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Shandong Xingshun New Material Co., Ltd.

Changzhou Wujin Linchuan Chemical Co., Ltd. is re-established in 1996 from an old stated factory. Changzhou Wujin Linchuan Chemical Co., Ltd. is a privately owned independent company plants located in Changzhou and Yan Cheng City, who is stri

4-Biphenyl methanol with low price and high quality from professional factory

Cas:3597-91-9

Min.Order:3 Metric Ton

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Biphenylmethanol Manufacturer/High quality/Best price/In stock

Cas:3597-91-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay 98%min ---------------------------------------------------------------------------------------------

High purity Various Specifications 4-Biphenylmethanol CAS:3597-91-9

Cas:3597-91-9

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

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Jinan Finer Chemical Co., Ltd

Product description: Product name 4-Biphenylmethanol CAS number 3597-91-9 Assay ≥99% Appearance Off-white crystalline powder Capacity 200mt/year Application Organic intermedi

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-Biphenylmethanol

Cas:3597-91-9

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 3597-91-9 4-Biphenylmethanol Manufacturer

Cas:3597-91-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Phenylbenzyl alcohol

Cas:3597-91-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 3597-91-9 with best price

Cas:3597-91-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: 4-Biphenylmethanol Synonyms: 4-Biphenylmethanol(6CI,7CI,8CI);4-(Hydroxymethyl)biphenyl;4-Biphenylylmethanol;4-Hydroxymethyl-1,1'-biphenyl;4-Phenylbenzyl alcohol;[1,1'-Biphenyl]-4-methanol;NSC 233860;NSC84169;p-Phenylbenzyl alcohol;

4-Biphenylmethanol CAS: 3597-91-9

Cas:3597-91-9

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

99%min best quality 4-Biphenylmethanol 3597-91-9 in large stock 1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appea

99%min best quality 4-Biphenylmethanol 3597-91-9 in large stock

Cas:3597-91-9

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

4-Biphenylmethanol 3597-91-9

Cas:3597-91-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:25 Milliliter

FOB Price: $90.0 / 115.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:3597-91-9

Cas:3597-91-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

superiorquality moderate price & quick delivery Appearance:white to beige powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used to make

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:1 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

-Biphenylmethanol

Cas:3597-91-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Product Name:4-Biphenylmethanol CAS No:3597-91-9 Sy

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 4-Biphenylmethanol Synonyms: (1,1’-biphenyl)-4-methanol;4hmb;NSC 233860;Biphenyl-4-methanol 98%;4-Biphenylyl-methanol for synthesis;RARECHEM AL BD 0106;P-PHENYLBENZYL ALCOHOL;BIPHENYL-4-METHANOL CAS: 3597-91-9 MF: C13H

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & CommercialHisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, special chemicals and OLED

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

4-Biphenylmethanol

Cas:3597-91-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Synthetic route

biphenyl-4-carboxylic acid
92-92-2

biphenyl-4-carboxylic acid

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
100%
Stage #1: biphenyl-4-carboxylic acid With lithium aluminium tetrahydride In tetrahydrofuran; diethyl ether at 20℃; for 4h; Cooling with ice; Inert atmosphere;
Stage #2: With water In tetrahydrofuran; diethyl ether for 16h;
99%
With lithium aluminium tetrahydride In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;89%
4-Phenylbenzaldehyde
3218-36-8

4-Phenylbenzaldehyde

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
Stage #1: 4-Phenylbenzaldehyde With zinc diacetate In tetrahydrofuran at 65℃; for 0.166667h;
Stage #2: With methyl-di(n-propoxy)silane In tetrahydrofuran at 65℃; for 24h;
Stage #3: With hydrogenchloride; water at 0℃; for 1h;
99%
With iron(II) fluoro{tris[2-(diphenylphosphino)phenyl]phospino}tetrafluoroborate; hydrogen; trifluoroacetic acid In isopropyl alcohol at 120℃; under 15001.5 Torr; for 2h; Inert atmosphere; Autoclave; chemoselective reaction;99%
With C46H49CoN3P4(2+)*2BF4(1-); hydrogen; potassium hydroxide In ethanol; acetonitrile at 60℃; under 22801.5 Torr; for 24h; Autoclave; Glovebox; chemoselective reaction;99%
4-bromobenzenemethanol
873-75-6

