Tricyclohexyl phosphine supplier

Name
Tricyclohexyl phosphine
EINECS 220-069-2
CAS No. 2622-14-2
Article Data55
CAS DataBase
Density 0.909 g/mL at 25 °C
Solubility Soluble in most organic solvents. Insoluble in water.
Melting Point 81-83 °C(lit.)
Formula C₁₈H₃₃P
Boiling Point 383.434 °C at 760 mmHg
Molecular Weight 280.434
Flash Point 195.609 °C
Transport Information UN 2056 3/PG 2
Appearance white to yellow crystalline powder
Safety 26-36/37-62-37/39-36-33-29-16
Risk Codes 36/37/38-22-37/38-36-19-11-67-65-63
Molecular Structure
Hazard Symbols Xn,Xi,F
Synonyms Phosphine,tricyclohexyl-;Tricyclohexylphosphine;tricyclohexylphosphine);
PSA 13.59000
LogP 6.46640

Synthetic route

: 110-86-1
pyridine

: RuCl2(PCy3)2(=13CH2)

A: RuCl2(13CH2PCy3)(py)3

B: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In benzene-d6 at 20℃; for 0.166667h; Inert atmosphere; Glovebox;	A 95% B n/a

...Expand

: PCy3*BH3

: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
With methanol; 4 A molecular sieve In 1,4-dioxane at 115℃; for 42h;	92%

: tricyclohexylphosphonium chloride

: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
With sodium hydroxide In water Product distribution / selectivity;	90%

: RuCl2(H2IMes)(PCy3)(=13CH2)

A: C18(13)CH36P(1+)*Cl(1-)

B: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
With pyridine In benzene-d6 at 25℃; Inert atmosphere; Glovebox;	A 87% B 13%

: 13689-19-5
tricyclohexylphosphine oxide

: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
With Bis(p-nitrophenyl) phosphate; 1,3-diphenyl-disiloxane In ethyl acetate at 23℃; for 70h; Sealed tube; chemoselective reaction;	84%
Stage #1: tricyclohexylphosphine oxide With triphenyl phosphite; diphenyl hydrogen phosphite; iodine; triethylamine In tetrahydrofuran at 25℃; for 63h; Inert atmosphere; Schlenk technique; Stage #2: With sodium hydroxide In water for 0.5h; Glovebox;	82%
With bis(2-chlorophenyl)borinic acid; phenylsilane In toluene at 80℃; for 36h; Inert atmosphere;	78%

: 112792-41-3
ICo(CO)2(P(C6H11)3)2

: 6591-07-7
diphenylphosphane sulfide

: 7087-68-5
N-ethyl-N,N-diisopropylamine

A: N,N-diisopropylethylamine hydroiodide

B: 112792-50-4
dicarbonyl(η2-diphenylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

C: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C6H5)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.;	A n/a B 71% C n/a

Yield

In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C6H5)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.;

A n/a
B 71%
C n/a

...Expand

: 55664-33-0
bis(tricyclohexylphosphine)platinum(0)

: [(OC)3Fe(BDur){BN(SiMe3)2}]

A: 1449520-96-0
[(OC)3Fe{μ-BN(SiMe3)2}(μ-BDur)Pt(PCy3)]

B: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In hexane Inert atmosphere; Schlenk technique; Glovebox;	A 71% B n/a

...Expand

: 6591-06-6
diethylphosphine sulfide

: 112792-41-3
ICo(CO)2(P(C6H11)3)2

: 7087-68-5
N-ethyl-N,N-diisopropylamine

A: N,N-diisopropylethylamine hydroiodide

: 112792-45-7
dicarbonyl(η2-diethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

C: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C2H5)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.;	A n/a B 65% C n/a

Yield

In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C2H5)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.;

