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Dayang Chem (Hangzhou) Co.,Ltd.

img _fcksaAppearance:White crystalline powder Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agr

high purity 5-Bromo-2-picoline 98% TOP1 supplier in China

Cas:3430-13-5

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 5-Bromo-2-Picoline? supplier in China

Cas:3430-13-5

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages Guaranteed purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Light yellow liquid Storage:Cool dry place Package:25kg/drum,200kg/drum Application:pharmaceutica

5-Bromo-2-methylpyridine Cas 3430-13-5

Cas:3430-13-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:Whit

5-Bromo-2-picoline

Cas:3430-13-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 5-Bromo-2-Picoline

Cas:3430-13-5

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

5-Bromo-α-picoline

Cas:3430-13-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

5-Bromo-2-picoline Basic information Product Name: 5-Bromo-2-picoline Synonyms: 2-METHYL-5-BROMOPYRIDINE;5-BROMOPICOLINE;3-BROMO-6-METHYLPYRIDINE;5-BROMO-2-METHYLPYRIDINE;5-BROMO-2-PICOL

TIANFU-CHEM CAS:3430-13-5 5-Bromo-2-picoline

Cas:3430-13-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

5-Bromo-2-methylpyridine

Cas:3430-13-5

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 3430-13-5 with fast shipping

Cas:3430-13-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Chemical Name 5-Bromo-2-picoline Synonyms 5-Bromo-2-methylpyridine; 2-Methyl-5-bromopyridine CAS No. 3430-13-5 Molecular formula C6H6BrN

5-Bromo-2-methylpyridine

Cas:3430-13-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

5-Bromo-2-picoline 3430-13-5

Cas:3430-13-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

5-Bromo-2-methylpyridine CAS:3430-13-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i

5-Bromo-2-methylpyridine CAS:3430-13-5

Cas:3430-13-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,

5-Bromo-2-methylpyridine CAS NO.3430-13-5

Cas:3430-13-5

Min.Order:20 Metric Ton

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:3430-13-5

Cas:3430-13-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

5-Bromo-2-Methylpyridine

Cas:3430-13-5

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Lorcaserin(856681-05-5)is an orally administered agent and a selective 5-HT2C receptor agonist for the treatment of obesity. It had been approved for marketing in US by FDA on 27 June in 2012. In clinical studies, lorcaserin h

5-bromo-2-methylpyridine

Cas:3430-13-5

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS3430-13-5 5-Bromo-2-methylpyridine

Cas:3430-13-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

5-Bromo-2-picoline

Cas:3430-13-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

5-bromo-2-methylpyridine

Cas:3430-13-5

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

5-Bromo-2-methylpyridine

Cas:3430-13-5

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

5-Bromo-2-picoline

Cas:3430-13-5

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

5-Bromo-2-methylpyridine

Cas:3430-13-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:Light yellow Cryst Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:5-Bromo-2-picoline is a halogenated pyridine deriva

5-Bromo-2-picoline

Cas:3430-13-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

5-Bromo-2-picoline

Cas:3430-13-5

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 5-Bromo-2-methylpyridine Synonyms: 5-broMo-1-Methylpyridine;5--2- MethylpyridinebroMide;2 - Methyl - 5 - broMide pyridine;2-METHYL-5-BROMOPYRIDINE;5-BROMOPICOLINE;3-BROMO-6-METHYLPYRIDINE;5-BROMO-2-METHYLPYRIDINE;5-BROMO-2-PICOLIN

5-Bromo-2-methylpyridine 3430-13-5 C6H6BrN

Cas:3430-13-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

5-Bromo-2-methylpyridine

Cas:3430-13-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

5-Bromo-2-methylpyridine CAS NO.3430-13-5 CAS NO.3430-13-5

Cas:3430-13-5

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

5-Bromo-2-picoline

Cas:3430-13-5

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Wuhu Nuowei Chemistry Technologies Co., Ltd.

