(3,3,3-Trifluoropropyl)dichloromethylsilane supplier

Name
(3,3,3-Trifluoropropyl)dichloromethylsilane
EINECS 211-623-4
CAS No. 675-62-7
Article Data10
CAS DataBase
Density 1.245 g/cm³
Solubility
Melting Point
Formula C₄H₇Cl₂F₃Si
Boiling Point 113.8 °C at 760 mmHg
Molecular Weight 211.086
Flash Point 22.6 °C
Transport Information
Appearance Colorless clear liquid
Safety 16-26-28-36/37/39-45
Risk Codes 11-34-37
Molecular Structure
Hazard Symbols C
Synonyms (3,3,3-Trifluoropropyl)methyldichlorosilane;Dichloromethyl(3,3,3-trifluoropropyl)silane;Methyl-3,3,3-trifluoropropyldichlorosilane;
PSA 0.00000
LogP 3.48840

Synthetic route

: 75-54-7
Dichloromethylsilane

: 677-21-4
1,1,1-trifluoropropylene

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

Conditions

Conditions	Yield
RhCl(PPh3)3 at 120℃; for 12h;	85%
Irradiation.unter Einwirkung von UV-Licht;
With platinum at 250℃;

: 75-54-7
Dichloromethylsilane

: 677-21-4
1,1,1-trifluoropropylene

A: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

B: Dichloro-methyl-((E)-3,3,3-trifluoro-propenyl)-silane

Conditions

Conditions	Yield
dodecacarbonyl-triangulo-triruthenium at 120℃; for 70h; Yield given. Yields of byproduct given;

...Expand

: 819-59-0
Chlor-methyl-<3,3,3-trifluor-propyl>-silan

A: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

B: 690-96-0
methyl(3,3,3-trifluoropropyl)silane

Conditions

Conditions	Yield
With tetrabutylammomium bromide at 105℃; for 24h; Equilibrium constant; Further Variations:; Temperatures; Disproportionation;

: 75-54-7
Dichloromethylsilane

: 754-12-1
2,3,3,3-tetrafluoro-propene

A: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

B: dichloro(methyl)(2,3,3,3-tetrafluoropropyl)silane

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate(IV) hexahydrate In neat (no solvent) at 100℃; for 20h;	A 19 %Spectr. B 56 %Spectr.
With dihydrogen hexachloroplatinate(IV) hexahydrate In neat (no solvent) at 80℃; for 48h; Temperature;	A 59 %Spectr. B 15 %Spectr.

...Expand

: 75-54-7
Dichloromethylsilane

: 754-12-1
2,3,3,3-tetrafluoro-propene

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

Conditions

Conditions	Yield
With Wilkinson's catalyst In neat (no solvent) at 100℃; for 20h;	48 %Spectr.

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 107-05-1
3-chloroprop-1-ene

: trifluoropropyl allyl methyl chlorosilane

Conditions

Conditions	Yield
With iodine; magnesium In tetrahydrofuran at 30 - 40℃; for 4h;	89%

: 3277-26-7
1,1,3,3-Tetramethyldisiloxane

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 28364-07-0
C8H21F3O2Si3

Conditions

Conditions	Yield
With hydrogenchloride at 10 - 20℃;	85%

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 947-42-2
diphenylsilanediol

: 67853-21-8
1,5-dichloro-1,5-dimethyl-1,5-bis(3,3,3-trifluoropropyl)-3,3-diphenyltrisiloxane

Conditions

Conditions	Yield
With triethylamine In ethyl acetate at 0 - 10℃; for 2h; Temperature; Inert atmosphere;	82.6%

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 690-96-0
methyl(3,3,3-trifluoropropyl)silane

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In dibutyl ether at 40℃; for 2h; Reduction;	82%

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 106-95-6
allyl bromide

: trifluoropropyl allyl methyl chlorosilane

Conditions

Conditions	Yield
With iodine; magnesium In tetrahydrofuran at 30 - 40℃; for 4h;	81%

: 75-89-8
2,2,2-trifluoroethanol

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 1233922-28-5
methyl(3,3,3-trifluoropropyl)bis(2,2,2-trifluoroethoxy)silane

Conditions

Conditions	Yield
at 40 - 50℃; Inert atmosphere;	65%

: 78-10-4
tetraethoxy orthosilicate

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 1546-86-7
Chlor-aethoxy-methyl-(3,3,3-trifluor-propyl)-silan

