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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Qingdao Greenchem international Trading Co.,Ltd. is the commercial company which is invested by BeiJing Greenchem Technology Co.,Ltd. in Qingdao. It takes charge of export and production promotion, as well as imports and selling relevant produc

Grubbs Catalyst 2nd Generation

Cas:246047-72-3

Min.Order:0 Metric Ton

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Type:Manufacturers

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Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Appearance:Reddish brown powder Storage:Refer to COA / MSD

Ru 11.9% Grubbs Catalyst 2nd Generation cas 246047-72-3

Cas:246047-72-3

Min.Order:1 Gram

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Win-Win chemical Co.Ltd

Stock products, own laboratory Product number PC00069 English Name Grubbs Catalyst 2Nd Generation CAS Number 246047-72-3 Purity 98

Grubbs Catalyst 2Nd Generation cas no. 246047-72-3 98%

Cas:246047-72-3

Min.Order:1 Metric Ton

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Grubbs Catalyst 2nd Generation Manufacturer/High quality/Best price/In stock

Cas:246047-72-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

GIHI CHEMICALS exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, GIHI CHEMICALS is your best choice. pls contact with us freely for getting detailed produc

GRUBBS CATALYST 2ND GENERATION

Cas:246047-72-3

Min.Order:1 Kilogram

FOB Price: $3.0

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Jinan Finer Chemical Co., Ltd

Product description: Product name Grubbs Catalyst 2nd Generation CAS number 246047-72-3 Assay ≥99% Appearance Red to brown powder Capacity 100mt/year Application Catalyst

Grubbs Catalyst 2nd Generation

Cas:246047-72-3

Min.Order:100 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply grubbs catalyst 2nd generation

Cas:246047-72-3

Min.Order:1

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Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

Grubbs Catalyst 2nd. generation

Cas:246047-72-3

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU CHEM---GRUBBS CATALYST 2ND GENERATION

Cas:246047-72-3

Min.Order:1 Kilogram

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

Grubbs Catalyst 2ND Generation; CAS No. 246047-72-3

Cas:246047-72-3

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 246047-72-3 with competitive price

Cas:246047-72-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Grubbs Catalyst 2nd. generation

Cas:246047-72-3

Min.Order:10 Kilogram

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

GRUBBS CATALYST 2ND GENERATION CAS246047-72-3

Cas:246047-72-3

Min.Order:1 Kilogram

FOB Price: $290.0 / 499.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Chemical Name: benzylidene-[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichlororuthenium,tricyclohexylphosphane Cas No.: 246047-72-3 Molecular Formula: C46H65Cl2N2PRu Molecular Weight: 848

Hangzhou Sartort Biopharma Co., Ltd

Appearance:Pink to brown crystalline powder Storage:R.T Package:100g/bottle Application:catalyst Transportation:Express/Sea/Air Port:Any port in China

Grubbs Catalyst 2nd Generation cas 246047-72-3

Cas:246047-72-3

Min.Order:100 Gram

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Chemical Catalyst, GRUBBS CATALYST 2ND GENERATION CAS:246047-72-3

Cas:246047-72-3

Min.Order:1 Kilogram

FOB Price: $32.0 / 36.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Beluga chemical professional supplyHigh quality Grubbs Catalyst 2nd Generation CAS 246047-72-3 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2

Grubbs Catalyst 2nd Generation CAS 246047-72-3

Cas:246047-72-3

Min.Order:1 Gram

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Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:246047-72-3

Cas:246047-72-3

Min.Order:0

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

GRUBBS CATALYST 2ND GENERATION

Cas:246047-72-3

Min.Order:1 Gram

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Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene][benzylidene]rut

Cas:246047-72-3

Min.Order:4 Kilogram

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Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

GRUBBS CATALYST 2ND GENERATION/High quality/Best price

Cas:246047-72-3

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality grubbs catalyst 2nd generation

Cas:246047-72-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Grubbs Catalyst 2nd. generation

Cas:246047-72-3

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:pink-brown to red-purple crystals or powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:100g/bottle,1kg/bottle,25kg/drum or as per your request

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

GRUBBS CATALYST 2ND GENERATION

Cas:246047-72-3

Min.Order:10 Gram

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Synthetic route

Grubbs catalyst first generation

Grubbs catalyst first generation

1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene
173035-11-5

1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
In tetrahydrofuran at 25℃; for 2h; Inert atmosphere; Glovebox;94%
1,3-di(2,4,6-trimethylphenyl)-2-(pentafluorophenyl)-2,4,5-trihydroimidazole
782479-45-2

