CAS No.592-85-8,Mercury(II) thiocyanate Suppliers,MSDS download

: mercuric(II) nitrate monohydrate

: 333-20-0
potassium thioacyanate

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
With HNO3 In water aq. soln. of 2 equiv. of KSCN was added to Hg-salt soln. contg. a few drops of 20 % aq. HNO3; crystn. for a several h, crystals were filtered off, washed with H2O anddried;	85%
With HNO3 In water aq. KSCN soln. was added to 0.05 equiv. of Hg-salt soln. contg. some drops of 20 % HNO3; soln. was kept for a few hours, crystals were filtered off, washed with H2O and dried;	85%

: 333-20-0
potassium thioacyanate

: mercury dichloride

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
In ethanol according standard method: Ramakrishna, R.S and Thuraisingham R., J.Inorg.Nuc.Chem., 35, 285, (1973);	80%
In not given excess HgCl2;
In not given excess HgCl2;

: 18139-82-7
n-prSi(NCS)3

A: 141-57-1
n-propyltrichlorosilane

B: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
With mercury dichloride at careful heating to reflux;;	A 65% B 65%
With HgCl2 at careful heating to reflux;;	A 65% B 65%

: 463-56-9
thiocyanic acid

: 92114-96-0
mercury fulminate

: 592-85-8
mercury(II) thiocyanate

: 463-56-9
thiocyanic acid

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
With mercuri oxide

: 1600-27-7
mercury(II) diacetate

: 333-20-0
potassium thioacyanate

: 592-85-8
mercury(II) thiocyanate

: 333-20-0
potassium thioacyanate

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
With mercury dichloride
With mercuri nitrate
With mercury dichloride In acetic acid methyl ester excess of KSCN;; precipitation;;
With mercury dichloride In water
With HgCl2 In acetic acid methyl ester excess of KSCN;; precipitation;;

HgSCN: HgSCN

thiocyanato: thiocyanato

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
With carbon disulfide
With tetrachloromethane

: 302-04-5
Thiocyanate

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
With mercury dichloride In water concentration: 0.00125-0.1mol/l;;
With HgCl2 In water concentration: 0.00125-0.1mol/l;;

: 302-04-5
Thiocyanate

: mercury(II) nitrate

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
With iron(III) In not given can be used for titrimetric determination of Hg(2+) with Fe(II) as indicator;;
With Fe(3+) In not given can be used for titrimetric determination of Hg(2+) with Fe(II) as indicator;;

: 302-04-5
Thiocyanate

: mercury dibromide

A: 592-85-8
mercury(II) thiocyanate

B: 7558-02-3
potassium bromide

Conditions

Conditions	Yield
In water alkali rhodanide;; not isolated;;

...Expand

: 1701-93-5
silver thiocyanate

: mercury(II) nitrate

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
In not given byproducts: {HgSCN}(1+); solving AgSCN in Hg(NO3)2 soln.;;
In not given byproducts: {HgSCN}(1+); solving AgSCN in Hg(NO3)2 soln.;;

: mercury(II) cyanide

: sodium thiosulfate

A: 592-85-8
mercury(II) thiocyanate

B: 540-72-7
sodium thiocyanide

C: mercury sulfide

D: 7757-82-6
sodium sulfate

E: 7757-83-7
sodium sulfite

Conditions

Conditions	Yield
With sodium oxide In water byproducts: NaCN; in alk. soln.;
With Na2O In water byproducts: NaCN; in alk. soln.;

...Expand

: 75-15-0
carbon disulfide

: 7727-37-9
nitrogen

: mercury

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: carbon, sulfur; reaction of CS2 vapor with liquid Hg in presence of N2, electrical discharge; a small amt. of Hg(II) thiocyanate forms;;
In neat (no solvent) byproducts: carbon, sulfur; reaction of CS2 vapor with liquid Hg in presence of N2, electrical discharge; a small amt. of Hg(II) thiocyanate forms;;

...Expand

: 333-20-0
potassium thioacyanate

: mercury(II) oxide

A: 592-85-8
mercury(II) thiocyanate

B: potassium hydroxide

Conditions

Conditions	Yield
With water In water equilibrium; depending on temp. (25.0-79.0°C); at 99.5°C complete decompn.;
With H2O In water

...Expand

: 540-72-7
sodium thiocyanide

: mercury(II) oxide

A: 592-85-8
mercury(II) thiocyanate

B: 1310-73-2
sodium hydroxide

Conditions

Conditions	Yield
With water In water equilibrium; depending on temp. (25.0-79.0°C); at 99.5°C complete decompn.;
With H2O In water

