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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

BeiJing Greenchem Technology Co.,Ltd. was established by many people who are experienced in both management and professional technology in large and medium-sized pharmaceutical enterprises. It is located in Zhongguancun Technology Park, the synthesis

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:0 Metric Ton

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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesis.

High purity and quality Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:100 Gram

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Tricyclohexyl phosphine Manufacturer/High quality/Best price/In stock

Cas:2622-14-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance White solid Conforms Assay ≥98.0% 98.6%

High purity Various Specifications tricyclohexylphosphine CAS:2622-14-2

Cas:2622-14-2

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Tricyclohexylphospine supplier in China

Cas:2622-14-2

Min.Order:1 Metric Ton

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GIHI CHEMICALS CO.,LIMITED

GIHI CHEMICALS exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, GIHI CHEMICALS is your best choice. pls contact with us freely for getting detailed produc

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:1 Kilogram

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

tricyclohexylphosphine

Cas:2622-14-2

Min.Order:1 Metric Ton

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Tricyclohexylphospine

Cas:2622-14-2

Min.Order:1

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Type:Other

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Henan Allgreen Chemical Co.,Ltd

high purity Storage:Sealed, dry, microtherm , avoid light and smell. Package:meet customer's demand Application:organic synthesis Transportation:by sea or by air Port:shanghai

Tricyclohexyl phosphine 2622-14-2

Cas:2622-14-2

Min.Order:1 Kilogram

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 2622-14-2 Tricyclohexyl phosphine Manufacturer

Cas:2622-14-2

Min.Order:1 Gram

FOB Price: $0.1

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Tricyclohexylphosphine

Cas:2622-14-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Product Name: Tricyclohexyl phosphine Synonyms: Tricyclohexylphosphine, 97% 1mol THF;tricyclohexyl-phosphin;TRICYCLOHEXYLPHOSPHINE, 20 WT. % SOLUTI&;TRICYCLOHEXYLPHOSPHINE, 1M IN TOLUENE;TRICYCLOHEXYLPHOSPHINE, 1M IN TETRAHYDR&;Tricyclohex

2622-14-2 Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:1 Kilogram

FOB Price: $500.0

Type:Lab/Research institutions

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LIDE PHARMACEUTICALS LIMITED

LIDE PHARMACEUTICALS LIMITED is a professional chemicals and APIs leading manufacturer in China. Our core business line covers APIs, Intermediates, Herb extract, etc.

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:1 Kilogram

FOB Price: $0.9 / 1.0

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product Description Product name Tricyclohexyl phosphine CAS 2622-14-2 Assay 99% Appearance white powde

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 2622-14-2 with best quality

Cas:2622-14-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: Tricyclohexyl phosphine Synonyms: tricyclohexylphosphine CAS:2622-14-2 MF: C18H33P Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:Syntheses Material Intermediates Transp

Tricyclohexyl phosphine CAS:2622-14-2

Cas:2622-14-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Tricyclohexyl phosphine 2622-14-2

Cas:2622-14-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Tricyclohexyl phosphine Basic information Product Name: Tricyclohexyl phosphine Synonyms: PHOSPHORUS TRICYCLOHEXYL;TCHP;TRICYCLOHEXYL-PHOSPHANE;TRICYCLOHEXYLPHOSPHINE;NSC 158657;ANTI-TCHP (CENTER) antibody produced in rabbit;Protein TCHP;Trich

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:1 Gram

FOB Price: $8.0 / 10.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Tricyclohexyl phosphine CAS:2622-14-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic in

Tricyclohexyl phosphine CAS:2622-14-2

Cas:2622-14-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:1 Kilogram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:2622-14-2

Cas:2622-14-2

Min.Order:0

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:1 Kilogram

FOB Price: $40.0 / 50.0

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Tricyclohexylphospine

Cas:2622-14-2

Min.Order:0

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:100 Gram

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:0 Metric Ton

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:0

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products Tricyclohexyl phosphine

Cas:2622-14-2

Min.Order:100 Gram

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Type:Other

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Synthetic route

pyridine
110-86-1

pyridine

RuCl2(PCy3)2(=13CH2)

