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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Boroxin,2,4,6-triphenyl-

Cas:3262-89-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Triphenyl boroxine

Cas:3262-89-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

3262-89-3 (Boroxin,2,4,6-triphenyl- )

Cas:3262-89-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 3262-89-3 with competitive price

Cas:3262-89-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Boroxin,2,4,6-triphenyl-

Cas:3262-89-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Boroxin,2,4,6-triphenyl-

Cas:3262-89-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Boroxin,2,4,6-triphenyl-

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Boroxin,2,4,6-triphenyl-

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

TRIPHENYLBOROXIN

Cas:3262-89-3

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

3262-89-3 CAS NO.3262-89-3

Cas:3262-89-3

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

3262-89-3

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou SuKaiLu Chemical Technology Co., Ltd.

Our Company main product 一:suzuki reaction customization 二:Boronic acid derivative ①:phenylboronic acid derivative ②:Phenylboronic acid pinacol ester derivative ③:Potassium phenyltrifluoroborate derivative ④:Phenylboronic acid MIDA ester derivative

TRIPHENYLBOROXIN

Cas:3262-89-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2,4,6-Triphenylboroxin

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high qualityAppearance:white crystalline powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

(1S)-(-)-(1-AMINO-2-METHYLPROPYL)PHOSPHONIC ACID

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

2,4,6-Triphenylboroxin

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Triphenylboroxin

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Pharm intermediate

TRIPHENYLBOROXIN

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

3262-89-3

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

TRIPHENYLBOROXIN

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:5g Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any port

Phenyl Boronic Acid Anhydride

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2,4,6-triphenyl-1,3,5,2,4,6-trioxatriborinane

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

3262-89-3

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

TRIPHENYLBOROXIN

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

TRIPHENYLBOROXIN

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

N-(2-bromo-4-chlorophenyl)-1-methyl-2-pyrrolidinimine

Cas:3262-89-3

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

TRIPHENYLBOROXIN

Cas:3262-89-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

Triphenyl boroxine

Cas:3262-89-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

Boroxin,2,4,6-triphenyl- CAS NO.3262-89-3

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuhan Sun-shine Bio-technology Corporation Limited

Wuhan Sun-shine Bio-technology Corporation Limited is specializing in the anticancer, antitumor,heart head blood-vessel,pharmaceutical intermediates,fine Chemicals production and customization..Company has strong ability of research and development,

TRIPHENYLBOROXIN

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Fine Chemicals Co., Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & CommercialHenan Fine Chemicals Co., LTD. is a diversified technology - oriented integrated company, which mainly concentrates on fine chemicals. Our company is committed to becom

Boroxin,2,4,6-triphenyl-

Cas:3262-89-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

phenylboronic acid
98-80-6

phenylboronic acid

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
at 110℃; for 6h;100%
at 110℃; for 6h; Inert atmosphere; Neat (no solvent);100%
Stage #1: phenylboronic acid With barium(II) hydroxide In water at 80℃; for 0.0833333h;
Stage #2: With Au38(SCH2CH2Ph)24 In toluene at 80℃; for 12h; Reagent/catalyst;
100%
N-(4-chlorobenzylidene)-4-methylbenzenesulfonamide
357417-22-2

N-(4-chlorobenzylidene)-4-methylbenzenesulfonamide

phenylboronic acid
98-80-6

phenylboronic acid

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
In toluene for 12h; Dean-Stark; Reflux;99%
boron trioxide

boron trioxide

triphenylborane
960-71-4

triphenylborane

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
In neat (no solvent) refluxing equimolar amounts for 48h;; dissolving in CCl4,;91%
In neat (no solvent)
iodobenzene
591-50-4

iodobenzene

phenylboronic acid
98-80-6

phenylboronic acid

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

biphenyl
92-52-4

biphenyl

Conditions
ConditionsYield
With potassium carbonate In ethanol at 78℃; for 1h; Catalytic behavior; Reagent/catalyst; Suzuki-Miyaura Coupling;A n/a
B 87%
With potassium carbonate In ethanol at 78℃; for 1h; Suzuki-Miyaura Coupling;A 49%
B 6%
dimethylsulfide borane complex
13292-87-0

dimethylsulfide borane complex

phenol
108-95-2

phenol

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
With water; pyridin-2-ylmethyl methanesulphonate In tetrahydrofuran; toluene at 90℃; for 0.666667h; Temperature; Inert atmosphere;80.26%
diphenyl(diethylamino)borane
7397-50-4

diphenyl(diethylamino)borane

N,N'-Bis-(diphenylboryl)-hydrazin
7360-71-6

N,N'-Bis-(diphenylboryl)-hydrazin

(n-C4H9)2BNHNC6H5B(n-C4H9)2
101550-01-0

(n-C4H9)2BNHNC6H5B(n-C4H9)2

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
byproducts: (C6H5)2CNNC(C6H5)2; 80°C, reflux, 1.5 h;75%
byproducts: (C6H5)2CNNC(C6H5)2; 80°C, reflux, 1.5 h;75%
2-phenyl-4H-benzo-1,3,2-dioxaborine
18885-85-3