4-bromobenzenemethanol

phenylboronic acid
98-80-6

phenylboronic acid

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With C20H20N2O2Pd; sodium hydrogencarbonate In water at 80℃; for 6h; Suzuki-Miyaura Coupling;99%
With trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); potassium carbonate In water for 0.5h; Catalytic behavior; Suzuki-Miyaura Coupling; Sealed tube; Inert atmosphere; Reflux;98%
With palladium diacetate; potassium carbonate In water; isopropyl alcohol at 20℃; for 0.25h; Suzuki-Miyaura Coupling;98%
methyl 4-phenylbenzoate
720-75-2

methyl 4-phenylbenzoate

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; Inert atmosphere;98%
With hydrogenchloride In water; acetone for 1.5h; pH=12;24%
With lithium aluminium tetrahydride
With diisobutylaluminium hydride In dichloromethane; toluene at -78℃;
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; for 1h; Inert atmosphere;
4-bromobenzenemethanol
873-75-6

4-bromobenzenemethanol

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With sodium carbonate at 80℃; for 1.16667h; Catalytic behavior; Suzuki Coupling;98%
With potassium carbonate for 4.25h; Suzuki-Miyaura Coupling;92%
With potassium carbonate at 100℃; for 5.25h; Catalytic behavior;90%
4-iodo-benzyl alcohol
18282-51-4

4-iodo-benzyl alcohol

phenylboronic acid
98-80-6

phenylboronic acid

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With sodium hydroxide; aluminum oxide; ruthenium In 1,2-dimethoxyethane; water at 90℃; for 12h; Suzuki-Miyaura-type cross coupling reaction;97%
With sodium t-butanolate In water at 28℃; for 4h; Catalytic behavior; Suzuki-Miyaura Coupling; Irradiation;96%
With potassium carbonate In ethanol at 20℃; for 6h; Suzuki-Miyaura Coupling;91%
p-hydroxymethylphenylboronic acid
59016-93-2

p-hydroxymethylphenylboronic acid

chlorobenzene
108-90-7

chlorobenzene

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With C37H44ClN2O3PPd; caesium carbonate In water at 100℃; for 12h; Suzuki Coupling; Schlenk technique; Inert atmosphere;97%
With potassium carbonate In water at 70℃; for 12h; Catalytic behavior; Temperature; Reagent/catalyst; Suzuki Coupling; Green chemistry;5 %Chromat.
4-bromobenzenemethanol
873-75-6

4-bromobenzenemethanol

triphenyltin chloride
639-58-7

triphenyltin chloride

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With potassium carbonate for 4h; Stille Cross Coupling;96%
With potassium carbonate at 100℃; for 5.5h; Catalytic behavior; Stille Cross Coupling;93%
para-Chlorobenzyl alcohol
873-76-7

para-Chlorobenzyl alcohol

phenylboronic acid
98-80-6

phenylboronic acid

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With [PdCl[(η5-C5H5)]Fe[(η5-C5H3)-C(CH3)=NOH](2-dicyclohexylphosphanyl-2'-(N,N-dimethylamino)biphenyl)]; caesium carbonate In water at 100℃; for 24h; Catalytic behavior; Reagent/catalyst; Concentration; Suzuki Coupling; Schlenk technique; Inert atmosphere;92%
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 5h; Catalytic behavior; Suzuki-Miyaura Coupling;88%
With C20H16Cl2N2Pd; potassium carbonate In N,N-dimethyl-formamide at 100℃; for 4h; Suzuki-Miyaura Coupling;83%
4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

phenylboronic acid
98-80-6

phenylboronic acid

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With potassium tert-butylate; C44H47I3IrN4PPd In tetrahydrofuran; isopropyl alcohol at 90℃; for 9h; Reagent/catalyst; Inert atmosphere; Schlenk technique;92%
With C31H37I3IrN5Pd; potassium tert-butylate; isopropyl alcohol In tetrahydrofuran at 90℃; for 2h; Reagent/catalyst; Inert atmosphere; Schlenk technique;85%
biphenyl-4-methylchloride
1667-11-4

biphenyl-4-methylchloride

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With water; sodium formate; sodium carbonate at 100 - 105℃; for 1h; pH=7 - 7.5; Reagent/catalyst;91%
With water at 100℃; for 24h;52%
With water In N,N-dimethyl-formamide at 80℃; under 2250.23 Torr; for 20h; Temperature; Sealed tube;
N, N-dimethyl [1,1’-biphenyl]-4-carboxamide
33322-67-7

