzo[d]oxazol-3(2H)-yl)-N-methyl-N-phenylacetamide

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

2-[5-[(4-chlorophenyl)amino]-2-oxo-1,3-benzoxazol-3(2H)-yl]-N-methyl-N-phenylacetamide

2-[5-[(4-chlorophenyl)amino]-2-oxo-1,3-benzoxazol-3(2H)-yl]-N-methyl-N-phenylacetamide

Conditions
ConditionsYield
With triethylamine; copper diacetate In dichloromethane at 20 - 25℃; for 15h;100%
3-Bromopyridine
626-55-1

3-Bromopyridine

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

4-(3'-pyridinyl)-1-chlorobenzene
5957-97-1

4-(3'-pyridinyl)-1-chlorobenzene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 75℃; for 24h; Inert atmosphere; Reflux;100%
With potassium carbonate In isopropyl alcohol at 85 - 90℃; for 24h; Suzuki-Miyaura Coupling;94%
With potassium phosphate tribasic heptahydrate; C18H24N3O2Pd In ethanol; water at 60℃; for 4h; Suzuki-Miyaura Coupling;88%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 24h; Suzuki-Miyaura coupling; Inert atmosphere; Reflux;86%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene
4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

4,4'-dithiobis [5-amino-3-cyano-1-{2,6-dichloro-4-(trifluoromethyl)phenyl}-1H-pyrazole]
130755-46-3

4,4'-dithiobis [5-amino-3-cyano-1-{2,6-dichloro-4-(trifluoromethyl)phenyl}-1H-pyrazole]

5-amino-4-[(4-chlorophenyl)thio]-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-1H-pyrazole-3-carbonitrile
1158997-68-2

5-amino-4-[(4-chlorophenyl)thio]-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-1H-pyrazole-3-carbonitrile

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; oxygen In water; dimethyl sulfoxide at 100℃; for 24h;100%
(2-nitroethenyl)benzene
102-96-5

(2-nitroethenyl)benzene

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

(R)-1-chloro-4-(2-nitro-1-phenylethyl)benzene
1245819-33-3

(R)-1-chloro-4-(2-nitro-1-phenylethyl)benzene

Conditions
ConditionsYield
With heterogeneous Rh/Ag bimetallic nanoparticle catalyst immobilized on chiral polymer In water; toluene at 100℃; for 24h; Inert atmosphere; enantioselective reaction;100%
With potassium hydrogen difluoride; C60H52Cl2Rh2 In water; toluene at 50℃; for 51h; Inert atmosphere; enantioselective reaction;94%
With chlorobis(ethylene)rhodium(I) dimer; potassium hydrogen bifluoride; C28H22 In water; toluene at 100℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction;92%
With chlorobis(ethylene)rhodium(I) dimer; C17H27NO In water; toluene at 100℃; for 16h; Reagent/catalyst; Inert atmosphere; enantioselective reaction;87 %Chromat.
6-chloro-4-iodo-5-(2,2,2-trifluoroethoxy)-2-pyridinemethanol
1364676-94-7

6-chloro-4-iodo-5-(2,2,2-trifluoroethoxy)-2-pyridinemethanol

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

6-chloro-4-(4-chlorophenyl)-5-(2,2,2-trifluoroethoxy)-2-pyridinemethanol
1364676-96-9

6-chloro-4-(4-chlorophenyl)-5-(2,2,2-trifluoroethoxy)-2-pyridinemethanol

Conditions
ConditionsYield
With sodium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In water; toluene at 90℃; for 1.5h; Inert atmosphere;100%
With sodium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In toluene at 90℃; for 1.5h; Inert atmosphere;100%
With sodium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In toluene at 90℃; for 1.5h; Inert atmosphere;100%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium carbonate In toluene at 90℃; for 1.5h; Inert atmosphere;100%
5-bromo-6-cyclobutyloxy-3-pyridinecarboxylic acid
1364678-46-5

5-bromo-6-cyclobutyloxy-3-pyridinecarboxylic acid

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

5-(4-chlorophenyl)-6-(cyclobutyloxy)-3-pyridinecarboxylic acid
1364678-51-2

5-(4-chlorophenyl)-6-(cyclobutyloxy)-3-pyridinecarboxylic acid

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; water at 100℃;100%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; ethanol; water at 85℃; for 3.5h; Inert atmosphere;89%
Stage #1: 5-bromo-6-cyclobutyloxy-3-pyridinecarboxylic acid; 4-Chlorophenylboronic acid With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; water at 100℃;
Stage #2: In water; ethyl acetate pH=2;
2-(3-bromophenyl)-N-methoxy-N-methylacetamide
866270-03-3

2-(3-bromophenyl)-N-methoxy-N-methylacetamide

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

2-(4'-chloro-3-biphenylyl)-N-methoxy-N-methylacetamide
1365177-17-8

2-(4'-chloro-3-biphenylyl)-N-methoxy-N-methylacetamide

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water at 90℃; for 5h; Inert atmosphere;100%
[4-bromo-6-chloro-5-(2,2,2-trifluoro-ethoxy)-pyridin-2-yl]-methanol
1382465-52-2