A n/a
B 65%
C n/a

...Expand

: 112792-41-3
ICo(CO)2(P(C6H11)3)2

: 6591-05-5
dimethylphosphine sulfide

: 7087-68-5
N-ethyl-N,N-diisopropylamine

A: N,N-diisopropylethylamine hydroiodide

B: oligomeric dicarbonyl(μ-dimethylthiophosphinito-P,S)(tricyclohexylphosphane)cobalt(I)

C: 112792-43-5
dicarbonyl(η2-dimethylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

D: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of Me2HPS to a soln. of Co compound in toluene and dropwise addn. of (Et)(i-Pr)2N in toluene at 25°C during 2 h, 8 h; decantation, concd. in vac., addn. of n-hexane, decantation, cooled to -30°C, filtration of pptn., suspension in toluene, filtration (polymeric product), addn. of hexane to the filtrate, crystn. at -30°C; elem. anal.;	A n/a B n/a C 46% D n/a

Yield

In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of Me2HPS to a soln. of Co compound in toluene and dropwise addn. of (Et)(i-Pr)2N in toluene at 25°C during 2 h, 8 h; decantation, concd. in vac., addn. of n-hexane, decantation, cooled to -30°C, filtration of pptn., suspension in toluene, filtration (polymeric product), addn. of hexane to the filtrate, crystn. at -30°C; elem. anal.;

A n/a
B n/a
C 46%
D n/a

...Expand

: 112792-41-3
ICo(CO)2(P(C6H11)3)2

: 14610-03-8
di(yclohexyl)phosphine sulfide

: 7087-68-5
N-ethyl-N,N-diisopropylamine

A: N,N-diisopropylethylamine hydroiodide

B: 112792-48-0
dicarbonyl(η2-dicyclohexylthiophosphinito)(tricyclohexylphosphane)cobalt(I)

C: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C6H11)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.;	A n/a B 37% C n/a

Yield

In toluene under N2 or Ar, exclusion of oxygen and moisture, addn. of soln. of amine in toluene to a part of soln. of Co compound in toluene at 25°C, addn. of the rest of this soln. together with (C6H11)2HPS during 2 h, 15 h; decantation, evapn. of solvent in vac., residue dissolved in n-hexane, filtration of ((Et)(i-Pr)2NH)I and excess ICo(CO)2(P(C6H11)3)2, crystn. at -5°C, recrystn. from n-hexane at -5°C; elem. anal.;

A n/a
B 37%
C n/a

...Expand

: 457605-90-2
1-benzyl-2,2-di(2-propenyl)pyrrolidine

(PCy3)2Cl2Ru=CHPh: (PCy3)2Cl2Ru=CHPh

A: 100-42-5
styrene

B: 103-50-4
dibenzyl ether

C: 457605-92-4
1-benzyl-10-azaspiro[4.4]non-7-ene

D: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In chloroform for 7h; Heating;	A 4% B 10% C 24% D 13%

...Expand

: 931-51-1
cyclohexylmagnesiumchloride

: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
With phosphorus trichloride

: 931-50-0
cyclohexylmagnesium bromide

: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
With phosphorus trichloride

: C24H36N3O6P

A: 99-35-4
1,3,5-trinitrobenzene

B: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In dimethyl sulfoxide at 25℃; Equilibrium constant;

: 70165-72-9
tricyclohexyl(dithiocarboxylato)phosphonium

: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In ethanol Heating;

: 603-35-0
triphenylphosphine

: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
With Nb(OC6H3Ph2-2,6)2(CH2C6H4-4Me)3; hydrogen In cyclohexane at 80℃; under 62057.8 Torr; for 24h;

: 603-35-0
triphenylphosphine

A: 6476-37-5
dicyclohexylphenylphosphine

B: 6372-42-5
cyclohexyldiphenylphosphine

C: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
With n-butyllithium; hydrogen; bis(2,6-diisopropylphenoxy) trichloroniobium(V) In hexane; benzene at 60℃; under 62057.8 Torr; Kinetics; var. of catalyst;
With n-butyllithium; hydrogen; In hexane; benzene at 60℃; under 62057.8 Torr;

