Conditions | Yield |
---|---|
With KU-2 cation exchanger; dihydrogen peroxide In 1,4-dioxane at 30℃; for 3h; | 99.3% |
With Pyridine-2,6-dicarboxylic acid; phosphoric acid; dihydrogen peroxide In Isopropyl acetate; 1-Propyl acetate at 80℃; under 675.068 Torr; for 5h; Catalytic behavior; Reagent/catalyst; Temperature; Solvent; Pressure; | 93% |
With sulfuric acid; dihydrogen peroxide at 25 - 30℃; for 24h; | 60% |
Conditions | Yield |
---|---|
With iron(III)-acetylacetonate; oxygen In acetone at 60℃; under 2250.23 Torr; | 84% |
Bei der Autoxydation in Gegenwart oder Abwesenheit von Katalysatoren; | |
With oxygen |
Conditions | Yield |
---|---|
With sulfuric acid; dihydrogen peroxide In water at 30 - 70℃; for 0.0533333h; Flow reactor; | 76.7% |
With dihydrogen peroxide; acetic acid at 35 - 40℃; | |
With dihydrogen peroxide |
Conditions | Yield |
---|---|
With dihydrogen peroxide; cation exchanger KU-2 x 8 In 1,4-dioxane at 29.9℃; Rate constant; Kinetics; Equilibrium constant; other temperature, other ratio; | A 72% B n/a |
Conditions | Yield |
---|---|
With dihydrogen peroxide; cation exchanger KU-2 x 8 In 1,4-dioxane at 29.9℃; Rate constant; Kinetics; Equilibrium constant; other temperature, other ratio; | A 68% B n/a |
Conditions | Yield |
---|---|
With dihydrogen peroxide; cation exchanger KU-2 x 8 In 1,4-dioxane at 29.9℃; Rate constant; Kinetics; Equilibrium constant; other temperature, other ratio; | A 65% B n/a |
Conditions | Yield |
---|---|
With dihydrogen peroxide; cation exchanger KU-2 x 8 In 1,4-dioxane at 29.9℃; Rate constant; Kinetics; Equilibrium constant; other temperature, other ratio; | A n/a B 63% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; cation exchanger KU-2 x 8 In 1,4-dioxane at 29.9℃; Rate constant; Kinetics; Equilibrium constant; other temperature, other ratio; | A 61% B n/a |
With Pseudomonas fluorescens esterase; dihydrogen peroxide In aq. buffer pH=6.5; Kinetics; Reagent/catalyst; Enzymatic reaction; |
N,N,N',N'-tetraacetylethylenediamine
peracetic acid
Conditions | Yield |
---|---|
With dihydrogen peroxide; sodium carbonate; sodium hydroxide In water | 52.56% |
With dihydrogen peroxide In water |
Conditions | Yield |
---|---|
With dihydrogen peroxide; cation exchanger KU-2 x 8 In 1,4-dioxane at 29.9℃; Rate constant; Kinetics; Equilibrium constant; other temperature, other ratio; | A n/a B 48% |
With pseudomonas fluorescens esterase L29P-PFE; dihydrogen peroxide; sodium bromide at 23℃; pH=6.5; Kinetics; Concentration; Reagent/catalyst; Enzymatic reaction; |
ethane
A
peracetic acid
B
methyl hydroperoxide
C
ethyl hydroperoxide
D
hydroxymethylhydroperoxide
Conditions | Yield |
---|---|
With nitrogen; oxygen; chlorine at 24.85℃; under 760 Torr; for 0.5h; Kinetics; Oxidation; Photolysis; | A 2% B 6.2% C 10.2% D 0.4% |
propane
A
peracetic acid
B
methyl hydroperoxide
C
ethyl hydroperoxide
D
hydroxymethylhydroperoxide
Conditions | Yield |
---|---|
With nitrogen; oxygen; chlorine at 24.85℃; under 760 Torr; for 0.333333h; Kinetics; Oxidation; Photolysis; | A 0.1% B 3.39% C 0.61% D 0.14% |