[4-bromo-6-chloro-5-(2,2,2-trifluoro-ethoxy)-pyridin-2-yl]-methanol

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

6-chloro-4-(4-chlorophenyl)-5-(2,2,2-trifluoroethoxy)-2-pyridinemethanol
1364676-96-9

6-chloro-4-(4-chlorophenyl)-5-(2,2,2-trifluoroethoxy)-2-pyridinemethanol

Conditions
ConditionsYield
With sodium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In toluene at 90℃; for 1.5h; Inert atmosphere;100%
N2-(5-bromo-2-methylphenyl)-N2-{2-[1,3-dihydro-2H-isoindol-2-yl(methyl)amino]-2-oxoethyl}-N1-{2-[(tert-butoxycarbonyl)(isopropyl)amino]ethyl}glycinamide

N2-(5-bromo-2-methylphenyl)-N2-{2-[1,3-dihydro-2H-isoindol-2-yl(methyl)amino]-2-oxoethyl}-N1-{2-[(tert-butoxycarbonyl)(isopropyl)amino]ethyl}glycinamide

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

N2-(4'-chloro-4-methylbiphenyl-3-yl)-N2-{2-[1,3-dihydro-2H-isoindol-2-yl(methyl)amino]-2-oxoethyl}-N1-{2-[(tert-butoxycarbonyl)(isopropyl)amino]ethyl}glycinamide
1190895-17-0

N2-(4'-chloro-4-methylbiphenyl-3-yl)-N2-{2-[1,3-dihydro-2H-isoindol-2-yl(methyl)amino]-2-oxoethyl}-N1-{2-[(tert-butoxycarbonyl)(isopropyl)amino]ethyl}glycinamide

Conditions
ConditionsYield
100%
(3-amino-2,6-difluoro-phenyl)-[5-bromo-1-(2,6-dichlorobenzoyl)pyrrolo[2,3-b]pyridin-3-yl]methanone

(3-amino-2,6-difluoro-phenyl)-[5-bromo-1-(2,6-dichlorobenzoyl)pyrrolo[2,3-b]pyridin-3-yl]methanone

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

(3-(3-amino-2,6-difluorobenzoyl)-5-(4-chlorophenyl)-1H-pyrrolo[2,3-b]pyridin-1-yl)(2,6-dichlorophenyl)methanone

(3-(3-amino-2,6-difluorobenzoyl)-5-(4-chlorophenyl)-1H-pyrrolo[2,3-b]pyridin-1-yl)(2,6-dichlorophenyl)methanone

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate In 2-methyltetrahydrofuran; water at 70 - 75℃; for 3h; Concentration; Temperature; Time; Inert atmosphere;100%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In 1,4-dioxane; water at 80 - 82℃; for 2h; Inert atmosphere;75%
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate In 2-methyltetrahydrofuran; water at 90℃; for 16h;
4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

4-chloro-aniline
106-47-8

4-chloro-aniline

bis(4-chlorophenyl)amine
6962-04-5

bis(4-chlorophenyl)amine

Conditions
ConditionsYield
With 2,6-dimethylpyridine; fac-tris(2-phenylpyridinato-N,C2')iridium(III); copper diacetate; n-tetradecanoic acid In toluene; acetonitrile at 35℃; for 20h; Reagent/catalyst; Chan-Lam Coupling; Irradiation;100%
With 2,6-dimethylpyridine; tetrabutylammonium perchlorate; copper diacetate; triethylamine In acetonitrile at 20℃; for 20h; Chan-Lam Coupling; Electrochemical reaction; chemoselective reaction;45%
With copper(II) acetate monohydrate Chan-Lam Coupling;
With C32H32Cl2Cu2N4O4; triethylamine In ethanol for 5h;93 %Chromat.
5-ethyl-3-iodo-2,5-dihydrofuran-2-one
1206522-04-4

5-ethyl-3-iodo-2,5-dihydrofuran-2-one

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

3-(4-chlorophenyl)-5-ethylfuran-2(5H)-one

3-(4-chlorophenyl)-5-ethylfuran-2(5H)-one

Conditions
ConditionsYield
With 1,1',1'',1'''-benzene-1,2,4,5-tetrayltetrakis(methylene)tetrakis-(piperidin-4-ol); palladium diacetate; potassium carbonate In ethanol; water at 20℃; for 0.25h; Suzuki-Miyaura Coupling;100%
4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

p-toluidine
106-49-0

p-toluidine

(4-chlorophenyl)(4-methylphenyl)amine
21648-16-8

(4-chlorophenyl)(4-methylphenyl)amine

Conditions
ConditionsYield
With 2,6-dimethylpyridine; fac-tris(2-phenylpyridinato-N,C2')iridium(III); copper diacetate; n-tetradecanoic acid In toluene; acetonitrile at 35℃; for 20h; Reagent/catalyst; Chan-Lam Coupling; Irradiation;100%
With 2,6-dimethylpyridine; tetrabutylammonium perchlorate; copper diacetate; triethylamine In acetonitrile at 20℃; for 20h; Chan-Lam Coupling; Electrochemical reaction; chemoselective reaction;97%
With C32H32Cl2Cu2N4O4; triethylamine In ethanol for 5h;94 %Chromat.
4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