2-phenyl-4H-benzo-1,3,2-dioxaborine

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

9',9'A-dihydro-4'aH-spiro[chroman-2,1'-xanthen]-2'-one
100152-08-7

9',9'A-dihydro-4'aH-spiro[chroman-2,1'-xanthen]-2'-one

C

C28H24O4
136352-96-0

C28H24O4

Conditions
ConditionsYield
at 900℃; under 0.005 Torr;A 70%
B 12%
C 31%
piperazine
110-85-0

piperazine

phenylboronic acid
98-80-6

phenylboronic acid

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

4-phenyl-1-piperazine
92-54-6

4-phenyl-1-piperazine

C

biphenyl
92-52-4

biphenyl

Conditions
ConditionsYield
With [Cu4I4(1,4-diazabicyclo[2.2.2]octane)2]n In methanol at 27℃; for 5h;A 9 %Chromat.
B 68%
C 20 %Chromat.
2,4-diphenylbenzo[j]-9-methyl-8-aza-1,3,5,2,4-trioxadiboracycloundec-8-ene
1309575-95-8

2,4-diphenylbenzo[j]-9-methyl-8-aza-1,3,5,2,4-trioxadiboracycloundec-8-ene

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

(rac)-2-(phenyl)benzo[j]-7-methyl-6-aza-1,3-dioxa-2-boracyclononen-6-ene
1309575-94-7

(rac)-2-(phenyl)benzo[j]-7-methyl-6-aza-1,3-dioxa-2-boracyclononen-6-ene

Conditions
ConditionsYield
In toluene for 24h; Reflux; diastereoselective reaction;A n/a
B 60%
2,4-diphenylbenzo[j]-9-methyl-8-aza-1,3,5,2,4-trioxadiboracycloundec-8-ene
1309575-95-8

2,4-diphenylbenzo[j]-9-methyl-8-aza-1,3,5,2,4-trioxadiboracycloundec-8-ene

phenylboronic acid
98-80-6

phenylboronic acid

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

(rac)-2-(phenyl)benzo[j]-7-methyl-6-aza-1,3-dioxa-2-boracyclononen-6-ene
1309575-94-7

(rac)-2-(phenyl)benzo[j]-7-methyl-6-aza-1,3-dioxa-2-boracyclononen-6-ene

Conditions
ConditionsYield
In toluene soln. of C6H4C(CH3)N(C2H4OB(C6H5)O)B(C6H5) refluxed for 24 h; solvent and water eliminated, residue washed with CH3Cl, recrystd. from chloroform; elem. anal.;A n/a
B 60%
phenylboronic acid
98-80-6

phenylboronic acid

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

biphenyl
92-52-4

biphenyl

C

phenol
108-95-2

phenol

Conditions
ConditionsYield
With bis(acetylacetonate)nickel(II); potassium phosphate; oxygen In tetrahydrofuran for 12h; Inert atmosphere; Reflux;A 60%
B 20%
C 10%
phenylboronic acid
98-80-6

phenylboronic acid

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

biphenyl
92-52-4

biphenyl

C

[18O]phenol
1739-18-0

[18O]phenol

Conditions
ConditionsYield
With bis(acetylacetonate)nickel(II); potassium phosphate; oxygen-18 In tetrahydrofuran for 12h; Reflux;A 33%
B 12%
C 42%
2,5-diphenyl-1,3,2,5-dioxaborataphosphorinane
72729-56-7

2,5-diphenyl-1,3,2,5-dioxaborataphosphorinane

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
With methyl iodide In diethyl ether byproducts: bis(hydroxymethyl)methyl(phenyl)phosphonium iodide; heated for 1 h at reflux with protection from atmospheric moisture; solvent removed; residue crystd. (acetone); IR; NMR; elem. anal.;40%
(trifluoromethyl)trimethylsilane
81290-20-2