...Expand

: 1858-25-9
phosphoryl-isothiocyanate

: mercury dichloride

A: 592-85-8
mercury(II) thiocyanate

B: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

...Expand

: 333-20-0
potassium thioacyanate

: mercury

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
In water Electrochem. Process; anodic dissolving of Hg in aq. KSCN soln., favoring by low current density and stirring;;

: ammonium thiocyanate

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
With mercury dichloride In acetic acid methyl ester excess of NH4SCN;; precipitation;;
With HgCl2 In acetic acid methyl ester excess of NH4SCN;; precipitation;;

: 505-14-6
thiocyanogen

: mercury(II) iodide

A: 592-85-8
mercury(II) thiocyanate

B: 7553-56-2
iodine

Conditions

Conditions	Yield
In tetrachloromethane
In diethyl ether
In chloroform

...Expand

: 333-20-0
potassium thioacyanate

: mercury(II) nitrate

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
In water immediate reaction;;
In not given addn. of KSCN to Hg(NO3)2 soln.;;
In not given addn. of KSCN to Hg(NO3)2 soln.;;
In water Hg(NO3)2 and KSCN in 1:2 molar ratio; dried in vac. for 30 h;

: 463-56-9
thiocyanic acid

: mercury(II) nitrate

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
In not given addn. of HSCN to Hg(NO3)2 soln.;;
In not given addn. of HSCN to Hg(NO3)2 soln.;;

: Hg(2+)*Cl(1-)*2SCN(1-)={HgCl(SCN)2}(1-)

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
With water In water
With H2O In water

: sulfinyl isothiocyanate

: mercury dichloride

A: mercurychloridesulfide

B: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
In potassium hydroxide aq. KOH;
In sodium hydroxide aq. NaOH;
In potassium hydroxide aq. KOH;
In sodium hydroxide aq. NaOH;

...Expand

: sulfonyl isothiocyanate

: mercury dichloride

A: mercurychloridesulfide

B: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
In potassium hydroxide aq. KOH;
In sodium hydroxide aq. NaOH;
In potassium hydroxide aq. KOH;
In sodium hydroxide aq. NaOH;

...Expand

: S2(SCN)2

: mercury dichloride

A: mercurychloridesulfide

B: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
In potassium hydroxide aq. KOH;
In sodium hydroxide aq. NaOH;
In potassium hydroxide aq. KOH;
In sodium hydroxide aq. NaOH;

...Expand

: 463-56-9
thiocyanic acid

: mercury(II) fulminate

A: Hg(2+)*2(SCN)(1-)*2(NH4)(1+)*2(SCN)(1-)=Hg(SCN)2*2NH4SCN

B: 124-38-9
carbon dioxide

C: 592-85-8
mercury(II) thiocyanate

D: mercury sulfide

Conditions

Conditions	Yield
With persulfocyanic acid In water byproducts: NH3; dissolution in aq. solution of HSCN;
With persulfocyanic acid In water byproducts: NH3; dissolution in aq. solution of HSCN;

...Expand

: ammonium thiocyanate

: mercury(II) fulminate

A: Hg(2+)*2(SCN)(1-)*2(NH4)(1+)*2(SCN)(1-)=Hg(SCN)2*2NH4SCN

B: 124-38-9
carbon dioxide

C: 592-85-8
mercury(II) thiocyanate

D: mercury sulfide

Conditions

Conditions	Yield
With persulfocyanic acid In water byproducts: NH3;
With persulfocyanic acid In water byproducts: NH3;

...Expand

: {Hg(SCN)4}(2-)

: 12596-26-8
dimercury(2+)

A: 592-85-8
mercury(II) thiocyanate

B: mercury(I) thiocyanate

Conditions

Conditions	Yield
In water reaction described in connection with its equlibrium constant;
In water reaction described in connection with its equlibrium constant;

...Expand

: mercury(I) thiocyanate

: 1191-10-2
dirhodane

: 592-85-8
mercury(II) thiocyanate

Conditions

Conditions	Yield
In carbon disulfide
In carbon disulfide

: 109-99-9
tetrahydrofuran

: 7439-91-0
lanthanum

: 592-85-8
mercury(II) thiocyanate

: [La(NCS)3(tetrahydrofuran)4]2

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: Hg; under N2 using Schlenk techniques; La powder (5.0 mmol) mixed with Hg(SCN)2 (2.5 mmol); thf added; stirred (ambient temp., 5 d); settled; filtered; concd.; crystd. (5°C); elem. anal.;	99%