1,3-di(2,4,6-trimethylphenyl)-2-(pentafluorophenyl)-2,4,5-trihydroimidazole

Grubbs catalyst first generation

Grubbs catalyst first generation

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
In toluene mixt. of Ru complex and imidazolidine in toluene was heated at 60°C for 4 h;91%
Grubbs catalyst first generation

Grubbs catalyst first generation

1,3-bis(2,4,6-trimethylphenyl)-2-(trichloromethyl)imidazolidine
260054-47-5

1,3-bis(2,4,6-trimethylphenyl)-2-(trichloromethyl)imidazolidine

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
In toluene mixt. of Ru complex and imidazolidine in toluene was heated at 60°C for 4 h;87%
In toluene byproducts: PCy3, CHCl3; (N2); using Schlenk techniques; mixing of (Mes2C3N2H5)(CCl3) and (PCy3)2Cl2Ru(CHPh) in toluene; heating at 60°C for 90 min; cooling to room temp., removal of solvent under vac., washing with methanol and pentane, drying under vac. for 12 h;84%
RuCl2(sIMes)(CHPh)(pyridine)2

RuCl2(sIMes)(CHPh)(pyridine)2

tris(cyclohexyl)phosphonium tetrafluoroborate
58656-04-5

tris(cyclohexyl)phosphonium tetrafluoroborate

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
In toluene byproducts: pyridinium tetrafluoroborate, pyridine; 1.1 equiv. of phosphonium salt; passage through silica plug;80%
Grubbs catalyst first generation

Grubbs catalyst first generation

1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride
173035-10-4

1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
With KO(C(CH3)3) In hexane byproducts: KCl, C(CH3)3OH, PCy3; using Schlenk techniques; mixing of (Mes2C3N2H5)(Cl), KO(t-Bu) and (PCy3)2Cl2Ru(CHPh) in anhyd. hexane; degassing of soln. by pulling vac. for afew minutes, heating at 60°C for 24 h in vac. with very vigorous stirring; cooling to room temp., opening the flask to air, addn. of 1:1 2-propanol:water; stirring in air for 30 min, filtration, washing with 2-propanol:water and with hexane, drying under vac. overnight, elem. anal.;75%
With potassium tert-butylate In hexane at 60℃; for 24h; Schlenk technique;75%
With KOC(CH3)3 In toluene mixing N compd., Ru complex, K compd. in toluene at 50°C;
Grubbs catalyst first generation

Grubbs catalyst first generation

N,N'-dimesityl-4,5-dihydro-1H-imidazolium tetrafluoroborate

N,N'-dimesityl-4,5-dihydro-1H-imidazolium tetrafluoroborate

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
Stage #1: N,N'-dimesityl-4,5-dihydro-1H-imidazolium tetrafluoroborate With potassium tert-butylate In tetrahydrofuran at 20℃; for 1h; Schlenk technique; Inert atmosphere;
Stage #2: Grubbs catalyst first generation In benzene at 80℃; for 1.5h; Schlenk technique; Inert atmosphere;
56%
With KO(C(CH3)3) In benzene byproducts: KBF4, C(CH3)3OH, PCy3; (N2); using Schlenk techniques; mixing of (Mes2C3N2H5)(BF4), KO(t-Bu) and THF; stirring for 1 h; addn. of (PCy3)2Cl2Ru(CHPh) in benzene; heatingat 80°C for 30 min; removal of volatiles under vac., suspending in benzene, filtration over Celite, concn., addn. of methanol, pptn., washing with methanol, pentaneand then drying under vac.;45%
RuCl2(sIMes)(CHPh)(pyridine)2

RuCl2(sIMes)(CHPh)(pyridine)2

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
With C5((2)H)5N In not given under Ar or N2; Ru complex reacts instantaneously with the phosphine; addn. of an excess of C5((2)H)5N leads to a formation of the bis(pyridine-d5) complex; evapn. of volatiles in vac. leads to a reformation of the phosphine complex;
Grubbs catalyst first generation

Grubbs catalyst first generation

bis[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)ruthenium(II)

bis[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)ruthenium(II)

