1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ
Cas:3673-79-8
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:3673-79-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:3673-79-8
Min.Order:10 Gram
Negotiable
Type:Lab/Research institutions
inquiryZhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed
Cas:3673-79-8
Min.Order:1 Kilogram
FOB Price: $2.0
Type:Lab/Research institutions
inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:3673-79-8
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryhight degree of purity Application:Fine chemical intermediates, used as the main raw material for he synthesis of various pesticides, medicines, surfactants, polymer monomers, Ond Ontifungal agents
Cas:3673-79-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquirylaboratory Application:Synthetic building block
Cas:3673-79-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?sale Application:Fine chemical intermediates, used as the main raw material for the synthesis of various pesticides, medicines, surfactants, polymer monomers, and antifungal agents
Cas:3673-79-8
Min.Order:0
Negotiable
Type:Other
inquiryConditions | Yield |
---|---|
With bromine at 0 - 20℃; | 98% |
With bromine In tetrachloromethane at 0℃; for 3.5h; | 94% |
With bromine In tetrachloromethane at 0℃; for 3.5h; Inert atmosphere; | 91% |
methacrylic acid methyl ester
A
methyl 2,3-dibromoisobutyrate
B
2-bromo-3-hydroxy-2-methylpropionate
C
3-bromo-2-hydroxy-2-methylpropionate
Conditions | Yield |
---|---|
With bromine In water at 30℃; Rate constant; Thermodynamic data; Product distribution; other temperatures (22, 38, 46, 54 deg C), ΔH*, ΔS*, ΔG*; | |
With bromine In water Mechanism; |
methyl 2,3-dibromoisobutyrate
methyl α,β-difluoroisobutyrate
Conditions | Yield |
---|---|
With chlorine monofluoride | 93% |
With bromine trifluoride In 1,1,2-Trichloro-1,2,2-trifluoroethane at 20℃; for 1.5h; | 65 % Turnov. |
Multi-step reaction with 2 steps 1: trifluoroacetyl hypochlorite/HF (l) / 5 h / Ambient temperature 2: hexachloromelamine/HF (l) / 4 h / -15 - 0 °C View Scheme |
methyl 2,3-dibromoisobutyrate
sodium methylate
methyl 3,3-dimethoxy-2-methylpropionate
Conditions | Yield |
---|---|
In methanol for 1h; Dehydrobromination; addition; Heating; | 92% |
In methanol at 70℃; for 3h; | 39.4 g |
In methanol at 70℃; for 3h; | |
In methanol | |
In methanol at 50 - 70℃; for 2h; Temperature; | 234.01 g |
methyl 2,3-dibromoisobutyrate
triphenylphosphine
C
Triphenylphosphine oxide
Conditions | Yield |
---|---|
Stage #1: methyl 2,3-dibromoisobutyrate; triphenylphosphine In acetonitrile for 12h; Heating; Stage #2: With water In acetonitrile at 20℃; Further stages.; | A 53.3% B 20% C 88% |
methyl 2,3-dibromoisobutyrate
triphenylphosphine
B
Triphenylphosphine oxide
Conditions | Yield |
---|---|
Stage #1: methyl 2,3-dibromoisobutyrate; triphenylphosphine In acetonitrile at 20℃; for 0.25h; Stage #2: With water In acetonitrile at 20℃; Further stages.; | A 32% B 86% |
methanol
methyl 2,3-dibromoisobutyrate
sodium methylate
methyl 3-methoxy-2-methyl-acrylate
Conditions | Yield |
---|---|
Stage #1: methanol; methyl 2,3-dibromoisobutyrate; sodium methylate at 68℃; for 14h; Inert atmosphere; Stage #2: With sodium hydrogensulfate monohydrate at 160℃; under 760.051 Torr; Inert atmosphere; | 72% |
methyl 2,3-dibromoisobutyrate
methyl (E)-3-bromo-2-methyl-2-propenoate
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran for 1.5h; Heating; | 71% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran for 2h; Reflux; | 66% |
With sodium methylate In methanol | 51% |
methyl 2,3-dibromoisobutyrate
A
methyl β-bromo-α-fluoroisobutyrate
B
methyl α-bromo-β-fluoroisobutyrate
Conditions | Yield |
---|---|
With hydrogen fluoride; hexachloromelamine at 0 - 15℃; | A 70% B 12% |
With chlorine monofluoride | A 68% B 24% |
With bromine trifluoride; hydrogen fluoride In various solvent(s) at 10 - 20℃; for 24h; | A 60% B 15% |
With trichloroisocyanuric acid; hydrogen fluoride for 5h; Ambient temperature; Yield given. Yields of byproduct given; | |