RuCl2(PCy3)2(=13CH2)

A

RuCl2(13CH2PCy3)(py)3

RuCl2(13CH2PCy3)(py)3

B

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In benzene-d6 at 20℃; for 0.166667h; Inert atmosphere; Glovebox;A 95%
B n/a
PCy3*BH3

PCy3*BH3

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
With methanol; 4 A molecular sieve In 1,4-dioxane at 115℃; for 42h;92%
tricyclohexylphosphonium chloride

tricyclohexylphosphonium chloride

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
With sodium hydroxide In water Product distribution / selectivity;90%
RuCl2(H2IMes)(PCy3)(=13CH2)

RuCl2(H2IMes)(PCy3)(=13CH2)

A

C18(13)CH36P(1+)*Cl(1-)

C18(13)CH36P(1+)*Cl(1-)

B

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
With pyridine In benzene-d6 at 25℃; Inert atmosphere; Glovebox;A 87%
B 13%
tricyclohexylphosphine oxide
13689-19-5

tricyclohexylphosphine oxide

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
With Bis(p-nitrophenyl) phosphate; 1,3-diphenyl-disiloxane In ethyl acetate at 23℃; for 70h; Sealed tube; chemoselective reaction;84%
Stage #1: tricyclohexylphosphine oxide With triphenyl phosphite; diphenyl hydrogen phosphite; iodine; triethylamine In tetrahydrofuran at 25℃; for 63h; Inert atmosphere; Schlenk technique;
Stage #2: With sodium hydroxide In water for 0.5h; Glovebox;
82%
With bis(2-chlorophenyl)borinic acid; phenylsilane In toluene at 80℃; for 36h; Inert atmosphere;78%
ICo(CO)2(P(C6H11)3)2
112792-41-3

ICo(CO)2(P(C6H11)3)2

diphenylphosphane sulfide
6591-07-7

diphenylphosphane sulfide

N-ethyl-N,N-diisopropylamine
7087-68-5

N-ethyl-N,N-diisopropylamine

A

N,N-diisopropylethylamine hydroiodide

N,N-diisopropylethylamine hydroiodide

B

dicarbonyl(η2-diphenylthiophosphinito)(tricyclohexylphosphane)cobalt(I)
112792-50-4

dicarbonyl(η2-diphenylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

C

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C6H5)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.;A n/a
B 71%
C n/a
bis(tricyclohexylphosphine)platinum(0)
55664-33-0

bis(tricyclohexylphosphine)platinum(0)

[(OC)3Fe(BDur){BN(SiMe3)2}]

[(OC)3Fe(BDur){BN(SiMe3)2}]

A

[(OC)3Fe{μ-BN(SiMe3)2}(μ-BDur)Pt(PCy3)]
1449520-96-0

[(OC)3Fe{μ-BN(SiMe3)2}(μ-BDur)Pt(PCy3)]

B

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In hexane Inert atmosphere; Schlenk technique; Glovebox;A 71%
B n/a
diethylphosphine sulfide
6591-06-6

diethylphosphine sulfide

ICo(CO)2(P(C6H11)3)2
112792-41-3

ICo(CO)2(P(C6H11)3)2

N-ethyl-N,N-diisopropylamine
7087-68-5

N-ethyl-N,N-diisopropylamine

A

N,N-diisopropylethylamine hydroiodide

N,N-diisopropylethylamine hydroiodide

dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)
112792-45-7

dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

C

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C2H5)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.;A n/a
B 65%
C n/a
ICo(CO)2(P(C6H11)3)2
112792-41-3

ICo(CO)2(P(C6H11)3)2

dimethylphosphine sulfide
6591-05-5

dimethylphosphine sulfide

N-ethyl-N,N-diisopropylamine
7087-68-5

N-ethyl-N,N-diisopropylamine

A

N,N-diisopropylethylamine hydroiodide

N,N-diisopropylethylamine hydroiodide

B

oligomeric dicarbonyl(μ-dimethylthiophosphinito-P,S)(tricyclohexylphosphane)cobalt(I)

oligomeric dicarbonyl(μ-dimethylthiophosphinito-P,S)(tricyclohexylphosphane)cobalt(I)

