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Suzhou Sinosun Imp.&Exp. Corporation

We supply good quality 3,5-dimethylphenylboronic acid CAS# 172975-69-8 at competitive price. Our 3,5-dimethylphenylboronic acid CAS# 172975-69-8 has been exported to many countries and regions. If you are looking for 3,5-dimethylphenylboronic aci

3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:1 Kilogram

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

3,5-Dimethylphenylboronic acid Manufacturer/High quality/Best price/In stock

Cas:172975-69-8

Min.Order:1 Kilogram

FOB Price: $3.0

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:1 Kilogram

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:1 Kilogram

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 172975-69-8 3,5-Dimethylphenylboronic acid Manufacturer

Cas:172975-69-8

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3,5-Dimethylbenzeneboronic acid

Cas:172975-69-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

Factory supply 3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com

3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:1 Gram

FOB Price: $52.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

3,5-Dimethylbenzeneboronic acid)

Cas:172975-69-8

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

C8H11BO2 3,5-Dimethylphenylboronic acid 172975-69-8

Cas:172975-69-8

Min.Order:1 Metric Ton

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 172975-69-8 with best quality

Cas:172975-69-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:powder Storage:Store in sealed containers at cool & dry pla

CAS NO. 172975-69-8 3,5-Dimethylphenylboronic acid with high purity

Cas:172975-69-8

Min.Order:100 Gram

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Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Boronic acid, B-(3,5-dimethylphenyl)- 172975-69-8

Cas:172975-69-8

Min.Order:1 Kilogram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Boronic acid, B-(3,5-dimethylphenyl)-

Cas:172975-69-8

Min.Order:1 Kilogram

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Wuhan Zenuo Biological Medicine Technology Co Ltd

Product Name: 3,5-Dimethylphenylboronic acid Synonyms: RARECHEM AH PB 0186;M-XYLENE-5-BORONIC ACID;TIMTEC-BB SBB004076;3,5-DIMETHYLBENZENEBORONIC ACID;3,5-DIMETHYLPHENYLBORONIC ACID;AKOS BRN-0067;3,5-Dimethylphenylboronic Acid (contains varying

3,5-Dimethylphenylboronic acid big supplier with lower price

Cas:172975-69-8

Min.Order:1 Kilogram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Boronic acid, B-(3,5-dimethylphenyl)-

Cas:172975-69-8

Min.Order:0

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:10 Kilogram

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Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

3,5-Dimethylphenylboronic Acid

Cas:172975-69-8

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Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

3,5-DiMethylphenylboronic acid

Cas:172975-69-8

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:0 Metric Ton

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3,5-dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:0

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3,5-Dimethylbenzeneboronic acid

Cas:172975-69-8

Min.Order:0 Metric Ton

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Type:Other

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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesi

factory of reasonable 3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:100 Gram

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white powder Storage:sealed and stored Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediates Transportation:as per your request. Port:Shangh

3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:1 Kilogram

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:1 Gram

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Top Purity Supplier3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:0

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Shanghai Minstar Chemical Co., Ltd

3,5-Dimethylphenylboronic acid Basic information Product Name: 3,5-Dimethylphenylboronic acid Synonyms: RARECHEM AH PB 0186;M-XYLENE-5-BORONIC ACID;TIMTEC-BB SBB004076;3,5-Dimethyl benzene;3,5-DIMETHYLBENZENEBORONIC ACID;3,5-DIMETHYLPHENYLBORO

3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Factory supply 3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

3,5-Dimethylphenylboronic acid

Cas:172975-69-8

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Synthetic route

methanol
67-56-1

methanol

diisopropylamine borane
55124-35-1

diisopropylamine borane

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
Stage #1: diisopropylamine borane With magnesium; phenylmagnesium bromide In tetrahydrofuran at 20℃; for 0.166667h;
Stage #2: 5-bromo-1,3-xylene In tetrahydrofuran at 70℃;
Stage #3: methanol Further stages;
89%
Trimethyl borate
121-43-7