...Expand

: 693-98-1
2-methylimidazole

: 592-85-8
mercury(II) thiocyanate

: 93394-91-3
(2-methylimidazolyl)HgSCN

Conditions

Conditions	Yield
In water byproducts: HSCN; A mixt. of aq. soln. of reagents was stirred for 3 days;; elem. anal.;	98%
In ethanol an ethanolic soln. of ligands was added to a stirred ethanol suspn. of Hg(SCN)2, the mixt. was kept overnight in refrigerator;; water was added; ppt. was filtered; elem. anal.;

: 592-85-8
mercury(II) thiocyanate

: 684-16-2
Hexafluoroacetone

: 93383-98-3
Bis<2,2,4,4-tetrakis(trifluormethyl)-4H-1,3,5-dioxazin-6-ylthio>quecksilber

Conditions

Conditions	Yield
With triethylamine In acetonitrile under exclusion of moisture, (CF3)2CO, CH3CN and some drops Et3N condensed at -196°C to Hg(SCN)2, warmed to room temp., stirred for 24 h; CH3CN removed at E-2 Torr; elem. anal.;	98%

: 288-88-0
1,2,4-Triazole

: 592-85-8
mercury(II) thiocyanate

: 93369-29-0
(1,2,4-triazolyl)Hg(SCN)

Conditions

Conditions	Yield
In ethanol an ethanolic soln. of ligand was added to a stirred ethanol suspn. of Hg(SCN)2,; elem. anal.;	97%

: 592-85-8
mercury(II) thiocyanate

: 5401-94-5
5-nitroindazole

: (5-nitroindazole)Hg(SCN)2

Conditions

Conditions	Yield
In ethanol an ethanolic soln. of ligand was added to a stirred ethanol suspn. of Hg(SCN)2, the mixt. was kept for 5 days;; elem. anal.;	95%

: 592-85-8
mercury(II) thiocyanate

: 220525-65-5
4′‐(2‐thienyl)‐2,2′;6′,2″‐terpyridine

: 1288936-77-5
dithiocyanato(4'-(2-thienyl)-2,2':6',2''-terpyridine)mercury(II)

Conditions

Conditions	Yield
In methanol; chloroform Hg(SCN)2 in MeOH added to soln. of ligand in CHCl3; stirred at ambient temp. for 10 min; filtered; ppt. washed with cold MeOH and cold Et2O; dried over silica gel; recrystd. from DMSO-MeOH; elem. anal.;	95%

: 15668-66-3
(2,2'-bipyridine)tetracarbonyltungsten(0)

: 592-85-8
mercury(II) thiocyanate

: (C5H4NC5H4N)*3(CO)*W*Hg(2+)*2(SCN)(1-)=(C5H4NC5H4N)(CO)3W*{Hg(SCN)2}

Conditions

Conditions	Yield
In acetone byproducts: CO; to suspn. of W complex in acetone in the dark under N2 added mercury rodanide, stirred at room temp. until CO evolution is complete; filtered, washed with acetone, dried under vac.; elem. anal.;	93%

: 128247-54-1
bis(η5-trimethylsilylcyclopentadienyl)bis(trimethylsilylethynyl)-titanium

: 592-85-8
mercury(II) thiocyanate

A: 82696-64-8
(C5H4Si(CH3)3)2Ti(NCS)2

B: mercury

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: (CH3)3SiCCCCSi(CH3)3; under N2; addn. of Hg(SCN)2 to Ti complex in THF at 0°C, stirring for 30 min at this temp.; filtration through Celite; removal of volatiles in vac. of oil pump, washing residue with cold n-pentane; elem. anal.;	A 93% B n/a

...Expand

: 592-85-8
mercury(II) thiocyanate

: 3879-01-4
Cesium thiocyanate

: dicesium tetrakis(thiocyanato)mercurate(II)

Conditions

Conditions	Yield
In ethanol stoich. amts., boiling; crystn. on cooling, collection, washing (EtOH), drying in air; elem. anal.;	93%

: 592-85-8
mercury(II) thiocyanate

: 333-20-0
potassium thioacyanate

: 6046-93-1
copper(II) acetate monohydrate

: 107-15-3
ethylenediamine

: [copper(II)mercury(II)(ethylenediamine)(μ-NCS-N,S)4]

Conditions

Conditions	Yield
With malonic acid In methanol; water soln. of Cu salt and malonic acid in distd. H2O heated with stirring to 1/2 vol., cooled to room temp., C2N2H8 added, stirred, then added to soln. of Hg and K salts in MeOH/H2O (3:1, v/v); soln. filtered, left undisturbed at room temp. to ppt.; elem. anal.;	93%