C

dicarbonyl(η2-dimethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)
112792-43-5

dicarbonyl(η2-dimethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

D

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of Me2HPS to a soln. of Co compound in toluene and dropwise addn. of (Et)(i-Pr)2N in toluene at 25°C during 2 h, 8 h; decantation, concd. in vac., addn. of n-hexane, decantation, cooled to -30°C, filtration of pptn., suspension in toluene, filtration (polymeric product), addn. of hexane to the filtrate, crystn. at -30°C; elem. anal.;A n/a
B n/a
C 46%
D n/a
ICo(CO)2(P(C6H11)3)2
112792-41-3

ICo(CO)2(P(C6H11)3)2

di(yclohexyl)phosphine sulfide
14610-03-8

di(yclohexyl)phosphine sulfide

N-ethyl-N,N-diisopropylamine
7087-68-5

N-ethyl-N,N-diisopropylamine

A

N,N-diisopropylethylamine hydroiodide

N,N-diisopropylethylamine hydroiodide

B

dicarbonyl(η2-dicyclohexylthiophosphinito)(tricyclohexylphosphane)cobalt(I)
112792-48-0

dicarbonyl(η2-dicyclohexylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

C

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C6H11)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.;A n/a
B 37%
C n/a
1-benzyl-2,2-di(2-propenyl)pyrrolidine
457605-90-2

1-benzyl-2,2-di(2-propenyl)pyrrolidine

(PCy3)2Cl2Ru=CHPh

(PCy3)2Cl2Ru=CHPh

A

styrene
100-42-5

styrene

B

dibenzyl ether
103-50-4

dibenzyl ether

C

1-benzyl-10-azaspiro[4.4]non-7-ene
457605-92-4

1-benzyl-10-azaspiro[4.4]non-7-ene

D

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In chloroform for 7h; Heating;A 4%
B 10%
C 24%
D 13%
cyclohexylmagnesiumchloride
931-51-1

cyclohexylmagnesiumchloride

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
With phosphorus trichloride
cyclohexylmagnesium bromide
931-50-0

cyclohexylmagnesium bromide

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
With phosphorus trichloride
C24H36N3O6P

C24H36N3O6P

A

1,3,5-trinitrobenzene
99-35-4

1,3,5-trinitrobenzene

B

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In dimethyl sulfoxide at 25℃; Equilibrium constant;
tricyclohexyl(dithiocarboxylato)phosphonium
70165-72-9

tricyclohexyl(dithiocarboxylato)phosphonium

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In ethanol Heating;
triphenylphosphine
603-35-0

triphenylphosphine

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
With Nb(OC6H3Ph2-2,6)2(CH2C6H4-4Me)3; hydrogen In cyclohexane at 80℃; under 62057.8 Torr; for 24h;
triphenylphosphine
603-35-0

triphenylphosphine

A

dicyclohexylphenylphosphine
6476-37-5

dicyclohexylphenylphosphine

B

cyclohexyldiphenylphosphine
6372-42-5

cyclohexyldiphenylphosphine

C

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
With n-butyllithium; hydrogen; bis(2,6-diisopropylphenoxy) trichloroniobium(V) In hexane; benzene at 60℃; under 62057.8 Torr; Kinetics; var. of catalyst;
With n-butyllithium; hydrogen; In hexane; benzene at 60℃; under 62057.8 Torr;
tributylphosphine
998-40-3

tributylphosphine

tricyclohexylphosphonium tetraphenylborate

tricyclohexylphosphonium tetraphenylborate

A

(HP(n-Bu)3)(BPh4)

(HP(n-Bu)3)(BPh4)

B

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; Equilibrium constant;
tributylphosphine
998-40-3

tributylphosphine

C32H12BF24(1-)*C18H33P*H(1+)

C32H12BF24(1-)*C18H33P*H(1+)