Trimethyl borate

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
With Mg; H2SO4 In tetrahydrofuran; diethyl ether aryl bromide in THF was added to Mg turnings, filtered, added dropwise with stirring to trimethyl borate in ether at -70°C, the suspn. was allowed to warm to room temp. overnight, added with stirring to ice, concd. H2SO4, stirred for 30 min (Ar); shaken with ether, dried over Na2SO4, evapd., filtered, dried in vac.; elem. anal.;85.6%
With Mg; iodomethane In diethyl ether under Ar atm. 1,3-dimethyl-5-bromobenzene in Et2O was added slowly to Mgturning in the presence of MeI, react. mixt. was refluxed for 6 h and a dded at -60°C to soln. B(OMe)3 in Et2O, allowed to warm slowly toroom temp. with stirring; react. mixt. was poured into 20% H2SO4, org. phase was separated, washedwith water and dried over MgSO4, solvent was removed in vacuo;82%
Trimethyl borate
121-43-7

Trimethyl borate

water
7732-18-5

water

3,5-dimethyphenylmagnesium bromide
34696-73-6

3,5-dimethyphenylmagnesium bromide

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
Stage #1: Trimethyl borate; 3,5-dimethyphenylmagnesium bromide In tetrahydrofuran at 20℃;
Stage #2: water With hydrogenchloride In tetrahydrofuran; diethyl ether
74%
Trimethyl borate
121-43-7

Trimethyl borate

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

water
7732-18-5

water

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
Stage #1: Trimethyl borate; 5-bromo-1,3-xylene With magnesium In tetrahydrofuran at -78 - 20℃;
Stage #2: water With hydrogenchloride In tetrahydrofuran; diethyl ether
74%
5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
With Trimethyl borate
Stage #1: 5-bromo-1,3-xylene With magnesium In tetrahydrofuran
Stage #2: With Trimethyl borate
Stage #3: With hydrogenchloride Further stages.;
Stage #1: 5-bromo-1,3-xylene With magnesium; methyl iodide In diethyl ether Inert atmosphere; Reflux;
Stage #2: With Trimethyl borate In diethyl ether at -60 - 20℃; Inert atmosphere;
Multi-step reaction with 2 steps
1.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C
1.2: -78 - 20 °C
2.1: water; hydrogenchloride / tetrahydrofuran; hexane / 20 °C / pH 3 - 5
View Scheme
2-(3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
325142-93-6

2-(3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
Stage #1: 2-(3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane With sodium periodate In tetrahydrofuran; water for 0.25h;
Stage #2: With hydrogenchloride In tetrahydrofuran; water for 4h;
Stage #1: 2-(3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane With sodium periodate In tetrahydrofuran; water for 0.5h;
Stage #2: With hydrogenchloride In tetrahydrofuran; water at 20℃; for 17h;
m-xylene
108-38-3

m-xylene

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 4,4'-di-tert-butyl-2,2'-bipyridine / [Ir(COD)(OMe)]2 / tetrahydrofuran / 16 h / 80 °C
2.1: sodium periodate / tetrahydrofuran; H2O / 0.25 h
2.2: HCl / H2O; tetrahydrofuran / 4 h
View Scheme
Multi-step reaction with 2 steps
1.1: 4,4'-di-tert-butyl-2,2'-bipyridine; pinacolborane / [(COD)Ir(OMe)]2 / cyclohexane / 24 h / 80 °C
2.1: sodium periodate / tetrahydrofuran; H2O / 0.5 h
2.2: hydrochloric acid / tetrahydrofuran; H2O / 17 h / 20 °C
View Scheme
Triisopropyl borate
5419-55-6

Triisopropyl borate

5-bromo-1,3-xylene
556-96-7

5-bromo-1,3-xylene

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
With N2 In tetrahydrofuran2.41 g (29.7%)
With N2 In tetrahydrofuran2.41 g (29.7%)
With sodium hydroxide; n-butyllithium In tetrahydrofuran; hydrogenchloride; hexane; dichloromethane
Stage #1: 5-bromo-1,3-xylene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.25h; Inert atmosphere;
Stage #2: Triisopropyl borate In tetrahydrofuran; hexane at 25℃; for 0.333333h; Inert atmosphere;
C26H31B3O5
1016971-57-5

C26H31B3O5

A

(4-methoxy-3,5-dimethylphenyl)boronic acid
301699-39-8

(4-methoxy-3,5-dimethylphenyl)boronic acid

B

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
With water at 25℃; Equilibrium constant;
C25H29B3O4
1016971-59-7

