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inquiryCobalt tetramethoxyphenylporphyrin CAS:28903-71-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qualit
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inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
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inquiryCobalt tetramethoxyphenylporphyrin Basic information Product Name: Cobalt tetramethoxyphenylporphyrin Synonyms: TMOPP-Co, 5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrine cobalt(II) Complex;Cobalt tetramethoxyphenylporphyrin,94%;5,10,15,20-TETRAK
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inquiryZhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed
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inquiryAppearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea
High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use
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inquiryStock products, own laboratoryAppearance:Purple to dark purple crystal Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai
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inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea
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inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
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inquiryWe product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate
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inquiryWe are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use
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inquiryTetrakis(4-methoxyphenyl)-21H,23H-porphine Cobalt(II)Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:pharmaceutical intermediate Transportation:by air, by sea, by express
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inquirycobalt(II) acetate
5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 110℃; for 1h; Inert atmosphere; | 86% |
In N,N-dimethyl-formamide for 0.00555556h; Reflux; | 67% |
In N,N-dimethyl-formamide at 150℃; for 24h; Inert atmosphere; | |
In N,N-dimethyl-formamide at 150℃; for 24h; Inert atmosphere; |
cobalt(II) acetate
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 140℃; for 12h; Inert atmosphere; | 59.4% |
In acetic acid heating of tetra4-methoxy-phenyl)-prophine and Co(II)-acetate in acetic acid;; chromatographic purification with CHCl3 as solvent; recrystallisation in a CHCl3-CH3OH-mixture;; | 33% |
In acetic acid heating of tetra4-methoxy-phenyl)-prophine and Co(II)-acetate in acetic acid;; chromatographic purification with CHCl3 as solvent; recrystallisation in a CHCl3-CH3OH-mixture;; | 33% |
cobalt(II) diacetate tetrahydrate
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
In acetic acid porphyrin was added to boiling soln. of acetate in acetic acid, mixt. was boiled for 0.5 h and kept at room temp. for 12 h; ppt. was filtered, washed with hot water, dried in air at 70°C, chromd. (silica gel, chloroform), recrystd. from chloroform-hexane mixt.; | 35% |
In acetic acid mixt. of porphin, Co salt, acetic acid refluxed; cooled; filtered; ppt. washed (hot water); dried (air, 353 K); dissolvedin CHCl3; chromd. (Al2O3); eluate evapd. to min. vol.; pptd. (MeOH); |
pyrrole
4-methoxy-benzaldehyde
cobalt(II) chloride
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
In propionic acid in situ synthesis on RB-carbon support; | 18% |
cobalt(II) chloride
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide two step procedure: absorbing of metal chloride on RB-carbon carrier followed by reaction with porphin; | 18% |
4-methoxy-benzaldehyde
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: propionic acid; acetic acid; trifluoroacetic acid; nitrobenzene / 4 h / 140 °C 2: N,N-dimethyl-formamide / 12 h / 140 °C / Inert atmosphere View Scheme | |
Multi-step reaction with 2 steps 1: propionic acid / 2 h / 145 °C / Inert atmosphere; Darkness 2: N,N-dimethyl-formamide / 24 h / 150 °C / Inert atmosphere View Scheme | |
Multi-step reaction with 2 steps 1: propionic acid / 2.25 h / 140 °C / Inert atmosphere 2: N,N-dimethyl-formamide / 1 h / 110 °C / Inert atmosphere View Scheme | |
Multi-step reaction with 2 steps 1: propionic acid / 2 h / 145 °C / Inert atmosphere; Darkness 2: N,N-dimethyl-formamide / 24 h / 150 °C / Inert atmosphere View Scheme |
oxygen
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
In benzene-d6 under 760.051 Torr; Irradiation; |
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
In benzene-d6 at 70℃; Thermodynamic data; Inert atmosphere; Darkness; |
cobalt(II) diacetate tetrahydrate
5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide Reflux; |
4-Methylanisole
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: oxygen; N-hydroxyphthalimide; cobalt(II) 5,10,15,20-tetra(o-methoxyphenyl)porphyrin complex / neat (no solvent) / 8 h / 120 °C / 7500.75 Torr / Autoclave 2: propionic acid / 2 h / 145 °C / Inert atmosphere; Darkness 3: N,N-dimethyl-formamide / 24 h / 150 °C / Inert atmosphere View Scheme |
dicobalt octacarbonyl
5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
With aluminum oxide; lithium hydroxide for 0.666667h; Milling; Green chemistry; |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
ethyl iodide
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide excess AIBN and org. substrate, sealed tube (vac.), 333 K; | 95% |
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide a soln. of the Co-complex, the organic substrate and the azocompd. in DMF was sealed in an evacuated ampoule, heated at 60°C for 180-240 min; detected by H-NMR (>95 % yield); | |
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 300 min; detected by H-NMR (<2 % yield); |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
2-methyl-3-buten-2-ol
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In chloroform excess AIBN and org. substrate, sealed tube (vac.), 333 K; | 95% |
With 2,2'-azobis(isobutyronitrile) In chloroform Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 360-420 min; detected by H-NMR (>95 % yield); | |
With 2,2'-azobis(2,4-dimethylpentanenitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, react. at 25°C for 1800-2400 min; detected by H-NMR (>95 % yield); |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile); methyl iodide In N,N-dimethyl-formamide excess AIBN and org. substrate, sealed tube (vac.), 333 K; | 95% |
With 2,2'-azobis(isobutyronitrile); methyl iodide In N,N-dimethyl-formamide a soln. of the Co-complex, the organic substrate and the azocompd. in DMF was sealed in an evacuated ampoule, heated at 60°C for 180-240 min; detected by H-NMR (>95 % yield); | |