A

C32H12BF24(1-)*C12H27P*H(1+)

C32H12BF24(1-)*C12H27P*H(1+)

B

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; Equilibrium constant;
tri-tert-butyl phosphine
13716-12-6

tri-tert-butyl phosphine

tricyclohexylphosphonium tetraphenylborate

tricyclohexylphosphonium tetraphenylborate

A

tri-t-butylphosphonium tetraphenylborate complex

tri-t-butylphosphonium tetraphenylborate complex

B

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; Equilibrium constant;
tri-tert-butyl phosphine
13716-12-6

tri-tert-butyl phosphine

C32H12BF24(1-)*C18H33P*H(1+)

C32H12BF24(1-)*C18H33P*H(1+)

A

C32H12BF24(1-)*C12H27P*H(1+)

C32H12BF24(1-)*C12H27P*H(1+)

B

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; Equilibrium constant;
C32H12BF24(1-)*C18H33P*H(1+)

C32H12BF24(1-)*C18H33P*H(1+)

tris(1-methylethyl)phosphine
6476-36-4

tris(1-methylethyl)phosphine

A

C32H12BF24(1-)*C9H21P*H(1+)

C32H12BF24(1-)*C9H21P*H(1+)

B

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; Equilibrium constant;
1H-imidazole-1-carbothioic acid O-cyclohexyl ester
131379-54-9

1H-imidazole-1-carbothioic acid O-cyclohexyl ester

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
With tris-(trimethylsilyl)silane; triethylamine; 1,1'-azobis(1-cyanocyclohexanenitrile) In benzene for 18h; Heating;
Grubbs catalyst first generation
172222-30-9

Grubbs catalyst first generation

(2Z)-methyl 2-N-acetylaminopenta-2,4-dienoate
548490-77-3

(2Z)-methyl 2-N-acetylaminopenta-2,4-dienoate

A

C37H66Cl2NO3P2Ru

C37H66Cl2NO3P2Ru

B

C43H75Cl2NO3P2Ru

C43H75Cl2NO3P2Ru

C

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In dichloromethane-d2 at 20℃; for 2h; Reactivity; NMR tube;
tributylphosphine
998-40-3

tributylphosphine

tricyclohexylphosphine tetrafluoroborate

tricyclohexylphosphine tetrafluoroborate

A

tris[tert-butyl]phosphonium tetrafluoroborate
113978-91-9

tris[tert-butyl]phosphonium tetrafluoroborate

B

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In dichloromethane-d2 at 20℃; Equilibrium constant;
cyclohexanol
108-93-0

cyclohexanol

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrahydrofuran / 72 h / 20 °C
2: Et3N; tris(trimethylsilyl)silane; 1,1'-azobis(cyclohexane-1-carbonitrile) / benzene / 18 h / Heating
View Scheme
(1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)(PCy3)Cl2Ru=CHPh
246047-72-3

(1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)(PCy3)Cl2Ru=CHPh

2-(2-{2-[2-(pyridin-4-yloxy)-ethoxy]-ethoxy}-ethoxy)-ethanol
872085-62-6

2-(2-{2-[2-(pyridin-4-yloxy)-ethoxy]-ethoxy}-ethoxy)-ethanol

C54H75Cl2N4O10Ru

C54H75Cl2N4O10Ru

B

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
In dichloromethane for 1h;
CH3CCo3(CO)7{P(C6H11-cyclo)3}2

CH3CCo3(CO)7{P(C6H11-cyclo)3}2

A

CH3CCo3(CO)9

CH3CCo3(CO)9

B

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Conditions
ConditionsYield
With carbon monoxide quick react.;
With CO quick react.;
bis(1,3-bis-tert-butyl-imidazol-2-ylidene)palladium(0)
199447-45-5

bis(1,3-bis-tert-butyl-imidazol-2-ylidene)palladium(0)

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

(N,N-bis(tert-butyl)-imidazole-2-ylidene)Pd(PCy3)

(N,N-bis(tert-butyl)-imidazole-2-ylidene)Pd(PCy3)