C25H29B3O4

A

(4-methoxy-3,5-dimethylphenyl)boronic acid
301699-39-8

(4-methoxy-3,5-dimethylphenyl)boronic acid

B

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
With water at 25℃; Equilibrium constant;
C38H55B3O5
1016971-63-3

C38H55B3O5

A

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

B

4-methoxy-3,5-di-tert-butylphenylboronic acid pinacol ester
233584-42-4

4-methoxy-3,5-di-tert-butylphenylboronic acid pinacol ester

Conditions
ConditionsYield
With water at 25℃; Equilibrium constant;
C31H41B3O4
1016971-64-4

C31H41B3O4

A

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

B

4-methoxy-3,5-di-tert-butylphenylboronic acid pinacol ester
233584-42-4

4-methoxy-3,5-di-tert-butylphenylboronic acid pinacol ester

Conditions
ConditionsYield
With water at 25℃; Equilibrium constant;
C25H29B3O6
1016971-54-2

C25H29B3O6

A

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

B

3,4,5-trimethoxyphenylboronic Acid
182163-96-8

3,4,5-trimethoxyphenylboronic Acid

Conditions
ConditionsYield
With water at 25℃; Equilibrium constant;
C26H31B3O9
1016971-55-3

C26H31B3O9

A

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

B

3,4,5-trimethoxyphenylboronic Acid
182163-96-8

3,4,5-trimethoxyphenylboronic Acid

Conditions
ConditionsYield
With water at 25℃; Equilibrium constant;
tris(3.5-dimethyl phenyl)boroxine
34907-38-5

tris(3.5-dimethyl phenyl)boroxine

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
With water at 25℃; Equilibrium constant;
3,5-dimethyphenylmagnesium bromide
34696-73-6

3,5-dimethyphenylmagnesium bromide

A

B,B-bis(3,5-dimethylphenyl)borinic acid

B,B-bis(3,5-dimethylphenyl)borinic acid

B

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
With Triisopropyl borate In tetrahydrofuran at -55 - 20℃; Temperature;
(3,5-dimethylphenyl)lithium
95070-94-3

(3,5-dimethylphenyl)lithium

A

B,B-bis(3,5-dimethylphenyl)borinic acid

B,B-bis(3,5-dimethylphenyl)borinic acid

B

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
With Triisopropyl borate In tetrahydrofuran at -70 - 20℃;
C10H15BO2

C10H15BO2

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
With hydrogenchloride; water In tetrahydrofuran; hexane at 20℃; pH=3 - 5;
With hydrogenchloride; water In tetrahydrofuran114.6 g
3,5-dimethyphenylmagnesium bromide
34696-73-6

3,5-dimethyphenylmagnesium bromide

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrahydrofuran / -78 - 20 °C
2: hydrogenchloride; water / tetrahydrofuran
View Scheme
2,6-dimethylaniline
87-62-7

2,6-dimethylaniline

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: bromine / methanol / 20 °C
2.1: sulfuric acid / ethanol / 1 h / 7 - 20 °C
2.2: 1.5 h / 20 °C / Cooling
2.3: 20 °C / Inert atmosphere
3.1: magnesium / tetrahydrofuran / -78 - 20 °C
View Scheme
3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

methyl (S)-2-[3-(2-benzyloxy-1-methylethyl)-2-iodo-1H-pyrrolo[2,3-b]pyridin-5-yl]-2-methylpropanoate
246219-75-0

methyl (S)-2-[3-(2-benzyloxy-1-methylethyl)-2-iodo-1H-pyrrolo[2,3-b]pyridin-5-yl]-2-methylpropanoate

methyl (S)-2-[3-(2-benzyloxy-1-methylethyl)-2-(3,5-dimethyl-phenyl)-1H-pyrrolo[2,3-b]pyridin-5-yl]-2-methylpropanoate
246219-76-1

methyl (S)-2-[3-(2-benzyloxy-1-methylethyl)-2-(3,5-dimethyl-phenyl)-1H-pyrrolo[2,3-b]pyridin-5-yl]-2-methylpropanoate

Conditions
ConditionsYield
With sodium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In ethanol; toluene at 85℃; for 15h; Suzuki-Miayura cross-coupling;100%
3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

