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Cas:4606-07-9
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inquiryProduct Description Product website: http://www.finerchem.com Product Name Ethyl cyclopropanecarboxylate CAS No. 4606-07-9 Appearan
Cas:4606-07-9
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiryDayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti
Cas:4606-07-9
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inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:4606-07-9
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inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O
Cas:4606-07-9
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:4606-07-9
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inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:4606-07-9
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inquiryEthyl cyclopropanecarboxylate CAS: 4606-07-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality org
Cas:4606-07-9
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Cas:4606-07-9
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inquiryAppearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By
Cas:4606-07-9
Min.Order:100 Gram
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Type:Lab/Research institutions
inquiryCompany Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments
Cas:4606-07-9
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:4606-07-9
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inquiryMassive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Cas:4606-07-9
Min.Order:1 Gram
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inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:4606-07-9
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryProduct name: Cyclopropanecarboxylic Acid Ethyl Ester CAS No.:4606-07-9 Molecule Formula:C6H10O2 Molecule Weight:114.14 Purity: 99.0% Package: 200kg/drum Description:Colorless to slight yellow liquid Manufacture Standards:Enterprise S
Cas:4606-07-9
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiryEthyl cyclopropanecarboxylate Basic information Product Name: Ethyl cyclopropanecarboxylate Synonyms: Ethyl cyclopropylcarboxylate;NSC 60696;ETHYLCYCLOPROPANCARBOXYL.S;(Ethoxycarbonyl)cyclopropane;Ethyl Cyclopropanecarboxylate, 97+%;ETHYL CYCL
Cas:4606-07-9
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryHigh quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use
Cas:4606-07-9
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inquiryStock products, own laboratoryAppearance:light yellow liquid Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai
Cas:4606-07-9
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Type:Lab/Research institutions
inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
Cas:4606-07-9
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inquiryShanghai Lonwin Chemical company is a subsidiary of Lonwin Industry Group Limited, was established in 2011 and is headquartered in Shanghai, adjacent to China National Convention and Exhibition Center and Hongqiao transportation hub.Lonwinchem is
Cas:4606-07-9
Min.Order:100 Kilogram
FOB Price: $100.0 / 150.0
Type:Other
inquiryOur clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
Cas:4606-07-9
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Type:Manufacturers
inquiryTAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp
Product Name: Ethyl cyclopropanecarboxylate Synonyms: NSC 60696;ETHYLCYCLOPROPANCARBOXYL.S;(Ethoxycarbonyl)cyclopropane;Ethyl Cyclopropanecarboxylate, 97+%;Ethyl cyclopropylcarboxylate;ETHYL CYCLOPROPANECAR
Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
Cas:4606-07-9
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inquiryAmoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi
High purity Ethyl cyclopropanecarboxylate 98% TOP1 supplier in China Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