Wuhu Nuovo Chemical Technology Co., Ltd. was established in August 2014, mainly engaged in the development, production and sales of ionic liquids, ribose, nucleosides, nucleotides and related chemicals; Products are mainly used in new energy, new ma

5-Bromo-2-picoline

Cas:3430-13-5

Min.Order:100 Gram

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

5-Bromo-2-methylpyridine

Cas:3430-13-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

5-Amino-2-methylpyridine
80287-53-2, 3430-14-6

5-Amino-2-methylpyridine

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

Conditions
ConditionsYield
Stage #1: 5-Amino-2-methylpyridine With hydrogen bromide; bromine at -20 - -15℃; for 1.66667h;
Stage #2: With sodium nitrite In water at 20℃; for 1h;
Stage #3: With sodium hydroxide In water at -15 - 20℃; for 1h;
99%
Stage #1: 5-Amino-2-methylpyridine With hydrogen bromide; bromine In water at -20 - -15℃; for 1.66667h;
Stage #2: With sodium hydroxide; sodium nitrite In water at -25 - 20℃; for 1h; Time;
99%
With potassium nitrite; sulfuric acid anschliessend Behandeln mit Kupfer(I)-bromid;
5-bromo-2-pyridylacetic acid hydrochloride

5-bromo-2-pyridylacetic acid hydrochloride

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

Conditions
ConditionsYield
at 180℃; under 33 Torr;61%
α-picoline
109-06-8

α-picoline

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

Conditions
ConditionsYield
With aluminium trichloride; bromine at 100℃; for 2.5h;11%
With aluminum (III) chloride; bromine
picoline hydrochloride
14401-91-3

picoline hydrochloride

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

Conditions
ConditionsYield
With bromine Erhitzen des Reaktionsprodukts auf 130grad;
α-picoline
109-06-8

α-picoline

A

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

B

3-bromo-2-picoline
38749-79-0

3-bromo-2-picoline

Conditions
ConditionsYield
With aluminium trichloride; bromine at 100℃; for 0.5h;A 14.4 g
B 9.5 g
With aluminium trichloride; bromine at 100℃; for 19h;A n/a
B 4.2 g
6-methylnicotinamide
6960-22-1

6-methylnicotinamide

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NaOCl; aqueous KOH
2: aqueous sulfuric acid; potassium nitrite / anschliessend Behandeln mit Kupfer(I)-bromid
View Scheme
ethyl 6-methylnicotinate
21684-59-3

ethyl 6-methylnicotinate

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: aqueous NH3
2: NaOCl; aqueous KOH
3: aqueous sulfuric acid; potassium nitrite / anschliessend Behandeln mit Kupfer(I)-bromid
View Scheme
Multi-step reaction with 5 steps
1: N2H4+H2O
2: KNO2; aqueous HCl
4: aqueous KOH
5: aqueous sulfuric acid; potassium nitrite / anschliessend Behandeln mit Kupfer(I)-bromid
View Scheme
6-methylpyridine-3-carbohydrazide
197079-25-7

6-methylpyridine-3-carbohydrazide

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: KNO2; aqueous HCl
3: aqueous KOH
4: aqueous sulfuric acid; potassium nitrite / anschliessend Behandeln mit Kupfer(I)-bromid
View Scheme
6-methyl-nicotinoyl azide
64038-04-6

6-methyl-nicotinoyl azide

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
2: aqueous KOH
3: aqueous sulfuric acid; potassium nitrite / anschliessend Behandeln mit Kupfer(I)-bromid
View Scheme
(6-methyl-[3]pyridyl)-carbamic acid ethyl ester
247077-42-5

(6-methyl-[3]pyridyl)-carbamic acid ethyl ester

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous KOH
2: aqueous sulfuric acid; potassium nitrite / anschliessend Behandeln mit Kupfer(I)-bromid
View Scheme
1,3-bis(6-methylpyridin-3-yl)urea
858844-85-6

1,3-bis(6-methylpyridin-3-yl)urea

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: concentrated aqueous HCl / 130 °C
2: aqueous sulfuric acid; potassium nitrite / anschliessend Behandeln mit Kupfer(I)-bromid
View Scheme
5-Hydroxy-2-methylpyridine
1121-78-4

5-Hydroxy-2-methylpyridine

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

6-methylnicotinonitrile
3222-48-8

6-methylnicotinonitrile

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

Conditions
ConditionsYield
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane Reflux;
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