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
In benzene-d6 (N2); using Schlenk techniques; charging of NMR tube with Ru(CHPh)Cl2(C3N2H4Mes2)2, (PCy3)2(Cl)2Ru(CHPh) (1 equiv.) and C6D6; heating at 70°C for 47 h; monitoring by NMR;
bis[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)ruthenium(II)

bis[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)ruthenium(II)

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
In benzene-d6 (N2); using Schlenk techniques; charging of NMR tube with Ru(CHPh)Cl2(C3N2H4Mes2)2, PCy3 (excess) and C6D6; heating at 80°C for 36 h; monitoring by NMR;
styrene
292638-84-7

styrene

[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro-(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II)

[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro-(3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II)

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
In tetrahydrofuran excess styrene;0%
In toluene excess styrene;0%
(N,N'-dimesityl-N,N'-dimethylformamidin-2-ylidene)(1,3-dimesitylimidazolin-2-ylidene)Cl2Ru=CHPh

(N,N'-dimesityl-N,N'-dimethylformamidin-2-ylidene)(1,3-dimesitylimidazolin-2-ylidene)Cl2Ru=CHPh

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
In benzene-d6 100°C, 8 h;
(N,N'-bis(2,6-di-isopropylphenyl)-N,N'-dimethylformamidin-2-ylidene)(1,3-dimesitylimidazolin-2-ylidene)Cl2Ru=CHPh

(N,N'-bis(2,6-di-isopropylphenyl)-N,N'-dimethylformamidin-2-ylidene)(1,3-dimesitylimidazolin-2-ylidene)Cl2Ru=CHPh

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
In benzene-d6 100°C, 2 h;
2,4,6-trimethylaniline
88-05-1

2,4,6-trimethylaniline

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: isopropyl alcohol; water / 24 h / 0 - 20 °C
2: sodium tetrahydroborate; hydrogenchloride / water; tetrahydrofuran / 0 - 20 °C
3: formic acid / 5 h / 120 °C / Inert atmosphere
4: potassium tert-butylate / hexane / 24 h / 60 °C / Schlenk technique
View Scheme
N,N'-bis(2,4,6-trimethylphenyl)ethanediimine
56222-36-7

N,N'-bis(2,4,6-trimethylphenyl)ethanediimine

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: sodium tetrahydroborate; hydrogenchloride / water; tetrahydrofuran / 0 - 20 °C
2: formic acid / 5 h / 120 °C / Inert atmosphere
3: potassium tert-butylate / hexane / 24 h / 60 °C / Schlenk technique
View Scheme
N1,N2-dimesitylethane-1,2-diaminium chloride
258278-23-8

N1,N2-dimesitylethane-1,2-diaminium chloride

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: formic acid / 5 h / 120 °C / Inert atmosphere
2: potassium tert-butylate / hexane / 24 h / 60 °C / Schlenk technique
View Scheme
(SIMes)Ru(S-DMSO)(CHPh)Cl2

(SIMes)Ru(S-DMSO)(CHPh)Cl2

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
for 0.5h; Inert atmosphere; Schlenk technique;
dichloro(1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylylidene)(benzylidene)bis(pyridine)ruthenium(II)

dichloro(1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylylidene)(benzylidene)bis(pyridine)ruthenium(II)

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NaN(Si(CH3)3)2 / toluene
2: benzene-d6
View Scheme
1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride
173035-10-4

1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium hexamethylsilazane / toluene / 1 h / 20 °C / Inert atmosphere; Schlenk technique
2: toluene / Schlenk technique; Inert atmosphere
View Scheme
Grubbs catalyst first generation

Grubbs catalyst first generation

1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene

1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Conditions
ConditionsYield
In toluene Schlenk technique; Inert atmosphere;
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

(4-isopropoxy-3-vinyl-phenyl)dimethyl-phosphoramidate ethyl ester

(4-isopropoxy-3-vinyl-phenyl)dimethyl-phosphoramidate ethyl ester

1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-isopropoxy)-5-(N,N-dimethylamino-ethylphosphite)phenyl]methyleneruthenium(II) dichloride

1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-isopropoxy)-5-(N,N-dimethylamino-ethylphosphite)phenyl]methyleneruthenium(II) dichloride

Conditions
ConditionsYield
With copper(l) chloride In dichloromethane at 30℃; for 1h; Schlenk technique;100%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