Conditions
ConditionsYield
In benzene-d6 at room temp. for < 15 min;100%
(μ-H)Fe4(μ-η(2)-CH)(CO)12
76547-44-9

(μ-H)Fe4(μ-η(2)-CH)(CO)12

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

HP(C6H11)3(1+)*HFe4C(CO)12(1-)=[HP(C6H11)3][HFe4C(CO)12]

HP(C6H11)3(1+)*HFe4C(CO)12(1-)=[HP(C6H11)3][HFe4C(CO)12]

Conditions
ConditionsYield
In tetrahydrofuran; hexane N2-atmosphere; room temp. (20 h); evapn. (vac.), washing (hexanes), drying (vac.); elem. anal.;100%
In dichloromethane N2-atmosphere; room temp. (20 h); evapn. (vac.), washing (hexanes), drying (vac.); elem. anal.;
tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

dicyclohexylphosphine oxide
14717-29-4

dicyclohexylphosphine oxide

Conditions
ConditionsYield
With lithium hexafluorophosphate; air at 120℃; for 2h;100%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

(E)-2-(2,4-pentadienyl)-2-(2-propynyl)malonic acid diethyl ester
478176-00-0

(E)-2-(2,4-pentadienyl)-2-(2-propynyl)malonic acid diethyl ester

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

C39H57NiO4P

C39H57NiO4P

Conditions
ConditionsYield
In tetrahydrofuran-d8 at -20 - 20℃; for 1h;100%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-trifluoromethylphenyl triflate

2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-trifluoromethylphenyl triflate

lithium bromide
7550-35-8

lithium bromide

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

trans-bromo[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-trifluoromethylphenyl][bis(tricyclohexylphosphine)]nickel(II)

trans-bromo[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-trifluoromethylphenyl][bis(tricyclohexylphosphine)]nickel(II)

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;100%
(furan-2-yl)ethylene
1487-18-9

(furan-2-yl)ethylene

bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

phenyl isocyanate
103-71-9

phenyl isocyanate

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

(tricyclohexylphosphane)NiN(Ph)C(O)CH2CH(C4H3O)

(tricyclohexylphosphane)NiN(Ph)C(O)CH2CH(C4H3O)

Conditions
ConditionsYield
In tetrahydrofuran exclusion of air; addn. of org. compds. to soln. opf Ni-compd. in THF (-78°C), warming with stirring (-10°C, 2 d); partial evapn., addn. of pentane, filtration (-10°C), washing (cold pentane), drying (vac.); elem. anal.;99.9%
tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

tricyclohexylphosphine oxide
13689-19-5

tricyclohexylphosphine oxide

Conditions
ConditionsYield
With water; Selectfluor In acetonitrile at 20℃; for 0.166667h;99%
With 4-phenylthioxanthone In methanol at 20℃; under 760.051 Torr; for 1h; Irradiation;98%
Stage #1: tricyclohexylphosphine With water; dihydrogen peroxide In toluene at 0 - 20℃; for 12h; Inert atmosphere;
Stage #2: In toluene at 20℃; for 4h; Molecular sieve;
91%
rhodium(III)chloride
10049-07-7

rhodium(III)chloride

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

HRhCl2(tricyclohexylphosphine)2
70897-33-5, 63736-69-6

HRhCl2(tricyclohexylphosphine)2

Conditions
ConditionsYield
In water; isopropyl alcohol bubbled N2 through a stirred soln. of RhCl3; added tricyclohexylphosphine; refluxed for 18 h under stirring; filtered; washed with ethanol; dried in vacuo;99%
Pt2(CH3)2(CH3SOCH3)2C15H9N3
335370-67-7

Pt2(CH3)2(CH3SOCH3)2C15H9N3

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Pt2(CH3)2(P(C6H11)3)2C15H9N3
335370-71-3