(trifluoromethyl)trimethylsilane

phenylboronic acid
98-80-6

phenylboronic acid

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

phenyl trifluoromethylsulfide
456-56-4

phenyl trifluoromethylsulfide

C

diphenyldisulfane
882-33-7

diphenyldisulfane

Conditions
ConditionsYield
With potassium fluoride; potassium phosphate; copper(l) iodide; 1,10-Phenanthroline; sulfur; silver carbonate In N,N-dimethyl-formamide at 20℃; Molecular sieve;A n/a
B 33%
C n/a
boric acid tributyl ester
688-74-4

boric acid tributyl ester

phenylmagnesium bromide

phenylmagnesium bromide

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
at 230℃;
diphenylborinic acid
2622-89-1

diphenylborinic acid

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

benzene
71-43-2

benzene

Conditions
ConditionsYield
at 175℃;
triphenylborane
960-71-4

triphenylborane

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
With boron trioxide
phenylborondichloride
873-51-8

phenylborondichloride

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
Einwirkung von Luftfeuchtigkeit;
Multi-step reaction with 2 steps
1: H2S2 / CS2
2: (hydrolysis)
View Scheme
Multi-step reaction with 2 steps
1: diethyl ether
2: SO2
View Scheme
benzyloxy-chloro-phenyl-borane
100375-51-7

benzyloxy-chloro-phenyl-borane

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

benzyl chloride
100-44-7

benzyl chloride

Conditions
ConditionsYield
Beim Aufbewahren;
room. temp., 1 day;
diphenylmercury(II)
587-85-9

diphenylmercury(II)

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With boron trichloride; benzene at 180 - 200℃; ueber mehrere Stufen;
3,5-diphenyl-1,2,4,3,5-trithiaborolane
17381-62-3

3,5-diphenyl-1,2,4,3,5-trithiaborolane

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
(hydrolysis);
hydrogen (μ-3-cyclohexyl-1,3-diaza-spiro[4.5]deca-1,3-dienium-2,4-diyl)-hexaphenyl-bis-borate(1-)

hydrogen (μ-3-cyclohexyl-1,3-diaza-spiro[4.5]deca-1,3-dienium-2,4-diyl)-hexaphenyl-bis-borate(1-)

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
With sulfuric acid In 1,4-dioxane Heating;
boric acid tributyl ester
688-74-4

boric acid tributyl ester

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

magnesium

magnesium

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

1-butylene
106-98-9

1-butylene

C

(Z)-2-Butene
590-18-1

(Z)-2-Butene

D

trans-2-Butene
624-64-6

trans-2-Butene

phenylboronic acid
98-80-6

phenylboronic acid

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

water
7732-18-5

water

Conditions
ConditionsYield
bei der Destillation;
In neat (no solvent) on standing at room temp., reversible react.;;
In neat (no solvent)
In tetrahydrofuran-d8 at 25℃; Equilibrium constant;
diphenylmercury(II)
587-85-9

diphenylmercury(II)

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: benzene; boron trichloride / 180 - 200 °C / ueber mehrere Stufen
2: Einwirkung von Luftfeuchtigkeit
View Scheme
3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

phenylboronic acid
98-80-6

phenylboronic acid

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

C20H19B3O3

C20H19B3O3

C

C22H23B3O3

C22H23B3O3

D

tris(3.5-dimethyl phenyl)boroxine
34907-38-5

tris(3.5-dimethyl phenyl)boroxine

Conditions
ConditionsYield
With water at 25℃;
phenylborondichloride
873-51-8

phenylborondichloride

water
7732-18-5

water

triphenylboroxine
3262-89-3

triphenylboroxine

Conditions
ConditionsYield
dehydration at 115°C;;
phenylboronic acid
98-80-6

phenylboronic acid

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

benzene
71-43-2

benzene

Conditions
ConditionsYield
In neat (no solvent) on heating in vac.;;
In neat (no solvent)
diiodophenylborane
17381-60-1

diiodophenylborane

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

triphenylboroxine
3262-89-3

triphenylboroxine

triphenylboroxine
3262-89-3

triphenylboroxine

benzyl (3,5-dimethylphenyl)carbamate

benzyl (3,5-dimethylphenyl)carbamate

N-(3,5-dimethylphenyl)-benzamide
25050-22-0

N-(3,5-dimethylphenyl)-benzamide

Conditions
ConditionsYield
With potassium fluoride; chloro(1,5-cyclooctadiene)rhodium(I) dimer In 1,4-dioxane at 100℃; for 24h; Inert atmosphere; Sealed tube;100%
With potassium fluoride; chloro(1,5-cyclooctadiene)rhodium(I) dimer In 1,4-dioxane at 100℃; for 24h;100%
triphenylboroxine
3262-89-3

