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inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China
Trifluoro(nitroso)methane Application:Trifluoro(nitroso)methane
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(trifluoromethyl)trimethylsilane
trifluoronitrosomethane
Conditions | Yield |
---|---|
With nitrosylchloride; cesium fluoride In 1,2-dimethoxyethane at -196 - 25℃; for 3h; | 92% |
perfluoro-NN'-dimethylethane-1,2-bis(amino-oxyl) diradical
A
trifluoronitrosomethane
B
perfluoro(4,7-dimethyl-1,3-dioxa-2-tetrafluorothia-4,7-diazacycloheptane)
Conditions | Yield |
---|---|
With sulfur tetrafluoride at -196℃; for 24h; | A n/a B 87% |
trifluoronitrosomethane
Conditions | Yield |
---|---|
With Trimethylzinn-nitrat monohydrat In acetonitrile Ambient temperature; | 60% |
Perfluoro-2-azapropen
A
carbon tetrafluoride
B
trifluoronitrosomethane
C
perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane)
Conditions | Yield |
---|---|
With difluoroether; fluorine; cesium fluoride at -78 - 25℃; for 48h; Addition; Decomposition; | A 11% B 12% C 77% |
trifluoronitrosomethane
Conditions | Yield |
---|---|
With aluminium trichloride; isopropyl nitrate at -15℃; | 47% |
trifluoronitrosomethane
Conditions | Yield |
---|---|
With nitrosylchloride | 98% |
bis(trifluoroacetyl)peroxide
A
trifluoronitrosomethane
B
bis-trifluoromethyl-aminooxyl
Conditions | Yield |
---|---|
With sodium nitrite In 1,1,2-Trichloro-1,2,2-trifluoroethane at 20℃; |
Conditions | Yield |
---|---|
With silver(II) fluoride | A n/a B 90% |
N,N-bis(trifluoromethyl)hydroxylamine
A
hypofluorous acid trifluoromethyl ester
B
trifluoronitrosomethane
C
difluoramino trifluoromethane
D
fluoro-bis-trifluoromethyl-amine
Conditions | Yield |
---|---|
With fluorine; cesium fluoride In trichlorofluoromethane at -78℃; for 24h; Fluorination; Further byproducts given; |
Conditions | Yield |
---|---|
With nitric oxide anion In gas at 36.9℃; Rate constant; | |
With nitrogen(II) oxide Irradiation.im UV-Licht; | |
With nitrogen(II) oxide under 200 Torr; Irradiation; |
perfluoro(2,6-dimethyl-3,5-dioxa-4-thia-2,6-diazaheptane 4,4-dioxide)
A
trifluoronitrosomethane
Conditions | Yield |
---|---|
at 350℃; under 1 Torr; |
Conditions | Yield |
---|---|
With Perfluorotributylamine; nitrogen(II) oxide Heating; | |
Heating; |
Dichloromethylsilane
bis-trifluoromethyl-aminooxyl
A
trifluoronitrosomethane
B
N,N-bis(trifluoromethyl)hydroxylamine
C
dichloromethylsilanedichloromethylsilane
Conditions | Yield |
---|---|
for 6h; Ambient temperature; in vacuo; | A n/a B 50% C 85% |
Conditions | Yield |
---|---|
100°C, 2 h in bomb tube, or warming to 200°C; | |
With mercury Irradiation (UV/VIS); in presence of Hg; | <1 |
With Hg Irradiation (UV/VIS); in presence of Hg; | <1 |
100°C, 2 h in bomb tube, or warming to 200°C; |
Conditions | Yield |
---|---|
With nitrogen(II) oxide; chlorine at 22.9℃; under 11.7 Torr; for 0.00833333h; Rate constant; Irradiation; var. of pressure; | A 9.17% B n/a |
Conditions | Yield |
---|---|
With mercury Irradiation (UV/VIS); 5 d in presence of Hg; | 4% |
With Hg Irradiation (UV/VIS); 5 d in presence of Hg; | 4% |