o-toluidine
95-53-4

o-toluidine

N-(4-chlorophenyl)-2-methylaniline
113965-93-8

N-(4-chlorophenyl)-2-methylaniline

Conditions
ConditionsYield
With 2,6-dimethylpyridine; fac-tris(2-phenylpyridinato-N,C2')iridium(III); copper diacetate; n-tetradecanoic acid In toluene; acetonitrile at 35℃; for 20h; Reagent/catalyst; Chan-Lam Coupling; Irradiation;100%
With 2,6-dimethylpyridine; tetrabutylammonium perchlorate; copper diacetate; triethylamine In acetonitrile at 20℃; for 20h; Chan-Lam Coupling; Electrochemical reaction; chemoselective reaction;84%
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; copper; acetic acid In acetonitrile47%
4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

4-bromopyridine hydrobromide salt

4-bromopyridine hydrobromide salt

4-(4-chlorophenyl)pyridine
5957-96-0

4-(4-chlorophenyl)pyridine

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate In 1,4-dioxane; water at 110℃; for 16h; Inert atmosphere;100%
N-acetyl-2-bromoaniline
614-76-6

N-acetyl-2-bromoaniline

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

N-[4’-chloro-(1,1’-biphenyl)-2-yl]acetamide

N-[4’-chloro-(1,1’-biphenyl)-2-yl]acetamide

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate; 10 wt% Pd(OH)2 on carbon; tetrabutylammomium bromide In N,N-dimethyl-formamide at 125℃; for 11h; Reagent/catalyst; Solvent; Temperature; Time; Suzuki Coupling;100%
With di-tert-butyl(phenyl)phosphonium tetrafluoroborate; bis(acetylacetonato)palladium(II) In water; butan-1-ol at 60℃; for 20h; Reagent/catalyst; Suzuki Coupling; Inert atmosphere;
With di-tert-butyl(phenyl)phosphonium tetrafluoroborate; palladium(II) acetylacetonate In aq. phosphate buffer; butan-1-ol at 60℃; for 13h; pH=7 - 10; Reagent/catalyst; Suzuki Coupling; Inert atmosphere;
1-(4-bromobenzyl)-1H-indole-3-carboxylic acid methyl ester
709004-41-1

1-(4-bromobenzyl)-1H-indole-3-carboxylic acid methyl ester

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

1-((4'-chloro-[1,1'-biphenyl]-4-yl)methyl)-1H-indole-3-carboxylic acid methyl ester

1-((4'-chloro-[1,1'-biphenyl]-4-yl)methyl)-1H-indole-3-carboxylic acid methyl ester

Conditions
ConditionsYield
With palladium diacetate; sodium carbonate; triphenylphosphine In dimethyl sulfoxide at 80℃; Suzuki Coupling; Inert atmosphere;100%
With palladium diacetate; sodium carbonate; triphenylphosphine In dimethyl sulfoxide at 80℃; Inert atmosphere;93%
2-bromo-2’-fluoro-1,1’-biphenyl
1554-05-8

2-bromo-2’-fluoro-1,1’-biphenyl

4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

4''-chloro-2-fluoro-1,1':2',1''-terphenyl

4''-chloro-2-fluoro-1,1':2',1''-terphenyl

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In N,N-dimethyl acetamide; water at 80℃; for 18h; Suzuki Coupling; Inert atmosphere;100%
4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

Cinnamyl bromide
4392-24-9

Cinnamyl bromide

(E)-1-chloro-4-(3-phenyl-2-propen-1-yl)benzene
6948-68-1

(E)-1-chloro-4-(3-phenyl-2-propen-1-yl)benzene

Conditions
ConditionsYield
With potassium carbonate; (3E,8E,13E)-1,6,11-[(2,4,6-iPr3Ph)SO2]3-1,6,11-C15H18N3Pd(0) In toluene at 80℃; for 4h; Arylation;99%
With dihydrogen peroxide; potassium carbonate; Pd(dba)n (n = 1.5-2) 1.) benzene, reflux, 15 h, 2.) r.t., 1 h; Multistep reaction;
4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

4,4'-dichlorobiphenyl
2050-68-2

4,4'-dichlorobiphenyl

Conditions
ConditionsYield
With (N-piperazinyl-N′-methyl)-2-methylene-4,6-di-tert-butylphenol; palladium diacetate; potassium carbonate In ethanol at 20℃; for 12h; Solvent; Reagent/catalyst; Time; Concentration; Suzuki Coupling; Green chemistry;99%
With sodium hydroxide In water at 120 - 130℃; Microwave irradiation;99%
With potassium acetate; silver(l) oxide In methanol at 40℃; for 15h;99%
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