Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Cas:1923-70-2
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryFactory supply Tetrabutylammonium perchlorate Cas 1923-70-2 with best purity Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Fo
Cas:1923-70-2
Min.Order:10 Kilogram
FOB Price: $10.0
Type:Trading Company
inquiry
Cas:1923-70-2
Min.Order:1 Metric Ton
FOB Price: $1.0
Type:Manufacturers
inquiryTetrabutylammonium perchlorate Basic information Product Name: Tetrabutylammonium perchlorate Synonyms: TETRA-N-BUTYLAMMONIUM PERCHLORATE;TETRABUTYLAMMONIUM PERCHLORATE;n,n,n-tributyl-1-
Cas:1923-70-2
Min.Order:1 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryOur Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con
Cas:1923-70-2
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FOB Price: $1.0 / 10.0
Type:Trading Company
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:1923-70-2
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
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inquiryhebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen
Cas:1923-70-2
Min.Order:20 Kilogram
FOB Price: $10.0 / 100.0
Type:Trading Company
inquiryChemical Name Tetrabutyl ammonium perchlorate Synonyms TBAHS CAS No. 1923-70-2 Molecular formula C16H36NClO4 Molecular weight
Cas:1923-70-2
Min.Order:1 Kilogram
FOB Price: $1.0
Type:Other
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:1923-70-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:1923-70-2
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Cas:1923-70-2
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryHangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting Tetrabutylammonium perchlorate 98%, CAS No.:1923-70-2;Please contact us by email freely. We are leading exporter in China. If you
Cas:1923-70-2
Min.Order:0 Metric Ton
Negotiable
Type:Other
inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:1923-70-2
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiry1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures
Cas:1923-70-2
Min.Order:1 Kilogram
FOB Price: $80.0 / 100.0
Type:Lab/Research institutions
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:1923-70-2
Min.Order:0 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:1923-70-2
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryChemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff
Cas:1923-70-2
Min.Order:100 Gram
Negotiable
Type:Other
inquirySuperior quality, moderate price & quick delivery. Appearance:white crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermed
Cas:1923-70-2
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h
Cas:1923-70-2
Min.Order:0
Negotiable
Type:Other
inquiryProduct name: Tetrabutylammonium Perchlorate CAS No.: 1923-70-2 Molecule Formula:C16H36N·ClO4 Molecule Weight:341.92 Purity: 99.0% Package: 25kg/drum Description:White to off-white solid Manufacture Standards:Enterprise Standard
Cas:1923-70-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiry1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd
Cas:1923-70-2
Min.Order:1 Kilogram
FOB Price: $100.0 / 102.0
Type:Trading Company
inquiryTetrabutylammonium perchlorate Basic information Product Name: Tetrabutylammonium perchlorate Synonyms: TETRABUTYLAMMONIUM PERCHLORATE ELECTRO-C HEMICAL GRADE;Tetrabutylammonium perchlorate, contains max. 10% water, 99%;n,n,n-tributyl-1-butana
Cas:1923-70-2
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:1923-70-2
Min.Order:1 Kilogram
FOB Price: $18.0 / 20.0
Type:Trading Company
inquiryZhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed
Cas:1923-70-2
Min.Order:1 Kilogram
FOB Price: $2.0
Type:Lab/Research institutions
inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:1923-70-2
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiry1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:1923-70-2
Min.Order:1 Metric Ton
FOB Price: $1.5
Type:Trading Company
inquiryAppearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea
High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use
Cas:1923-70-2
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquirySAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe
Cas:1923-70-2
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryConditions | Yield |
---|---|
With trimethyl phosphite; perchloric acid at 0 - 60℃; for 15h; Inert atmosphere; neat (no solvent); | 95% |
With perchloric acid | |
With perchloric acid | |
With perchloric acid |
(NBu4)2{palladium(μ-Br)bis(pentafluorophenyl)}2
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.; | A 90% B n/a |