1-methylcyclohex-1-ene
A
peracetic acid
B
methyl hydroperoxide
C
hydroxymethylhydroperoxide
Conditions | Yield |
---|---|
With ozone under 787.563 Torr; Product distribution; Criegee cleavage; | A 0.19% B 0.95% C 0.007% |
Pinene
A
peracetic acid
B
methyl hydroperoxide
C
hydroxymethylhydroperoxide
Conditions | Yield |
---|---|
With ozone under 787.563 Torr; Product distribution; Criegee cleavage; | A 0.39% B 0.71% C 0.089% |
pyridine
1-hydroxyethyl ethaneperoxoate
benzene
A
peracetic acid
B
acetaldehyde
Conditions | Yield |
---|---|
at 25℃; under 110 Torr; |
Conditions | Yield |
---|---|
With dihydrogen peroxide |
Conditions | Yield |
---|---|
With dihydrogen peroxide | |
With water Hydrolysis; | |
With dihydrogen peroxide In water at 25℃; Rate constant; carbonate, borate and phosphate buffers; |
Conditions | Yield |
---|---|
With water |
Conditions | Yield |
---|---|
With sulfuric acid; dihydrogen peroxide at 35 - 40℃; |
Conditions | Yield |
---|---|
With water; oxygen; cobalt ions at 25 - 35℃; Mechanism; other concentration of water, other temperature; | |
With oxygen at 15℃; under 759811 Torr; Product distribution; Rate constant; study of the effects of ultrasound intensity, external pressure, and temperature on the oxidation of acetaldehyde under cavitation conditions; | |
With tetrachloromethane; ozone at -20℃; | |
With tetrachloromethane; ozone at -30℃; | |
With ozone at -10℃; |
Conditions | Yield |
---|---|
With dihydrogen peroxide |
Conditions | Yield |
---|---|
With sulfuric acid; dihydrogen peroxide In 1,4-dioxane; nitrobenzene at 50℃; for 9h; Thermodynamic data; Kinetics; different mixtures of solvents, 20 - 40 deg C, ΔH(excit.),ΔS(excit.), ΔG(excit.); |
N,N,N',N'-tetraacetylethylenediamine
A
peracetic acid
B
N,Ν,Ν'-triacetylenediamine
Conditions | Yield |
---|---|
With 1,2-ethanediylbistetraphosphonic acid; dihydrogen peroxide at 25℃; Rate constant; pH 9.60 (carbonate buffer); |
N,Ν,Ν'-triacetylenediamine
A
peracetic acid
B
N,N'-diacetylethylenediamine
Conditions | Yield |
---|---|
With 1,2-ethanediylbistetraphosphonic acid; dihydrogen peroxide at 25℃; Kinetics; Thermodynamic data; various pH values (carbonate buffer), other temperatures; ΔH(excit.), ΔS(excit.); |
1,1-Dichloroethyl hydroperoxide
peracetic acid
Conditions | Yield |
---|---|
With water In chloroform-d1 at 0℃; for 0.166667h; Mechanism; Dioxane-d8, -10 deg C; |
acetaldehyde
A
peracetic acid
B
methane
C
carbon dioxide
D
carbon monoxide
E
acetic acid
Conditions | Yield |
---|---|
With oxygen In water Rate constant; accelerated by ultrasound; |
ethyl acetate
A
peracetic acid
B
acetic anhydride
C
acetaldehyde
D
acetic acid
Conditions | Yield |
---|---|
With air at 120℃; under 10500.8 Torr; Product distribution; Mechanism; Other temperature; |
Conditions | Yield |
---|---|
With peroxide anion In 1,4-dioxane; water at 22℃; Rate constant; pH=12.7; different reagent concentrations; |
butanone
A
peracetic acid
B
3-hydroperoxy-butan-2-one
C