5-bromo-2-methyl-pyridine-N-oxide
31181-64-3

5-bromo-2-methyl-pyridine-N-oxide

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In chloroform at 0 - 20℃; for 2h;100%
Stage #1: 5-bromo-2-methylpyridine With dihydrogen peroxide; acetic acid In dichloromethane at 50℃; for 18h;
Stage #2: With potassium carbonate In dichloromethane; water pH=9;
99%
With 3-chloro-benzenecarboperoxoic acid In chloroform at 20℃; for 4h;99%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-methyl-5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)pyridine

2-methyl-5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)pyridine

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane at 85℃; for 16h; Suzuki Coupling;100%
With (C5H5FeC5H3C(CH3)NC6H4CH3)PdCl(tricyclohexylphosphine); potassium acetate In 1,4-dioxane at 100℃; for 6h; Suzuki coupling; Inert atmosphere;
With palladium bis[bis(diphenylphosphino)ferrocene] dichloride; potassium acetate In N,N-dimethyl-formamide at 80℃; for 16h;
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

3-iodo-6-methylpyridine
695-17-0

3-iodo-6-methylpyridine

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methylpyridine With n-butyllithium; isopropylmagnesium chloride In tetrahydrofuran; hexane at -10℃; for 0.5h;
Stage #2: With iodine In tetrahydrofuran at 0℃; for 2h;
99.5%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

tert-butyl(trimethylsilyl)phosphine
67033-70-9

tert-butyl(trimethylsilyl)phosphine

tert-butyl(6-methyl-3-pyridyl)phosphine

tert-butyl(6-methyl-3-pyridyl)phosphine

Conditions
ConditionsYield
bis-triphenylphosphine-palladium(II) chloride at 100℃; for 20h;99%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

4-dibenzofurylboronic acid
100124-06-9

4-dibenzofurylboronic acid

5-(dibenzo[b,d]furan-4-yl)-2-methylpyridine
1062229-27-9

5-(dibenzo[b,d]furan-4-yl)-2-methylpyridine

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In 1,2-dimethoxyethane; water at 80℃; Inert atmosphere;99%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

6-aminomethylpyridine-3-carbonitrile
782428-98-2

6-aminomethylpyridine-3-carbonitrile

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methylpyridine With iminodicarboxylic acid di-tert-butyl ester; sodium hydride In tetrahydrofuran at 5 - 20℃;
Stage #2: With hydrogenchloride In methanol at 0 - 20℃; for 3h;
97%
2,4-dimethylthiazole
541-58-2

2,4-dimethylthiazole

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

2,4-dimethyl-5-(6-methylpyridin-3-yl)thiazole

2,4-dimethyl-5-(6-methylpyridin-3-yl)thiazole

Conditions
ConditionsYield
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;97%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

5-(3-fluorophenyl)-2-methylpyridine
713143-67-0

5-(3-fluorophenyl)-2-methylpyridine

Conditions
ConditionsYield
With potassium phosphate; {2-[2-(di(2-naphthyloxy)phosphinoxy)-3,5-bis(tert-butyl)phenyl]-4,6-bis(tert-butyl)phenoxy}di(2-naphthyloxy)phosphine; (1,5-cyclo-octadiene) nickel complexes In toluene at 80℃; for 6h;96%
3,5-dimethyl-1,2-oxazole
300-87-8

3,5-dimethyl-1,2-oxazole

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

3,5-dimethyl-4-(6-methylpyridin-3-yl)isoxazol

3,5-dimethyl-4-(6-methylpyridin-3-yl)isoxazol

Conditions
ConditionsYield
With C68H65Cl2N3Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 12h; regioselective reaction;96%
1-methyl-1H-imidazole
616-47-7

1-methyl-1H-imidazole

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

2-methyl-5-(1-methyl-1H-imidazol-5-yl)pyridine

2-methyl-5-(1-methyl-1H-imidazol-5-yl)pyridine

Conditions
ConditionsYield
With C68H65Cl2N3Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 12h; regioselective reaction;96%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