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane AgClO4 added to (NBu4)(Au(C6Cl5)2) in dichloromethane and stirred at room temp. for 6 h;; ppt. filtered off and washed with diethylether; elem. anal.; | A 90% B n/a |
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In diethyl ether stirred at room temp. for 8 h; filtered off (N(C4H9)4)(ClO4), soln. concd., addn. of n-hexane, pptn.; elem. anal.; | A 85% B n/a |
(NBu4)2{palladium(μ-Br)bis(pentachlorophenyl)}2
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.; | A 80% B n/a |
[Ag(OClO3)(tetrahydrothiophene)]
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, treated with Et2O, filtration, evapn. to dryness, washeed with hexane, dried in vac.; | A 80% B n/a |
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, treated with Et2O, filtration, evapn. to dryness, washed with hexane, elem. anal.; | A 79% B n/a |
perchlorato(triphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, washing with i-PrOH, elem. anal.; | A 78% B n/a |
perchlorato(triphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:1), stirring (room temp., 1 h); evapn., treatment with cold MeOH (0°C), filtn., washing (MeOH); elem. anal.; | A 77% B n/a |
perchlorato(triphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.; | A 77% B n/a |
(NBu4)2{platinum2(μ-pentafluorophenyl)2(pentafluorophenyl)4}
A
(NBu4){platinum2(silver)(μ-pentafluorophenyl)2(pentafluorophenyl)4(diethyl ether)}
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In diethyl ether; dichloromethane Addn. of AgClO4 to a CH2Cl2 soln. of Pt-complex (molar ratio 1:1) and stirring of mixt. (exclusion of light, room temp., 1 h).; Evapn. of soln. to dryness and treatment of resulting oily residue with O(C2H5)2 to separate the insoluble org. compd. Evapn. of ether soln. to dryness gives a solid.; | A 76% B n/a |
(NBu4)2{platinum(pentafluorophenyl)3Cl}
A
(NBu4)2{platinum2(μ-pentafluorophenyl)2(pentafluorophenyl)4}
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane Addn. of AgClO4 to a CH2Cl2 soln. of Pt-complex and stirring of mixt. (exclusion of light, room temp., 2 h).; Filtn. of formed AgCl, evapn. of resulting yellow soln. to dryness and treatment of obtained oily residue with O(C2H5)2 to separate the insoluble org. compd. Evapn. of ether soln. to dryness gives a solid.; | A 76% B n/a C n/a |
perchlorato(triphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.; | A 75% B n/a |
perchlorato(triphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.; | A 73% B n/a |
(NBu4)2{platinum(pentafluorophenyl)3Cl}
A
(NBu4){platinum2(silver)(μ-pentafluorophenyl)2(pentafluorophenyl)4(diethyl ether)}
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In diethyl ether; dichloromethane Addn. of AgClO4 to a CH2Cl2 soln. of Pt-complex (molar ratio 2:1) and stirring of mixt. (exclusion of light, room temp., 2 h).; Filtn. of formed AgCl and of excess of AgClO4, evapn. of resulting yellow soln. to dryness and washing of obtained oily residue with O(C2H5)2 to separate the insoluble org. compd. Partial evapn. of yellow soln. and addn. of n-hexane gives a solid.; | A 72% B n/a C n/a |
perchlorato(triphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.; | A 72% B n/a |
perchlorato(triphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.; | A 70% B n/a |
(NBu4)2{platinum2(μ-pentafluorophenyl)2(pentafluorophenyl)4}
A
(NBu4){platinum2(silver)(μ-pentafluorophenyl)2(pentafluorophenyl)4(PPh3)}
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane Addn. of O3ClOAgPPh3 to a soln. of Pt-compd. (CH2Cl2, -30°C) and stirring of mixt. (30 min, -30°C, exclusion of light).; Pumping of soln. to dryness (-30°C) and treatment of residue with O(C2H5)2 (-30°C). Evapn. of soln. to dryness and addn. of n-hexane after sepn. of insoluble NBu4ClO4.; | A 69% B n/a |
perchlorato(triphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, addn. of Et2O, filtration, evapn. to dryness, treated with hexane, drying in vac., elem. anal.; | A 68% B n/a |
perchlorato(triphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.; | A 68% B n/a |
trans-dichlorobis(pyridine)platinum(II)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane; acetone addn. of trans-(PtCl2(py)2) to soln. of Pt-complex in CH2Cl2/acetone (2:1), stirring (1 h); evapn. to dryness, washing (diethyl ether, 2.product solid), evapn. of washings to dryness, treatment with i-PrOH/hexane; | A 58% B n/a |
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In diethyl ether equimolar amt. of AgClO4 was added to soln. of Au-compound in Et2O, stirred for 1 h; filtered, filtrate evapd., hexane added; elem. anal.; | A 56% B >99 |