(S)-1-(2-Azabicyclo[2.2.2]oct-2-yl)-2-[3-(2-benzyloxy-1-methylethyl)-2-iodo-1H-pyrrolo[2,3-c]pyridin-5-yl]-2-methyl propan-1-one
292600-31-8

(S)-1-(2-Azabicyclo[2.2.2]oct-2-yl)-2-[3-(2-benzyloxy-1-methylethyl)-2-iodo-1H-pyrrolo[2,3-c]pyridin-5-yl]-2-methyl propan-1-one

(S)-1-(2-Azabicyclo[2.2.2]oct-2-yl)-2-[3-(2-benzyloxy-1-methylethyl)-2-(3,5-dimethylphenyl)-1H-pyrrolo[2,3-c]pyridin-5-yl]-2-methylpropan-1-one
292600-32-9

(S)-1-(2-Azabicyclo[2.2.2]oct-2-yl)-2-[3-(2-benzyloxy-1-methylethyl)-2-(3,5-dimethylphenyl)-1H-pyrrolo[2,3-c]pyridin-5-yl]-2-methylpropan-1-one

Conditions
ConditionsYield
With sodium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In ethanol; toluene at 90℃; for 15h; Suzuki-Miayura cross-coupling;100%
3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

3,3',5,5'-tetramethyl-1,1'-biphenyl
25570-02-9

3,3',5,5'-tetramethyl-1,1'-biphenyl

Conditions
ConditionsYield
With air; palladium diacetate In methanol at 20℃;100%
With potassium acetate; silver(l) oxide In methanol at 40℃; for 15h;99%
With bromo-phenyl-acetic acid methyl ester; potassium fluoride; dichloro[2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) In 1,4-dioxane; water at 100℃; for 24h;95%
4-(4-bromo-2-formylphenyl)piperazine-1-carboxylic acid tert-butyl ester
628326-05-6

4-(4-bromo-2-formylphenyl)piperazine-1-carboxylic acid tert-butyl ester

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

4-(3-formyl-3',5'-dimethylbiphenyl-4-yl)piperazine-1-carboxylic acid tert-butyl ester
628325-65-5

4-(3-formyl-3',5'-dimethylbiphenyl-4-yl)piperazine-1-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate In 1,2-dimethoxyethane Suzuki coupling; Heating;100%
7-chloro-2-cyclohexylmethylindan-1-one
1147270-21-0

7-chloro-2-cyclohexylmethylindan-1-one

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

7-(3',5'-dimethylphenyl)-2-cyclohexylmethylindan-1-one
1147270-27-6

7-(3',5'-dimethylphenyl)-2-cyclohexylmethylindan-1-one

Conditions
ConditionsYield
With trisodium tris(3-sulfophenyl)phosphine; palladium diacetate; sodium carbonate In water; ethylene glycol at 125℃; for 4h; Inert atmosphere;100%
N-(2-(4-bromo-5-(4-(tert-butyl)phenyl)-3-phenylthiophen-2-yl)-2-(p-tolyl)ethyl)-4-methylbenzenesulfonamide

N-(2-(4-bromo-5-(4-(tert-butyl)phenyl)-3-phenylthiophen-2-yl)-2-(p-tolyl)ethyl)-4-methylbenzenesulfonamide

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

N-(2-(5-(4-(tert-butyl)phenyl)-4-(3,5-dimethylphenyl)-3-phenylthiophen-2-yl)-2-(p-tolyl)ethyl)-4-methylbenzenesulfonamide

N-(2-(5-(4-(tert-butyl)phenyl)-4-(3,5-dimethylphenyl)-3-phenylthiophen-2-yl)-2-(p-tolyl)ethyl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; sodium hydroxide; tri-t-butylphosphonium tetraphenylborate complex In tetrahydrofuran; water at 65℃; for 24h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;100%
bromobenzene
108-86-1

bromobenzene

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

3,5-dimethylbiphenyl
17057-88-4

3,5-dimethylbiphenyl

Conditions
ConditionsYield
With Pd/C; potassium carbonate In water; N,N-dimethyl-formamide at 40℃; for 5h; Suzuki Coupling;99%
With potassium carbonate In ethanol; water at 80℃; for 7h; Suzuki Coupling;90%
With tris-(o-tolyl)phosphine; microencapsulated Pd(PPh3) In acetonitrile for 6h; Heating;83%
With potassium phosphate tribasic trihydrate In water at 80℃; for 15h; Suzuki-Miyaura Coupling; Green chemistry;82%
(Ra)-3,3’-dibromo-2,2’-dimethoxy-5,5’,6,6’,7,7’,8,8’-octahydro-1,1’-binaphthalene
78229-12-6