(IMesH2)(C7H10N2)2(Cl)2Ru=CHPh

(IMesH2)(C7H10N2)2(Cl)2Ru=CHPh

Conditions
ConditionsYield
In toluene at 20 - 25℃; for 12h;99%
In neat (no solvent) for 0.333333h; Milling;87%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

hydrogen
1333-74-0

hydrogen

ethylenediamine
107-15-3

ethylenediamine

[RuHCl(NH2CH2CH2NH2)(P(C6H11)3)(C3H4N2(C6H2(CH3)3)2)]

[RuHCl(NH2CH2CH2NH2)(P(C6H11)3)(C3H4N2(C6H2(CH3)3)2)]

Conditions
ConditionsYield
In sodium hydroxide under H2 (1 atm.); NMR;99%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

(4-isopropoxy-3-vinylphenyl)(diphenyl)methanol
934165-44-3

(4-isopropoxy-3-vinylphenyl)(diphenyl)methanol

((2,4,6-trimethylphenyl)2(C3H4N2))Cl2Ru(CH(C6H3)(OC3H7)(5-C(OH)Ph2))

((2,4,6-trimethylphenyl)2(C3H4N2))Cl2Ru(CH(C6H3)(OC3H7)(5-C(OH)Ph2))

Conditions
ConditionsYield
With copper(l) chloride In dichloromethane carbene complex (0.075 mmol), CuCl (0.09 mmol), and CH2Cl2 (4 ml) placedin Schlenk tube; styrene (0.09 mmol) in CH2Cl2 added; stirred (under Ar , 40°C, 1 h); concd. (vac.); column chromy. (silica gel, cyclohexane/ethyl acetate 3:1); green band removed; evapd.; washed with min. amt. of cold n-pentane; dried (vac.);99%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

1-(4-isopropoxy-3-vinylphenyl)-pyridinium hexafluorophosphate

1-(4-isopropoxy-3-vinylphenyl)-pyridinium hexafluorophosphate

(C3H4N2(C6H2(CH3)3)2)RuCl2(CHC6H3(NC5H5)OCH(CH3)2)(1+)*PF6(1-)=((C3H4N2(C6H2(CH3)3)2)RuCl2(CHC6H3(NC5H5)OCH(CH3)2))PF6

(C3H4N2(C6H2(CH3)3)2)RuCl2(CHC6H3(NC5H5)OCH(CH3)2)(1+)*PF6(1-)=((C3H4N2(C6H2(CH3)3)2)RuCl2(CHC6H3(NC5H5)OCH(CH3)2))PF6

Conditions
ConditionsYield
With copper(l) chloride In dichloromethane under Ar; soln. of pyridinium compd. in CH2Cl2 added to Ru complex and CuCl (molar ratio 1.2:1:1.5) in CH2Cl2; stirred at 45°C for 15 min; under air; concd. in vac.; EtOAc added; soln. filtered off; solvent removed; washed with cold n-pentane; dried under vac.;99%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

C2H4OS2(2-)*2Li(1+)

C2H4OS2(2-)*2Li(1+)

[ruthenium(III)(O(CH2CH2S)2)(CHPh)(1,3-bis-(2,4,6-trimethylphenyl)-4,5-dihydroimidazole)]

[ruthenium(III)(O(CH2CH2S)2)(CHPh)(1,3-bis-(2,4,6-trimethylphenyl)-4,5-dihydroimidazole)]

Conditions
ConditionsYield
In tetrahydrofuran for 16h; Inert atmosphere; Schlenk technique;99%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

(LiSCH2CH2)2O·2THF

(LiSCH2CH2)2O·2THF

Ru(Mes2Im)(=CHPh)[O(CH2CH2S)2]

Ru(Mes2Im)(=CHPh)[O(CH2CH2S)2]

Conditions
ConditionsYield
In toluene; acetonitrile for 16h; Inert atmosphere; Schlenk technique; Glovebox;99%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

2C4H8O*C4H8S3(2-)*2Li(1+)

2C4H8O*C4H8S3(2-)*2Li(1+)

Ru(Mes2Im)(=CHPh)[O(CH2CH2S)2]

Ru(Mes2Im)(=CHPh)[O(CH2CH2S)2]

Conditions
ConditionsYield
In tetrahydrofuran98%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