N, N-dimethyl [1,1’-biphenyl]-4-carboxamide

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With sodium hydride; sodium iodide; zinc(II) iodide In tetrahydrofuran; mineral oil at 40℃; for 10h; Sealed tube;89%
bromobenzene
108-86-1

bromobenzene

p-hydroxymethylphenylboronic acid
59016-93-2

p-hydroxymethylphenylboronic acid

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With potassium carbonate In methanol; water at 40 - 45℃; for 4h; Suzuki Coupling;88%
With palladium diacetate; potassium carbonate In 2-methoxy-ethanol; water at 21℃; for 0.5h; Suzuki coupling;> 99 %Chromat.
With potassium phosphate In ethanol; water at 80℃; for 2h; Solvent; Reagent/catalyst; Time; Temperature; Suzuki-Miyaura Coupling;
With potassium carbonate In water at 70℃; for 12h; Catalytic behavior; Temperature; Reagent/catalyst; Suzuki Coupling; Green chemistry;75 %Chromat.
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

benzenediazonium tetrafluoroborate
369-57-3

benzenediazonium tetrafluoroborate

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
polystyrene-supported N-heterocyclic carbene-Pd complex In ethanol at 20℃; for 10h; Suzuki-Miyaura cross-coupling;87%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

2-bromomethoxy-tetrahydro-pyran
199998-50-0

2-bromomethoxy-tetrahydro-pyran

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With n-Butyl chloride; iodine; magnesium In 2-methyltetrahydrofuran at 60℃; for 2h; Inert atmosphere; Reflux;
Stage #2: 2-bromomethoxy-tetrahydro-pyran In 2-methyltetrahydrofuran at -20 - 20℃; for 3h; Inert atmosphere;
Stage #3: With hydrogenchloride In 2-methyltetrahydrofuran; water at 0 - 20℃;
86%
biphenyl-4-ylmethyl (4R,5S)-2,2-di-tert-butyl-5-methyl-1,3,2-dioxasilolane-4-carboxylate
1365259-42-2

biphenyl-4-ylmethyl (4R,5S)-2,2-di-tert-butyl-5-methyl-1,3,2-dioxasilolane-4-carboxylate

methylmagnesium chloride
676-58-4

methylmagnesium chloride

A

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

B

(3R,4S)-4-((di-tert-butyl(methyl)silyl)oxy)-3-hydroxypentan-2-one
1365259-43-3

(3R,4S)-4-((di-tert-butyl(methyl)silyl)oxy)-3-hydroxypentan-2-one

C

(3R,4S)-4-((di-tert-butyl(methyl)silyl)oxy)-2-methylpentane-2,3-diol
1365259-44-4

(3R,4S)-4-((di-tert-butyl(methyl)silyl)oxy)-2-methylpentane-2,3-diol

Conditions
ConditionsYield
Stage #1: biphenyl-4-ylmethyl (4R,5S)-2,2-di-tert-butyl-5-methyl-1,3,2-dioxasilolane-4-carboxylate; methylmagnesium chloride With N,O-dimethylhydroxylamine*hydrochloride In tetrahydrofuran at -10℃; for 0.166667h; Inert atmosphere;
Stage #2: With ammonium chloride In tetrahydrofuran; water at -10℃; Inert atmosphere; regioselective reaction;
A 85%
B 65%
C 16%
C4H11BrOSi

C4H11BrOSi

4'-biphenyl chloride
2051-62-9

4'-biphenyl chloride

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
Stage #1: 4'-biphenyl chloride With n-Butyl chloride; iodine; magnesium In 2-methyltetrahydrofuran at 60℃; for 2h; Inert atmosphere; Reflux;
Stage #2: C4H11BrOSi In 2-methyltetrahydrofuran at -20 - 20℃; for 3h; Inert atmosphere;
Stage #3: With hydrogenchloride In 2-methyltetrahydrofuran; water at 0 - 20℃;
85%
4-iodo-benzyl alcohol
18282-51-4