triphenylboroxine

N-(4-chlorobenzylidene)-4-methylbenzenesulfonamide
357417-22-2

N-(4-chlorobenzylidene)-4-methylbenzenesulfonamide

A

(R)-N-((4-chlorophenyl)(phenyl)methyl)-4-methylbenzenesulfonamide
796966-21-7

(R)-N-((4-chlorophenyl)(phenyl)methyl)-4-methylbenzenesulfonamide

B

(S)-N-((4-chlorophenyl)(phenyl)methyl)-4-methylbenzenesulfonamide
796966-17-1

(S)-N-((4-chlorophenyl)(phenyl)methyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With di-μ-chloro-bis[(η5-(4`R,5`R)-(Sp)-2-(2`-4`,5`-dihydro-4`,5`-diphenyl-1`-tosyl-1`H-imidazolyl)cyclopentadienyl,1-C,3`-N)(η5-cyclopentadienyl)-iron(II)]dipalladium(II); silver(I) acetate In chlorobenzene at 65℃; for 20h; Inert atmosphere;A 100%
B 11%
triphenylboroxine
3262-89-3

triphenylboroxine

(E)-N-(furan-2-ylmethylene)-4-methylbenzenesulfonamide
135822-87-6

(E)-N-(furan-2-ylmethylene)-4-methylbenzenesulfonamide

(S)-N-((furan-2-yl(phenyl)methyl)-4-methylbenzenesulfonamide)
158471-23-9

(S)-N-((furan-2-yl(phenyl)methyl)-4-methylbenzenesulfonamide)

Conditions
ConditionsYield
With potassium hydroxide; bis(ethylene)rhodium(I) chloride dimer; (1R,4R)-2,5-diphenylbicyclo[2.2.2]octa-2,5-diene In 1,4-dioxane at 60℃; for 6h;99%
triphenylboroxine
3262-89-3

triphenylboroxine

(S)-3-methyl-2-[(napthalen-1ylmethyl)-amino]-1,1-diphenyl-butan-1-ol
850661-64-2

(S)-3-methyl-2-[(napthalen-1ylmethyl)-amino]-1,1-diphenyl-butan-1-ol

(4S)-4-(1-methylethyl)-3-(1-naphthalenylmethyl)-2,5,5-triphenyl-1,3,2-oxazaborolidine

(4S)-4-(1-methylethyl)-3-(1-naphthalenylmethyl)-2,5,5-triphenyl-1,3,2-oxazaborolidine

Conditions
ConditionsYield
In toluene microwave irradiation;99%
With 4 A molecular sieve In toluene for 15h; microwave heating;
In toluene at 200℃; Molecular sieve; Inert atmosphere; Microwave irradiation;
triphenylboroxine
3262-89-3

triphenylboroxine

(2S)-3-methyl-2-[(octyl)amino]-1,1-diphenyl-butan-1-ol
850661-63-1

(2S)-3-methyl-2-[(octyl)amino]-1,1-diphenyl-butan-1-ol

(S)-4-Isopropyl-3-octyl-2,5,5-triphenyl-[1,3,2]oxazaborolidine

(S)-4-Isopropyl-3-octyl-2,5,5-triphenyl-[1,3,2]oxazaborolidine

Conditions
ConditionsYield
In toluene microwave irradiation;99%
triphenylboroxine
3262-89-3

triphenylboroxine

ortho-anisaldehyde
135-02-4

ortho-anisaldehyde

2-methoxyphenyl(phenyl)methanol
22788-49-4

2-methoxyphenyl(phenyl)methanol

Conditions
ConditionsYield
With sodium t-butanolate; bis(1,5-cyclooctadiene)nickel (0) In 1,2-dimethoxyethane; water at 100℃; for 48h;99%
With bis(1,5-cyclooctadiene)nickel(0); (+/-)-Et-Duphos; sodium t-butanolate In 1,2-dimethoxyethane; water at 100℃; for 48h;99%
Stage #1: triphenylboroxine With bis(1,5-cyclooctadiene)nickel(0); potassium phosphate; 4-chlorobenzophenone In tetrahydrofuran at 20℃;
Stage #2: ortho-anisaldehyde In tetrahydrofuran at 20℃;
85%
triphenylboroxine
3262-89-3

