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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Phosphonium,tetramethyl-, iodide (8CI,9CI)

Cas:993-11-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

TETRAMETHYLPHOSPHONIUM IODIDE CAS:993-11-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality orga

TETRAMETHYLPHOSPHONIUM IODIDE CAS:993-11-3

Cas:993-11-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Phosphonium,tetramethyl-, iodide (8CI,9CI)

Cas:993-11-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Tetramethylphosphoniumiodide Supply

Cas:993-11-3

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Phosphonium,tetramethyl-, iodide (8CI,9CI)

Cas:993-11-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Tetramethylphosphoniumiodide

Cas:993-11-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Phosphonium,tetramethyl-, iodide (8CI,9CI)

Cas:993-11-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Tetramethylphosphoniumiodide

Cas:993-11-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Tetramethylphosphoniumiodide Supply

Cas:993-11-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Tetramethylphosphoniumiodide Supply

Cas:993-11-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Tetramethylphosphoniumiodide Supply

Cas:993-11-3

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

993-11-3 Application:993-11-3

Tetramethylphosphoniumiodide/993-11-3

Cas:993-11-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Tetramethylphosphoniumiodide Supply

Cas:993-11-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Tetramethylphosphoniumiodide

Cas:993-11-3

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Phosphonium,tetramethyl-, iodide (8CI,9CI)

Cas:993-11-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

Tetramethylphosphoniumiodide Supply Application:Tetramethylphosphoniumiodide Supply

Tetramethylphosphoniumiodide Supply

Cas:993-11-3

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

TETRAMETHYLPHOSPHONIUM IODIDE

Cas:993-11-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

TETRAMETHYLPHOSPHONIUM IODIDE

Cas:993-11-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

993-11-3

Cas:993-11-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

Tetramethylphosphoniumiodide SupplyAppearance:white crystals Storage:Keep in dry and cool condition Package:25Kg/Drum Application:tetramethylphosphanium iodide;NSC 617058 Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amou

Tetramethylphosphoniumiodide Supply

Cas:993-11-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Saiwante (shanghai) New Material Technology Co., Ltd.

Stable supply of goods and provision of high-quality services Application:As raw materials in the field of medicine and biology

Tetramethylphosphoniumiodide Supply

Cas:993-11-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

TETRAMETHYLPHOSPHONIUM IODIDE

Cas:993-11-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Zouping Mingxing Chemical Co.,Ltd.

strong products Storage:Storing at room temperature Package:according to quantity Application:organic synthesis Transportation:by sea or by air Port:Shanghai port

TETRAMETHYLPHOSPHONIUM IODIDE

Cas:993-11-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Suzhou Wedo Chemicals Co., Ltd.

Tetramethylphosphonium iodide

Cas:993-11-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Taizhou volsen chemical Co., Ltd

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

Tetramethylphosphoniumiodide Supply

Cas:993-11-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Raymon Biotech Co., Ltd.

Phosphonium,tetramethyl-, iodide (8CI,9CI) Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/

Phosphonium,tetramethyl-, iodide (8CI,9CI)

Cas:993-11-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Minshang Biotechnology Co., Ltd

Tetramethylphosphoniumiodide Supply Application:tetramethylphosphanium iodide;NSC 617058

993-11-3

Cas:993-11-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Jiangxi shengwei chemical technology co. LTD

Jiangxi Shengwei Chemical Technology Co., Ltd.supplies scientific research products as below:1.High-purity organic chemical reagents;2.Analytical reagents; 3.Biochemical reagents;4.Chemical raw materials;5.Experimental instruments;6.Experimental cons

Tetramethylphosphonium iodide

Cas:993-11-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Skyrun Industrial Co.,Ltd

Adequate stocks available,prompt shipment,Strictly control on quality,Timely after-sales Application:flavours and fragrances

Tetramethylphosphoniumiodide

Cas:993-11-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fenjun Chemical Co Ltd.