4-iodo-benzyl alcohol

triphenylbismuthane
603-33-8

triphenylbismuthane

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With tetrabutylammomium bromide; potassium acetate; palladium diacetate; tris-(o-tolyl)phosphine In 1-methyl-pyrrolidin-2-one at 110℃; for 4h; Schlenk technique; Inert atmosphere;85%
4-methoxybenzenediazonium tetrafluoroborate
459-64-3

4-methoxybenzenediazonium tetrafluoroborate

phenylboronic acid
98-80-6

phenylboronic acid

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
polystyrene-supported N-heterocyclic carbene-Pd complex In ethanol at 20℃; for 12h; Suzuki-Miyaura cross-coupling;84%
iodobenzene
591-50-4

iodobenzene

p-hydroxymethylphenylboronic acid
59016-93-2

p-hydroxymethylphenylboronic acid

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With sodium hydroxide In water at 20℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Green chemistry;84%
With potassium carbonate In water at 70℃; for 12h; Catalytic behavior; Temperature; Reagent/catalyst; Suzuki Coupling; Green chemistry;100 %Chromat.
bromethyl methyl ether
13057-17-5

bromethyl methyl ether

4'-biphenyl chloride
2051-62-9

4'-biphenyl chloride

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
Stage #1: 4'-biphenyl chloride With n-Butyl chloride; iodine; magnesium In tetrahydrofuran at 60℃; for 2h; Inert atmosphere; Reflux;
Stage #2: bromethyl methyl ether In tetrahydrofuran at -20 - 20℃; for 3h; Inert atmosphere;
Stage #3: With hydrogen bromide In tetrahydrofuran at 0 - 10℃;
84%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

chloromethyl trimethylsilyl ether
23586-77-8

chloromethyl trimethylsilyl ether

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With n-Butyl chloride; iodine; magnesium In 2-methyltetrahydrofuran at 60℃; for 2h; Inert atmosphere; Reflux;
Stage #2: trimethylsilyl chloromethyl ether In 2-methyltetrahydrofuran at -20 - 20℃; for 3h; Inert atmosphere;
83%
C6H11ClO2

C6H11ClO2

4'-biphenyl chloride
2051-62-9

4'-biphenyl chloride

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
Stage #1: 4'-biphenyl chloride With n-Butyl chloride; iodine; magnesium In tetrahydrofuran at 60℃; for 2h; Inert atmosphere; Reflux;
Stage #2: C6H11ClO2 In tetrahydrofuran at -20 - 20℃; for 3h; Inert atmosphere;
Stage #3: With hydrogenchloride In tetrahydrofuran; water at 0 - 20℃;
83%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With n-Butyl chloride; iodine; magnesium In tetrahydrofuran at 60℃; for 2h; Inert atmosphere; Reflux;
Stage #2: chloromethyl methyl ether In tetrahydrofuran at -20 - 20℃; for 3h; Inert atmosphere;
Stage #3: With hydrogen bromide In tetrahydrofuran at 0 - 10℃;
81%
biphenyl-4-methylchloride
1667-11-4

biphenyl-4-methylchloride

potassium carbonate
584-08-7

potassium carbonate

A

di(biphenyl-4-ylmethyl)carbonate
30952-04-6

di(biphenyl-4-ylmethyl)carbonate

B

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 110℃; for 36h;A 80%
B 2%
potassium (acetoxymethyl)trifluoroborate

potassium (acetoxymethyl)trifluoroborate

4'-biphenyl chloride
2051-62-9

4'-biphenyl chloride

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
With potassium phosphate; water; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate In 1,4-dioxane at 20℃; Heating / reflux;80%
4-bromobenzenemethanol
873-75-6