...Expand

: 998-40-3
tributylphosphine

: tricyclohexylphosphonium tetraphenylborate

A: (HP(n-Bu)3)(BPh4)

B: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; Equilibrium constant;

...Expand

: 998-40-3
tributylphosphine

: C32H12BF24(1-)*C18H33P*H(1+)

A: C32H12BF24(1-)*C12H27P*H(1+)

B: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; Equilibrium constant;

...Expand

: 13716-12-6
tri-tert-butyl phosphine

: tricyclohexylphosphonium tetraphenylborate

A: tri-t-butylphosphonium tetraphenylborate complex

B: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; Equilibrium constant;

...Expand

: 13716-12-6
tri-tert-butyl phosphine

: C32H12BF24(1-)*C18H33P*H(1+)

A: C32H12BF24(1-)*C12H27P*H(1+)

B: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; Equilibrium constant;

...Expand

: C32H12BF24(1-)*C18H33P*H(1+)

: 6476-36-4
tris(1-methylethyl)phosphine

A: C32H12BF24(1-)*C9H21P*H(1+)

B: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; Equilibrium constant;

...Expand

: 131379-54-9
1H-imidazole-1-carbothioic acid O-cyclohexyl ester

: 16523-54-9
chlorodicyclohexylphosphane

: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
With tris-(trimethylsilyl)silane; triethylamine; 1,1'-azobis(1-cyanocyclohexanenitrile) In benzene for 18h; Heating;

: 172222-30-9
Grubbs catalyst first generation

: 548490-77-3
(2Z)-methyl 2-N-acetylaminopenta-2,4-dienoate

A: C37H66Cl2NO3P2Ru

B: C43H75Cl2NO3P2Ru

C: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In dichloromethane-d2 at 20℃; for 2h; Reactivity; NMR tube;

...Expand

: 998-40-3
tributylphosphine

: tricyclohexylphosphine tetrafluoroborate

A: 113978-91-9
tris[tert-butyl]phosphonium tetrafluoroborate

B: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In dichloromethane-d2 at 20℃; Equilibrium constant;

...Expand

: 108-93-0
cyclohexanol

: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: tetrahydrofuran / 72 h / 20 °C 2: Et3N; tris(trimethylsilyl)silane; 1,1'-azobis(cyclohexane-1-carbonitrile) / benzene / 18 h / Heating View Scheme

: 246047-72-3
(1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)(PCy3)Cl2Ru=CHPh

: 872085-62-6
2-(2-{2-[2-(pyridin-4-yloxy)-ethoxy]-ethoxy}-ethoxy)-ethanol

: C54H75Cl2N4O10Ru

B: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
In dichloromethane for 1h;

...Expand

: CH3CCo3(CO)7{P(C6H11-cyclo)3}2

A: CH3CCo3(CO)9

B: 2622-14-2
tricyclohexylphosphine

Conditions

Conditions	Yield
With carbon monoxide quick react.;
With CO quick react.;

: 199447-45-5
bis(1,3-bis-tert-butyl-imidazol-2-ylidene)palladium(0)

: 2622-14-2
tricyclohexylphosphine

: (N,N-bis(tert-butyl)-imidazole-2-ylidene)Pd(PCy3)

Conditions

Conditions	Yield
In benzene-d6 at room temp. for < 15 min;	100%

: 76547-44-9
(μ-H)Fe4(μ-η(2)-CH)(CO)12

: 2622-14-2
tricyclohexylphosphine

: HP(C6H11)3(1+)*HFe4C(CO)12(1-)=[HP(C6H11)3][HFe4C(CO)12]