triphenylboroxine

3-methoxy-benzaldehyde
591-31-1

3-methoxy-benzaldehyde

Conditions
ConditionsYield
With sodium t-butanolate; bis(1,5-cyclooctadiene)nickel (0) In 1,2-dimethoxyethane; water at 100℃; for 48h;99%
With bis(1,5-cyclooctadiene)nickel(0); (+/-)-Et-Duphos; sodium t-butanolate In 1,2-dimethoxyethane; water at 100℃; for 48h;99%
triphenylboroxine
3262-89-3

triphenylboroxine

(2E,4E)-N,N-diphenyl-2,4-hexadienamide
61859-44-7

(2E,4E)-N,N-diphenyl-2,4-hexadienamide

C24H25NO

C24H25NO

Conditions
ConditionsYield
Stage #1: triphenylboroxine; (2E,4E)-N,N-diphenyl-2,4-hexadienamide With [IrCl((S,S)-Me-tfb*)]2; potassium carbonate In methanol at 30℃; for 20h;
Stage #2: With Crabtree's catalyst; hydrogen In dichloromethane at 20℃; under 760.051 Torr; for 12h; optical yield given as %ee; enantioselective reaction;
99%
triphenylboroxine
3262-89-3

triphenylboroxine

3-methylcyclohexen-2-one
1193-18-6

3-methylcyclohexen-2-one

(R)-3-methyl-3-phenylcyclohexan-1-one
905832-87-3

(R)-3-methyl-3-phenylcyclohexan-1-one

Conditions
ConditionsYield
Stage #1: triphenylboroxine; 3-methylcyclohexen-2-one With 2C24H14F4*2HO(1-)*2Rh(1+) In 1,4-dioxane at 60℃; for 24h; Inert atmosphere;
Stage #2: With water In 1,4-dioxane Inert atmosphere; optical yield given as %ee; enantioselective reaction;
99%
triphenylboroxine
3262-89-3

triphenylboroxine

3-hydroxy-3-(4-methoxyphenyl)-2,3-dihydro-1H-isoindol-1-one
92553-10-1

3-hydroxy-3-(4-methoxyphenyl)-2,3-dihydro-1H-isoindol-1-one

C22H19NO2

C22H19NO2

Conditions
ConditionsYield
With C64H46F8Fe4O2Rh2 In 1,4-dioxane at 80℃; for 24h; Schlenk technique; Inert atmosphere; enantioselective reaction;99%
triphenylboroxine
3262-89-3

triphenylboroxine

3-methylcyclohexen-2-one
1193-18-6

3-methylcyclohexen-2-one

C13H15(2)HO

C13H15(2)HO

Conditions
ConditionsYield
Stage #1: triphenylboroxine With ammonium hexafluorophosphate; palladium(II) trifluoroacetate; 2-[(S)-4,5-dihydro-4-tert-butyl-1,3-oxazol-2-yl]pyridine In 1,2-dichloro-ethane at 20℃; for 0.0333333h; Glovebox;
Stage #2: 3-methylcyclohexen-2-one With water-d2 In 1,2-dichloro-ethane for 12h; Glovebox; enantioselective reaction;
99%
triphenylboroxine
3262-89-3

triphenylboroxine

2-furaldehyde tosylimine
13707-47-6

2-furaldehyde tosylimine

(S)-N-((furan-2-yl(phenyl)methyl)-4-methylbenzenesulfonamide)
158471-23-9

(S)-N-((furan-2-yl(phenyl)methyl)-4-methylbenzenesulfonamide)

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; (S)-(-)-[η5-1-bis(3,5-di(trifluormethylphenyl)phosphino-2-(3-diphenylphosphino-2-methylpropenyl)cyclopentadienyl-P)]manganese(I) dicarbonyl; potassium hydroxide In 1,4-dioxane; water at 40℃; for 7h; Reagent/catalyst; Inert atmosphere; enantioselective reaction;99%
With chlorobis(ethylene)rhodium(I) dimer; potassium hydroxide; (1R,4R)-2,5-diphenylbicyclo[2.2.2]octa-2,5-diene In 1,4-dioxane; water at 60℃; for 6h;97%
With chlorobis(ethylene)rhodium(I) dimer; potassium hydroxide; (1R,4R)-2,5-diphenylbicyclo[2.2.2]octa-2,5-diene In 1,4-dioxane; water at 20 - 60℃; for 6.25h; Inert atmosphere;97%
triphenylboroxine
3262-89-3