4-bromobenzenemethanol

tri(allyl)phenylsilane
2633-57-0

tri(allyl)phenylsilane

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
Stage #1: triallyl(phenyl)silane With tetrabutyl ammonium fluoride In water; dimethyl sulfoxide at 20℃; for 1h;
Stage #2: 4-bromobenzenemethanol With tricyclohexylphosphine; palladium dichloride In water; dimethyl sulfoxide at 80℃; for 4h;
79%
iodobenzene
591-50-4

iodobenzene

4-iodo-benzyl alcohol
18282-51-4

4-iodo-benzyl alcohol

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
Stage #1: 4-iodo-benzyl alcohol With dilithium tetra(tert-butyl)zincate In tetrahydrofuran at 20℃; for 2h;
Stage #2: iodobenzene With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; for 18h;
73%
Stage #1: 4-iodo-benzyl alcohol With dilithium tetra(tert-butyl)zincate In tetrahydrofuran at -78 - 20℃; Inert atmosphere;
Stage #2: iodobenzene With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at -78 - 20℃; Inert atmosphere; chemoselective reaction;
73%
(1S,3S,4S,5R,6R,7R)-1-((4S,5R)-4-Acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-4-(biphenyl-4-ylmethoxy)-7-hydroxy-6-methanesulfonyloxy-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3S,4S,5R,6R,7R)-1-((4S,5R)-4-Acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-4-(biphenyl-4-ylmethoxy)-7-hydroxy-6-methanesulfonyloxy-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

A

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

B

(1S,3R,5S,7R,8R,9R)-3-((4S,5R)-4-Acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-8-methanesulfonyloxy-2,4,6-trioxa-tricyclo[3.3.1.03,7]nonane-1,5,9-tricarboxylic acid tri-tert-butyl ester

(1S,3R,5S,7R,8R,9R)-3-((4S,5R)-4-Acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-8-methanesulfonyloxy-2,4,6-trioxa-tricyclo[3.3.1.03,7]nonane-1,5,9-tricarboxylic acid tri-tert-butyl ester

C

(1S,3R,4S,5S,6S,7R)-1-((4S,5R)-4-Acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-4-(biphenyl-4-ylmethoxy)-7-hydroxy-2,8-dioxa-tricyclo[3.2.1.03,6]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

(1S,3R,4S,5S,6S,7R)-1-((4S,5R)-4-Acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-4-(biphenyl-4-ylmethoxy)-7-hydroxy-2,8-dioxa-tricyclo[3.2.1.03,6]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

Conditions
ConditionsYield
With cesium fluoride In N,N-dimethyl-formamide at 70℃;A 21%
B 2%
C 70%
[1,1'-biphenyl]-4-ylmethyl methanesulfonate
376640-26-5

[1,1'-biphenyl]-4-ylmethyl methanesulfonate

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

Conditions
ConditionsYield
Multistep reaction;70%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

trichloroacetonitrile
545-06-2

trichloroacetonitrile

4-phenylbenzyl trichloroacetimidate
200057-74-5

4-phenylbenzyl trichloroacetimidate

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydrogensulfate; potassium hydroxide In dichloromethane; water at 0 - 25℃;100%
Stage #1: biphenyl-4-yl methanol With sodium hydride In diethyl ether; oil at 20℃; for 0.0833333h;
Stage #2: trichloroacetonitrile In diethyl ether; oil at 20℃; for 2h;
97%
With sodium hydride In diethyl ether 1.) 20 min, 2.) r.t., 1 h;69%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

4-Phenylbenzaldehyde
3218-36-8

4-Phenylbenzaldehyde

Conditions
ConditionsYield
With n-butyltriphenylphosphonium permanganate In acetonitrile at 20℃; for 0.25h;100%
With silica-supported Jones reagent In dichloromethane for 0.00269444h;99.7%
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; N-methyl-N-[3-(4'-diacetoxyiodo)phenoxy-1-propyl]pyrrolidinium 4-methylbenzenesulfonate In dichloromethane at 20℃; for 6h;99%
methyl 2-isocyanatobenzoate
1793-07-3

methyl 2-isocyanatobenzoate

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

methyl 2-({[(4-biphenylylmethyl)oxy]carbonyl}amino)benzoate
906089-93-8

methyl 2-({[(4-biphenylylmethyl)oxy]carbonyl}amino)benzoate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; Heating / reflux;100%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

4-(azidomethyl)-1,1'-biphenyl
222716-16-7

4-(azidomethyl)-1,1'-biphenyl

Conditions
ConditionsYield
Stage #1: biphenyl-4-yl methanol With 1,2-Diiodoethane; N,N-dimethyl-formamide; triphenylphosphine at 20℃; for 0.0166667h; Sealed tube; Inert atmosphere;
Stage #2: With sodium azide at 20℃; Sealed tube; Inert atmosphere;
100%
With 2-azido-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-ium hexafluorophosphate (V); 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 20℃; for 0.166667h;93%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