(Ra)-3,3’-dibromo-2,2’-dimethoxy-5,5’,6,6’,7,7’,8,8’-octahydro-1,1’-binaphthalene

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

(R)-3,3'-bis-(3,5-dimethylphenyl)-2,2'-dimethoxy-5,6,7,8,5',6',7',8'-octahydro-[1,1']binaphthalenyl

(R)-3,3'-bis-(3,5-dimethylphenyl)-2,2'-dimethoxy-5,6,7,8,5',6',7',8'-octahydro-[1,1']binaphthalenyl

Conditions
ConditionsYield
With potassium fluoride; tris-(dibenzylideneacetone)dipalladium(0); tricyclohexylphosphine In tetrahydrofuran at 75℃; for 22h;99%
Stage #1: (Ra)-3,3’-dibromo-2,2’-dimethoxy-5,5’,6,6’,7,7’,8,8’-octahydro-1,1’-binaphthalene; tetrakis(triphenylphosphine) palladium(0) at 20℃; for 0.166667h; Suzuki coupling;
Stage #2: 3,5-dimethylphenyl boronic acid With sodium carbonate In ethanol at 90℃; for 18h; Further stages.;
97%
para-bromotoluene
106-38-7

para-bromotoluene

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

1-(4-methylphenyl)-3,5-dimethylbenzene
7383-87-1

1-(4-methylphenyl)-3,5-dimethylbenzene

Conditions
ConditionsYield
With bis-(1-methylimidazole)palladium(II) dichloride; sodium hydroxide In water at 80℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Green chemistry;99%
With sodium carbonate; 1,2-bis(2'-pyrazineethynyl)benzene palladium dichloride In water; acetonitrile at 70℃; for 6h; Suzuki coupling;91%
3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

3-bromoaniline
591-19-5

3-bromoaniline

3-amino-3',5'-dimethylbiphenyl
783325-73-5

3-amino-3',5'-dimethylbiphenyl

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine; cesium fluoride In tetrahydrofuran at 20℃; for 2h; Suzuki coupling;99%
With cesium fluoride; tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine In tetrahydrofuran at 20℃; for 2h; Suzuki Coupling;99%
indole-2,3-dione
91-56-5

indole-2,3-dione

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

3-(3',5'-dimethylphenyl)-3-hydroxy-1,3-dihydro-indol-2-one

3-(3',5'-dimethylphenyl)-3-hydroxy-1,3-dihydro-indol-2-one

Conditions
ConditionsYield
With triphenyl phosphite; [(C2H4)2Rh(acac)] In acetone for 4h; Heating;99%
6-chloro-2-picoline
18368-63-3

6-chloro-2-picoline

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

2-(3',5'-dimethylphenyl)-6-methylpyridine

2-(3',5'-dimethylphenyl)-6-methylpyridine

Conditions
ConditionsYield
With potassium phosphate; tris(dibenzylideneacetone)dipalladium (0) In toluene at 100℃; for 16h; Suzuki-Miyaura coupling;99%
N-(5'-bromo-3'-phenylpyraz-2'-yl)pyridinium aminide
910791-84-3

N-(5'-bromo-3'-phenylpyraz-2'-yl)pyridinium aminide

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

N-[5-(3,5-dimethylphenyl)-3-phenylpyrazin-2-yl]pyridinium aminide
1011793-95-5

N-[5-(3,5-dimethylphenyl)-3-phenylpyrazin-2-yl]pyridinium aminide

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene for 8h; Suzuki coupling reaction; Heating;99%
3'-Chloroacetophenone
99-02-5