Cas:4606-07-9
Min.Order:0 Metric Ton
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Type:Other
inquirygood quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:25kg,50kg,180kg,200kg,250kg,1000kg,customization Application:Pharma;Industry;Agricultural;chemical reaserch Tran
Cas:4606-07-9
Min.Order:0
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inquiryWe are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white to yellow powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as
Conditions | Yield |
---|---|
With sulfuric acid In ethanol | 98% |
ethyl α,γ-dichlorobutyrate
ethyl cyclopropylcarboxylate
Conditions | Yield |
---|---|
With tetraethylammonium tosylate In dimethyl sulfoxide electrolysis; | 82% |
4-bromoethylbutanoate
A
ethyl 4-hydroxybutanoate
B
ethyl cyclopropylcarboxylate
Conditions | Yield |
---|---|
With oxygen; tetraethylammonium perchlorate In N,N-dimethyl-formamide at 20℃; electroreduction at -1.1 V; | A 10% B 68% |
Conditions | Yield |
---|---|
Stage #1: n-octyne With n-butyllithium In tetrahydrofuran at 20℃; Stage #2: ethyl 4-iodobutyrate In tetrahydrofuran at 20℃; | A 9% B 65% |
Conditions | Yield |
---|---|
With sodium tert-pentoxide; benzene | |
With sodium tert-pentoxide In benzene | |
With N-(diphenylmethylidene)phenylamine at -78℃; | |
With copper(I) oxide; Cyclohexyl isocyanide | |
With potassium hydroxide; tetrabutylammomium bromide In toluene at 40℃; for 2h; | 91 % Chromat. |
3-Bromo-2-bromomethyl-propionic acid ethyl ester
ethyl cyclopropylcarboxylate
Conditions | Yield |
---|---|
With ethanol; zinc |
4-bromoethylbutanoate
ethyl 2-oxocyclohexane carboxylate
A
ethyl cyclopropylcarboxylate
B
ethyl 1-(3-(ethoxycarbonyl)propyl)-2-oxocyclohexanecarboxylate
Conditions | Yield |
---|---|
With sodium ethanolate |
Conditions | Yield |
---|---|
With sulfuric acid | |
With ε-caprolactam methyl sulfonate at 30℃; for 8h; chemoselective reaction; | 87 %Chromat. |
With quaternary ammonium salt functionalized methoxypolyethylene glycols-supported phosphotungstic acid catalyst at 50℃; for 3h; | |
With thionyl chloride Reflux; | |
With sulfuric acid for 12h; Inert atmosphere; Reflux; |
Tosylat von 4-Aethoxy-butin-(3)-ol
ethyl cyclopropylcarboxylate
Conditions | Yield |
---|---|
With pyridine In water; acetone at 55℃; for 120h; |
oxirane
diethoxyphosphoryl-acetic acid ethyl ester
ethyl cyclopropylcarboxylate
Conditions | Yield |
---|---|
With 1.) base Multistep reaction; |
ethyl 2,4-dibromobutyrate
A
4-bromoethylbutanoate
B
ethyl cyclopropylcarboxylate
C
butanoic acid ethyl ester
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 20℃; Product distribution; Mechanism; electrolysis; I*, napp; various conc. of the ester; in the presence and in the absence of 3,4-xylenol; |
4-bromoethylbutanoate
Boc-Tyr-OH
A
ethyl cyclopropylcarboxylate
B
ethyl 4-<4'-<<2-<(tert-butoxycarbonyl)amino>-2-carboxy>ethyl>phenoxy>butanoate
Conditions | Yield |
---|---|
With sodium hydride 1.) THF, RT, 5 min, 2.) THF, reflux, 21 h; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With 1-hydroxy-2(1H)-pyridinethione; dicyclohexyl-carbodiimide 1.) CHCl3, room temperature, 6 h, 2.) CHCl3, room temperature, irradiation; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With 2-mercaptopyridine-1-oxide sodium salt 2.) room temperature, irradiation; Multistep reaction; |
4-chloro-butyric acid ethyl ester
A
4-butanolide
B
ethyl cyclopropylcarboxylate
C
cyclopropanecarboxylic acid
Conditions | Yield |
---|---|
at 180℃; |
Conditions | Yield |
---|---|
With potassium hydroxide; pumice stone at 180℃; |
Conditions | Yield |
---|---|
With sulfuric acid |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 58 percent / magnesium iodide / toluene / 8 h / Heating 2: 1.) 1-hydroxy-pyridine-2-thione, dicyclohexyl-carbodiimide / 1.) CHCl3, room temperature, 6 h, 2.) CHCl3, room temperature, irradiation View Scheme |
Conditions | Yield |