Conditions

Conditions	Yield
With N,N,N,N,N,N-hexamethylphosphoric triamide for 24h;	62%

: 67-56-1
methanol

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 358-67-8
methyl(3,3,3-trifluoro-n-propyl)dimethoxysilane

Conditions

Conditions	Yield
at 40 - 50℃; Inert atmosphere;	54%

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 690-96-0
methyl(3,3,3-trifluoropropyl)silane

: 819-59-0
Chlor-methyl-<3,3,3-trifluor-propyl>-silan

Conditions

Conditions	Yield
With tetrabutylammomium bromide at 105℃; for 24h; Equilibrium constant; Further Variations:; Temperatures; redistribution;	50%
With tetrabutylammomium bromide at 105℃; for 24h; redistribution;	50%

: 4518-94-9
dichloromethylpropylsilane

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

polymer; monomer(s): methyl(propyl)dichlorosilane; methyl-3,3,3-trifluoropropyldichlorosilane: polymer; monomer(s): methyl(propyl)dichlorosilane; methyl-3,3,3-trifluoropropyldichlorosilane

Conditions

Conditions	Yield
With sodium In octane at 120℃; for 3h;	15.8%

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

poly(methyl-3,3,3-trifluoropropylsilane); monomer(s): methyl-3,3,3-trifluoropropyldichlorosilane: poly(methyl-3,3,3-trifluoropropylsilane); monomer(s): methyl-3,3,3-trifluoropropyldichlorosilane

Conditions

Conditions	Yield
With sodium In octane at 125℃; for 4h;	2.5%

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 1826-67-1
vinyl magnesium bromide

: 757-85-7
methyl(3,3,3-trifluoropropyl)divinylsilane

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

A: 2374-14-3
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane

B: 429-67-4
2,4,6,8-tetramethyl-2,4,6,8-tetrakis-(3,3,3-trifluoro-propyl)-cyclotetrasiloxane

Conditions

Conditions	Yield
With diethyl ether; water

: 75-77-4
chloro-trimethyl-silane

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 40330-60-7
C10H27F3N2Si3

Conditions

Conditions	Yield
With ammonia

: 1066-35-9
dimethylmonochlorosilane

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 28364-07-0
C8H21F3O2Si3

Conditions

Conditions	Yield
With water

: 64-17-5
ethanol

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 1546-86-7
Chlor-aethoxy-methyl-(3,3,3-trifluor-propyl)-silan

Conditions

Conditions	Yield
In toluene

: 79-41-4
poly(methacrylic acid)

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 23416-01-5
Dimethacryloyloxy-methyl-(3,3,3-trifluor-propyl)-silan

Conditions

Conditions	Yield
With N,N-dimethyl-aniline

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 556-67-2
octamethylcyclotetrasiloxane

: 13092-29-0
C12H31Cl2F3O4Si5

Conditions

Conditions	Yield
at 250℃;

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 556-67-2
octamethylcyclotetrasiloxane

: 13092-28-9
C20H55Cl2F3O8Si9

Conditions

Conditions	Yield
at 250℃;

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 40330-59-4
2,4,6,8-Tetramethyl-2,4,6,8-tetrakis-(3,3,3-trifluoro-propyl)-[1,3,5,7,2,4,6,8]tetrazatetrasilocane

Conditions

Conditions	Yield
With ammonia

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 64176-25-6
2,4,6-Trimethyl-2,4,6-tris-(3,3,3-trifluoro-propyl)-[1,3,5,2,4,6]trithiatrisilinane

Conditions

Conditions	Yield
With pyridine; hexamethyldisilathiane

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 1537-84-4
3-Chlor-3-(dichlor-methyl-silyl)-1,1,1-trifluor-propan

Conditions

Conditions	Yield
With chlorine Irradiation;

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 1732-87-2
3-(Dichlor-chlormethyl-silyl)-1,1,1-trifluor-propan

Conditions

Conditions	Yield
With chlorine Irradiation;

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

A: 2,4,6-Trimethyl-2,4,6-tris-(3,3,3-trifluoro-propyl)-[1,3,5,2,4,6]triazatrisilinane

B: 2,4,6-Trimethyl-2,4,6-tris-(3,3,3-trifluoro-propyl)-[1,3,5,2,4,6]triazatrisilinane