Tetramethylphosphoniumiodide Supply Application:Tetramethylphosphoniumiodide Supply

Tetramethylphosphoniumiodide Supply

Cas:993-11-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

trimethyl(methylene)phosphorane
14580-91-7, 29218-61-9

trimethyl(methylene)phosphorane

dicarbonyl(η5-cyclopentadienyl)[η1-(2-trimethylphosphonio)propionyl]iron(II) iodide
77812-56-7

dicarbonyl(η5-cyclopentadienyl)[η1-(2-trimethylphosphonio)propionyl]iron(II) iodide

A

C5H5(CO)2FeC(O)C(CH3)P(CH3)3
84083-95-4

C5H5(CO)2FeC(O)C(CH3)P(CH3)3

B

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
In diethyl ether to suspn. of Fe complex in ether Me3PCH2 dissolved in ether added dropwise at room temp., allowed to react for 45 h; filtered, concd. in vac., treated with pentane, ppt. washed with pentane, dried in vac.; elem. anal.;A 90%
B 98%
methyl iodide
74-88-4

methyl iodide

A

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

B

Methyl-bis(trimethylphosphinomethyl)-phosphan-diiodid

Methyl-bis(trimethylphosphinomethyl)-phosphan-diiodid

C

(Dimethyl-phosphinoylmethyl)-trimethyl-phosphonium; iodide

(Dimethyl-phosphinoylmethyl)-trimethyl-phosphonium; iodide

D

Dimethyl-bis(trimethylphosphoniomethyl)phosphiumtriiodid

Dimethyl-bis(trimethylphosphoniomethyl)phosphiumtriiodid

Conditions
ConditionsYield
In methanol Further byproducts given;A n/a
B n/a
C n/a
D 58%
methyl iodide
74-88-4

methyl iodide

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
With calcium phosphide; water In methanol at 0℃; for 51h; Reflux;53%
methanol
67-56-1

methanol

A

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
With phosphonium iodide at 160 - 180℃; das Hydrojodid bildet sich;
methyl magnesium iodide
917-64-6

methyl magnesium iodide

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
With diethyl ether; phosphorus diiodide Einw. das Reaktionsprodukts von Wasser;
Dimethyl ether
115-10-6

Dimethyl ether

A

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
With phosphonium iodide at 120 - 140℃;
methyl iodide
74-88-4

methyl iodide

trimethylphosphane
594-09-2

trimethylphosphane

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

iodotrifluoromethane
2314-97-8

iodotrifluoromethane

trimethylphosphane
594-09-2

trimethylphosphane

A

trifluoromethan
75-46-7

trifluoromethan

B

dimethyl(trifluoromethyl)phosphine
421-57-8

dimethyl(trifluoromethyl)phosphine

C

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
analoge Reaktionen mit Trimethylarsin und mit Trimethylstibin;
tetramethyldiphosphane
3676-91-3

tetramethyldiphosphane

methyl iodide
74-88-4

methyl iodide

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
at 200℃;
Dimethyl-bis(trimethylphosphoniomethyl)phosphiumtriiodid

Dimethyl-bis(trimethylphosphoniomethyl)phosphiumtriiodid

A

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

B

C7H20P2(2+)*2I(1-)

C7H20P2(2+)*2I(1-)

C

(Dimethyl-phosphinoylmethyl)-trimethyl-phosphonium; iodide

(Dimethyl-phosphinoylmethyl)-trimethyl-phosphonium; iodide

Conditions
ConditionsYield
In water-d2 at 25℃; Product distribution; other solvents: CD3OD, CD3OD/D2O, CD3OD/H2O; influence of solvent on rate of hydrolysis, solvent isotope effect;
iodotrifluoromethane
2314-97-8

