1,2,2,3-tetrachloropropane
1,2,3-trichloropropene
Conditions | Yield |
---|---|
With triethylbenzylammonium ethanolate In ethyl acetate | 97.7% |
With sodium hydroxide | |
chromium(III) oxide at 350℃; for 2h; | |
With caustic feed at 93.5 - 120℃; |
2,3-Dichloroprop-1-ene
A
1,2,3-trichloropropene
B
1,2,2,3-tetrachloropropane
C
1,1,2,2,3-pentachloropropane
Conditions | Yield |
---|---|
With chlorine at 25℃; Product distribution; addition of FeCl3, addition of hydroquinone, periodic or continuous chlorina ion; | A 2% B 94% C 4% D n/a |
2-bromo-1,2,3-trichloro-propane
1,2,3-trichloropropene
Conditions | Yield |
---|---|
With sodium hydroxide | |
With octanol; sodium octanolate |
2,3-Dichloroprop-1-ene
A
1,2,3-trichloropropene
B
1,2,2,3-tetrachloropropane
Conditions | Yield |
---|---|
With chlorine; phenol at 20℃; Rate constant; Product distribution; other radical reaction inhibitors, such as o-chlorophenol, ionol; other temp.; | |
With aluminium trichloride; chlorine In various solvent(s) at 24.85℃; Kinetics; Further Variations:; Temperatures; Reagents; | |
With chlorine In various solvent(s) at -0.15℃; | |
With 2,2'-azobis(isobutyronitrile); chlorine In various solvent(s) at 24.85℃; |
1,1,2,3-tetrachloropropane
A
1,2,3-trichloropropene
B
3,3-dichloroallyl chloride
Conditions | Yield |
---|---|
With sodium hydroxide; cetylpyridinium bromide at 130℃; for 2h; Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
Destillieren; das Natriumsalz reagiert; |
1,2,3-trichloropropene
Conditions | Yield |
---|---|
With potassium carbonate |
1,2,2,3-tetrachloropropane
1,2,3-trichloropropene
1,2,3-trichloropropene
Conditions | Yield |
---|---|
With water beim Destillieren; |
Conditions | Yield |
---|---|
FeCl3/C at 200℃; |
prop-1-yne
A
1,2,3-trichloropropene
B
1,1,2,2-tetrachloropropane
C
1,2,2,3-tetrachloropropane
Conditions | Yield |
---|---|
With chlorine at 60 - 80℃; |
1,2,3-trichloropropene
1,1,2,2,3-pentachloropropane
Conditions | Yield |
---|---|
With chlorine at 70℃; under 11251.1 Torr; Temperature; Pressure; Flow reactor; | 98% |
With chlorine im Licht; | |
With chlorine at 40 - 60℃; for 3.5h; |
Conditions | Yield |
---|---|
With sodium hydride In N,N-dimethyl-formamide | 91% |
8-quinolinol
1,2,3-trichloropropene
8-((Z)-2,3-Dichloro-allyloxy)-quinoline
Conditions | Yield |
---|---|
With sodium hydroxide; tetrabutylammomium bromide In dichloromethane; water at 25℃; for 4h; | 77% |
chloroxine
1,2,3-trichloropropene
5,7-Dichloro-8-((Z)-2,3-dichloro-allyloxy)-quinoline
Conditions | Yield |
---|---|
With sodium hydroxide; tetrabutylammomium bromide In dichloromethane; water at 25℃; for 4h; | 57% |
1,2,3-trichloropropene
2,4-dichlorophenol
2,4-Dichloro-1-((Z)-2,3-dichloro-allyloxy)-benzene
Conditions | Yield |
---|---|
With sodium hydroxide; tetrabutylammomium bromide In dichloromethane; water at 30℃; for 5h; | 44% |
Conditions | Yield |
---|---|
With sodium iodide; tin(ll) chloride In N,N-dimethyl-formamide at 60℃; for 24h; | A 36% B 28% |
1,2,3-trichloropropene
sodium 4-methylphenoxide
4-methyl-2-(2,3-dichloro-2-propenyl)phenol
Conditions | Yield |
---|---|
20.5% |
1,2,3-trichloropropene
2-methoxy-phenol
1-((Z)-2,3-Dichloro-allyloxy)-2-methoxy-benzene
Conditions | Yield |
---|---|
With sodium hydroxide; tetrabutylammomium bromide In dichloromethane; water at 25℃; for 8h; | 16% |
1,2,3-trichloropropene
2-hydroxynitrobenzene
1-((Z)-2,3-Dichloro-allyloxy)-2-nitro-benzene
Conditions | Yield |
---|---|
With sodium hydroxide; tetrabutylammomium bromide In dichloromethane; water at 55℃; for 4h; | 10% |
1,2,3-trichloropropene
sodium acetate
acetic acid-(2,3-dichloro-allyl ester)
Conditions | Yield |
---|---|
With ethanol |
1,2,3-trichloropropene
potassium phtalimide
N-(2,3-dichloro-allyl)-phthalimide