3'-Chloroacetophenone

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

1-(3',5'-dimethylbiphenyl-3-yl)ethanone

1-(3',5'-dimethylbiphenyl-3-yl)ethanone

Conditions
ConditionsYield
With potassium phosphate; palladium diacetate In tetrahydrofuran at 100℃; for 24h; Suzuki-Miyaura coupling;99%
iodobenzene
591-50-4

iodobenzene

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

3,5-dimethylbiphenyl
17057-88-4

3,5-dimethylbiphenyl

Conditions
ConditionsYield
With palladium diacetate; sodium carbonate In water; acetone at 35℃; for 0.5h; Inert atmosphere;99%
With bis-(1-methylimidazole)palladium(II) dichloride; sodium hydroxide In water at 80℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Green chemistry;99%
With potassium carbonate In water at 80℃; for 1.5h; Suzuki Coupling; Green chemistry;90%
4,4'-dithiobis [5-amino-3-cyano-1-{2,6-dichloro-4-(trifluoromethyl)phenyl}-1H-pyrazole]
130755-46-3

4,4'-dithiobis [5-amino-3-cyano-1-{2,6-dichloro-4-(trifluoromethyl)phenyl}-1H-pyrazole]

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

C19H13Cl2F3N4S
1158997-64-8

C19H13Cl2F3N4S

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; oxygen In water; dimethyl sulfoxide at 100℃; for 36h;99%
C19H15NO4

C19H15NO4

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

C27H25NO4
1204518-49-9

C27H25NO4

Conditions
ConditionsYield
With C52H36F8O2Rh2 In 1,4-dioxane; water at 50℃; for 12h; optical yield given as %ee; enantioselective reaction;99%
cyclohexenone
930-68-7

cyclohexenone

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

(R)-3-(3,5-dimethyl-phenyl)cyclohexanone
1220531-61-2

(R)-3-(3,5-dimethyl-phenyl)cyclohexanone

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; (R)-(6-(tert-butylsulfinyl)-2,3-dimethoxyphenyl)diphenylphosphine; potassium hydroxide In water; toluene at 20 - 40℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
Stage #1: 3,5-dimethylphenyl boronic acid With chlorobis(ethylene)rhodium(I) dimer; C8H16N2O4S2 In 1,4-dioxane at 50℃; for 0.25h; Inert atmosphere;
Stage #2: cyclohexenone With potassium hydroxide In 1,4-dioxane; methanol at 10℃; for 2h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
99%
With potassium fluoride; chlorobis(ethylene)rhodium(I) dimer; (R,Z)-1-(tert-butylsulfinyl)-2-(prop-1-enyl)benzene In methanol; water at 40℃; for 3h; Hayashi-Miyaura reaction; Inert atmosphere; optical yield given as %ee; stereoselective reaction;99%
3-Bromopyridine
626-55-1

3-Bromopyridine

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

3,5-dimethyl-1-(3-pyridyl)benzene

3,5-dimethyl-1-(3-pyridyl)benzene

Conditions
ConditionsYield
With bis-(1-methylimidazole)palladium(II) dichloride; sodium hydroxide In water at 80℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Green chemistry;99%
With sodium carbonate In methanol at 60℃; for 0.5h; Suzuki-Miyaura cross-coupling;> 99 %Chromat.
para-bromoacetophenone
99-90-1

para-bromoacetophenone

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

1-(3’,5’-dimethylbiphenyl-4-yl)ethanone
677022-27-4

1-(3’,5’-dimethylbiphenyl-4-yl)ethanone

Conditions
ConditionsYield
With potassium carbonate In water at 80℃; for 10h; Suzuki-Miyaura Coupling; Green chemistry;99%
With potassium carbonate; palladium dichloride; 3,3'-dimethyl-1,1’-(1,3-phenylenedimethylene)-bis(1H-imidazolium) dichloride In water; N,N-dimethyl-formamide for 3h; Suzuki Coupling; Reflux;97%
With sodium acetate In water; N,N-dimethyl-formamide for 12h; Suzuki coupling; Reflux;94%
(E)-2-fluorovinyl 4-methylbenzenesulfonate
1262431-28-6

(E)-2-fluorovinyl 4-methylbenzenesulfonate

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

(E)-1-(2-fluorovinyl)-3,5-dimethylbenzene
1262431-30-0

(E)-1-(2-fluorovinyl)-3,5-dimethylbenzene

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium phosphate; tricyclohexylphosphine In 1,4-dioxane at 100℃; for 14h; Suzuki-Miyaura reaction; Inert atmosphere; stereoselective reaction;99%
1-methoxy-4-(2-nitro-vinyl)-benzene
3179-10-0