Conditions

Conditions	Yield
In tetrahydrofuran; hexane N2-atmosphere; room temp. (20 h); evapn. (vac.), washing (hexanes), drying (vac.); elem. anal.;	100%
In dichloromethane N2-atmosphere; room temp. (20 h); evapn. (vac.), washing (hexanes), drying (vac.); elem. anal.;

: 2622-14-2
tricyclohexylphosphine

: 14717-29-4
dicyclohexylphosphine oxide

Conditions

Conditions	Yield
With lithium hexafluorophosphate; air at 120℃; for 2h;	100%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel (0)

: 478176-00-0
(E)-2-(2,4-pentadienyl)-2-(2-propynyl)malonic acid diethyl ester

: 2622-14-2
tricyclohexylphosphine

: C39H57NiO4P

Conditions

Conditions	Yield
In tetrahydrofuran-d8 at -20 - 20℃; for 1h;	100%

...Expand

: 1295-35-8
bis(1,5-cyclooctadiene)nickel (0)

: 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-trifluoromethylphenyl triflate

: 7550-35-8
lithium bromide

: 2622-14-2
tricyclohexylphosphine

: trans-bromo[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-trifluoromethylphenyl][bis(tricyclohexylphosphine)]nickel(II)

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;	100%

...Expand

: 1487-18-9
(furan-2-yl)ethylene

: 1295-35-8
bis(1,5-cyclooctadiene)nickel (0)

: 103-71-9
phenyl isocyanate

: 2622-14-2
tricyclohexylphosphine

: (tricyclohexylphosphane)NiN(Ph)C(O)CH2CH(C4H3O)

Conditions

Conditions	Yield
In tetrahydrofuran exclusion of air; addn. of org. compds. to soln. opf Ni-compd. in THF (-78°C), warming with stirring (-10°C, 2 d); partial evapn., addn. of pentane, filtration (-10°C), washing (cold pentane), drying (vac.); elem. anal.;	99.9%

...Expand

: 2622-14-2
tricyclohexylphosphine

: 13689-19-5
tricyclohexylphosphine oxide

Conditions

Conditions	Yield
With water; Selectfluor In acetonitrile at 20℃; for 0.166667h;	99%
With 4-phenylthioxanthone In methanol at 20℃; under 760.051 Torr; for 1h; Irradiation;	98%
Stage #1: tricyclohexylphosphine With water; dihydrogen peroxide In toluene at 0 - 20℃; for 12h; Inert atmosphere; Stage #2: In toluene at 20℃; for 4h; Molecular sieve;	91%

: 10049-07-7
rhodium(III)chloride

: 2622-14-2
tricyclohexylphosphine

: 70897-33-5, 63736-69-6
HRhCl2(tricyclohexylphosphine)2

Conditions

Conditions	Yield
In water; isopropyl alcohol bubbled N2 through a stirred soln. of RhCl3; added tricyclohexylphosphine; refluxed for 18 h under stirring; filtered; washed with ethanol; dried in vacuo;	99%

: 335370-67-7
Pt2(CH3)2(CH3SOCH3)2C15H9N3

: 2622-14-2
tricyclohexylphosphine

: 335370-71-3
Pt2(CH3)2(P(C6H11)3)2C15H9N3

Conditions

Conditions	Yield
In dichloromethane stoichiometric amounts of phosphine, CH2Cl2, room temp., Ar; elem. anal.;	99%

: di-μ-chloro-bis[bis(cyclo-octene)rhodium]

: 525-06-4
diphenyl ketene

: 2622-14-2
tricyclohexylphosphine

: 365215-02-7
trans-chlorobis(tricyclohexylphosphine)(η2-C,O-diphenylketene)rhodium

Conditions

Conditions	Yield
2 equiv. of Ph2CCO and 4 equiv. of P(i-Pr)3;	99%
In benzene-d6 to suspn. ((μ-Cl)Rh(cyclooctene)2)2 in C6D6 were added Ph2C=C=O and P(Cy)3 and kept at room temp. for 24 h; mixt. was concd. under vac., product was crystd. from hexane; elem. anal.;	96%