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide |
1,2,3-trichloropropene
A
3-bromo-1c,2-dichloro-propene
B
3-bromo-1t,2-dichloro-propene
Conditions | Yield |
---|---|
With acetone; sodium bromide |
Conditions | Yield |
---|---|
With sodium carbonate |
carbon disulfide
N-Demethylchlordimeform
1,2,3-trichloropropene
{[(Z)-4-Chloro-2-methyl-phenylimino]-methyl}-methyl-dithiocarbamic acid (Z)-2,3-dichloro-allyl ester
Conditions | Yield |
---|---|
(i) Et3N, (ii) /BRN= 1633563/; Multistep reaction; |
1,2,3-trichloropropene
1,2,2,3-tetrachloropropane
1,1,2,2,3-pentachloropropane
Conditions | Yield |
---|---|
With chlorine at 19.9℃; Kinetics; Mechanism; Thermodynamic data; other temperature; |
1,2,3-trichloropropene
di(2,3-dichloroallyl) sulfide
Conditions | Yield |
---|---|
With sodium sulfide; tetrabutylammomium bromide In water at 70 - 80℃; for 2h; | 68 % Chromat. |
IUPAC Name: (Z)-1,2,3-Trichloroprop-1-ene
Synonyms: 1,2,3-Trichlor-1-propene ; 1,2,3-Trichloro-1-propene ; 1,2,3-Trichloropropene
CAS NO:96-19-5
Molecular Formula of 1,2,3-Trichloropropene (CAS NO.96-19-5) :C3H3Cl3
Molecular Weight of 1,2,3-Trichloropropene (CAS NO.96-19-5) : 145.41
Molecular Structure of 1,2,3-Trichloropropene (CAS NO.96-19-5):
EINECS: 202-487-7
Index of Refraction: 1.487
Surface Tension: 31.4 dyne/cm
Density: 1.376 g/cm3
Flash Point: 65.5 °C
Enthalpy of Vaporization: 36.35 kJ/mol
Boiling Point: 142 °C at 760 mmHg
Vapour Pressure: 7.14 mmHg at 25°C
Appearance:An amber liquid
Solubility:Soluble in carbon tetrachloride and chloroform, insoluble in water
1,2,3-Trichloropropene (CAS NO.96-19-5) is used as the intermediate of diallate herbicide.
Raw materials: Dichloroethane
Adding Tetrachloro-propane and Ethanol into the reactor,stirring ,heated to reflux, adding Potassium hydroxide in batches within 1 h, After finishing,reflux 2 h, cooling, filtration, the filtration washed two times, the water layer with dichloroethane extraction, combined with the reservoir, desolventizing, vacuum distillation, collecting at 74 ~ 91 °C / 13.3 kPa,then obtaining 1,2,3-Trichloropropene (CAS NO.96-19-5) .
ClCH2Cl2CH2Cl + KOH → ClCH2ClC = CHCl + KCl + H2O
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rabbit | LD50 | skin | 640uL/kg (0.64mL/kg) | American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. | |
rat | LCLo | inhalation | 500ppm/4H (500ppm) | Union Carbide Data Sheet. Vol. 5/4/1960, | |
rat | LD50 | oral | 616mg/kg (616mg/kg) | Union Carbide Data Sheet. Vol. 5/4/1960, |
Reported in EPA TSCA Inventory.
Moderately toxic by ingestion, inhalation, and skin contact. Mutation data reported. An eye and severe skin irritant. Combustible when exposed to heat, flames (sparks) or powerful oxidizers. To fight fire, use water (as a blanket), spray, mist, dry chemical. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
Risk Statements 20/21/22-36/37/38
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 26-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RIDADR 2810
RTECS UD2450000
HazardClass 6.1(b)
PackingGroup III
1.General Description :May be absorbed through the skin. Vapors are heavier than air. Contact with vapors or liquid may cause burns or irritation.
2.Air & Water Reactions :Flammable.
3.Reactivity Profile: 1,2,3-Trichloropropene incompatible with strong oxidizing and reducing agents. Incompatible with many amines, nitrides, azo/diazo compounds, with alkali metals, and with epoxides. Reacts with bases. Produces toxic fumes when heated to decomposition. Avoid contact with iron, plastics, and aluminum.
4.Health Hazard TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
5.Fire Hazard :Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
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