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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHINE COBALT(II)

Cas:28903-71-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 28903-71-1 Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

5,10,15,10-Tetrakis-(4-methoxyphenyl)-21H,23H-porphine cobalt

Cas:28903-71-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can

Cobalt tetramethoxyphenylporphyrin CAS:28903-71-1

Cas:28903-71-1

Min.Order:1 Metric Ton

FOB Price: $520.0 / 888.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 28903-71-1 with best quality

Cas:28903-71-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Cobalt tetramethoxyphenylporphyrin 28903-71-1

Cas:28903-71-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

Cobalt tetramethoxyphenylporphyrin CAS:28903-71-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qualit

Cobalt tetramethoxyphenylporphyrin CAS:28903-71-1

Cas:28903-71-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

Cobalt(II) tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Trading Company

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Cobalt Tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

28903-71-1 Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:5 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

Cobalt tetramethoxyphenylporphyrinCAS NO.: 28903-71-1

Cas:28903-71-1

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Cobalt tetramethoxyphenylporphyrin Basic information Product Name: Cobalt tetramethoxyphenylporphyrin Synonyms: TMOPP-Co, 5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrine cobalt(II) Complex;Cobalt tetramethoxyphenylporphyrin,94%;5,10,15,20-TETRAK

Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Manufacturers

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Cobalt Tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Win-Win chemical Co.Ltd

Stock products, own laboratoryAppearance:Purple to dark purple crystal Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Cobalt tetramethoxyphenylporphyrin cas no. 28903-71-1 97%

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Other

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec [5,10,15,20-Tetrakis(4-Methoxyphenyl)Porphyrinato]Cobalt(II) 5g

Cas:28903-71-1

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

[5,10,15,20-Tetrakis(4-Methoxyphenyl)porphyrinato]cobalt(II)

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Manufacturers

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Trading Company

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DB BIOTECH CO., LTD

best seller Application:API

Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Trading Company

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BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use

[5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato]cobalt(II)

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Fandachem Co.,Ltd

Tetrakis(4-methoxyphenyl)-21H,23H-porphine Cobalt(II)Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:pharmaceutical intermediate Transportation:by air, by sea, by express

Tetrakis(4-methoxyphenyl)-21H,23H-porphine Cobalt(II)

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:Purple powder Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

Cobalt Tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Cobalt tetramethoxyphenylporphyrin

Cas:28903-71-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Synthetic route

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin
22112-78-3

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 110℃; for 1h; Inert atmosphere;86%
In N,N-dimethyl-formamide for 0.00555556h; Reflux;67%
In N,N-dimethyl-formamide at 150℃; for 24h; Inert atmosphere;
In N,N-dimethyl-formamide at 150℃; for 24h; Inert atmosphere;
5,10,15,20-meso-tetra(p-methoxyphenyl) porphyrin

5,10,15,20-meso-tetra(p-methoxyphenyl) porphyrin

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 140℃; for 12h; Inert atmosphere;59.4%
In acetic acid heating of tetra4-methoxy-phenyl)-prophine and Co(II)-acetate in acetic acid;; chromatographic purification with CHCl3 as solvent; recrystallisation in a CHCl3-CH3OH-mixture;;33%
In acetic acid heating of tetra4-methoxy-phenyl)-prophine and Co(II)-acetate in acetic acid;; chromatographic purification with CHCl3 as solvent; recrystallisation in a CHCl3-CH3OH-mixture;;33%
5,10,15,20-meso-tetra(p-methoxyphenyl) porphyrin

5,10,15,20-meso-tetra(p-methoxyphenyl) porphyrin

cobalt(II) diacetate tetrahydrate
6147-53-1

cobalt(II) diacetate tetrahydrate

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions
ConditionsYield
In acetic acid porphyrin was added to boiling soln. of acetate in acetic acid, mixt. was boiled for 0.5 h and kept at room temp. for 12 h; ppt. was filtered, washed with hot water, dried in air at 70°C, chromd. (silica gel, chloroform), recrystd. from chloroform-hexane mixt.;35%
In acetic acid mixt. of porphin, Co salt, acetic acid refluxed; cooled; filtered; ppt. washed (hot water); dried (air, 353 K); dissolvedin CHCl3; chromd. (Al2O3); eluate evapd. to min. vol.; pptd. (MeOH);
pyrrole
109-97-7

pyrrole

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions
ConditionsYield
In propionic acid in situ synthesis on RB-carbon support;18%
5,10,15,20-meso-tetra(p-methoxyphenyl) porphyrin