...Expand

: 15529-49-4, 41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: 908094-04-2
phenyldiazomethane

: 2622-14-2
tricyclohexylphosphine

: Grubbs catalyst first generation

Conditions

Conditions	Yield
In dichloromethane (Ar); stirring (-78 to -60°C, 5-10 min, room temp., 10 min); pptn. (MeOH);	99%

...Expand

: (η(5)-cyclopentadienyl)W(CO)3I

: 2622-14-2
tricyclohexylphosphine

: 206565-77-7, 206443-32-5
(η(5)-cyclopentadienyl)W(CO)2(PCy3)I

Conditions

Conditions	Yield
With Me3NO In tetrahydrofuran Ar-atmosphere; 1 equiv. of Me3NO, 1 equiv. of ligand, stirring for 15 min; evapn., extn. (CH2Cl2), chromy. (TLC, CH2Cl2:hexane 1:2), recrystn. (CH2Cl2:hexane, -20°C);	99%
In tetrahydrofuran Ar-atmosphere; addn. of slight excess of phosphine to W-complex soln., heating to 50°C; filtration, evapn. (reduced pressure), extn. into CH2Cl2, TLC (CH2Cl2/hexane=1:2); mixt. of isomers (cis/trans=95:5) not sepd.; elem. anal.;

: cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate

: 2622-14-2
tricyclohexylphosphine

: 247064-70-6
[(cyclopentadienyl)bis(acetonitrile)(tricyclohexylphosphine)ruthenium(II)] hexafluorophosphate

Conditions

Conditions	Yield
1 equiv. of phosphine;	99%
In dichloromethane Ar-atmosphere; stirring (room temp., 2 h); evapn., filtering, washing (Et2O), drying (vac.); elem. anal.;	94%

: [(μ-hydrido)4(η5-cyclopentadienylruthenium(III))2]

: 2622-14-2
tricyclohexylphosphine

: [(μ-hydrido)2(η5-cyclopentadienylruthenium(II))2P(C6H11)3]

Conditions

Conditions	Yield
In toluene equimol.;	99%

: 41766-80-7
Os3(μ-H)2(CO)10

: 2622-14-2
tricyclohexylphosphine

: (μ-H)HOs3(CO)10(PCy3)

Conditions

Conditions	Yield
In n-heptane; dichloromethane Ar-atmosphere; in CH2Cl2/heptane=1:10 v/v, equimolar amts., room temp. (UV-control); vol. reduction (Ar-stream), crystn. (-15°C);	99%

: dichloro(p-cymene)ruthenium(II) dimer

: 548490-95-5
C6(CH3)3(CH2OC6H4CCH)3

: 2622-14-2
tricyclohexylphosphine

: C6(CH3)3(CH2OC6H4CHCRu(P(C6H11)3)2Cl2)3

Conditions

Conditions	Yield
In toluene the suspn. in toluene was stirred for 24 h at 80°C (Ar); the solvent was removed in vac., the residue was washed with dry methanol; elem. anal.;	99%

...Expand

: 721399-48-0
[Ru(η5-C5H4CH2CH(Ph)-κ1P-PPh2)(acetonitrile)2]BF4

: 2622-14-2
tricyclohexylphosphine

: [(η5-C5H4-CH2CHPhPPh2-κP)Ru(MeCN)(PCy3)]BF4

Conditions

Conditions	Yield
In dichloromethane Ru-complex in CH2Cl2 was mixed with ligand, stirred at room temp. under N2; concd., Et2O was added dropwise, filtered; elem. anal.;	99%

: bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

: 2622-14-2
tricyclohexylphosphine

: 244159-83-9, 821786-06-5
tricyclohexylphosphinepalladium cinnamyl chloride

Conditions

Conditions	Yield
In dichloromethane at 292 K; ligand added to a soln. of Pd complex, stirred for 30 min; evapd.;	99%
In dichloromethane (Ar); std. Schlenk technique; soln. of P ligand (1.03 equiv.) in CH2Cl2 was canulated over 5 min to soln. of Pd complex (0.5 equiv.) in CH2Cl2; stirred for 30 min; evapd. (vac.); triturated with hexane; rinsed with hexane;	75%

: [((triphenylphosphane)2Pd)2(P2C(=N(iPr)2))](BF4)

: 2622-14-2
tricyclohexylphosphine

: [((triphenylphosphane)(tricyclohexylphosphane)Pd)2(P2C(=N(iPr)2))](BF4)

Conditions

Conditions	Yield
In dichloromethane 4 equivs. of phosphine, stirring for 30 min at room temp.; evapn., washing (MePh, ether); NMR spectroscopy;	99%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel (0)

: 27607-77-8
trimethylsilyl trifluoromethanesulfonate

: 100-52-7
benzaldehyde

: 2622-14-2
tricyclohexylphosphine

: 907606-54-6
[(η1:η1-Me3SiOCH(Ph)Ni(PCy3)OTf]

Conditions

Conditions	Yield
In benzene-d6 C6D6, room temp., 5 min;	99%

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: 1295-35-8
bis(1,5-cyclooctadiene)nickel (0)

: 13909-34-7
N-benzylidenephenylsulfonamide

: 501-65-5
diphenyl acetylene

: 2622-14-2
tricyclohexylphosphine

: 947696-31-3
[Ni(P(C6H11)3)(OS(C6H5)(O)NCH(C6H5)C2(C6H5)2)]

Conditions

Conditions	Yield
In benzene-d6 at room temp., 10 min; elem. anal.;	99%

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: 942516-63-4
di[(2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)dichlororuthenium(III)]

: 942516-63-4
[RuCl2(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)]2

: 2622-14-2
tricyclohexylphosphine

: 942516-66-7
(2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)(tricyclohexylphosphine)chlororuthenium(III)

Conditions

Conditions	Yield
With zinc In tetrahydrofuran byproducts: ZnCl2; (N2); addn. of PCy3 and excess Zn dust to soln. of (RuCl2(C5H(OMe)(CMe3)2(CH2CMe3)))2 in THF; stirring at ambient temp. for 12 h; filtration, removal of solvent under high vac., addn. of hexane; removalof solvent under vac., extn. with hexane; removal of hexane under vac., elem. anal.;	99%

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: [Pd(Cl)(κ2N,C-(2,6-diisopropylphenyl)(benzylidene)amine(-1H))]2

: 2622-14-2
tricyclohexylphosphine

: [PdCl(κ2N,C-(2,6-diisopropylphenyl)(benzylidene)amine(-1H))(PCy3)]

Conditions

Conditions	Yield
In dichloromethane (N2); phosphine was added to soln. of Pd complex in CH2Cl2; mixt. was stirred at room temp. for 2 h; solvent evapd.; recrystd. (CH2Cl2/ether); elem. anal.;	99%

: 849023-64-9
[Pd(Cl)(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2

: 2622-14-2
tricyclohexylphosphine

: 849023-67-2
[PdCl(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))(PCy3)]

Conditions

Conditions	Yield
In dichloromethane (N2); phosphine was added to soln. of Pd complex in CH2Cl2; mixt. was stirred at room temp. for 2 h; solvent evapd.; recrystd. (CH2Cl2/ether); elem. anal.;	99%

: 845783-87-1
[Pd(Cl)(kappa.2N,C-(2,6-diisopropylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2

: 2622-14-2
tricyclohexylphosphine

: 849023-69-4
[PdCl(κ2N,C-(2,6-diisopropylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))(PCy3)]

Conditions

Conditions	Yield
In dichloromethane (N2); phosphine was added to soln. of Pd complex in CH2Cl2; mixt. was stirred at room temp. for 2 h; solvent evapd.; recrystd. (CH2Cl2/ether); elem. anal.;	99%