iodotrifluoromethane

trimethylphosphane
594-09-2

trimethylphosphane

A

dimethyl(trifluoromethyl)phosphine
421-57-8

dimethyl(trifluoromethyl)phosphine

B

diiodotrimethylphosphorane
98026-25-6

diiodotrimethylphosphorane

C

Bis-trifluormethyl-trimethyl-phosphoran
57539-05-6

Bis-trifluormethyl-trimethyl-phosphoran

D

trifluormethyltrimethylphosphoniumiodid
354-46-1

trifluormethyltrimethylphosphoniumiodid

E

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
In neat (no solvent) Product distribution; trifluoromethylating of phosphorus compounds;
iodotrifluoromethane
2314-97-8

iodotrifluoromethane

trimethylphosphane
594-09-2

trimethylphosphane

A

dimethyl(trifluoromethyl)phosphine
421-57-8

dimethyl(trifluoromethyl)phosphine

B

Bis-trifluormethyl-trimethyl-phosphoran
57539-05-6

Bis-trifluormethyl-trimethyl-phosphoran

C

trifluormethyltrimethylphosphoniumiodid
354-46-1

trifluormethyltrimethylphosphoniumiodid

D

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
In neat (no solvent) Further byproducts given;
dimesitylbis(trimethylphosphine)chromium(II)
55272-61-2

dimesitylbis(trimethylphosphine)chromium(II)

A

chromium(II) iodide

chromium(II) iodide

B

1,2,3,5-Tetramethylbenzene
527-53-7

1,2,3,5-Tetramethylbenzene

C

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
With CH3I In diethyl ether; toluene soln. of CH3I in toluene is added to stirred room-temp. soln. of Cr(C6H2Me3)2(PMe3)2 in diethyl ether, stirring for 3 h; elem. anal.;
8-formylquinoline
38707-70-9

8-formylquinoline

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

8-ethenylquinoline
96911-08-9

8-ethenylquinoline

Conditions
ConditionsYield
Stage #1: tetramethylphosphonium iodide With n-butyllithium In tetrahydrofuran; hexane at -70 - 20℃; for 2h; Inert atmosphere;
Stage #2: 8-formylquinoline In tetrahydrofuran; hexane at -20℃; for 5h; Inert atmosphere; Reflux;
84%
phenyl(pyridin-2-yl)methanone
91-02-1

phenyl(pyridin-2-yl)methanone

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

2-(1-phenylvinyl)pyridine
15260-65-8

2-(1-phenylvinyl)pyridine

Conditions
ConditionsYield
Stage #1: tetramethylphosphonium iodide With n-butyllithium In tetrahydrofuran; hexane at -70 - 20℃; for 2h; Inert atmosphere;
Stage #2: phenyl(pyridin-2-yl)methanone In tetrahydrofuran; hexane at -20℃; for 5h; Inert atmosphere; Reflux;
84%
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

chloroditetradecyl phosphate
181591-24-2

chloroditetradecyl phosphate

ditetradecyl (trimethylphosphonio)methylphosphonate iodide

ditetradecyl (trimethylphosphonio)methylphosphonate iodide

Conditions
ConditionsYield
Stage #1: tetramethylphosphonium iodide With n-butyllithium In tetrahydrofuran; hexane at -10℃;
Stage #2: chloroditetradecyl phosphate In tetrahydrofuran; hexane at 20℃; for 2h; Further stages.;
76%
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Phosphorochloridic acid bis-((Z)-octadec-9-enyl) ester