5,10,15,20-meso-tetra(p-methoxyphenyl) porphyrin

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions
ConditionsYield
In N,N-dimethyl-formamide two step procedure: absorbing of metal chloride on RB-carbon carrier followed by reaction with porphin;18%
4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: propionic acid; acetic acid; trifluoroacetic acid; nitrobenzene / 4 h / 140 °C
2: N,N-dimethyl-formamide / 12 h / 140 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: propionic acid / 2 h / 145 °C / Inert atmosphere; Darkness
2: N,N-dimethyl-formamide / 24 h / 150 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: propionic acid / 2.25 h / 140 °C / Inert atmosphere
2: N,N-dimethyl-formamide / 1 h / 110 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: propionic acid / 2 h / 145 °C / Inert atmosphere; Darkness
2: N,N-dimethyl-formamide / 24 h / 150 °C / Inert atmosphere
View Scheme
C85H44CoF15N8O4Sn

C85H44CoF15N8O4Sn

oxygen
80937-33-3

oxygen

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

C74H16F30N8OSn2

C74H16F30N8OSn2

Conditions
ConditionsYield
In benzene-d6 under 760.051 Torr; Irradiation;
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical
2564-83-2, 45842-10-2

2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

C85H44CoF15N8O4Sn

C85H44CoF15N8O4Sn

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

C37H8F15N4OSn

C37H8F15N4OSn

Conditions
ConditionsYield
In benzene-d6 at 70℃; Thermodynamic data; Inert atmosphere; Darkness;
cobalt(II) diacetate tetrahydrate
6147-53-1

cobalt(II) diacetate tetrahydrate

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin
22112-78-3

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions
ConditionsYield
In N,N-dimethyl-formamide Reflux;
4-Methylanisole
104-93-8

4-Methylanisole

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: oxygen; N-hydroxyphthalimide; cobalt(II) 5,10,15,20-tetra(o-methoxyphenyl)porphyrin complex / neat (no solvent) / 8 h / 120 °C / 7500.75 Torr / Autoclave
2: propionic acid / 2 h / 145 °C / Inert atmosphere; Darkness
3: N,N-dimethyl-formamide / 24 h / 150 °C / Inert atmosphere
View Scheme
5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin
22112-78-3

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions
ConditionsYield
With aluminum oxide; lithium hydroxide for 0.666667h; Milling; Green chemistry;
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

ethyl iodide
75-03-6

ethyl iodide

Co(C48H36N4O4)(C2H5)

Co(C48H36N4O4)(C2H5)

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide excess AIBN and org. substrate, sealed tube (vac.), 333 K;95%
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide a soln. of the Co-complex, the organic substrate and the azocompd. in DMF was sealed in an evacuated ampoule, heated at 60°C for 180-240 min; detected by H-NMR (>95 % yield);
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 300 min; detected by H-NMR (<2 % yield);
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

2-methyl-3-buten-2-ol
115-18-4

2-methyl-3-buten-2-ol

Co(C48H36N4O4)(CH2CH2C(CH3)2OH)

Co(C48H36N4O4)(CH2CH2C(CH3)2OH)

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In chloroform excess AIBN and org. substrate, sealed tube (vac.), 333 K;95%
With 2,2'-azobis(isobutyronitrile) In chloroform Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 360-420 min; detected by H-NMR (>95 % yield);
With 2,2'-azobis(2,4-dimethylpentanenitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, react. at 25°C for 1800-2400 min; detected by H-NMR (>95 % yield);
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Co(C48H36N4O4)(CH3)

Co(C48H36N4O4)(CH3)

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); methyl iodide In N,N-dimethyl-formamide excess AIBN and org. substrate, sealed tube (vac.), 333 K;95%
With 2,2'-azobis(isobutyronitrile); methyl iodide In N,N-dimethyl-formamide a soln. of the Co-complex, the organic substrate and the azocompd. in DMF was sealed in an evacuated ampoule, heated at 60°C for 180-240 min; detected by H-NMR (>95 % yield);
With 2,2'-azobis(isobutyronitrile); methyl iodide In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 400 min; detected by H-NMR (5 % yield);
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

carbon monoxide
201230-82-2

carbon monoxide

4-bromobenzenemethanol
873-75-6

4-bromobenzenemethanol

4-bromobenzyloxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

4-bromobenzyloxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness;94%
hydrogenchloride
7647-01-0

hydrogenchloride

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

water
7732-18-5

water

[5,10,15,20-tetra(p-methoxy)phenylporphyrin]cobalt(III) chloride monohydrate
158671-51-3