With 2,2'-azobis(isobutyronitrile); methyl iodide In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 400 min; detected by H-NMR (5 % yield); |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
carbon monoxide
4-bromobenzenemethanol
Conditions | Yield |
---|---|
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness; | 94% |
hydrogenchloride
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
water
[5,10,15,20-tetra(p-methoxy)phenylporphyrin]cobalt(III) chloride monohydrate
Conditions | Yield |
---|---|
In methanol at 50℃; Inert atmosphere; | 93% |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
carbon monoxide
benzyl alcohol
Conditions | Yield |
---|---|
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness; | 93% |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
carbon monoxide
1-Phenylethanol
Conditions | Yield |
---|---|
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness; | 92% |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
2,4-dimethylpentan-3-one
Conditions | Yield |
---|---|
With water; triphenylphosphine In acetone at 25℃; for 1.5h; Darkness; Inert atmosphere; | 89% |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
ethanol
carbon monoxide
Conditions | Yield |
---|---|
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness; | 87% |
pyridine-4-carbonitrile
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
chloroform
Conditions | Yield |
---|---|
for 24h; | 80% |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
chloroform
hexamethylenetetramine
Conditions | Yield |
---|---|
for 4h; | 80% |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
nitrogen(II) oxide
Conditions | Yield |
---|---|
In dichloromethane absence of air and moisture; bubbling NO for 20 min; vol. reduction (boiling), pptn. on MeOH addn., decantation, drying (vac.), recrystn. (PhMe/hexane=10:1); elem. anal.; | 72% |
With piperidine In dichloromethane absence of air and moisture; excess piperidine, bubbling NO for 20 min; bubbling N2 for 2 min, vol. reduction (boiling), pptn. on MeOH addn., cooling to room temp., collection (filtration), washing (MeOH), recrystn. (CH2Cl2/hexane=1:1); | 63% |
With piperidine In dichloromethane Co-compd. dissoln., soln. degassing carefully, piperidine addn., NO bubbling into soln. for 0.5 h, NO excess removal on soln. purging with N2, heating to boiling, pptn. after MeOH addn.; ppt. filtration, vac. drying; | 50% |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
acrylic acid methyl ester
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In chloroform excess AIBN and org. substrate, sealed tube (vac.), 333 K; | 70% |
With 2,2'-azobis(isobutyronitrile) In chloroform-d1 Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in CDCl3 was sealed in an evacuated ampoule, heated at 60°C; detected by H-NMR; | |
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 90 min; detected by H-NMR (70 % yield); |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 24h; Solvent; | A 70% B n/a |
bromobenzene
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
C54H41CoN4O4
Conditions | Yield |
---|---|
With potassium hydroxide; tert-butyl alcohol In benzene at 150℃; for 1.5h; Inert atmosphere; Darkness; | 69% |
ethyloxirane
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide excess AIBN and org. substrate, sealed tube (vac.), 333 K; | 65% |
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide a soln. of the Co-complex, the organic substrate and the azocompd. in DMF was sealed in an evacuated ampoule, heated at 60°C for 180-240 min; detected by H-NMR (65 % yield); | |
With 2,2'-azobis(2,4-dimethylpentanenitrile) In N,N-dimethyl-formamide Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in DMF was sealed in an evacuated ampoule, react. at 40°C for 500-660 min; detected by H-NMR (84 % yield); | |
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 100-200 min; detected by H-NMR (<2 % yield); |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
phenylacetylene
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In chloroform excess AIBN and org. substrate, sealed tube (vac.), 333 K; | 60% |
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 80 min; detected by H-NMR (60 % yield); |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
fullerene-C60
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)*C60
Conditions | Yield |
---|---|
With ferrocene In toluene a soln. in toluene containing Co-complex, C60 and ferrocene at a 1:1:10 molar ratio, was evapd. under Ar; the solvent was decanted, crystals were washed with dry acetone; | 60% |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
With [C5H10NH2](+)[C5H10NN(O)NO](-) In dichloromethane N2-atmosphere; stirring for 30 min, then boiling; pptn. on MeOH addn., cooling to room temp., collection (filtration), washing (MeOH), drying (vac.); | 60% |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
carbon monoxide
tert-butyl alcohol
Conditions | Yield |
---|---|
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness; | 60% |
styrene
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In chloroform excess AIBN and org. substrate, sealed tube (vac.), 333 K; | 50% |
With 2,2'-azobis(isobutyronitrile) In chloroform-d1 Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in CDCl3 was sealed in an evacuated ampoule, heated at 60°C; detected by H-NMR; | |
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 90-120 min; detected by H-NMR (47 % yield); |
hydrogenchloride
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
5,10,15,20-tetra(4-methoxyphenyl) porphyrinato cobalt chloride
Conditions | Yield |
---|---|
With air In hydrogenchloride; methanol air flow was passed through suspn. of Co(II) complex in MeOH and concd. HCl for 10 h; ppt. was filtered, soln. was neutralized by concd. soln. of NH4OH; | 47% |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
water
2,3-dicyano-5,6-dichloro-p-benzoquinone
Conditions | Yield |
---|---|
In chloroform at 20℃; for 2h; | 0.6% |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
homoalylic alcohol
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, react. at 60°C for 120-150 min; detected by H-NMR (52/28 % yield); |
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
homoalylic alcohol
Conditions | Yield |
---|---|
With 2,2'-azobis(2,4-dimethylpentanenitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, react. at 40°C for 300-360 min; detected by H-NMR (>95 % yield); | |
With 2,2'-azobis(isobutyronitrile) In chloroform-d1 Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in CDCl3 was sealed in an evacuated ampoule, react. at 60°C; detected by H-NMR; |
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