1,3,5-Tribromobenzene supplier

Name
Tribromobenzene
EINECS 210-947-3
CAS No. 626-39-1
Article Data56
CAS DataBase
Density 2.281 g/cm³
Solubility insoluble in water
Melting Point 117-121 °C(lit.)
Formula C₆H₃Br₃
Boiling Point 269.4 °C at 760 mmHg
Molecular Weight 314.802
Flash Point 115.5 °C
Transport Information
Appearance Lump powder
Safety 22-24/25-37/39-26
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Benzene,1,3,5-tribromo-;NSC 62439;
PSA 0.00000
LogP 3.97410

Synthetic route

: 2,4,6-tribromobenzenediazonium o-benzenedisulfonimide

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
With dihydrogen peroxide In tetrahydrofuran for 0.166667h; Heating;	100%
Multi-step reaction with 2 steps 1: 92 percent / aq. NaOH / 0.5 h / 0 - 5 °C 2: 2 percent / aq. HI; HBF4 / acetonitrile / 24 h / 60 °C View Scheme
Multi-step reaction with 2 steps 1: 92 percent / aq. NaOH / 0.5 h / 0 - 5 °C 2: 13 percent / Et3PhCH2N(+)Cl(-); MeSO3H; Cu / acetonitrile / 1 h / 40 °C View Scheme

: 147-82-0
2,4,6-tribromoaniline

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
Stage #1: 2,4,6-tribromoaniline With hydrogenchloride; sodium nitrite In water Stage #2: With ethanol In water	92%
With sulfuric acid; sodium nitrite In ethanol at 20℃; Reflux;	90%
With ethanol; sulfuric acid; benzene Reagens 4: Natriumnitrit;

: 722540-83-2
(2,4,6-tribromophenyl)triethylsilane

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
With potassium fluoride In tetrahydrofuran; water for 12h; Heating;	91%

: 401631-91-2
C10H12Br3N3

A: 626-39-1
1,3,5-trisbromobenzene

B: 21521-51-7
2,4,6-tribromoiodobenzene

Conditions

Conditions	Yield
With tetrafluoroboric acid; hydrogen iodide In acetonitrile at 60℃; for 24h;	A 2% B 84%

: 401631-91-2
C10H12Br3N3

A: 626-39-1
1,3,5-trisbromobenzene

B: 78904-10-6
1,3,5-tribromo-2-chloro-benzene

Conditions

Conditions	Yield
With methanesulfonic acid; N-benzyl-N,N,N-triethylammonium chloride; copper In acetonitrile at 40℃; for 1h;	A 13% B 78%

: 2-methoxycarbonyl-3',5'-dibromobiphenyl

: 374538-03-1
2-methoxycarbonylphenylboronic acid

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
	54%

: tribromo-benzenediazonium tetrafluoroborate

A: 626-39-1
1,3,5-trisbromobenzene

B: 134253-67-1
2,4,6-tribromobenzenediazohydroxide

Conditions

Conditions	Yield
With 2,2,2-trifluoroethanol at 34℃; for 24h; Irradiation; Further byproducts given;	A 47% B 8.8%
With 2,2,2-trifluoroethanol at 34℃; for 24h; Irradiation; Further byproducts given;	A 47% B 8.8%
With 2,2,2-trifluoroethanol at 34℃; for 24h; Further byproducts given;	A 35.5% B 4.1%

: tribromo-benzenediazonium tetrafluoroborate

A: 626-39-1
1,3,5-trisbromobenzene

B: 134253-67-1
2,4,6-tribromobenzenediazohydroxide

C dibromo-hydroxybenzene: dibromo-hydroxybenzene

Conditions

Conditions	Yield
With 2,2,2-trifluoroethanol at 34℃; for 24h; Product distribution; influence of magnetic field;	A 47% B 8.8% C n/a