N-benzoyloxybenzotriazole
54769-36-7

N-benzoyloxybenzotriazole

[1,1'-biphenyl]-4-ylmethyl benzoate
38418-12-1

[1,1'-biphenyl]-4-ylmethyl benzoate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃;100%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

N-methylaniline
100-61-8

N-methylaniline

N-([1,1'-biphenyl]-4-ylmethyl)-N-methylaniline

N-([1,1'-biphenyl]-4-ylmethyl)-N-methylaniline

Conditions
ConditionsYield
Stage #1: biphenyl-4-yl methanol With 1,2-Diiodoethane; N,N-dimethyl-formamide; triphenylphosphine at 50℃; for 0.0166667h; Sealed tube; Inert atmosphere;
Stage #2: N-methylaniline at 50℃; Sealed tube; Inert atmosphere;
100%
sodium benzoate
532-32-1

sodium benzoate

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

[1,1'-biphenyl]-4-ylmethyl benzoate
38418-12-1

[1,1'-biphenyl]-4-ylmethyl benzoate

Conditions
ConditionsYield
Stage #1: biphenyl-4-yl methanol With 1,2-Diiodoethane; N,N-dimethyl-formamide; triphenylphosphine at 20℃; for 0.0166667h; Sealed tube; Inert atmosphere;
Stage #2: sodium benzoate at 20℃; Sealed tube; Inert atmosphere;
100%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

biphenyl-4-carboxylic acid
92-92-2

biphenyl-4-carboxylic acid

Conditions
ConditionsYield
With silica-supported Jones reagent In dichloromethane for 0.035h;99.5%
With diethylene glycol dimethyl ether at 70℃; for 0.583333h; Sonication;96%
With sodium tetrahydroborate; 1% Pd/C; water; potassium hydroxide In methanol at 20℃; for 6h; In air;89%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

4-cyano-1,1'-biphenyl
2920-38-9

4-cyano-1,1'-biphenyl

Conditions
ConditionsYield
Stage #1: biphenyl-4-yl methanol With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; tert-butylhypochlorite In dichloromethane at 20℃; for 2h; Inert atmosphere;
Stage #2: With ammonia; iodine In dichloromethane; water at 20℃; for 2h; Inert atmosphere;
99%
With ammonia; oxygen In tert-Amyl alcohol; water at 100℃; under 3750.38 Torr; for 6h; Autoclave; High pressure;99%
With 1,4-diaza-bicyclo[2.2.2]octane; TEMPOL; ammonia; copper(l) chloride In water; acetonitrile at 20℃; for 24h;91%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

potassium acetate
127-08-2

potassium acetate

[1,1’-biphenyl]-4-ylmethyl acetate
62037-98-3

[1,1’-biphenyl]-4-ylmethyl acetate

Conditions
ConditionsYield
Stage #1: biphenyl-4-yl methanol With 1,2-Diiodoethane; N,N-dimethyl-formamide; triphenylphosphine at 20℃; for 0.0166667h; Sealed tube; Inert atmosphere;
Stage #2: potassium acetate at 20℃; Sealed tube; Inert atmosphere;
99%
carbon disulfide
75-15-0

carbon disulfide

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

C14H11OS2(1-)*K(1+)

C14H11OS2(1-)*K(1+)

Conditions
ConditionsYield
With potassium hydroxide In diethyl ether at 20℃; for 12h;99%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

[1,1'-biphenyl]-4-ylmethyl formate

[1,1'-biphenyl]-4-ylmethyl formate

Conditions
ConditionsYield
With fluorosulfonyl fluoride; caesium carbonate at 20℃; for 12h; Reagent/catalyst; Sealed tube;99%
9H-fluorene
86-73-7

9H-fluorene

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

9-([1,1′-biphenyl]-4-methyl)-9H-fluorene

9-([1,1′-biphenyl]-4-methyl)-9H-fluorene

Conditions
ConditionsYield
With potassium tert-butylate In toluene at 120℃; for 3h; Inert atmosphere;99%
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; potassium tert-butylate In toluene at 120℃; for 18h; Inert atmosphere; Sealed tube;73%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

p-phenylbenzyl bromide
2567-29-5

p-phenylbenzyl bromide

Conditions
ConditionsYield
With bromine; triphenylphosphine In dichloromethane at -78 - 20℃; for 18h; Inert atmosphere;98%
With bromine; triphenylphosphine In dichloromethane at -78 - 25℃; for 18h;97%
With carbon tetrabromide; triphenylphosphine In dichloromethane at 20℃; for 1.5h;95%
N,N-dimethyl acetamide
127-19-5