triphenylboroxine

3-butyl-1,2-benzisothiazole-1,1-dioxide
55379-09-4

3-butyl-1,2-benzisothiazole-1,1-dioxide

(R)-3-butyl-3-phenyl-2,3-dihydrobenzo[d]isothiazole 1,1-dioxide

(R)-3-butyl-3-phenyl-2,3-dihydrobenzo[d]isothiazole 1,1-dioxide

Conditions
ConditionsYield
Stage #1: triphenylboroxine; 3-butyl-1,2-benzisothiazole-1,1-dioxide With chlorobis(cyclooctene)rhodium(I) dimer; C18H23NOS In 1,2-dichloro-ethane at 20℃; for 0.5h; Inert atmosphere;
Stage #2: With potassium hydroxide In water; 1,2-dichloro-ethane at 60℃; for 12h; Inert atmosphere; enantioselective reaction;
99%
triphenylboroxine
3262-89-3

triphenylboroxine

3-benzyl-1,2-benzisothiazole-1,1-dioxide
131556-56-4

3-benzyl-1,2-benzisothiazole-1,1-dioxide

(R)-3-benzyl-3-phenyl-2,3-dihydrobenzo[d]isothiazole 1,1-dioxide

(R)-3-benzyl-3-phenyl-2,3-dihydrobenzo[d]isothiazole 1,1-dioxide

Conditions
ConditionsYield
Stage #1: triphenylboroxine; 3-benzyl-1,2-benzisothiazole-1,1-dioxide With chlorobis(cyclooctene)rhodium(I) dimer; C18H23NOS In 1,2-dichloro-ethane at 20℃; for 0.5h; Inert atmosphere;
Stage #2: With potassium hydroxide In water; 1,2-dichloro-ethane at 60℃; for 12h; Inert atmosphere; enantioselective reaction;
99%
triphenylboroxine
3262-89-3

triphenylboroxine

3-cyclohexyl-1,2-benziothiazole-1,1-dioxide

3-cyclohexyl-1,2-benziothiazole-1,1-dioxide

(R)-3-cyclohexyl-3-phenyl-2,3-dihydrobenzo[d]isothiazole 1,1-dioxide

(R)-3-cyclohexyl-3-phenyl-2,3-dihydrobenzo[d]isothiazole 1,1-dioxide

Conditions
ConditionsYield
Stage #1: triphenylboroxine; 3-cyclohexyl-1,2-benziothiazole-1,1-dioxide With chlorobis(cyclooctene)rhodium(I) dimer; C18H23NOS In 1,2-dichloro-ethane at 20℃; for 0.5h; Inert atmosphere;
Stage #2: With potassium hydroxide In water; 1,2-dichloro-ethane at 60℃; for 12h; Inert atmosphere; enantioselective reaction;
99%
triphenylboroxine
3262-89-3

triphenylboroxine

3-methylbenzo[d]isothiazole-1,1-dioxide
34989-82-7

3-methylbenzo[d]isothiazole-1,1-dioxide

(R)-3-methyl-3-phenyl-2,3-dihydrobenzo[d]isothiazole 1,1-dioxide

(R)-3-methyl-3-phenyl-2,3-dihydrobenzo[d]isothiazole 1,1-dioxide

Conditions
ConditionsYield
Stage #1: triphenylboroxine; 3-methylbenzo[d]isothiazole-1,1-dioxide With chlorobis(cyclooctene)rhodium(I) dimer; C18H23NOS In 1,2-dichloro-ethane at 20℃; for 0.5h; Inert atmosphere;
Stage #2: With potassium hydroxide In water; 1,2-dichloro-ethane at 60℃; for 12h; Inert atmosphere; enantioselective reaction;
99%
triphenylboroxine
3262-89-3