...Expand

: 147-82-0
2,4,6-tribromoaniline

: 544-92-3
copper(I) cyanide

A: 626-39-1
1,3,5-trisbromobenzene

B: 634-89-9
1,2,3,5-tetrabromobenzene

C: 3463-40-9
2,4,6-tribromonitrobenzene

D: 35851-93-5
2,4,6-tribromobenzonitrile

E: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With tert.-butylnitrite In dimethyl sulfoxide at 60℃; for 1.5h; Product distribution; Mechanism; other anilines;	A 37% B 7% C 4% D 20% E 4%

...Expand

: 147-82-0
2,4,6-tribromoaniline

: 544-92-3
copper(I) cyanide

A: 626-39-1
1,3,5-trisbromobenzene

B: 3463-40-9
2,4,6-tribromonitrobenzene

C: 35851-93-5
2,4,6-tribromobenzonitrile

D: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With tert.-butylnitrite In dimethyl sulfoxide at 60℃; for 1.5h; Further byproducts given;	A 37% B 4% C 20% D 4%

...Expand

: 147-82-0
2,4,6-tribromoaniline

A: 626-39-1
1,3,5-trisbromobenzene

B: 634-89-9
1,2,3,5-tetrabromobenzene

C: 3463-40-9
2,4,6-tribromonitrobenzene

D: 35851-93-5
2,4,6-tribromobenzonitrile

Conditions

Conditions	Yield
With tert.-butylnitrite In dimethyl sulfoxide at 60℃; for 1.5h; Further byproducts given;	A 37% B 7% C 4% D 20%

...Expand

: 147-82-0
2,4,6-tribromoaniline

A: 626-39-1
1,3,5-trisbromobenzene

B: 3463-40-9
2,4,6-tribromonitrobenzene

C: 35851-93-5
2,4,6-tribromobenzonitrile

D: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With tert.-butylnitrite In dimethyl sulfoxide at 60℃; for 1.5h; Further byproducts given;	A 37% B 4% C 20% D 4%

...Expand

: C6H2Br3ClN2

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid at 25℃; for 24h; Irradiation;	34.3%

: tribromo-benzenediazonium tetrafluoroborate

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid at 34℃; for 24h; Further byproducts given. Yields of byproduct given;	25%

: C8H2Br3F3N2O2

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid at 25℃; for 24h; Irradiation;	20%

2,4,6-tribromophenyl diazonium salt: 2,4,6-tribromophenyl diazonium salt

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
With nitroxide	13%

: C7H2Br3F3N2O3S

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid at 25℃; for 24h; Irradiation;	4.4%

: 67-56-1
methanol

: 2,4,6-tribromo-benzenediazonium; hydrogen sulfate

: 626-39-1
1,3,5-trisbromobenzene

: 67-56-1
methanol

: 2,4,6-tribromo-benzenediazonium; hydrogen sulfate

A: 626-39-1
1,3,5-trisbromobenzene

B: 607-99-8
2,4,6-tribromoanisole

C: 20648-40-2
3,5-dibromo-ortho quinone diazide

D: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
bei der Belichtung.Irradiation;

...Expand

: 64-18-6
formic acid

: 2,4,6-tribromo-benzenediazonium; hydrogen sulfate

A: 626-39-1
1,3,5-trisbromobenzene

B: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
bei der Belichtung.Irradiation;

...Expand

: 64-17-5
ethanol

: 2,4,6-tribromo-benzenediazonium; hexachloro plumbate(IV)

A: 626-39-1
1,3,5-trisbromobenzene

B: 78904-10-6
1,3,5-tribromo-2-chloro-benzene

...Expand

: 64-17-5
ethanol

: 2,4,6-tribromo-benzenediazonium; hydrogen sulfate

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
zersetzt sich in Dunkel;

: 64-17-5
ethanol

: 2,4,6-tribromo-benzenediazonium; hydrogen sulfate

A: 626-39-1
1,3,5-trisbromobenzene

B: 98437-52-6
1,3,5-tribromo-2-ethoxybenzene

Conditions

Conditions	Yield
zersetzt sich in Sonnenlicht.Irradiation;