Phosphorochloridic acid bis-((Z)-octadec-9-enyl) ester

dioleyl (trimethylphosphonio)methylphosphonate iodide

dioleyl (trimethylphosphonio)methylphosphonate iodide

Conditions
ConditionsYield
Stage #1: tetramethylphosphonium iodide With n-butyllithium In tetrahydrofuran; hexane at -10℃;
Stage #2: Phosphorochloridic acid bis-((Z)-octadec-9-enyl) ester In tetrahydrofuran; hexane at 20℃; for 2h; Further stages.;
68%
pentamethylcyclopentadienyllithium
51905-34-1

pentamethylcyclopentadienyllithium

samarium(III) chloride
10361-82-7

samarium(III) chloride

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

(C5(CH3)5)2Sm{(CH2)(CH2)P(CH3)2}*2LiCl

(C5(CH3)5)2Sm{(CH2)(CH2)P(CH3)2}*2LiCl

Conditions
ConditionsYield
With methyllithium In tetrahydrofuran suspn. of Cp'Li and anhydrous SmCl3 refluxed overnight, filtered, addn. of a soln. of Li(THF)2Cp'2SmCl2 to a soln. of LiCH2CH2PMe2 (from MeLi and Me4PI in Et2O prepd.) at -78°C under N2, warming to room temp., stirring (4 h); filtered, extd. (THF), evapn. (vac.), extd. (CH2Cl2), concd., cooling (-20°C), filtered, dried (vacuo), elem. anal.;63%
With methyllithium In toluene suspn. of Cp'Li and anhydrous SmCl3 refluxed overnight, filtered, addn. of a soln. of Li(THF)2Cp'2SmCl2 to a soln. of LiCH2CH2PMe2 (from MeLi and Me4PI in Et2O prepd.) at -78°C under N2, warming to room temp., stirring (4 h); filtered, extd. (THF), evapn. (vac.), extd. (CH2Cl2), concd., cooling (-20°C), filtered, dried (vacuo), elem. anal.;63%
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

trimethyl(methylene)phosphorane
14580-91-7, 29218-61-9

trimethyl(methylene)phosphorane

Conditions
ConditionsYield
With diethyl ether; phenyllithium
With diethyl ether; methyllithium
With n-butyllithium In hexane at -78℃; Inert atmosphere;
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

tetramethylphosphonium hydroxide
14814-27-8

tetramethylphosphonium hydroxide

Conditions
ConditionsYield
With silver(l) oxide
diethyl ether
60-29-7

diethyl ether

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

phenyllithium
591-51-5

phenyllithium

trimethyl(methylene)phosphorane
14580-91-7, 29218-61-9

trimethyl(methylene)phosphorane

Conditions
ConditionsYield
je nach dem Mengenverhaeltnis;
diethyl ether
60-29-7

diethyl ether

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

phenyllithium
591-51-5

phenyllithium

(dimethyl-methylene-phosphoranyl)-methyl lithium
21752-68-1

(dimethyl-methylene-phosphoranyl)-methyl lithium

Conditions
ConditionsYield
je nach dem Mengenverhaeltnis;
trimethyl(methylene)phosphorane
14580-91-7, 29218-61-9

trimethyl(methylene)phosphorane

dicarbonyl(η5-cyclopentadienyl)[η1-(2-trimethylphosphonio)propionyl]iron(II) iodide
77812-56-7

dicarbonyl(η5-cyclopentadienyl)[η1-(2-trimethylphosphonio)propionyl]iron(II) iodide

A

C5H5(CO)2FeC(O)C(CH3)P(CH3)3
84083-95-4

C5H5(CO)2FeC(O)C(CH3)P(CH3)3

B

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
In diethyl ether to suspn. of Fe complex in ether Me3PCH2 dissolved in ether added dropwise at room temp., allowed to react for 45 h; filtered, concd. in vac., treated with pentane, ppt. washed with pentane, dried in vac.; elem. anal.;A 90%
B 98%
methyl iodide
74-88-4

methyl iodide

A

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

B

Methyl-bis(trimethylphosphinomethyl)-phosphan-diiodid

Methyl-bis(trimethylphosphinomethyl)-phosphan-diiodid

C

(Dimethyl-phosphinoylmethyl)-trimethyl-phosphonium; iodide

(Dimethyl-phosphinoylmethyl)-trimethyl-phosphonium; iodide

D

Dimethyl-bis(trimethylphosphoniomethyl)phosphiumtriiodid

Dimethyl-bis(trimethylphosphoniomethyl)phosphiumtriiodid

Conditions
ConditionsYield
In methanol Further byproducts given;A n/a
B n/a
C n/a
D 58%
methyl iodide
74-88-4