...Expand

: 592-85-8
mercury(II) thiocyanate

: 3879-01-4
Cesium thiocyanate

: casium tris(thiocyanato)mercurate(II)

Conditions

Conditions	Yield
In ethanol stoich. amts., boiling; crystn. on cooling, collection, washing (EtOH), drying in air; can be recrystallized (hot MeOH); elem. anal.;	92%

: 288-32-4
1H-imidazole

: 592-85-8
mercury(II) thiocyanate

: mercury(II) imidazolate

Conditions

Conditions	Yield
In water Aq. soln. of reagents were mixed;; elem. anal.;	91%

: 592-85-8
mercury(II) thiocyanate

: 53597-69-6
(1,3,5-triaza-7-phosphaadamantane)

: PTAHg(SCN)2

Conditions

Conditions	Yield
In methanol addn. of hot methanolic soln. of mercury salt to hot methanolic soln. of PTA, molar ratios Hg:PTA 1:2 and 1:1, immediate pptn. of mercury complex, filtered; washed with hot methanol; elem. anal.;	90%

: 437713-19-4
9-ethyl-3,6-bis[2-(4-pyridyl)ethenyl]carbazole

: 592-85-8
mercury(II) thiocyanate

: (9-ethyl-3,6-bis[2-(4-pyridyl)ethenyl]carbazole)bis(thiocyanate)mercury(II)

Conditions

Conditions	Yield
In methanol; dichloromethane soln. of carbazole derivative in CH2Cl2 layered onto soln. of Hg(SCN)2 in CH3OH, stored for several d; crystals isolated; elem. anal.;	90%

: 592-85-8
mercury(II) thiocyanate

: 1-hydrosilatrane

: 187027-67-4
1-isothiocyanato-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane

Conditions

Conditions	Yield
In o-xylene at 20℃; for 1h;	90%

: 102780-88-1
2-iodo-2-trifluoromethylperfluoropentane

: 592-85-8
mercury(II) thiocyanate

: 125510-68-1
1,1,1,2,2,3,3,5,5,5-Decafluoro-4-thiocyanato-4-trifluoromethyl-pentane

Conditions

Conditions	Yield
	89%

: 17567-17-8
potassium hydridotris(3,5-dimethylpyrazolyl)borate

: 592-85-8
mercury(II) thiocyanate

: {hydrotris(3,5-dimethyl-1-pyrazolyl)borato}thiocyanatomercury(II)

Conditions

Conditions	Yield
In dichloromethane under stirring; filtered, dried in vacuo until constant weight (20°C, 0.1 Torr), recrystd. (CH2Cl2-Et2O); elem. anal.;	89%

: 22718-70-3
tetracarbonyl(2,9-dimethyl-1,10-phenanthroline)tungsten(0)

: 592-85-8
mercury(II) thiocyanate

: (C6H5NC2H2C6H5N)*3(CO)*W*Hg(2+)*2{(SCN)(1-)}={(C6H5NC2H2C6H5N)(CO)3W}*{Hg(2+)*2(SCN)(1-)}

Conditions

Conditions	Yield
In acetone byproducts: CO; to suspn. of W complex in acetone in the dark under N2 added mercury rodanide, stirred at room temp. until CO evolution is complete; filtered, washed with acetone, dried under vac.; elem. anal.;	89%

: 15200-35-8
(C12H8N2)(CO)3(C5H5N)Mo

: 592-85-8
mercury(II) thiocyanate

: 92451-74-6
(C12H8N2)(CO)3MoHg(SCN)2

Conditions

Conditions	Yield
In acetone under N2, in the absence of light, molar ratio complex:Hg(SCN)2=1:1, stirred for several minutes in the dark; filtered off, washed with acetone, dried in vac., elem. anal.;	88%

: 4-[4-(dimethylamino)phenyl]-2,6-bis(4-pyridinyl)pyridine

: 592-85-8
mercury(II) thiocyanate

: 2CNS(1-)*Hg(2+)*C23H20N4

Conditions

Conditions	Yield
In methanol; dichloromethane at 20℃; for 168h; Sealed tube;	87.3%

: ruthenium Cl(CO)(NO)(P(C6H5)3)2

: 592-85-8
mercury(II) thiocyanate

: {Ru(SCN)2(HgSCN)(CO)(NO)(P(C6H5)3)}

Conditions

Conditions	Yield
In ethanol; dichloromethane under N2, refluxed for 2 h; collected, washed (CH2Cl2, EtOH and Et2O); elem. anal.;	87%