[5,10,15,20-tetra(p-methoxy)phenylporphyrin]cobalt(III) chloride monohydrate

Conditions
ConditionsYield
In methanol at 50℃; Inert atmosphere;93%
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

carbon monoxide
201230-82-2

carbon monoxide

benzyl alcohol
100-51-6

benzyl alcohol

benzyloxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

benzyloxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness;93%
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

carbon monoxide
201230-82-2

carbon monoxide

1-Phenylethanol
98-85-1, 13323-81-4

1-Phenylethanol

1-phenethyloxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

1-phenethyloxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness;92%
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

2,4-dimethylpentan-3-one
565-80-0

2,4-dimethylpentan-3-one

C52H43CoN4O5

C52H43CoN4O5

Conditions
ConditionsYield
With water; triphenylphosphine In acetone at 25℃; for 1.5h; Darkness; Inert atmosphere;89%
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

ethanol
64-17-5

ethanol

carbon monoxide
201230-82-2

carbon monoxide

ethoxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

ethoxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness;87%
pyridine-4-carbonitrile
100-48-1

pyridine-4-carbonitrile

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

chloroform
67-66-3

chloroform

C54H40CoN6O4*CHCl3

C54H40CoN6O4*CHCl3

Conditions
ConditionsYield
for 24h;80%
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

chloroform
67-66-3

chloroform

hexamethylenetetramine
100-97-0

hexamethylenetetramine

[CoII(TMPP)(HMTA)]•2CHCl3

[CoII(TMPP)(HMTA)]•2CHCl3

Conditions
ConditionsYield
for 4h;80%
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

nitrolsylcobalt(II) meso-tetra(p-methoxyphenyl)porphyrin

nitrolsylcobalt(II) meso-tetra(p-methoxyphenyl)porphyrin

Conditions
ConditionsYield
In dichloromethane absence of air and moisture; bubbling NO for 20 min; vol. reduction (boiling), pptn. on MeOH addn., decantation, drying (vac.), recrystn. (PhMe/hexane=10:1); elem. anal.;72%
With piperidine In dichloromethane absence of air and moisture; excess piperidine, bubbling NO for 20 min; bubbling N2 for 2 min, vol. reduction (boiling), pptn. on MeOH addn., cooling to room temp., collection (filtration), washing (MeOH), recrystn. (CH2Cl2/hexane=1:1);63%
With piperidine In dichloromethane Co-compd. dissoln., soln. degassing carefully, piperidine addn., NO bubbling into soln. for 0.5 h, NO excess removal on soln. purging with N2, heating to boiling, pptn. after MeOH addn.; ppt. filtration, vac. drying;50%
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

Co(C48H36N4O4)(CH(CH3)CO2CH3)

Co(C48H36N4O4)(CH(CH3)CO2CH3)

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In chloroform excess AIBN and org. substrate, sealed tube (vac.), 333 K;70%
With 2,2'-azobis(isobutyronitrile) In chloroform-d1 Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in CDCl3 was sealed in an evacuated ampoule, heated at 60°C; detected by H-NMR;
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 90 min; detected by H-NMR (70 % yield);
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

(Et4N)2[{Ni(κ2-SPh-o-NNO-p-CF3)(NO)}2]

(Et4N)2[{Ni(κ2-SPh-o-NNO-p-CF3)(NO)}2]

nitrolsylcobalt(II) meso-tetra(p-methoxyphenyl)porphyrin

nitrolsylcobalt(II) meso-tetra(p-methoxyphenyl)porphyrin

trans-(Et4N)2[Ni(SPh-o-NNO-p-CF3)2]

trans-(Et4N)2[Ni(SPh-o-NNO-p-CF3)2]

Conditions
ConditionsYield
In dichloromethane at 20℃; for 24h; Solvent;A 70%
B n/a
bromobenzene
108-86-1

bromobenzene

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

C54H41CoN4O4
571165-61-2

C54H41CoN4O4

Conditions
ConditionsYield
With potassium hydroxide; tert-butyl alcohol In benzene at 150℃; for 1.5h; Inert atmosphere; Darkness;69%
ethyloxirane
106-88-7

ethyloxirane

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Co(C48H36N4O4)(CH2CH(OH)C2H5)