methyl iodide

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
With calcium phosphide; water In methanol at 0℃; for 51h; Reflux;53%
methanol
67-56-1

methanol

A

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
With phosphonium iodide at 160 - 180℃; das Hydrojodid bildet sich;
methyl magnesium iodide
917-64-6

methyl magnesium iodide

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
With diethyl ether; phosphorus diiodide Einw. das Reaktionsprodukts von Wasser;
Dimethyl ether
115-10-6

Dimethyl ether

A

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

B

trimethylphosphane
594-09-2

trimethylphosphane

Conditions
ConditionsYield
With phosphonium iodide at 120 - 140℃;
methyl iodide
74-88-4

methyl iodide

trimethylphosphane
594-09-2

trimethylphosphane

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

iodotrifluoromethane
2314-97-8

iodotrifluoromethane

trimethylphosphane
594-09-2

trimethylphosphane

A

trifluoromethan
75-46-7

trifluoromethan

B

dimethyl(trifluoromethyl)phosphine
421-57-8

dimethyl(trifluoromethyl)phosphine

C

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
analoge Reaktionen mit Trimethylarsin und mit Trimethylstibin;
tetramethyldiphosphane
3676-91-3

tetramethyldiphosphane

methyl iodide
74-88-4

methyl iodide

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
at 200℃;
Dimethyl-bis(trimethylphosphoniomethyl)phosphiumtriiodid

Dimethyl-bis(trimethylphosphoniomethyl)phosphiumtriiodid

A

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

B

C7H20P2(2+)*2I(1-)

C7H20P2(2+)*2I(1-)

C

(Dimethyl-phosphinoylmethyl)-trimethyl-phosphonium; iodide

(Dimethyl-phosphinoylmethyl)-trimethyl-phosphonium; iodide

Conditions
ConditionsYield
In water-d2 at 25℃; Product distribution; other solvents: CD3OD, CD3OD/D2O, CD3OD/H2O; influence of solvent on rate of hydrolysis, solvent isotope effect;
iodotrifluoromethane
2314-97-8

iodotrifluoromethane

trimethylphosphane
594-09-2

trimethylphosphane

A

dimethyl(trifluoromethyl)phosphine
421-57-8

dimethyl(trifluoromethyl)phosphine

B

diiodotrimethylphosphorane
98026-25-6

diiodotrimethylphosphorane

C

Bis-trifluormethyl-trimethyl-phosphoran
57539-05-6

Bis-trifluormethyl-trimethyl-phosphoran

D

trifluormethyltrimethylphosphoniumiodid
354-46-1

trifluormethyltrimethylphosphoniumiodid

E

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
In neat (no solvent) Product distribution; trifluoromethylating of phosphorus compounds;
iodotrifluoromethane
2314-97-8

iodotrifluoromethane

trimethylphosphane
594-09-2

trimethylphosphane

A

dimethyl(trifluoromethyl)phosphine
421-57-8

dimethyl(trifluoromethyl)phosphine

B

Bis-trifluormethyl-trimethyl-phosphoran
57539-05-6

Bis-trifluormethyl-trimethyl-phosphoran

C

trifluormethyltrimethylphosphoniumiodid
354-46-1

trifluormethyltrimethylphosphoniumiodid

D

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
In neat (no solvent) Further byproducts given;
methylmagnesium iodide

methylmagnesium iodide

P2I4

P2I4

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

methanol
67-56-1

methanol

A

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

B

trimethylphosphonium iodide

trimethylphosphonium iodide

Conditions
ConditionsYield
With phosphonium iodide at 160 - 180℃;
Dimethyl ether
115-10-6