---|---|
With phenylhydrazine In toluene | |
In ethyl acetate; toluene |
Conditions | Yield |
---|---|
With chloro(1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene)gold(I); sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In dichloromethane at 40℃; under 6000.6 Torr; for 14h; Catalytic behavior; Temperature; Inert atmosphere; Schlenk technique; | 70 %Chromat. |
diazoacetic acid ethyl ester
ethene
A
ethyl cyclopropylcarboxylate
B
diethyl Fumarate
C
Diethyl maleate
Conditions | Yield |
---|---|
With tetrakis(trifluoroacetato)rhodium(II) In dichloromethane at 20℃; under 6000.6 Torr; for 14h; Reagent/catalyst; Inert atmosphere; Schlenk technique; | A 41 %Chromat. B n/a C n/a |
diazoacetic acid ethyl ester
ethene
A
ethyl cyclopropylcarboxylate
(E)-Cyclopropan-1,2,3-tricarbonsaeuretriethylester
Conditions | Yield |
---|---|
With chloro(1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene)gold(I); sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In dichloromethane at 20℃; under 1500.15 Torr; for 14h; Catalytic behavior; Pressure; Inert atmosphere; Schlenk technique; | A 39 %Chromat. B 35 %Chromat. |
Conditions | Yield |
---|---|
With hydrazine hydrate at 120℃; for 16h; | 100% |
With hydrazine hydrate | |
With hydrazine In ethanol for 3h; Heating; | |
With hydrazine hydrate at 80℃; | |
With hydrazine hydrate In ethanol at 80℃; for 18h; Sealed tube; |
ethyl cyclopropylcarboxylate
2-((2-methoxyphenyl)thio)acetonitrile
Conditions | Yield |
---|---|
Stage #1: 2-((2-methoxyphenyl)thio)acetonitrile With n-butyllithium In hexane at -78℃; Stage #2: ethyl cyclopropylcarboxylate In hexane at -78 - 20℃; | 100% |
ethyl cyclopropylcarboxylate
dimethyl aluminum selenide
Cyclopropanecarboselenoic acid Se-methyl ester
Conditions | Yield |
---|---|
In dichloromethane; toluene 1.) 0 deg C, 2.) up to RT; | 96% |
ethyl cyclopropylcarboxylate
benzene
2,3-dihydro-2-methyl-1H-inden-1-one
Conditions | Yield |
---|---|
aluminium trichloride for 16h; Heating; | 93% |
Conditions | Yield |
---|---|
With magnesium In diethyl ether 1) room temp., 30 min, 2) reflux, 1 h; | 92.7% |
ethyl cyclopropylcarboxylate
acetonitrile
3-cyclopropyl-3-oxo-propionitrile
Conditions | Yield |
---|---|
With sodium hydride In 1,4-dioxane; mineral oil at 20℃; for 16h; | 90% |
With potassium tert-butylate; isopropyl alcohol In 2-methyltetrahydrofuran at 20℃; for 2h; Solvent; Time; Inert atmosphere; | 48% |
With sodium hydride In tetrahydrofuran for 15h; Heating / reflux; |
ethyl cyclopropylcarboxylate
(2-fluorophenyl)acetic acid
1-cyclopropyl-2-(2-fluorophenyl)ethanone
Conditions | Yield |
---|---|
With sodium hydride In dimethyl sulfoxide; toluene at 95 - 110℃; for 1.5h; Large scale; | 88% |
Stage #1: (2-fluorophenyl)acetic acid With magnesium; isopropyl bromide In tetrahydrofuran; toluene at 15 - 65℃; Stage #2: ethyl cyclopropylcarboxylate In tetrahydrofuran; toluene at 5 - 65℃; |
Conditions | Yield |
---|---|
With boron trifluoride In Hexadecane at 110℃; for 18h; Autoclave; | 88% |
bromobenzene
ethyl cyclopropylcarboxylate
cyclopropyl diphenyl carbinol
Conditions | Yield |
---|---|
With magnesium; copper(II) oxide In tetrahydrofuran at 65℃; for 4h; Barbier Coupling Reaction; chemoselective reaction; | 84% |
With magnesium; copper(II) oxide In tetrahydrofuran at 65℃; for 4h; chemoselective reaction; | 84% |
ethyl cyclopropylcarboxylate
N,N-bis(2-bromoallyl)-4-methylaniline
3-(2-cyclopropyl-2-oxoethyl)-2,5-dihydro-4-methyl-1-(4-methylphenyl)-1H-pyrrole
Conditions | Yield |
---|---|
Stage #1: N,N-bis(2-bromoallyl)-4-methylaniline With tert.-butyl lithium In diethyl ether; pentane at -78 - 20℃; for 1.5h; Stage #2: ethyl cyclopropylcarboxylate In diethyl ether; pentane at -78℃; for 1h; | 82% |
Conditions | Yield |
---|---|
With chromium chloride; magnesium In tetrahydrofuran at 80℃; for 12h; Inert atmosphere; | 82% |
ethyl cyclopropylcarboxylate
N,N-bis(2-bromoallyl)-4-methylaniline