: 14729-20-5
tetracarbonyl(1,10-phenanthroline)tungsten(0)

: 592-85-8
mercury(II) thiocyanate

: (C5H3NC2H2C5H3N)*3(CO)*W*Hg(2+)*2(SCN)(1-)=(C5H3NC2H2C5H3N)(CO)3W*{Hg(SCN)2}

Conditions

Conditions	Yield
In acetone byproducts: CO; to suspn. of W complex in acetone in the dark under N2 added mercury rodanide, stirred until CO evolution is complete; filtered, washed with acetone, dried under vac.; elem. anal.;	87%

: 7439-91-0
lanthanum

: 110-71-4
1,2-dimethoxyethane

: 592-85-8
mercury(II) thiocyanate

: [La(NCS)3(1,2-dimethoxyethane)3]

Conditions

Conditions	Yield
In 1,2-dimethoxyethane byproducts: Hg; under N2 using Schlenk techniques; La powder (6.3 mmol) mixed with Hg(SCN)2 (3.1 mmol); dme added; stirred (ambient temp., 3 d); settled; filtered; concd.; heated; dme added; filtered; crystd. (5°C); washed with toluene; elem. anal.;	87%

...Expand

: 110-71-4
1,2-dimethoxyethane

: [Yb(NCS)2(tetrahydrofuran)2]

: 592-85-8
mercury(II) thiocyanate

: [Yb(NCS)3(1,2-dimethoxyethane)2]

Conditions

Conditions	Yield
In 1,2-dimethoxyethane byproducts: Hg; under N2 using Schlenk techniques; Yb(NCS)2(thf)2 (0.46 mmol) mixed withHg(SCN)2 (0.23 mmol); stirred (room temp., 3 d); settled; filtered; concd.; toluene added; crystd. (room temp., 1 wk); elem. anal.;	87%

...Expand

: 36947-68-9
2-isopropylimidazole

: 592-85-8
mercury(II) thiocyanate

: (2-isopropylimidazole)2Hg(SCN)2

Conditions

Conditions	Yield
In ethanol an ethanolic soln. of ligands was added to a stirred ethanol suspn. of Hg(SCN)2, the mixt. was kept overnight in refrigerator;; water was added; ppt. was filtered; elem. anal.;	86%

: ammonium thiocyanate

: 91-02-1
phenyl(pyridin-2-yl)methanone

: 592-85-8
mercury(II) thiocyanate

: copper dichloride

: [CuHg(2-benzoylpyridine)(thiocyanate)4]n

Conditions

Conditions	Yield
In methanol; water dissolving mixt. of ammonium and mercury thiocyanates in water, addn. tomethanolic soln. of copper compd. and pyridine deriv., stirring at room m temp. for 2 h; filtration, drying, recrystn. (methanol), elem. anal.;	85%

...Expand

: ammonium thiocyanate

: copper(II) choride dihydrate

: 592-85-8
mercury(II) thiocyanate

: 27258-04-4
bis(pyrazol-1-yl)methane

: [Cu(bis(pyrazol-1-yl)methane)Hg(SCN)4]n

Conditions

Conditions	Yield
In methanol; water NH4SCN, Hg(SCN)2 dissolved in H2O, slowly added to MeOH soln. of CuCl2*2H2O and bis(pyrazol-1-yl)methane, stirred at room temp. for 6 h; filtered, dried in air, slowly recrystd. from MeOH; elem. anal.;	85%

...Expand

: ammonium thiocyanate

: copper(II) choride dihydrate

: 592-85-8
mercury(II) thiocyanate

: 27258-04-4
bis(pyrazol-1-yl)methane

: [Cu(bis(pyrazol-1-yl)methane)2Hg(thiocyanato)4]

Conditions

Conditions	Yield
In methanol; water NH4SCN and Hg(SCN)2 dissolved in H2O; added slowly to MeOH soln. of Cu salt and ligand; stirred at room temp. for 6 h; filtered; ppt. dried in air; elem. anal.;	85%

...Expand

: ammonium thiocyanate

: manganese(II) chloride tetrahydrate

: 592-85-8
mercury(II) thiocyanate

: 27258-04-4
bis(pyrazol-1-yl)methane

: [Mn(bis(pyrazol-1-yl)methane)Hg(SCN)4](n)

Conditions

Conditions	Yield
In methanol; water NH4SCN and Hg(SCN)2 dissolved in H2O; slowly added to MeOH soln. of Mn salt and ligand; stirred at room temp. for 6 h; filtered; ppt. dried in air; elem. anal.;	85%

...Expand

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