N,N-dimethyl acetamide

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

N,N-dimethyl-3-((1,1'-biphenyl)-4-yl)propanamide

N,N-dimethyl-3-((1,1'-biphenyl)-4-yl)propanamide

Conditions
ConditionsYield
With tri-tert-butyl phosphine; potassium tert-butylate; nickel diacetate In 1,4-dioxane; toluene at 80℃; for 12h; Inert atmosphere; Glovebox; Schlenk technique;98%
With [2,2]bipyridinyl; (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); potassium tert-butylate at 140℃; for 18h;89%
With potassium tert-butylate In 1,3,5-trimethyl-benzene at 164℃; for 6h;75%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

t-butyl 2-benzoyloximino-2-cyanoacetate

t-butyl 2-benzoyloximino-2-cyanoacetate

[1,1'-biphenyl]-4-ylmethyl benzoate
38418-12-1

[1,1'-biphenyl]-4-ylmethyl benzoate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃;98%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

sodium phenoxide
139-02-6

sodium phenoxide

1-phenyl-4-phenoxymethylbenzene
29263-69-2

1-phenyl-4-phenoxymethylbenzene

Conditions
ConditionsYield
Stage #1: biphenyl-4-yl methanol With 1,2-Diiodoethane; N,N-dimethyl-formamide; triphenylphosphine at 20℃; for 0.0166667h; Sealed tube; Inert atmosphere;
Stage #2: sodium phenoxide at 20℃; Sealed tube; Inert atmosphere;
98%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

[1,1'-biphenyl]-4-ylmethyl nitrite

[1,1'-biphenyl]-4-ylmethyl nitrite

Conditions
ConditionsYield
With 3,3-dimethyl-2-nitroso-2,3-dihydrobenzo[d]isothiazole 1,1-dioxide; trifluoroacetic acid In acetonitrile at 20℃; for 0.5h; Temperature; Solvent; Sealed tube;98%
5-Fluoro-4-trifluoromethyl-2-phenyloxazole
70276-69-6

5-Fluoro-4-trifluoromethyl-2-phenyloxazole

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

5-(Biphenyl-4-ylmethoxy)-2-phenyl-4-trifluoromethyl-oxazole
126745-85-5

5-(Biphenyl-4-ylmethoxy)-2-phenyl-4-trifluoromethyl-oxazole

Conditions
ConditionsYield
With potassium hydroxide In 1,4-dioxane97%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

benzonitrile
100-47-0

benzonitrile

N-(4-phenylbenzyl)benzamide
372137-79-6

N-(4-phenylbenzyl)benzamide

Conditions
ConditionsYield
With magnesium hydrogen sulfate at 20℃; for 4h;97%
Phthalic acid mono-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethyl) ester

Phthalic acid mono-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethyl) ester

biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

phenyl 2,3,4-tri-O-benzyl-6-O-[2-[(4-phenylbenzyl)oxycarbonyl]benzoyl]-1-thio-α-D-glucopyranoside
848866-41-1

phenyl 2,3,4-tri-O-benzyl-6-O-[2-[(4-phenylbenzyl)oxycarbonyl]benzoyl]-1-thio-α-D-glucopyranoside

Conditions
ConditionsYield
With dacarbazine; dmap In dichloromethane97%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

acetic anhydride
108-24-7

acetic anhydride

[1,1’-biphenyl]-4-ylmethyl acetate
62037-98-3

[1,1’-biphenyl]-4-ylmethyl acetate

Conditions
ConditionsYield
With colloidal gold nanoparticle-supported gadolinium complex In N,N-dimethyl-formamide for 0.0166667h; Reagent/catalyst; Microwave irradiation;97%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

3-acetylenephenylamine
54060-30-9

3-acetylenephenylamine

C21H15N

C21H15N

Conditions
ConditionsYield
With oxygen In toluene at 90℃; Sealed tube;97%
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