Dimethyl ether

A

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

B

trimethylphosphonium iodide

trimethylphosphonium iodide

Conditions
ConditionsYield
With phosphonium iodide at 120 - 140℃;
dimesitylbis(trimethylphosphine)chromium(II)
55272-61-2

dimesitylbis(trimethylphosphine)chromium(II)

A

chromium(II) iodide

chromium(II) iodide

B

1,2,3,5-Tetramethylbenzene
527-53-7

1,2,3,5-Tetramethylbenzene

C

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Conditions
ConditionsYield
With CH3I In diethyl ether; toluene soln. of CH3I in toluene is added to stirred room-temp. soln. of Cr(C6H2Me3)2(PMe3)2 in diethyl ether, stirring for 3 h; elem. anal.;
8-formylquinoline
38707-70-9

8-formylquinoline

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

8-ethenylquinoline
96911-08-9

8-ethenylquinoline

Conditions
ConditionsYield
Stage #1: tetramethylphosphonium iodide With n-butyllithium In tetrahydrofuran; hexane at -70 - 20℃; for 2h; Inert atmosphere;
Stage #2: 8-formylquinoline In tetrahydrofuran; hexane at -20℃; for 5h; Inert atmosphere; Reflux;
84%
phenyl(pyridin-2-yl)methanone
91-02-1

phenyl(pyridin-2-yl)methanone

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

2-(1-phenylvinyl)pyridine
15260-65-8

2-(1-phenylvinyl)pyridine

Conditions
ConditionsYield
Stage #1: tetramethylphosphonium iodide With n-butyllithium In tetrahydrofuran; hexane at -70 - 20℃; for 2h; Inert atmosphere;
Stage #2: phenyl(pyridin-2-yl)methanone In tetrahydrofuran; hexane at -20℃; for 5h; Inert atmosphere; Reflux;
84%
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

chloroditetradecyl phosphate
181591-24-2

chloroditetradecyl phosphate

ditetradecyl (trimethylphosphonio)methylphosphonate iodide

ditetradecyl (trimethylphosphonio)methylphosphonate iodide

Conditions
ConditionsYield
Stage #1: tetramethylphosphonium iodide With n-butyllithium In tetrahydrofuran; hexane at -10℃;
Stage #2: chloroditetradecyl phosphate In tetrahydrofuran; hexane at 20℃; for 2h; Further stages.;
76%
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

Phosphorochloridic acid bis-((Z)-octadec-9-enyl) ester

Phosphorochloridic acid bis-((Z)-octadec-9-enyl) ester

dioleyl (trimethylphosphonio)methylphosphonate iodide

dioleyl (trimethylphosphonio)methylphosphonate iodide

Conditions
ConditionsYield
Stage #1: tetramethylphosphonium iodide With n-butyllithium In tetrahydrofuran; hexane at -10℃;
Stage #2: Phosphorochloridic acid bis-((Z)-octadec-9-enyl) ester In tetrahydrofuran; hexane at 20℃; for 2h; Further stages.;
68%
pentamethylcyclopentadienyllithium
51905-34-1

pentamethylcyclopentadienyllithium

samarium(III) chloride
10361-82-7

samarium(III) chloride

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

(C5(CH3)5)2Sm{(CH2)(CH2)P(CH3)2}*2LiCl

(C5(CH3)5)2Sm{(CH2)(CH2)P(CH3)2}*2LiCl

Conditions
ConditionsYield
With methyllithium In tetrahydrofuran suspn. of Cp'Li and anhydrous SmCl3 refluxed overnight, filtered, addn. of a soln. of Li(THF)2Cp'2SmCl2 to a soln. of LiCH2CH2PMe2 (from MeLi and Me4PI in Et2O prepd.) at -78°C under N2, warming to room temp., stirring (4 h); filtered, extd. (THF), evapn. (vac.), extd. (CH2Cl2), concd., cooling (-20°C), filtered, dried (vacuo), elem. anal.;63%
With methyllithium In toluene suspn. of Cp'Li and anhydrous SmCl3 refluxed overnight, filtered, addn. of a soln. of Li(THF)2Cp'2SmCl2 to a soln. of LiCH2CH2PMe2 (from MeLi and Me4PI in Et2O prepd.) at -78°C under N2, warming to room temp., stirring (4 h); filtered, extd. (THF), evapn. (vac.), extd. (CH2Cl2), concd., cooling (-20°C), filtered, dried (vacuo), elem. anal.;63%
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