Conditions

Conditions	Yield
With ammonia

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 75-78-5
dimethylsilicon dichloride

: 1744-30-5
Heptamethyl-<3,3,3-trifluor-propyl>-cyclotetrasiloxan

Conditions

Conditions	Yield
With water In diethyl ether

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 75-78-5
dimethylsilicon dichloride

: 20442-93-7
2.6-Bis-<3.3.3-trifluor-propyl>-hexamethylcyclotetrasiloxan

Conditions

Conditions	Yield
With water In diethyl ether

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

: 2374-14-3
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane

Conditions

Conditions	Yield
hydrolysis;

: 78-10-4
tetraethoxy orthosilicate

: 75-00-3
chloroethane

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

A: 78-07-9
ethyltriethoxy silane

B: 5021-93-2
diethyldiethoxysilane

C: diethoxy-methyl-(3, 3, 3-trifluoro-propyl)-silane

D: Ethoxy-ethyl-methyl-(3,3,3-trifluoro-propyl)-silane

Conditions

Conditions	Yield
With magnesium In toluene at 60℃; for 1h; Product distribution; other temperature, reaction time;

...Expand

(3,3,3-Trifluoropropyl)dichloromethylsilane Chemical Properties

IUPAC Name: Dichloro-methyl-(3,3,3-trifluoropropyl)silane
Molecular Formula: C₄H₇Cl₂F₃Si
Molecular Weight: 211.10g/mol
EINECS: 211-623-4
Liansport Information: 2985
Appearance: clear, colorless Liquid
Density: 1.245 g/cm³
Boiling Point: 113.8 °C at 760 mmHg
Flash Point: 22.6 °C
Freely Rotating Bonds: 2
Polar Surface Area: 0 Å²
Index of Refraction: 1.382
Molar Refractivity: 39.45 cm³
Molar Volume: 169.4 cm³
Polarizability: 15.64× 10^-24 cm³
Surface Tension: 18.3 dyne/cm
Enthalpy of Vaporization: 33.77 kJ/mol
Vapour Pressure: 24.2 mmHg at 25°C
The chemical synonyms of Dichloromethyl-3,3,3-trifluoro-propylsilane (675-62-70) are Dichloromethyl(3,3,3-trifluoropropyl)-silan ; Dichloro-methyl-(3,3,3-trifluoro-propyl)-silane ; Dichloromethyl(3,3,3-trifluoropropyl)-Silane ; Dichloro-methyl-3,3,3-trifluoro-propyl-silane ; Dichloromethyl-3,3,3-trifluoropropylsilane ; (3,3,3-Trifluoropropyl)dichloromethylsilane ; (3,3,3-Trifluoropropyl)methyldichlorosilane ; Dichloromethyl(3,3,3-trifluoropropyl)silane ; (3,3,3)-Trifluoropropyl dichloromethylsilane .Product categories of Dichloromethyl-3,3,3-trifluoro-propylsilane (675-62-70) are Fluoro ; Fluoro Silanes .The molecular structure of Dichloromethyl-3,3,3-trifluoro-propylsilane (675-62-70) is .

(3,3,3-Trifluoropropyl)dichloromethylsilane Toxicity Data With Reference

ihl-mus LC50:300 mg/m3/2H

85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1223.

(3,3,3-Trifluoropropyl)dichloromethylsilane Consensus Reports

Reported in EPA TSCA Inventory.

(3,3,3-Trifluoropropyl)dichloromethylsilane Safety Profile

Poison by inhalation. When heated to decomposition it emits toxic vapors of F⁻ and Cl⁻.
Hazard Codes: C
C: Corrosive
Risk Statements: 11-34-37
11: Highly Flammable
34: Causes burns
37: Irritating to the respiratory system
Safety Statements: 16-26-28-36/37/39-45
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
HazardClass: 3

Product Name

(3,3,3-Trifluoropropyl)dichloromethylsilane

Synthetic route

(3,3,3-Trifluoropropyl)dichloromethylsilane Chemical Properties

(3,3,3-Trifluoropropyl)dichloromethylsilane Toxicity Data With Reference

(3,3,3-Trifluoropropyl)dichloromethylsilane Consensus Reports

(3,3,3-Trifluoropropyl)dichloromethylsilane Safety Profile

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