3-hydroxy-2-butanon
D
acetaldehyde
E
acetic acid
F
dimethylglyoxal
Conditions | Yield |
---|---|
With air at 123℃; under 11025.9 Torr; for 0.583333h; Product distribution; |
Conditions | Yield |
---|---|
In dichloromethane at -20℃; | 100% |
peracetic acid
dimethyl 2,2'-((2-iodo-5-1,3-phenylene)bis(oxy))diacetate
C16H19IO10
Conditions | Yield |
---|---|
In acetic acid at 20℃; for 24h; | 100% |
peracetic acid
acetic acid
1,3,9,11-tetramethyl-5λ3,7λ3-dibenzo[d,f][1,3,2]diiodaoxepine-5,7-diyl diacetate
Conditions | Yield |
---|---|
In acetonitrile at 20℃; | 100% |
peracetic acid
2,4,5-trimethylphenol
A
2,3,5-trimethyl-1,6-benzoquinone
B
1-acetoxy-2,4,5-trimethylbenzene
C
1,4-dimethoxy-2,3,5-trimethyl-benzene
D
1-methoxy-2,4,5-trimethylbenzene
Conditions | Yield |
---|---|
sulfuric acid at 50℃; for 0.5h; Mechanism; Thermodynamic data; effect of catalysts; | A n/a B 0.03% C 0.07% D 0.07% E 99.76% |
peracetic acid
2,3,6-trimethylphenol
A
2,3,5-Trimethyl-1,4-benzoquinone
B
Duroquinone
C
Trimethylhydroquinone
D
pentamethylphenol
E
1-methoxy-2,3,6-trimethylbenzene
F
2,3,6-trimethylphenyl acetate
Conditions | Yield |
---|---|
sulfuric acid at 50℃; for 0.5h; Mechanism; Thermodynamic data; effect of catalysts; | A 99.7% B 0.04% C 0.01% D 0.01% E 0.03% F 0.04% |
peracetic acid
Trimethylhydroquinone
A
2,3,5-Trimethyl-1,4-benzoquinone
B
1,4-dimethoxy-2,3,5-trimethyl-benzene
C
2,3,5-trimethyl-1,4-hydroquinone diacetate
D
4-acetoxy-2,3,5-trimethylphenol
E
4-methoxy-2,3,5-trimethylphenol
Conditions | Yield |
---|---|
sulfuric acid at 50℃; for 0.5h; Mechanism; Thermodynamic data; effect of catalysts; | A 99.5% B 0.05% C 0.06% D 0.05% E 0.04% F 0.07% |
Conditions | Yield |
---|---|
at 60℃; under 150.015 Torr; for 4h; Pressure; | 99.2% |
With acetone | |
at 50℃; for 0.13h; Temperature; |
peracetic acid
(1'R,3S)-3-<1'-<(tert-butyldimethylsilyl)oxy>ethyl>azetidin-2-one
(3R,4R)-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]-4-acetoxyazetidin-2-one
Conditions | Yield |
---|---|
With Ru-carbon; sodium acetate; acetic acid In ethyl acetate for 2.5h; Ambient temperature; | 99% |
With Ru-carbon; sodium acetate; acetic acid In ethyl acetate for 2.5h; Product distribution; Ambient temperature; other amides and lactams; other catalyst; | 99% |
With sodium acetate; acetic acid; cobalt(II) chloride In ethyl acetate at 0 - 40℃; for 3.5h; Reagent/catalyst; Temperature; | 91% |
With Ru/C; sodium acetate; acetic acid |
peracetic acid
(2R,2'R)-dimethyl 2,2'-((2-iodo-1,3-phenylene)bis(oxy))dipropanoate
dimethyl-2,2'-((2-(diacetoxy-λ3-iodanyl)-1,3-phenylene)bis(oxy))(2R,2'R)-dipropionate
Conditions | Yield |
---|---|
In acetic acid at 20℃; | 99% |
peracetic acid
but-3-enoic acid
(S)-β-acetoxy-γ-butyrolactone
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid In acetic acid at 20℃; Cooling with ice; | 99% |
peracetic acid
N,N'-((2S,2'S)-((2-iodo-1,3-phenylene)bis(oxy))bis(propane-2,1-diyl))bis-(2,4,6-trimethylbenzamide)
C36H45IN2O8
Conditions | Yield |
---|---|
With acetic acid at 25℃; for 9h; | 99% |