trimethyl(methylene)phosphorane
14580-91-7, 29218-61-9

trimethyl(methylene)phosphorane

Conditions
ConditionsYield
With diethyl ether; phenyllithium
With diethyl ether; methyllithium
With n-butyllithium In hexane at -78℃; Inert atmosphere;
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

tetramethylphosphonium hydroxide
14814-27-8

tetramethylphosphonium hydroxide

Conditions
ConditionsYield
With silver(l) oxide
diethyl ether
60-29-7

diethyl ether

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

phenyllithium
591-51-5

phenyllithium

trimethyl(methylene)phosphorane
14580-91-7, 29218-61-9

trimethyl(methylene)phosphorane

Conditions
ConditionsYield
je nach dem Mengenverhaeltnis;
diethyl ether
60-29-7

diethyl ether

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

phenyllithium
591-51-5

phenyllithium

(dimethyl-methylene-phosphoranyl)-methyl lithium
21752-68-1

(dimethyl-methylene-phosphoranyl)-methyl lithium

Conditions
ConditionsYield
je nach dem Mengenverhaeltnis;
diethyl ether
60-29-7

diethyl ether

tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

phenyllithium
591-51-5

phenyllithium

tris-lithiomethyl-methylene-phosphorane

tris-lithiomethyl-methylene-phosphorane

Conditions
ConditionsYield
je nach dem Mengenverhaeltnis;
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

phenyllithium
591-51-5

phenyllithium

(dimethyl-methylene-phosphoranyl)-methyl lithium
21752-68-1

(dimethyl-methylene-phosphoranyl)-methyl lithium

Conditions
ConditionsYield
With diethyl ether
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

phenyllithium
591-51-5

phenyllithium

tris-lithiomethyl-methylene-phosphorane

tris-lithiomethyl-methylene-phosphorane

Conditions
ConditionsYield
With diethyl ether
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

phenyllithium
591-51-5

phenyllithium

bis-(2-hydroxy-2,2-diphenyl-ethyl)-dimethyl-phosphonium; iodide

bis-(2-hydroxy-2,2-diphenyl-ethyl)-dimethyl-phosphonium; iodide

Conditions
ConditionsYield
With diethyl ether beim Behandeln des Reaktionsgemisches mit Benzophenon;
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

sodium tetraethylaluminate
2397-68-4

sodium tetraethylaluminate

C8H20Al(1-)*C4H12P(1+)

C8H20Al(1-)*C4H12P(1+)

Conditions
ConditionsYield
With triethylaluminum In toluene
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

sodium aluminum diethyl dihydride

sodium aluminum diethyl dihydride

C4H12Al(1-)*C4H12P(1+)

C4H12Al(1-)*C4H12P(1+)

Conditions
ConditionsYield
With triethylaluminum In toluene
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

tetramethylphosphonium triiodide

tetramethylphosphonium triiodide

Conditions
ConditionsYield
With trifluoroacetic acid
With iodine In solid at 40℃;
tetramethylphosphonium iodide
993-11-3

tetramethylphosphonium iodide

7,7',8,8'-tetracyanoquinodimethane
1518-16-7

7,7',8,8'-tetracyanoquinodimethane

2C12H4N4*C4H12P(1+)*I(1-)
94017-56-8

2C12H4N4*C4H12P(1+)*I(1-)

Conditions
ConditionsYield
In acetonitrile at 35℃;

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