triphenylboroxine

N-(4-chlorobenzylidene)-4-methylbenzenesulfonamide
357417-22-2

N-(4-chlorobenzylidene)-4-methylbenzenesulfonamide

(R)-N-((4-chlorophenyl)(phenyl)methyl)-4-methylbenzenesulfonamide
796966-21-7

(R)-N-((4-chlorophenyl)(phenyl)methyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With di-μ-chlorobis[η5-(4'R,5'R)-(Sp)-2-(2'-4',5'-dihydro-4',5'-diphenyl-1'-tosyl-1'H-imidazolyl)cyclopentadienyl, (1-C,3'-N)(η5-cyclopentadienyl)-iron(II)]dipalladium(II); silver(I) acetate In chlorobenzene; acetonitrile at 65℃; for 20h; Reagent/catalyst; Temperature; Inert atmosphere; enantioselective reaction;99%
With di-μ-chloro-bis[(η5-(4`R,5`R)-(Sp)-2-(2`-4`,5`-dihydro-4`,5`-diphenyl-1`-tosyl-1`H-imidazolyl)cyclopentadienyl,1-C,3`-N)(η5-cyclopentadienyl)-iron(II)]dipalladium(II); silver(I) acetate In chlorobenzene at 65℃; for 20h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere; Schlenk technique; enantioselective reaction;99%
With chlorobis(ethylene)rhodium(I) dimer; (R)-4-isopropyl-3-((1R,4S)-3-phenylbicyclo[2.2.1]hepta-2,5-diene-2-carbonyl)oxazolidin-2-one; potassium hydroxide; n-octyl β-D-glucopyranoside In 1,4-dioxane; water at 29.84℃; for 1h; Reagent/catalyst; Solvent; Inert atmosphere;99%
triphenylboroxine
3262-89-3

triphenylboroxine

N-(2-methylphenyl)methylidene-4-methylbenzenesulfonamide
343598-64-1

N-(2-methylphenyl)methylidene-4-methylbenzenesulfonamide

(S)-N-[(2-methylphenyl)phenylmethyl]-4-methylbenzenesulfonamide
738626-20-5

(S)-N-[(2-methylphenyl)phenylmethyl]-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; potassium hydroxide In tetrahydrofuran at 60℃; for 24h; enantioselective reaction;99%
With [{(M,SS,SS)-p-Tol-binaso}Rh(OH)]2 In water; toluene at 25℃; for 14h; Glovebox; Sealed tube; Inert atmosphere; enantioselective reaction;95%
triphenylboroxine
3262-89-3

triphenylboroxine

N-[1-(3-Methoxy-phenyl)-meth-(E)-ylidene]-4-methyl-benzenesulfonamide
160955-96-4

N-[1-(3-Methoxy-phenyl)-meth-(E)-ylidene]-4-methyl-benzenesulfonamide

(S)-N-((3-methoxyphenyl)(phenyl)methyl)-4-methylbenzenesulfonamide

(S)-N-((3-methoxyphenyl)(phenyl)methyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; potassium hydroxide In tetrahydrofuran at 60℃; for 24h; enantioselective reaction;99%
With [{(M,SS,SS)-p-Tol-binaso}Rh(OH)]2 In water; toluene at 25℃; for 14h; Glovebox; Sealed tube; Inert atmosphere; enantioselective reaction;88%
triphenylboroxine
3262-89-3

triphenylboroxine

N-(4-methoxybenzylidene)-p-toluenesulfonamide
14674-38-5

N-(4-methoxybenzylidene)-p-toluenesulfonamide

(S)-N-((4-methoxyphenyl)(phenyl)methyl)-4-methylbenzenesulfonamide
258277-16-6, 796966-18-2

(S)-N-((4-methoxyphenyl)(phenyl)methyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; (S)-(-)-[η5-1-bis(3,5-di(trifluormethylphenyl)phosphino-2-(3-diphenylphosphino-2-methylpropenyl)cyclopentadienyl-P)]manganese(I) dicarbonyl; potassium hydroxide In 1,4-dioxane; water at 40℃; for 7h; Reagent/catalyst; Inert atmosphere; enantioselective reaction;99%
With chlorobis(ethylene)rhodium(I) dimer; potassium hydroxide In tetrahydrofuran at 60℃; for 24h; enantioselective reaction;29%
triphenylboroxine
3262-89-3

triphenylboroxine

N-(2-methoxybenzylidene)-p-toluenesulfonamide
100200-70-2

N-(2-methoxybenzylidene)-p-toluenesulfonamide

(S)-N-((2-methoxyphenyl)(phenyl)methyl)-4-methylbenzenesulfonamide
258277-17-7

(S)-N-((2-methoxyphenyl)(phenyl)methyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; (S)-(-)-[η5-1-bis(3,5-di(trifluormethylphenyl)phosphino-2-(3-diphenylphosphino-2-methylpropenyl)cyclopentadienyl-P)]manganese(I) dicarbonyl; potassium hydroxide In 1,4-dioxane; water at 40℃; for 7h; Reagent/catalyst; Inert atmosphere; enantioselective reaction;99%
triphenylboroxine
3262-89-3