2Li(1+)*SCH2CH2SCH2CH2S(2-)=LiSCH2CH2SCH2CH2SLi

2Li(1+)*SCH2CH2SCH2CH2S(2-)=LiSCH2CH2SCH2CH2SLi

(SIMes)Ru(CHPh)(SCH2CH2)2S

(SIMes)Ru(CHPh)(SCH2CH2)2S

Conditions
ConditionsYield
In toluene; acetonitrile for 16h; Inert atmosphere; Schlenk technique; Glovebox;98%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

Vinylidene fluoride
75-38-7

Vinylidene fluoride

1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene-dichloro(phenylmethylene)-(tricyclohexyl-phosphine)difluoromethylene ruthenium

1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene-dichloro(phenylmethylene)-(tricyclohexyl-phosphine)difluoromethylene ruthenium

Conditions
ConditionsYield
In benzene under 1140.08 Torr; for 12h; Heating;98%
In benzene soln. of Ru(Cl)2(P(C6H11)3)(CH(C6H5))(C3H5N2(C6H2(CH3)3)2) in dry degassed benzene in thick-walled glass ampule put under approx. 1.5 atm of 1,1-difluoroethylene; mixt. heated at 60°C for 12 h; color changed from reddish to brown; soln. concd. and purifed by column chromy. in air (silica gel, 5:1 pentane:THF); orange fraction stripped of solvent; dried under vac.;86%
In benzene-d6 at 60℃; under 760.051 Torr; for 12h;
In benzene-d6 at 60℃; under 760.051 Torr; for 12h;
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

p-phenylpyridine
939-23-1

p-phenylpyridine

(IMesH2)(C11H9N)2(Cl)2Ru=CHPh

(IMesH2)(C11H9N)2(Cl)2Ru=CHPh

Conditions
ConditionsYield
In toluene at 20 - 25℃; for 12h;97%
In toluene at 20 - 25℃; for 12h;97%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

C21H23NO3S

C21H23NO3S

C42H49Cl2N3O3RuS

C42H49Cl2N3O3RuS

Conditions
ConditionsYield
In dichloromethane at 45℃;97%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

2-methyl-8-vinylquinoline
261899-66-5

2-methyl-8-vinylquinoline

[RuCl2(ImH2Mes)((2-methyl-8-quinolinyl)methylene)]

[RuCl2(ImH2Mes)((2-methyl-8-quinolinyl)methylene)]

Conditions
ConditionsYield
With copper(l) chloride In dichloromethane at 30℃; for 1.5h;96%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

(IMesH2)(C12H8N2)(Cl)2Ru=CHPh

(IMesH2)(C12H8N2)(Cl)2Ru=CHPh

Conditions
ConditionsYield
In toluene at 20 - 25℃; for 12h;96%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

acetonitrile
75-05-8

acetonitrile

[(MeCN)3(H2IMes)(benzylidene)ruthenium](triflate)2

[(MeCN)3(H2IMes)(benzylidene)ruthenium](triflate)2

Conditions
ConditionsYield
In chloroform byproducts: AgCl, PCy3; using standard Schlenk techniques; mixt. of Ru complex and Ag salt (2 equiv.) in CHCl3 stirred in presence of MeCN (3 equiv.) at 25°C for30 min; filtered; n-pentane added to filtrate; filtered; ppt. washed with n-pentane; dried under vac.; elem. anal.;96%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

C16H14FNO

C16H14FNO

C36H38Cl2FN3ORu

C36H38Cl2FN3ORu

Conditions
ConditionsYield
With copper(l) chloride In dichloromethane at 20℃; for 0.5h; Inert atmosphere;96%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

iodine
7553-56-2

iodine

5I(1-)*C2H6*C46H64Cl2N2PRu(1+)*I5(1-)

5I(1-)*C2H6*C46H64Cl2N2PRu(1+)*I5(1-)

Conditions
ConditionsYield
In dichloromethane at 25℃; for 0.5h; Inert atmosphere;95%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

(2R,4aR,5aS,10aR,11R,11aS)-2-(naphthalen-2-yl)-4,4a,5a,6,9,10a,11,11a-octahydro-[1,3]dioxino[40,50:5,6]pyrano[3,2-b]oxepin-11-ol
784157-67-1

(2R,4aR,5aS,10aR,11R,11aS)-2-(naphthalen-2-yl)-4,4a,5a,6,9,10a,11,11a-octahydro-[1,3]dioxino[40,50:5,6]pyrano[3,2-b]oxepin-11-ol