(E)-5-bromo-2-(4-chlorostyryl)pyridine

(E)-5-bromo-2-(4-chlorostyryl)pyridine

Conditions
ConditionsYield
With 1,10-phenanthroline-5,6-dione; trifluorormethanesulfonic acid; oxygen In chlorobenzene at 120℃; under 760.051 Torr; for 24h;96%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

benzophenone hydrazone
5350-57-2

benzophenone hydrazone

N-benzhydrylidene-N'-(6-methyl-pyridin-3-yl)-hydrazine
337533-94-5

N-benzhydrylidene-N'-(6-methyl-pyridin-3-yl)-hydrazine

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate95%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

2-methyl-but-3-yn-2-ol
115-19-5

2-methyl-but-3-yn-2-ol

2-methyl-4-(6-methylpyridin-3-yl)but-3-yn-2-ol
52535-35-0

2-methyl-4-(6-methylpyridin-3-yl)but-3-yn-2-ol

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diisopropylamine at 60℃; for 6h;95%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

phenylmethanethiol
100-53-8

phenylmethanethiol

5-(benzylthio)-2-methylpyridine
907202-06-6

5-(benzylthio)-2-methylpyridine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); triethylamine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 100℃; for 16h; Inert atmosphere;95%
With N-ethyl-N,N-diisopropylamine; tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 110℃; for 3h;94%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

1,2-dimethyl-1H-imidazole
1739-84-0

1,2-dimethyl-1H-imidazole

5-(1,2-dimethyl-1H-imidazol-5-yl)-2-methylpyridine

5-(1,2-dimethyl-1H-imidazol-5-yl)-2-methylpyridine

Conditions
ConditionsYield
With C68H64Cl3N3Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 12h; Reagent/catalyst; regioselective reaction;95%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

2-[3-{(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)phenyl}-5-(9-phenanthryl)phenyl]-4,6-diphenyl-1,3,5-triazine
1380445-20-4

2-[3-{(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)phenyl}-5-(9-phenanthryl)phenyl]-4,6-diphenyl-1,3,5-triazine

4,6-diphenyl-2-[3-(6-methylpyridin-3-yl)-5-(9-phenanthryl)phenyl]-1,3,5-triazine

4,6-diphenyl-2-[3-(6-methylpyridin-3-yl)-5-(9-phenanthryl)phenyl]-1,3,5-triazine

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; XPhos In 1,4-dioxane; water at 80℃; for 24h; Inert atmosphere;94%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

benzaldehyde
100-52-7

benzaldehyde

5-(α-hydroxybenzyl)-2-methylpyridine

5-(α-hydroxybenzyl)-2-methylpyridine

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methylpyridine With n-butyllithium; isopropylmagnesium chloride In tetrahydrofuran; hexane at -10℃; for 0.5h;
Stage #2: benzaldehyde In tetrahydrofuran at 0℃; for 2h;
93%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

p-methoxybenzylmercaptan
6258-60-2

p-methoxybenzylmercaptan

5-(4-methoxybenzylsulfanyl)-2-methylpyridine

5-(4-methoxybenzylsulfanyl)-2-methylpyridine

Conditions
ConditionsYield
With C47H54OP2PdSi2; N-ethyl-N,N-diisopropylamine In 1,4-dioxane at 100℃; for 1h; Sealed tube; Inert atmosphere;92%
With N-ethyl-N,N-diisopropylamine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane for 7h; Heating;85%
With N-ethyl-N,N-diisopropylamine; tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In 1,4-dioxane for 7h; Suzuki-Miyaura reaction; Heating / reflux;85%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

allyl bromide
106-95-6

allyl bromide

5-allyl-2-methyl-pyridine

5-allyl-2-methyl-pyridine

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methylpyridine With n-butyllithium; isopropylmagnesium chloride In tetrahydrofuran; hexane at -10℃; for 0.5h;
Stage #2: allyl bromide In tetrahydrofuran at 0℃; for 2h;
92%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