Co(C48H36N4O4)(CH2CH(OH)C2H5)

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide excess AIBN and org. substrate, sealed tube (vac.), 333 K;65%
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide a soln. of the Co-complex, the organic substrate and the azocompd. in DMF was sealed in an evacuated ampoule, heated at 60°C for 180-240 min; detected by H-NMR (65 % yield);
With 2,2'-azobis(2,4-dimethylpentanenitrile) In N,N-dimethyl-formamide Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in DMF was sealed in an evacuated ampoule, react. at 40°C for 500-660 min; detected by H-NMR (84 % yield);
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 100-200 min; detected by H-NMR (<2 % yield);
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

phenylacetylene
536-74-3

phenylacetylene

Co(C48H36N4O4)(C(C6H5)CH2)

Co(C48H36N4O4)(C(C6H5)CH2)

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In chloroform excess AIBN and org. substrate, sealed tube (vac.), 333 K;60%
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 80 min; detected by H-NMR (60 % yield);
Conditions
ConditionsYield
With ferrocene In toluene a soln. in toluene containing Co-complex, C60 and ferrocene at a 1:1:10 molar ratio, was evapd. under Ar; the solvent was decanted, crystals were washed with dry acetone;60%
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

nitrolsylcobalt(II) meso-tetra(p-methoxyphenyl)porphyrin

nitrolsylcobalt(II) meso-tetra(p-methoxyphenyl)porphyrin

Conditions
ConditionsYield
With [C5H10NH2](+)[C5H10NN(O)NO](-) In dichloromethane N2-atmosphere; stirring for 30 min, then boiling; pptn. on MeOH addn., cooling to room temp., collection (filtration), washing (MeOH), drying (vac.);60%
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

carbon monoxide
201230-82-2

carbon monoxide

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyloxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

tert-butyloxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness;60%
styrene
292638-84-7

styrene

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Co(C48H36N4O4)(CH(CH3)C6H5)

Co(C48H36N4O4)(CH(CH3)C6H5)

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In chloroform excess AIBN and org. substrate, sealed tube (vac.), 333 K;50%
With 2,2'-azobis(isobutyronitrile) In chloroform-d1 Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in CDCl3 was sealed in an evacuated ampoule, heated at 60°C; detected by H-NMR;
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 90-120 min; detected by H-NMR (47 % yield);
hydrogenchloride
7647-01-0

hydrogenchloride

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

5,10,15,20-tetra(4-methoxyphenyl) porphyrinato cobalt chloride
82150-28-5

5,10,15,20-tetra(4-methoxyphenyl) porphyrinato cobalt chloride

Conditions
ConditionsYield
With air In hydrogenchloride; methanol air flow was passed through suspn. of Co(II) complex in MeOH and concd. HCl for 10 h; ppt. was filtered, soln. was neutralized by concd. soln. of NH4OH;47%
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

water
7732-18-5

water

2,3-dicyano-5,6-dichloro-p-benzoquinone
84-58-2

2,3-dicyano-5,6-dichloro-p-benzoquinone

C48H36CoN4O4(1+)*CN(1-)*H2O

C48H36CoN4O4(1+)*CN(1-)*H2O

Conditions
ConditionsYield
In chloroform at 20℃; for 2h;0.6%
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

homoalylic alcohol
627-27-0

homoalylic alcohol

Co(C20N4H8(C6H4OCH3)4)(CH2(CH2)3OH)

Co(C20N4H8(C6H4OCH3)4)(CH2(CH2)3OH)

Co(C20N4H8(C6H4OCH3)4)(CH(CH3)(CH2)2OH)

Co(C20N4H8(C6H4OCH3)4)(CH(CH3)(CH2)2OH)

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, react. at 60°C for 120-150 min; detected by H-NMR (52/28 % yield);
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)
28903-71-1

(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

homoalylic alcohol
627-27-0

homoalylic alcohol

Co(C20N4H8(C6H4OCH3)4)(CH(CH3)(CH2)2OH)

Co(C20N4H8(C6H4OCH3)4)(CH(CH3)(CH2)2OH)

Conditions
ConditionsYield
With 2,2'-azobis(2,4-dimethylpentanenitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, react. at 40°C for 300-360 min; detected by H-NMR (>95 % yield);
With 2,2'-azobis(isobutyronitrile) In chloroform-d1 Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in CDCl3 was sealed in an evacuated ampoule, react. at 60°C; detected by H-NMR;

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