Pt2(CH3)2(P(C6H11)3)2C15H9N3

Conditions
ConditionsYield
In dichloromethane stoichiometric amounts of phosphine, CH2Cl2, room temp., Ar; elem. anal.;99%
di-μ-chloro-bis[bis(cyclo-octene)rhodium]

di-μ-chloro-bis[bis(cyclo-octene)rhodium]

diphenyl ketene
525-06-4

diphenyl ketene

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

trans-chlorobis(tricyclohexylphosphine)(η2-C,O-diphenylketene)rhodium
365215-02-7

trans-chlorobis(tricyclohexylphosphine)(η2-C,O-diphenylketene)rhodium

Conditions
ConditionsYield
2 equiv. of Ph2CCO and 4 equiv. of P(i-Pr)3;99%
In benzene-d6 to suspn. ((μ-Cl)Rh(cyclooctene)2)2 in C6D6 were added Ph2C=C=O and P(Cy)3 and kept at room temp. for 24 h; mixt. was concd. under vac., product was crystd. from hexane; elem. anal.;96%
tris(triphenylphosphine)ruthenium(II) chloride
15529-49-4, 41756-81-4

tris(triphenylphosphine)ruthenium(II) chloride

phenyldiazomethane
908094-04-2

phenyldiazomethane

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

Grubbs catalyst first generation

Grubbs catalyst first generation

Conditions
ConditionsYield
In dichloromethane (Ar); stirring (-78 to -60°C, 5-10 min, room temp., 10 min); pptn. (MeOH);99%
(η(5)-cyclopentadienyl)W(CO)3I

(η(5)-cyclopentadienyl)W(CO)3I

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

(η(5)-cyclopentadienyl)W(CO)2(PCy3)I
206565-77-7, 206443-32-5

(η(5)-cyclopentadienyl)W(CO)2(PCy3)I

Conditions
ConditionsYield
With Me3NO In tetrahydrofuran Ar-atmosphere; 1 equiv. of Me3NO, 1 equiv. of ligand, stirring for 15 min; evapn., extn. (CH2Cl2), chromy. (TLC, CH2Cl2:hexane 1:2), recrystn. (CH2Cl2:hexane, -20°C);99%
In tetrahydrofuran Ar-atmosphere; addn. of slight excess of phosphine to W-complex soln., heating to 50°C; filtration, evapn. (reduced pressure), extn. into CH2Cl2, TLC (CH2Cl2/hexane=1:2); mixt. of isomers (cis/trans=95:5) not sepd.; elem. anal.;
cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate

cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

[(cyclopentadienyl)bis(acetonitrile)(tricyclohexylphosphine)ruthenium(II)] hexafluorophosphate
247064-70-6

[(cyclopentadienyl)bis(acetonitrile)(tricyclohexylphosphine)ruthenium(II)] hexafluorophosphate

Conditions
ConditionsYield
1 equiv. of phosphine;99%
In dichloromethane Ar-atmosphere; stirring (room temp., 2 h); evapn., filtering, washing (Et2O), drying (vac.); elem. anal.;94%
[(μ-hydrido)4(η5-cyclopentadienylruthenium(III))2]

[(μ-hydrido)4(η5-cyclopentadienylruthenium(III))2]

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

[(μ-hydrido)2(η5-cyclopentadienylruthenium(II))2P(C6H11)3]

[(μ-hydrido)2(η5-cyclopentadienylruthenium(II))2P(C6H11)3]

Conditions
ConditionsYield
In toluene equimol.;99%
Os3(μ-H)2(CO)10
41766-80-7

Os3(μ-H)2(CO)10

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

(μ-H)HOs3(CO)10(PCy3)

(μ-H)HOs3(CO)10(PCy3)