O3ClOAg(P(C2H5)3)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:2), stirring (room temp., 2 h); evapn., treatment with MeOH, filtn., washing (MeOH); elem. anal.; | A 51% B n/a |
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, addn. of Et2O, filtration, evapn. to dryness, treated with hexane, drying in vac., elem. anal.; | A 50% B n/a |
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
With diethyl ether In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, addn. of Et2O, filtration, evapn. to dryness, treated with hexane, drying in vac., elem. anal.; | A 50% B n/a |
perchlorato(methyldiphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:1), stirring (room temp., 1 h); filtn., evapn., treatment with MeOH; elem. anal.; | A 39% B n/a |
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:2), stirring (room temp., 1 h); filtn., evapn., treatment with MeOH; elem. anal.; | A 73-77 B n/a |
A
didodecyl sulfide
B
tetrabutylammonium perchlorate
C
(methyl-2 butene-3 yl-2) phosphate de potassium
Conditions | Yield |
---|---|
With Potassium benzoate; copper(I) bromide In dichloromethane | A n/a B n/a C 17% |
tetrabutylammonium perchlorate
boron trichloride
tetrabutylammonium trichloroperchloratoborate
Conditions | Yield |
---|---|
In chloroform introducing of gaseous BCl3 to soln. of <(C4H9)4N> in CHCl3 at 20°C; distn. and drying in vac.; | 100% |
In neat (no solvent) Bu4NClO4 reacted slowly with excess of BCl3 at 20°C; elem. anal.; | |
In chloroform Bu4NClO4 reacted slowly with BCl3 in CHCl3 at 20°C; elem. anal.; | |
In chloroform |
4,5-dimethylethylene (trans,trans) sulphate
tetrabutylammonium perchlorate
A
trans-2-Butene
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 20℃; Product distribution; electrolysis, oth. solvent, var. cathodes; | A 99% B 42% C n/a |
Conditions | Yield |
---|---|
In chloroform Bu4NClO4 reacted with BF3 in CHCl3 at 20°C; | 99% |
Ru(2,6-(C6H5NCO)2C5H3N)(2,2',2''-terpyridine)
tetrabutylammonium perchlorate
[Ru(2,6-(C6H5NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4
Conditions | Yield |
---|---|
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.; | 99% |
Ru(2,6-(4-CH3C6H4NCO)2C5H3N)(2,2',2''-terpyridine)
tetrabutylammonium perchlorate
[Ru(2,6-(4-CH3C6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4
Conditions | Yield |
---|---|
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.; | 99% |
Ru(2,6-(4-CH3OC6H4NCO)2C5H3N)(2,2',2''-terpyridine)
tetrabutylammonium perchlorate
[Ru(2,6-(4-CH3OC6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4
Conditions | Yield |
---|---|
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.; | 99% |
Ru(N,N'-bis(4'-chlorophenyl)pyridine-2,6-dicarboxamide)(2,2',2''-terpyridine)
tetrabutylammonium perchlorate
[Ru(2,6-(ClC6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4
Conditions | Yield |
---|---|
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.; | 99% |
Ru(2,6-(O2NC6H4NCO)2C5H3N)(2,2',2''-terpyridine)
tetrabutylammonium perchlorate
[Ru(2,6-(O2NC6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4
Conditions | Yield |
---|---|
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.; | 99% |
Conditions | Yield |
---|---|
In dichloromethane Electrolysis; | 99% |
pyridine
Vanadium (III) chloride-(tris-tetrahydrofuran)
tetrabutylammonium perchlorate
water
sodium acetate
[V3O(O2CMe)6(pyridine)3](ClO4)
Conditions | Yield |
---|---|
In pyridine; acetic acid; acetonitrile byproducts: NaCl; N2-atmosphere; stirring V-complex with AcONa in MeCN/AcOH/pyridine=2:1:2v/v/v for 24 h, filtration off of NaCl, Bu4NClO4 addn.; further educt: acetic acid; vol. reduction (vac.), pptn. on Et2O addn., collection (filtration), washing (Et2O), drying (vac.); elem. anal.; | 95% |
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
With N2H4*H2O In methanol NH4SCN and (NH4)2TcBr6 refluxed in methanol under N2 or Ar for 24 h, system cooled to room temp., N2H4*H2O added, mixt. filtered under inert atm., filtrate treated with n-Bu4NClO4 in methanol; solid filtered under inert atm., washed with water, methanol, dried in vac.; elem. anal.; | 93% |
picoline
Vanadium (III) chloride-(tris-tetrahydrofuran)
tetrabutylammonium perchlorate
water
sodium acetate
Conditions | Yield |
---|---|
In acetic acid; acetonitrile N2-atmosphere; stirring V-complex with AcONa in MeCN/AcOH/4-picoline=2:1:2.2 v/v/v for 24 h, filtration off of NaCl, Bu4NClO4 addn.; further educt: acetic acid; vol. reduction (vac.), pptn. on Et2O addn., collection (filtration), washing (Et2O), drying (vac.); elem. anal.; | 91% |