phenylboronic acid
98-80-6

phenylboronic acid

5-phenyl-2-picoline
3256-88-0

5-phenyl-2-picoline

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water at 140℃; for 0.25h; Inert atmosphere; Microwave irradiation;92%
With 1-butyl-3-methylimidazolium hexafluorophosphate; palladium diacetate; sodium carbonate In water at 80℃; for 12h; Suzuki coupling; Inert atmosphere;86%
With potassium phosphate; [Pd2(3,4-dichloroacetophenone thiosemicarbazone)2(bis(diphenylphosphino)ferrocene)] In N,N-dimethyl-formamide at 130℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;73%
Conditions
ConditionsYield
With N4,N7-bis(2-hydroxyethyl)-1,10-phenanthroline-4,7-diamine; sodium L-ascorbate; potassium hydroxide; copper(I) bromide In water; N,N-dimethyl-formamide at 120℃; for 48h; Inert atmosphere; Sealed tube; regioselective reaction;92%
2-methylfuran
534-22-5

2-methylfuran

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

2-methyl-5-(5-methylfuran-2-yl)pyridine

2-methyl-5-(5-methylfuran-2-yl)pyridine

Conditions
ConditionsYield
With [Pd(IPr*IMe)An(3-Cl-pyridinyl)Cl2]; potassium carbonate; acetic acid In N,N-dimethyl acetamide at 130℃; for 12h; regioselective reaction;92%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

benzylamine
100-46-9

benzylamine

(E)-5-bromo-2-styrylpyridine

(E)-5-bromo-2-styrylpyridine

Conditions
ConditionsYield
With 1,10-phenanthroline-5,6-dione; trifluorormethanesulfonic acid; oxygen In chlorobenzene at 120℃; under 760.051 Torr; for 24h;92%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

2-isopropylbenzenethiol
6262-87-9

2-isopropylbenzenethiol

5-(2-isopropylphenylsulfanyl)-2-methylpyridine

5-(2-isopropylphenylsulfanyl)-2-methylpyridine

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane for 6h; Heating;91%
With N-ethyl-N,N-diisopropylamine; tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In 1,4-dioxane for 6h; Suzuki-Miyaura reaction; Heating / reflux;91%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

6,6’-dimethyl-3,3’-bipyridine
85484-42-0

6,6’-dimethyl-3,3’-bipyridine

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; cesium fluoride In dimethyl sulfoxide at 120℃; for 8h;91%
With tetrabutylammomium bromide; potassium carbonate; palladium diacetate In water; N,N-dimethyl-formamide; isopropyl alcohol for 48h; Heating;51%
Stage #1: 5-bromo-2-methylpyridine With tetrabutylammomium bromide; palladium diacetate; potassium carbonate In water; N,N-dimethyl-formamide at 115℃; for 0.0333333h; Inert atmosphere;
Stage #2: With isopropyl alcohol In water; N,N-dimethyl-formamide for 48h;
51%
4-Methylthiazole
693-95-8

4-Methylthiazole

5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

4-methyl-5-(6-methylpyridin-3-yl)thiazole

4-methyl-5-(6-methylpyridin-3-yl)thiazole

Conditions
ConditionsYield
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;91%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

4-methoxy-benzylamine
2393-23-9

4-methoxy-benzylamine

(E)-5-bromo-2-(4-methoxystyryl)pyridine

(E)-5-bromo-2-(4-methoxystyryl)pyridine

Conditions
ConditionsYield
With 1,10-phenanthroline-5,6-dione; trifluorormethanesulfonic acid; oxygen In chlorobenzene at 120℃; under 760.051 Torr; for 24h;90%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

C6(2)H6BrN

C6(2)H6BrN

Conditions
ConditionsYield
With water-d2; potassium carbonate; silver carbonate; cyclohexyldiphenylphosphine In toluene at 120℃; for 12h;90%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

tetraisopropylothiuram disulphide
4136-91-8

tetraisopropylothiuram disulphide

diisopropyl-dithiocarbamic acid 6-methyl-pyridin-3-yl ester

diisopropyl-dithiocarbamic acid 6-methyl-pyridin-3-yl ester

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methylpyridine With n-butyllithium; isopropylmagnesium chloride In tetrahydrofuran; hexane at -10℃; for 0.5h;
Stage #2: tetraisopropylothiuram disulphide In tetrahydrofuran at 0℃; for 2h;
89%

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