Conditions
ConditionsYield
In n-heptane; dichloromethane Ar-atmosphere; in CH2Cl2/heptane=1:10 v/v, equimolar amts., room temp. (UV-control); vol. reduction (Ar-stream), crystn. (-15°C);99%
dichloro(p-cymene)ruthenium(II) dimer

dichloro(p-cymene)ruthenium(II) dimer

C6(CH3)3(CH2OC6H4CCH)3
548490-95-5

C6(CH3)3(CH2OC6H4CCH)3

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

C6(CH3)3(CH2OC6H4CHCRu(P(C6H11)3)2Cl2)3

C6(CH3)3(CH2OC6H4CHCRu(P(C6H11)3)2Cl2)3

Conditions
ConditionsYield
In toluene the suspn. in toluene was stirred for 24 h at 80°C (Ar); the solvent was removed in vac., the residue was washed with dry methanol; elem. anal.;99%
[Ru(η5-C5H4CH2CH(Ph)-κ1P-PPh2)(acetonitrile)2]BF4
721399-48-0

[Ru(η5-C5H4CH2CH(Ph)-κ1P-PPh2)(acetonitrile)2]BF4

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

[(η5-C5H4-CH2CHPhPPh2-κP)Ru(MeCN)(PCy3)]BF4

[(η5-C5H4-CH2CHPhPPh2-κP)Ru(MeCN)(PCy3)]BF4

Conditions
ConditionsYield
In dichloromethane Ru-complex in CH2Cl2 was mixed with ligand, stirred at room temp. under N2; concd., Et2O was added dropwise, filtered; elem. anal.;99%
bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

tricyclohexylphosphinepalladium cinnamyl chloride
244159-83-9, 821786-06-5

tricyclohexylphosphinepalladium cinnamyl chloride

Conditions
ConditionsYield
In dichloromethane at 292 K; ligand added to a soln. of Pd complex, stirred for 30 min; evapd.;99%
In dichloromethane (Ar); std. Schlenk technique; soln. of P ligand (1.03 equiv.) in CH2Cl2 was canulated over 5 min to soln. of Pd complex (0.5 equiv.) in CH2Cl2; stirred for 30 min; evapd. (vac.); triturated with hexane; rinsed with hexane;75%
[((triphenylphosphane)2Pd)2(P2C(=N(iPr)2))](BF4)

[((triphenylphosphane)2Pd)2(P2C(=N(iPr)2))](BF4)

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

[((triphenylphosphane)(tricyclohexylphosphane)Pd)2(P2C(=N(iPr)2))](BF4)

[((triphenylphosphane)(tricyclohexylphosphane)Pd)2(P2C(=N(iPr)2))](BF4)

Conditions
ConditionsYield
In dichloromethane 4 equivs. of phosphine, stirring for 30 min at room temp.; evapn., washing (MePh, ether); NMR spectroscopy;99%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

trimethylsilyl trifluoromethanesulfonate
27607-77-8

trimethylsilyl trifluoromethanesulfonate

benzaldehyde
100-52-7

benzaldehyde

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

[(η1:η1-Me3SiOCH(Ph)Ni(PCy3)OTf]
907606-54-6

[(η1:η1-Me3SiOCH(Ph)Ni(PCy3)OTf]

Conditions
ConditionsYield
In benzene-d6 C6D6, room temp., 5 min;99%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

N-benzylidenephenylsulfonamide
13909-34-7

N-benzylidenephenylsulfonamide

diphenyl acetylene
501-65-5

diphenyl acetylene

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

[Ni(P(C6H11)3)(OS(C6H5)(O)NCH(C6H5)C2(C6H5)2)]
947696-31-3

[Ni(P(C6H11)3)(OS(C6H5)(O)NCH(C6H5)C2(C6H5)2)]

Conditions
ConditionsYield
In benzene-d6 at room temp., 10 min; elem. anal.;99%
di[(2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)dichlororuthenium(III)]
942516-63-4

di[(2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)dichlororuthenium(III)]

[RuCl2(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)]2
942516-63-4

[RuCl2(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)]2

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

(2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)(tricyclohexylphosphine)chlororuthenium(III)
942516-66-7

(2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)(tricyclohexylphosphine)chlororuthenium(III)

Conditions
ConditionsYield
With zinc In tetrahydrofuran byproducts: ZnCl2; (N2); addn. of PCy3 and excess Zn dust to soln. of (RuCl2(C5H(OMe)(CMe3)2(CH2CMe3)))2 in THF; stirring at ambient temp. for 12 h; filtration, removal of solvent under high vac., addn. of hexane; removalof solvent under vac., extn. with hexane; removal of hexane under vac., elem. anal.;99%
[Pd(Cl)(κ2N,C-(2,6-diisopropylphenyl)(benzylidene)amine(-1H))]2