: [(cycloheptatrienyl)PdCl2]2

: 2622-14-2
tricyclohexylphosphine

: cis-dichloro(cycloheptatrienylidene)(tricyclohexylphosphane)palladium(II)

Conditions

Conditions	Yield
In benzene	99%

: 148892-95-9
tris(2,3,5,6-tetrafluorophenyl)borane triethylphosphine oxide

: 1333-74-0
hydrogen

: 2622-14-2
tricyclohexylphosphine

: 1094249-97-4
[Cy3PH][HB(p-C6F4H)3]

Conditions

Conditions	Yield
In not given	99%
In hexane High Pressure; (N2); mixing hexane soln. of phosphine deriv. and borane deriv. in C6H5Br, freezing at -196°C, exposure to H2, warming to room temp., stirring overnight; pressure of H2 after warming to room temp. was 4 atm; evapn., recrystn. by addn. of hexanes to concd. CH2Cl2 soln. and keepingat -35°C for wk, elem. anal.;	72%

...Expand

: 563-63-3
silver(I) acetate

: 2622-14-2
tricyclohexylphosphine

: 1189748-30-8
[(PCy3)AgOAc]

Conditions

Conditions	Yield
In toluene to suspn. AcOAg in toluene soln. Cy3P in toluene was added dropwise, stirred for 8 h; soln. was filtered through Celite and concd. in vacuo, pentane was added, ppt. was collected and dried; elem. anal.;	99%

: ReBr(NO)(PCy3)2H(η2-HCCPh)

: 2622-14-2
tricyclohexylphosphine

: ReBr(NO)(PCy3)2(HCCHPh)

Conditions

Conditions	Yield
In benzene-d6 (under N2, Schlenk); Re-complex and ligand mixed in benzene-d6, kept at 75°C for 30 min; monitored by NMR;	99%

Tricyclohexyl phosphine Specification

The Tricyclohexyl phosphine, with the CAS registry number 2622-14-2,is also known as Phosphine,tricyclohexyl-. It belongs to the product categories of organophosphorus ligand;organophosphine ligand.Its EINECS number is 220-069-2. This chemical's molecular formula is C₁₈H₃₃P and molecular weight is 280.43. What's more,Its systematic name is Tricyclohexyl phosphine.It is a clear colorless to pale yellow solution.

Physical properties about Tricyclohexyl phosphine are:
(1)ACD/LogP: 6.352; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 6.35; (4)ACD/LogD (pH 7.4): 6.35; (5)ACD/BCF (pH 5.5): 39568.81; (6)ACD/BCF (pH 7.4): 39568.81; (7)ACD/KOC (pH 5.5): 67978.00; (8)ACD/KOC (pH 7.4): 67978.00; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 3; (12)Flash Point: 195.609 °C; (13)Enthalpy of Vaporization: 60.723 kJ/mol; (14)Boiling Point: 383.434 °C at 760 mmHg; (15)Vapour Pressure: 0 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES:C1CCC(CC1)P(C2CCCCC2)C3CCCCC3;
(2)Std. InChI:InChI=1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2;
(3)Std. InChIKey:WLPUWLXVBWGYMZ-UHFFFAOYSA-N.

Safety Information of Tricyclohexyl phosphine:
The Tricyclohexyl phosphine is Irritating to eyes, respiratory system and skin. It May form explosive peroxides and its Vapours may cause drowsiness and dizziness.And it may cause lung damage if swallowed. There is possible risk of harm to the unborn child.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.When you use it ,wear suitable protective clothing, gloves and eye/face protection. If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. Take precautionary measures against static discharges. This chemical is highly flammable,keep away from sources of ignition.

Product Name

Tricyclohexyl phosphine

Synthetic route

Tricyclohexyl phosphine Specification

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