trifluoronitrosomethane
Conditions | Yield |
---|---|
With nitrosylchloride Erhitzen des Reaktionsprodukts; |
Conditions | Yield |
---|---|
With calcium fluoride; fluorine beim vermindertem Druck; | |
With calcium fluoride; fluorine; potassium nitrate; silver(l) oxide beim vermindertem Druck; |
Conditions | Yield |
---|---|
In neat (no solvent) | |
In neat (no solvent) |
Conditions | Yield |
---|---|
With nitric oxide anion In gas at 36.9℃; Rate constant; |
tris(trifluoromethyl)arsine
nitrosylchloride
A
trifluoronitrosomethane
B
arsenic trichloride
Conditions | Yield |
---|---|
In neat (no solvent) heating at 100 - 200°C in tube;; | |
In neat (no solvent) heating at 100 - 200°C in tube;; |
trans-chlorotetrafluoro(trifluoromethyl)sulfur(VI)
nitrosylchloride
A
trifluoronitrosomethane
B
silicon tetrafluoride
Conditions | Yield |
---|---|
byproducts: Cl2; Irradiation (UV/VIS); 150°C, 12 h; | A 40% B n/a |
byproducts: Cl2; Irradiation (UV/VIS); 150°C, 12 h; | A 40% B n/a |
Conditions | Yield |
---|---|
With silver(II) fluoride |
trifluoroacetyl peroxynitrate
A
Carbonyl fluoride
B
trifluoronitrosomethane
Conditions | Yield |
---|---|
With nitrogen(II) oxide at 26.4℃; under 750.06 Torr; Rate constant; Mechanism; |
Conditions | Yield |
---|---|
With nitric oxide anion In gas at 36.9℃; Rate constant; |
(trifluoromethyl)phosphonous dichloride
nitrogen(II) oxide
A
trifluoronitrosomethane
B
(trifluoromethyl)phoshporyl dichloride
C
trichlorophosphate
Conditions | Yield |
---|---|
byproducts: NOCl, N2O, N2; 100°C (72 h); oxydation; | A n/a B 54% C 13% |
iodotrifluoromethane
nitrogen(II) oxide
A
carbon tetrafluoride
B
Hexafluoroethane
C
trifluoronitrosomethane
D
trifluoronitromethane
E
iodine
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: N2, NO2; other Radiation; radiation with γ-rays in the presence of NO as radical trap; mechanism discussed;; |
iodotrifluoromethane
nitrogen(II) oxide
A
carbon tetrafluoride
B
Carbonyl fluoride
C
Hexafluoroethane
D
trifluoronitrosomethane
E
iodine
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: N2, NO2; other Radiation; radiation with γ-rays and NO as radical trap; mechanism discussed; further products;; yields given;; |
tris(trifluoromethyl)arsine
nitrogen(II) oxide
A
trifluoronitrosomethane
B
trifluoronitromethane
Conditions | Yield |
---|---|
70°C, 4 d; further unidentified products; | |
70°C, 4 d; further unidentified products; |
trifluoronitrosomethane
cyclohexa-1,3-diene
3-Trifluoromethyl-2-oxa-3-aza-bicyclo[2.2.2]oct-5-ene
Conditions | Yield |
---|---|
at 25℃; for 1h; | 100% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 0℃; for 12h; | 100% |
Conditions | Yield |
---|---|
In methanol at 20℃; for 24h; | 100% |
trifluoronitrosomethane
benzenesufonyl hydrazide
N-trifluoromethyl-N-hydroxybenzenesulfonamide
Conditions | Yield |
---|---|
In tetrahydrofuran for 1.5h; Product distribution; Ambient temperature; oth. arenesulfonohydrazides, oth. solvent,; | 99% |
Conditions | Yield |
---|---|
In methanol Ambient temperature; | 98% |
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