With acetic acid at 20℃; | 94% |
peracetic acid
2,6-dimethyliodobenzene
(2,6-dimethylphenyl)-λ3-iodanediyl diacetate
Conditions | Yield |
---|---|
In acetic acid at 20℃; for 20h; | 99% |
With acetic anhydride; acetic acid at -10 - 20℃; | 69% |
peracetic acid
3-acetoxymethyl-7(R)-glutaroylaminoceph-3-em-4-carboxylic acid
3-acetoxymethyl-7(R)-glutaroylaminoceph-3-em-4-carboxylic acid 1(S)-oxide
Conditions | Yield |
---|---|
In isopropyl alcohol at 2 - 4℃; Industrial scale; | 98% |
peracetic acid
pent-4-enoic acid
(5-oxotetrahydrofuran-2-yl)methyl acetate
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid In acetic acid at 20℃; Cooling with ice; | 97% |
peracetic acid
Conditions | Yield |
---|---|
In acetic acid at 0 - 30℃; for 2h; Inert atmosphere; | 97% |
Conditions | Yield |
---|---|
at 4 - 30℃; | 96% |
at 30℃; for 12h; | 92% |
peracetic acid
(2S,3S)-3-((R)-1-((tert-butyldimethylsilyl)oxy)ethyl)-1-(4-methoxyphenyl)-4-oxoazetidine-2-carboxylic acid
Conditions | Yield |
---|---|
With dicyclohexyl-carbodiimide In dichloromethane at 0 - 5℃; Temperature; Solvent; | 96% |
Conditions | Yield |
---|---|
In diethyl ether for 0.5h; Ambient temperature; | 95% |
Conditions | Yield |
---|---|
With Ru-carbon; sodium acetate; acetic acid In ethyl acetate for 2.5h; Ambient temperature; | 94% |
peracetic acid
ethyl 6-(4-iodophenoxy)hexanoate
ethyl 6-(4-diacetoxyiodophenoxy)hexanoate
Conditions | Yield |
---|---|
In dichloromethane at 0 - 20℃; for 2h; | 94% |
In dichloromethane | 40% |
peracetic acid
Conditions | Yield |
---|---|
With ruthenium trichloride In dichloromethane; acetic acid; acetonitrile at 0℃; | 93.3% |
Conditions | Yield |
---|---|
for 0.383333h; | 93% |
With acetic anhydride; acetic acid at -10 - 20℃; | 65% |
Conditions | Yield |
---|---|
In acetic acid at 20℃; for 20h; | 93% |
With acetic anhydride; acetic acid at -10 - 20℃; | 83% |
In acetic acid at 0 - 20℃; | 46% |
In diethyl ether; acetic acid for 2h; Ambient temperature; 1.) below 10 deg C, 1 h, 2.) r.t., 2 h; | |
With acetic acid |
peracetic acid
acetic acid
but-3-enenitrile
3,4-diacetoxybutyronitrile
Conditions | Yield |
---|---|
C22H26ClN3O2Pd at 25℃; for 8h; | 93% |
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 18h; Inert atmosphere; | 93% |
Conditions | Yield |
---|---|
With acetic acid for 4h; | 92% |
With acetic acid at 23℃; for 7h; | 92% |
With sulfuric acid; dihydrogen peroxide; acetic acid In water 1.) 29-31 deg C, 65 min; 2.) 0 deg C, 75 min; | 88.8% |
With acetic acid at 20℃; |
Conditions | Yield |
---|---|
at 35℃; for 19h; Baeyer-Villiger Oxidation; | 92% |
peracetic acid
(2R)-N,N-dibenzyl-2-chloropropan-1-amine
(2S)-2-[(dibenzylamino)oxy]propyl acetate
Conditions | Yield |
---|---|
Stage #1: peracetic acid; (2R)-N,N-dibenzyl-2-chloropropan-1-amine In dichloromethane; acetic acid at 0℃; for 1.5h; Stage #2: With silver nitrate; triethylamine In dichloromethane; acetic acid at 0℃; for 3h; optical yield given as %ee; | 92% |
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