With Trifluoracylhypochlorit; hydrogen fluoride for 5h; Ambient temperature; Yield given. Yields of byproduct given; |
methyl 2,3-dibromoisobutyrate
1,1-dimethylhydrazine
methyl α-formylpropionate E-N,N-dimethylhydrazone
Conditions | Yield |
---|---|
With triethylamine In acetonitrile at 25℃; for 72h; | 51.5% |
methyl 2,3-dibromoisobutyrate
methyl 3-bromo-2-methyl-2-propenoate
Conditions | Yield |
---|---|
With 1-Methyl-1-phenylhydrazine; triethylamine In acetonitrile 1.)25 deg C, 1 month 2.)reflux, 18 h; | 51% |
With potassium carbonate In acetone for 7h; Heating; in the presence of catechol; | |
With methanol; sodium methylate |
Conditions | Yield |
---|---|
With tert-butyl alcohol |
methyl 2,3-dibromoisobutyrate
sodium methylate
Methyl 3-methoxy-2-methyl-2-propenoate
Conditions | Yield |
---|---|
With methanol Erhitzen des Reaktionsprodukts mit wenig Kaliumhydrogensulfat,Natriummethylat oder Natriumhydrogensulfat bis auf 170grad; | |
With sodium hydrogensulfite Yield given. Multistep reaction; |
methyl 2,3-dibromoisobutyrate
sodium ethanolate
ethyl bromomethacrylate
Conditions | Yield |
---|---|
With ethanol |
methyl 2,3-dibromoisobutyrate
sodium ethanolate
ethyl (ethoxymethylene)methylacetate
Conditions | Yield |
---|---|
With ethanol Erhitzen des Reaktionsprodukts mit wenig Kaliumhydrogensulfat bis auf 200grad; |
methyl 2,3-dibromoisobutyrate
sodium phenoxide
2-methyl-3ξ-phenoxy-acrylic acid methyl ester
Conditions | Yield |
---|---|
at 150℃; |
methyl 2,3-dibromoisobutyrate
2,3-Dibromo-2-methylpropanamide
Conditions | Yield |
---|---|
With ammonia; water |
methyl 2,3-dibromoisobutyrate
aniline
N-phenyl α,β-dibromo-α-methylpropionamide
morpholine
methyl 2,3-dibromoisobutyrate
2-methyl-3-morpholin-4-yl-acrylic acid methyl ester
methyl 2,3-dibromoisobutyrate
potassium thioacetate
methyl L-(+)-3-acetylthio-2-methylpropionate
methyl 2,3-dibromoisobutyrate
methyl (Z)-3-bromo-2-methyl-propenoate
Conditions | Yield |
---|---|
With triethylamine In acetonitrile |
1H-imidazole
methyl 2,3-dibromoisobutyrate
methyl E-3-(1-imidazolyl)methacrylate
Conditions | Yield |
---|---|
With sodium hydride 1.) DMF, benzene, ice methanol bath; 2.) room temp., overnight.; Yield given. Multistep reaction; |
methyl 2,3-dibromoisobutyrate
sodium methylate
A
methyl 3-methoxy-2-methyl-acrylate
B
methyl 3,3-dimethoxy-2-methylpropionate
Conditions | Yield |
---|---|
In methanol at 25℃; for 16h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; |
methyl 2,3-dibromoisobutyrate
benzene-1,2-diol
A
methyl 3-bromo-2-methyl-2-propenoate
B
methyl 2-(1,3-benzodioxol-2-yl)-propanoate
Conditions | Yield |
---|---|
With sodium hydride In N,N-dimethyl-formamide at 120℃; for 8h; | A 2 g B 2.7 g |
methyl 2,3-dibromoisobutyrate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 51 percent / NaOMe / methanol 2: 45 percent / NaOMe / methanol / 12 h / 0 - 20 °C View Scheme |
methyl 2,3-dibromoisobutyrate
methyl 2-methyl-3-oxopropanoate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 92 percent / methanol / 1 h / Heating 2: aq. HCl / 1 h / 20 °C View Scheme | |
Multi-step reaction with 3 steps 1: NaOMe / methanol 3: aq. H2SO4 View Scheme |
methyl 2,3-dibromoisobutyrate
2-Methyl-3,3-bis-(2-trimethylsilanyl-ethoxy)-propan-1-ol
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: methanol / 16 h / 25 °C 2: 40 percent / p-toluenesulfonic acid monohydrate / 12 h / 80 °C 3: 82 percent / LiAlH4 / tetrahydrofuran / 6 h / 25 °C View Scheme |
methyl 2,3-dibromoisobutyrate
2-Methyl-3,3-bis-(2-trimethylsilanyl-ethoxy)-propionaldehyde
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: methanol / 16 h / 25 °C 2: 40 percent / p-toluenesulfonic acid monohydrate / 12 h / 80 °C 3: 82 percent / LiAlH4 / tetrahydrofuran / 6 h / 25 °C 4: 40 percent / pyridinium chlorochromate, sodium acetate, magnesium sulfate / CH2Cl2 / 3 h / 25 °C View Scheme |
methyl 2,3-dibromoisobutyrate
2-Methyl-3,3-bis-(2-trimethylsilanyl-ethoxy)-propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: methanol / 16 h / 25 °C 2: 40 percent / p-toluenesulfonic acid monohydrate / 12 h / 80 °C View Scheme |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View