1-methoxy-4-(2-nitro-vinyl)-benzene

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

1-methoxy-4-(1-(3,5-dimethylphenyl)-2-nitroethyl)benzene

1-methoxy-4-(1-(3,5-dimethylphenyl)-2-nitroethyl)benzene

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; tert-butanesulfinylphosphine; triethylamine In ethanol at 40℃; for 10h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
9-Chloroacridine
1207-69-8

9-Chloroacridine

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

9-(3,5-dimethylphenyl)acridine
1352136-18-5

9-(3,5-dimethylphenyl)acridine

Conditions
ConditionsYield
With potassium phosphate In toluene at 100℃; for 24h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;99%
With potassium phosphate; palladium diacetate; tricyclohexylphosphine In water; toluene Reflux;
benzil
134-81-6

benzil

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

C22H20O2

C22H20O2

Conditions
ConditionsYield
With bis(ethylene)rhodium(I) chloride dimer; C19H23NOS; potassium hydroxide In 1,4-dioxane; water at 20 - 50℃; for 12h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
benzoic acid anhydride
93-97-0

benzoic acid anhydride

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

3,5-dimethylbenzophenone
13319-70-5

3,5-dimethylbenzophenone

Conditions
ConditionsYield
With NHC-Pd(II)-Im; sodium hydrogencarbonate In water at 20℃; for 12h; Inert atmosphere;99%
Stage #1: benzoic acid anhydride; 3,5-dimethylphenyl boronic acid With sodium hydrogencarbonate In water at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: With C19H25Br2N5Pd In water at 20℃; for 36h; Inert atmosphere;
86%
3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

1,3-diphenyl-propen-3-one
614-47-1

1,3-diphenyl-propen-3-one

(S)-3-(3, 5-dimethylphenyl)-1,3-diphenylpropan-1-one
1383843-81-9

(S)-3-(3, 5-dimethylphenyl)-1,3-diphenylpropan-1-one

Conditions
ConditionsYield
With potassium fluoride; chlorobis(ethylene)rhodium(I) dimer; (R)-(6-(tert-butylsulfinyl)-2,3-dimethoxyphenyl)diphenylphosphine In water; isopropyl alcohol at 40℃; for 3h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
3-butyl-1,2-benzisothiazole-1,1-dioxide
55379-09-4

3-butyl-1,2-benzisothiazole-1,1-dioxide

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

(R)-3-butyl-3-(3,5-dimethylphenyl)-2,3-dihydrobenzo[d]isothiazole 1,1-dioxide

(R)-3-butyl-3-(3,5-dimethylphenyl)-2,3-dihydrobenzo[d]isothiazole 1,1-dioxide

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; (S)-methyl 6-(4-(tert-butyl)-4,5-dihydrooxazol-2-yl)nicotinate; oxygen In 2,2,2-trifluoroethanol at 40℃; for 12h; enantioselective reaction;99%
methyl o-formylbenzoate
4122-56-9

methyl o-formylbenzoate

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

(S)-3-(3,5-dimethylphenyl)-1,3-dihydro-2-benzofuran-1-one
1227504-98-4

(S)-3-(3,5-dimethylphenyl)-1,3-dihydro-2-benzofuran-1-one

Conditions
ConditionsYield
With (R)-Me-BIPAM; tris(triphenylphosphine)ruthenium(II) chloride; potassium carbonate In water; toluene at 50℃; for 18h; Inert atmosphere; enantioselective reaction;99%
2-methylbenzyl carbamate

2-methylbenzyl carbamate

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

C16H18

C16H18

Conditions
ConditionsYield
With NHC-Pd(II)-Im; lithium tert-butoxide In water at 80℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; Green chemistry;99%
3-methylbenzyl N,N-dimethylcarbamate
16605-27-9

3-methylbenzyl N,N-dimethylcarbamate

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

3,3',5-Trimethyl-diphenylmethan
16134-73-9

3,3',5-Trimethyl-diphenylmethan

Conditions
ConditionsYield
With NHC-Pd(II)-Im; lithium tert-butoxide In water at 80℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; Green chemistry;99%

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