5-cyclopropyl-1,2,3,4,5,6-hexahydro-2-(4-methylphenyl)cyclopenta[c]pyrrol-5-ol
Conditions | Yield |
---|---|
Stage #1: N,N-bis(2-bromoallyl)-4-methylaniline With tert.-butyl lithium In diethyl ether; pentane at -78 - 20℃; for 1.5h; Stage #2: ethyl cyclopropylcarboxylate In diethyl ether; pentane at -78 - 20℃; | 80% |
para-bromotoluene
ethyl cyclopropylcarboxylate
(cyclopropyl)(di-p-tolyl)methanol
Conditions | Yield |
---|---|
With magnesium; copper(II) oxide In tetrahydrofuran at 65℃; for 4h; Barbier Coupling Reaction; chemoselective reaction; | 78% |
With magnesium; copper(II) oxide In tetrahydrofuran at 65℃; for 4h; chemoselective reaction; | 78% |
ethyl cyclopropylcarboxylate
(trimethylsilyl)methylmagnesium chloride
2-cyclopropyl-2-propenyltrimethylsilane
Conditions | Yield |
---|---|
With cesium chloride; silica gel | 73% |
n-butyllithium
carbon monoxide
ethyl cyclopropylcarboxylate
1-Cyclopropyl-hexane-1,2-dione
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether; hexane; pentane a) -110 deg C, 2 h, b) to r.t.; | 67% |
Conditions | Yield |
---|---|
aluminium trichloride In toluene Heating; | 67% |
Conditions | Yield |
---|---|
Stage #1: 2,2'-(2-(2,4-dimethylphenyl)ethane-1,1-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) With 2,2,6,6-tetramethylpiperidinyl-lithium In tetrahydrofuran; hexane at 0℃; for 0.25h; Inert atmosphere; Stage #2: ethyl cyclopropylcarboxylate In tetrahydrofuran; hexane at 50℃; for 0.25h; Inert atmosphere; Stage #3: methyl iodide In tetrahydrofuran; hexane at 20℃; for 0.25h; Inert atmosphere; regioselective reaction; | 65% |
ethyl cyclopropylcarboxylate
1-benzyloxy-2-iodobenzene
Conditions | Yield |
---|---|
Stage #1: 1-benzyloxy-2-iodobenzene With tert.-butyl lithium In tetrahydrofuran; pentane at -78 - -25℃; Stage #2: ethyl cyclopropylcarboxylate In tetrahydrofuran; pentane at -78 - 20℃; Stage #3: With hydrogenchloride In tetrahydrofuran; water; pentane at 20℃; | 64% |
Conditions | Yield |
---|---|
With sodium hydroxide; hydroxylamine hydrochloride In ethanol for 8h; Ambient temperature; | 60% |
With hydroxylamine; sodium methylate | |
With potassium hydroxide; hydroxylamine hydrochloride In methanol |
carbon monoxide
ethyl cyclopropylcarboxylate
tert.-butyl lithium
A
1-cyclohexyl-2,2-dimethyl-1-propanone
B
Cyclopropyl-1-dimethyl-3,3-butan-dion-1,2
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether; hexane; pentane a) -110 deg C, 2 h, b) to r.t.; | A 3% B 60% |
Conditions | Yield |
---|---|
Stage #1: 2-chloro-4-methylpyrimidine With lithium hexamethyldisilazane In tetrahydrofuran at -78℃; for 1h; Stage #2: ethyl cyclopropylcarboxylate In tetrahydrofuran at -78℃; for 5h; | 46% |
Conditions | Yield |
---|---|
Stage #1: 1-(benzyloxy)-2-bromo-4-methylbenzene With tert.-butyl lithium In tetrahydrofuran; pentane at -78 - -25℃; Stage #2: ethyl cyclopropylcarboxylate In tetrahydrofuran; pentane at -78 - 20℃; Stage #3: With hydrogenchloride In tetrahydrofuran; water; pentane at 20℃; | 45% |
ethyl cyclopropylcarboxylate
(2-(4-bromophenyl)cyclopropane-1,1-diyl)dibenzene
cyclopropyl[bis-(4-(2,2-diphenylcyclopropyl)phenyl)]methanol
Conditions | Yield |
---|---|
Stage #1: (2-(4-bromophenyl)cyclopropane-1,1-diyl)dibenzene With magnesium In tetrahydrofuran Stage #2: ethyl cyclopropylcarboxylate In tetrahydrofuran | 43% |
5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)
ethyl cyclopropylcarboxylate
Conditions | Yield |
---|---|
Stage #1: 5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) With triphenylphosphine In benzene at 25℃; for 0.166667h; Stage #2: ethyl cyclopropylcarboxylate In benzene at 25℃; for 96h; Inert atmosphere; Darkness; regioselective reaction; | 38% |
Conditions | Yield |
---|---|
With triisopropoxytitanium(IV) chloride; cyclohexylmagnesiumchloride In tetrahydrofuran; diethyl ether at 20℃; for 2h; Inert atmosphere; | 33% |
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