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃; for 5h;95%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

acetonitrile
75-05-8

acetonitrile

C32H38Cl2N4Ru

C32H38Cl2N4Ru

Conditions
ConditionsYield
With copper(l) chloride at 20℃; for 3h;95%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

C17H17NO3S

C17H17NO3S

C37H41Cl2N3O3RuS

C37H41Cl2N3O3RuS

Conditions
ConditionsYield
In dichloromethane at 45℃;95%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

3-Bromopyridine
626-55-1

3-Bromopyridine

Grubbs catalyst third generation
477218-66-9

Grubbs catalyst third generation

Conditions
ConditionsYield
Inert atmosphere;94%
In not given byproducts: P(C6H11)3; within minutes; pptn. with pentane;89%
at 20 - 25℃; for 12h;86%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

2-(prop-1-enyl)phenol
6380-21-8

2-(prop-1-enyl)phenol

C46H64ClN2OPRu

C46H64ClN2OPRu

Conditions
ConditionsYield
With tricyclohexylphosphine In dichloromethane at 40℃; for 24h; Inert atmosphere; Schlenk technique;94%
With tricyclohexylphosphine In dichloromethane at 40℃; for 5h;72%
With tricyclohexylphosphine In dichloromethane at 40℃; for 5h;72%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

2-(prop-1-enyl)phenol
6380-21-8

2-(prop-1-enyl)phenol

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

C46H64ClN2OPRu

C46H64ClN2OPRu

Conditions
ConditionsYield
In dichloromethane at 40℃; for 24h; Inert atmosphere;94%
N-(but-3-enyl)-4-methyl-N-(phenylethynyl)benzenesulfonamide
853688-25-2

N-(but-3-enyl)-4-methyl-N-(phenylethynyl)benzenesulfonamide

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

C40H45Cl2N3O2RuS

C40H45Cl2N3O2RuS

Conditions
ConditionsYield
In dichloromethane at 45℃;94%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

2,2'-biquinoline
119-91-5

2,2'-biquinoline

(IMesH2)(C18H12N2)2(Cl)2Ru=CHPh

(IMesH2)(C18H12N2)2(Cl)2Ru=CHPh

Conditions
ConditionsYield
In toluene at 20 - 25℃; for 12h;93%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

4-pyrrolidin-1-ylpyridine
2456-81-7

4-pyrrolidin-1-ylpyridine

(IMesH2)(C9H12N2)2(Cl)2Ru=CHP

(IMesH2)(C9H12N2)2(Cl)2Ru=CHP

Conditions
ConditionsYield
at 20 - 25℃; for 12h;93%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

ethyl vinyl ether
109-92-2

ethyl vinyl ether

RuCl2(ethoxymethylidene)(1-mesityl-3-mesityl-4,5-dihydroimidazol-2-ylidene)(PCy3)

RuCl2(ethoxymethylidene)(1-mesityl-3-mesityl-4,5-dihydroimidazol-2-ylidene)(PCy3)

Conditions
ConditionsYield
In dichloromethane ligand was added to CH2Cl2 soln. of Ru-complex, stirred at room temp. for 2 h under N2; solvent was evapd. under vac., washed with pentane and MeOH;93%
In benzene-d6 Kinetics; at 25°C; monitoring by NMR;
In toluene at 50℃; for 1h; Schlenk technique; Inert atmosphere;
In (2)H8-toluene at 30℃;
pyridine
110-86-1

pyridine

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

dichloro(1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylylidene)(benzylidene)bis(pyridine)ruthenium(II)

dichloro(1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylylidene)(benzylidene)bis(pyridine)ruthenium(II)

Conditions
ConditionsYield
In toluene at 20℃; for 0.5h; Inert atmosphere;92%
In toluene at 20℃; for 0.5h; Inert atmosphere; Glovebox;92%
In toluene at 20℃; for 0.5h; Inert atmosphere; Glovebox;92%
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride
246047-72-3

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

2-hydroxy-5-nitrostyrene
83520-63-2

2-hydroxy-5-nitrostyrene

C46H63ClN3O3PRu

C46H63ClN3O3PRu

Conditions
ConditionsYield
With tricyclohexylphosphine In dichloromethane at 40℃; for 24h; Inert atmosphere; Schlenk technique;92%
With tricyclohexylphosphine In dichloromethane at 40℃; for 1h;50%
With tricyclohexylphosphine In dichloromethane at 40℃; for 1h;50%
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