triphenylboroxine

4-methyl-N-(thiophen-2-ylmethylene)benzenesulfonamide
158293-42-6

4-methyl-N-(thiophen-2-ylmethylene)benzenesulfonamide

(S)-4-methyl-N-(phenyl(thiophen-2-yl)methyl)benzenesulfonamide

(S)-4-methyl-N-(phenyl(thiophen-2-yl)methyl)benzenesulfonamide

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; (S)-(-)-[η5-1-bis(3,5-di(trifluormethylphenyl)phosphino-2-(3-diphenylphosphino-2-methylpropenyl)cyclopentadienyl-P)]manganese(I) dicarbonyl; potassium hydroxide In 1,4-dioxane; water at 40℃; for 7h; Reagent/catalyst; Inert atmosphere; enantioselective reaction;99%
triphenylboroxine
3262-89-3

triphenylboroxine

C27H34N2O3SSi

C27H34N2O3SSi

C33H40N2O3SSi

C33H40N2O3SSi

Conditions
ConditionsYield
Stage #1: triphenylboroxine; C27H34N2O3SSi With [RhCl(cis-cyclooctene)2]2; (R)-N-(4,4-dimethyl-2-methylenepentyl)-2-methylpropane-2-sulfinamide In toluene at 20℃; for 0.5h; Schlenk technique; Inert atmosphere;
Stage #2: With potassium hydroxide In water; toluene at 60℃; for 6h;
99%
triphenylboroxine
3262-89-3

triphenylboroxine

cyclohexenone
930-68-7

cyclohexenone

(S)-3-phenylcyclohexanone
57344-86-2

(S)-3-phenylcyclohexanone

Conditions
ConditionsYield
With [Rh(OH)((S)-binap)]2 at 35℃; for 3h;98%
With potassium hydroxide; [RhCl((S,S)-2,5-dibenzylbicyclo[2.2.2]octa-2,5-diene)]2 In 1,4-dioxane; water at 30℃; for 1h;96%
triphenylboroxine
3262-89-3

triphenylboroxine

N-(2-methoxyphenyl)methylidene-4-methylbenzenesulfonamide
100200-70-2

N-(2-methoxyphenyl)methylidene-4-methylbenzenesulfonamide

(S)-N-((2-methoxyphenyl)(phenyl)methyl)-4-methylbenzenesulfonamide
258277-17-7

(S)-N-((2-methoxyphenyl)(phenyl)methyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With potassium hydroxide; bis(ethylene)rhodium(I) chloride dimer; (1R,4R)-2,5-diphenylbicyclo[2.2.2]octa-2,5-diene In 1,4-dioxane at 60℃; for 6h;98%
N-(4-methoxyphenyl)methylidene-4-nitrobenzenesulfonamide

N-(4-methoxyphenyl)methylidene-4-nitrobenzenesulfonamide

triphenylboroxine
3262-89-3

triphenylboroxine

N-[(S)-(4-methoxyphenyl)(phenyl)methyl]-4-nitrobenzenesulfonamide
840529-68-2

N-[(S)-(4-methoxyphenyl)(phenyl)methyl]-4-nitrobenzenesulfonamide

Conditions
ConditionsYield
With potassium hydroxide; [RhCl((1R,5R)-2,6-diphenylbicyclo[3.3.1]nona-2,6-diene)]2 In 1,4-dioxane at 60℃; for 6h;98%
triphenylboroxine
3262-89-3

triphenylboroxine

N-(4-bromophenyl)methylidene-4-nitrobenzenesulfonamide
36176-92-8

N-(4-bromophenyl)methylidene-4-nitrobenzenesulfonamide

(S)-N-[(4-bromophenyl)phenylmethyl]-4-nitrobenzenesulfonamide
840529-67-1

(S)-N-[(4-bromophenyl)phenylmethyl]-4-nitrobenzenesulfonamide

Conditions
ConditionsYield
With potassium hydroxide; [RhCl((1R,5R)-2,6-diphenylbicyclo[3.3.1]nona-2,6-diene)]2 In 1,4-dioxane at 60℃; for 6h;98%
triphenylboroxine
3262-89-3

triphenylboroxine

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

(S)-(+)-(4-fluorophenyl)phenylmethanol

(S)-(+)-(4-fluorophenyl)phenylmethanol

Conditions
ConditionsYield
Stage #1: triphenylboroxine With diethylzinc In toluene at 60℃; for 4h;
Stage #2: 4-fluorobenzaldehyde With (S)-dendritic pyrrolidinylmethanol C116H105NO15 In toluene at -15℃; for 6h;
98%

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