[Pd(Cl)(κ2N,C-(2,6-diisopropylphenyl)(benzylidene)amine(-1H))]2

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

[PdCl(κ2N,C-(2,6-diisopropylphenyl)(benzylidene)amine(-1H))(PCy3)]

[PdCl(κ2N,C-(2,6-diisopropylphenyl)(benzylidene)amine(-1H))(PCy3)]

Conditions
ConditionsYield
In dichloromethane (N2); phosphine was added to soln. of Pd complex in CH2Cl2; mixt. was stirred at room temp. for 2 h; solvent evapd.; recrystd. (CH2Cl2/ether); elem. anal.;99%
[Pd(Cl)(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2
849023-64-9

[Pd(Cl)(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

[PdCl(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))(PCy3)]
849023-67-2

[PdCl(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))(PCy3)]

Conditions
ConditionsYield
In dichloromethane (N2); phosphine was added to soln. of Pd complex in CH2Cl2; mixt. was stirred at room temp. for 2 h; solvent evapd.; recrystd. (CH2Cl2/ether); elem. anal.;99%
[Pd(Cl)(kappa.2N,C-(2,6-diisopropylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2
845783-87-1

[Pd(Cl)(kappa.2N,C-(2,6-diisopropylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

[PdCl(κ2N,C-(2,6-diisopropylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))(PCy3)]
849023-69-4

[PdCl(κ2N,C-(2,6-diisopropylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))(PCy3)]

Conditions
ConditionsYield
In dichloromethane (N2); phosphine was added to soln. of Pd complex in CH2Cl2; mixt. was stirred at room temp. for 2 h; solvent evapd.; recrystd. (CH2Cl2/ether); elem. anal.;99%
[(cycloheptatrienyl)PdCl2]2

[(cycloheptatrienyl)PdCl2]2

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

cis-dichloro(cycloheptatrienylidene)(tricyclohexylphosphane)palladium(II)

cis-dichloro(cycloheptatrienylidene)(tricyclohexylphosphane)palladium(II)

Conditions
ConditionsYield
In benzene99%
tris(2,3,5,6-tetrafluorophenyl)borane triethylphosphine oxide
148892-95-9

tris(2,3,5,6-tetrafluorophenyl)borane triethylphosphine oxide

hydrogen
1333-74-0

hydrogen

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

[Cy3PH][HB(p-C6F4H)3]
1094249-97-4

[Cy3PH][HB(p-C6F4H)3]

Conditions
ConditionsYield
In not given99%
In hexane High Pressure; (N2); mixing hexane soln. of phosphine deriv. and borane deriv. in C6H5Br, freezing at -196°C, exposure to H2, warming to room temp., stirring overnight; pressure of H2 after warming to room temp. was 4 atm; evapn., recrystn. by addn. of hexanes to concd. CH2Cl2 soln. and keepingat -35°C for wk, elem. anal.;72%
silver(I) acetate
563-63-3

silver(I) acetate

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

[(PCy3)AgOAc]
1189748-30-8

[(PCy3)AgOAc]

Conditions
ConditionsYield
In toluene to suspn. AcOAg in toluene soln. Cy3P in toluene was added dropwise, stirred for 8 h; soln. was filtered through Celite and concd. in vacuo, pentane was added, ppt. was collected and dried; elem. anal.;99%
ReBr(NO)(PCy3)2H(η2-HCCPh)

ReBr(NO)(PCy3)2H(η2-HCCPh)

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

ReBr(NO)(PCy3)2(HCCHPh)

ReBr(NO)(PCy3)2(HCCHPh)

Conditions
ConditionsYield
In benzene-d6 (under N2, Schlenk); Re-complex and ligand mixed in benzene-d6, kept at 75°C for 30 min; monitored by NMR;99%
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