(tetrahydrothiophene)gold(I) chloride
tetrabutylammonium perchlorate
lithium-2,4,6-trifluorophenyl
Conditions | Yield |
---|---|
In diethyl ether byproducts: Au; mixing soln. of Au-complex and ligand (-78°C), stirring for 20 min, warming to room temp., stirring (30 min), filtration, addn. to Bu4N(ClO4) soln. (pptn.); recrystn. (CH2Cl2/EtOH); | 90% |
osmium(2,2'-bipyridine)2(3,5-di-tert-butylcatechol)
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In methanol; dichloromethane stirred in air at room temp. for 24h; cooled in a refrigerator; elem. anal.; | 90% |
[platinum(II)(μ-chloride)(2-( p-tolyl)-pyridine(-H))]2
tetrabutylammonium perchlorate
acetonitrile
Conditions | Yield |
---|---|
Stage #1: [platinum(II)(μ-chloride)(2-( p-tolyl)-pyridine(-H))]2 With silver perchlorate In acetonitrile for 7h; Darkness; Stage #2: potassium cyanide In methanol for 2h; Stage #3: tetrabutylammonium perchlorate; acetonitrile Further stages; | 90% |
2-(1,8-naphthyridin-2-yl)thiazole
tetrabutylammonium perchlorate
water
Conditions | Yield |
---|---|
Stage #1: 2-(2-thiazolyl)-1,8-naphthyridine; tetraacetatodiruthenium chloride; tetrabutylammonium perchlorate In methanol Inert atmosphere; Schlenk technique; Reflux; Stage #2: water Inert atmosphere; Schlenk technique; | 90% |
Conditions | Yield |
---|---|
Glovebox; Inert atmosphere; Electrochemical reaction; | 90% |
Conditions | Yield |
---|---|
In dichloromethane; acetone byproducts: NaClO4; to soln. of Au complex in acetone added Na(S2CNMe2)*2H2O, stirred for 2 h at room temp., evapd. to dryness, soln. of (NBu4)ClO4 in CH2Cl2 added, stirred for 1h at room temp.; filtered, washed with CH2Cl2, filtrate and washings were evapd. in vac. to ca. 5 ml, upon addition of n-hexane pptd. product; elem. anal.; | 89% |
Conditions | Yield |
---|---|
In dichloromethane; acetone to soln. of Au complex in acetone added Na(S2CNMe2)*2H2O, stirred for 2 h at room temp., evapd. to dryness, soln. of (NBu4)ClO4 in CH2Cl2 added, stirred for 1h at room temp.; filtered, washed (2*5 ml) with CH2Cl2, filtrate and washings were evapd. in vac. to ca. 5 ml, upon addition of n-hexane pptd. product; elem. anal.; | 89% |
1,4,8,11-Tetraazacyclotetradecane
tetrabutylammonium perchlorate
iron
acetonitrile
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid In acetonitrile Ar-atmosphere; refluxing excess Fe with CF3SO3H for 4 h, filtration, mixing with cyclam, refluxing for 30 min, addn. of Bu4NClO4, refluxing for 30 min; cooling in ice bath, Et2O addn. (pptn.); | 88% |
[Pt(2-phenylpyridinate)(NCMe)2]ClO4
tetrabutylammonium perchlorate
tetrabutylammonium dicyano[(2-pyridyl)phenyl-2-ido]platinate(II)
Conditions | Yield |
---|---|
In methanol KCN was added to suspn. Pt complex in MeOH at room temp. and stirred for1 h, soln. was filtered through Celite and evapd. to dryness, Bu4NClO4 and acetone were added and stirred for 1 h; soln. was filtered through Celite, soln. was evapd. to dryness, residue was treated with water, filtered, dried (110°C) and recrystd. from CH2Cl2-Et2O; elem. anal.; | 88% |
[2,2]bipyridinyl
tetrabutylammonium perchlorate
[Pd2(μ-PPh2)(C6F5)4(bipy)2][ClO4]
Conditions | Yield |
---|---|
In isopropyl alcohol; acetone stirring Pd-complex with bipy (in Me2CO) for 10 min, partial evapn., add. if i-PrOH and Bu4NClO4; pptn. on partial evapn.., collection (filtration), washing (i-PrOH), drying in air; elem. anal.; | 87% |
tetrabutylammonium perchlorate
1,10-phenanthroline hydrate
[Pd2(μ-PPh2)(C6F5)4(phen)2][ClO4]
Conditions | Yield |
---|---|
In isopropyl alcohol; acetone stirring Pd-complex with phen (in Me2CO) for 10 min, partial evapn., add. if i-PrOH and Bu4NClO4; pptn. on partial evapn.., collection (filtration), washing (i-PrOH), drying in air; elem. anal.; | 87% |
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In acetone at 20℃; for 12h; | 87% |
tetrabutylammonium perchlorate
sodium diethyldithiocarbamate trihydrate
Conditions | Yield |
---|---|
In dichloromethane; acetone appropriated choice of molar ratio of educts; to soln. of Au complex in acetone added Na(S2CNEt2)*3H2O, stirred for 2 h at room temp., evapd. to dryness, soln. of (NBu4)ClO4 in CH2Cl2 added, stirred for 1h at room temp.; filtered, washed (2*5 ml) with CH2Cl2, filtrate and washings were evapd. in vac. to ca. 5 ml, upon addition of n-hexane pptd. product; elem. anal.; | 84% |
Conditions | Yield |
---|---|
In methanol at 20℃; | 84% |
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