...Expand

: 106-37-6
1.4-dibromobenzene

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
With aluminium trichloride

: 106-37-6
1.4-dibromobenzene

A: 626-39-1
1,3,5-trisbromobenzene

B: 615-54-3
1,2,4-tribromobenzene

Conditions

Conditions	Yield
With aluminium trichloride

: 626-40-4
3,5-dibromoaniline

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
durch Ueberfuehrung in das Diazoniumperbromid und dessen Zersetzung mit Alkohol;

: 634-89-9
1,2,3,5-tetrabromobenzene

: 141-52-6
sodium ethanolate

: 626-39-1
1,3,5-trisbromobenzene

: 2537-67-9
2,4,6-tribromoacetophenone

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
With potassium hydroxide at 150℃;

: 45859-98-1
2,4,6-tribromobenzaldehyde

: 626-39-1
1,3,5-trisbromobenzene

Conditions

Conditions	Yield
With potassium hydroxide

: 101870-36-4
2,4,6-tribromo-benzenesulfonic acid

: 626-39-1
1,3,5-trisbromobenzene

: 626-39-1
1,3,5-trisbromobenzene

: methyl 5-propyloxy-2-aminobenzoate

: 1,3,5-tris(2-carbomethoxy-4-propyloxyphenylamino)benzene

Conditions

Conditions	Yield
With tri-tert-butyl phosphine; palladium diacetate; caesium carbonate In toluene for 72h; Inert atmosphere; Reflux;	100%

: 67-56-1
methanol

: 626-39-1
1,3,5-trisbromobenzene

: 621-23-8
1,2,3-trimethoxybenzene

Conditions

Conditions	Yield
Stage #1: methanol; 1,3,5-trisbromobenzene In toluene at 135℃; under 5320.36 Torr; for 0.75h; Stage #2: With triethylamine In toluene at 165℃; under 8360.56 Torr; for 11h; Temperature;	99.5%
With sodium methylate; copper(l) chloride In N,N-dimethyl-formamide at 100 - 110℃; for 6h;	90%
Stage #1: methanol; 1,3,5-trisbromobenzene In N,N-dimethyl-formamide Stage #2: With copper(l) iodide; sodium methylate

: 626-39-1
1,3,5-trisbromobenzene

: 1066-54-2
trimethylsilylacetylene

: 18772-58-2
1,3,5-tris-(1-trimethylsilylethynyl)benzene

Conditions

Conditions	Yield
Stage #1: 1,3,5-trisbromobenzene With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine at 50℃; for 0.25h; Sonogashira Cross-Coupling; Stage #2: trimethylsilylacetylene at 90℃; for 48h; Sonogashira Cross-Coupling;	99%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 65℃; for 16h; Sonogashira coupling;	96.4%
With pyridine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 90℃; for 12h; Inert atmosphere;	96.6%

: 626-39-1
1,3,5-trisbromobenzene

: 250643-76-6
tris((2-phenyl)ethynyl)indium

: 118688-56-5
1,3,5-tris(2-phenylethynyl)benzene

Conditions

Conditions	Yield
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran Heating;	99%

: 75-77-4
chloro-trimethyl-silane

: 626-39-1
1,3,5-trisbromobenzene

: 81500-92-7
3,5-Bis-trimethylsilyl-bromobenzene

Conditions

Conditions	Yield
Stage #1: 1,3,5-trisbromobenzene With n-butyllithium In diethyl ether at -78℃; for 1h; Stage #2: chloro-trimethyl-silane In diethyl ether at -78 - 20℃; Further stages.;	99%
Stage #1: 1,3,5-trisbromobenzene With n-butyllithium In diethyl ether; hexane at -80℃; for 0.25h; Inert atmosphere; Stage #2: chloro-trimethyl-silane In diethyl ether; hexane at -80 - 20℃; for 1h; Inert atmosphere;	98%
Stage #1: 1,3,5-trisbromobenzene With n-butyllithium In diethyl ether; hexane at -78℃; Stage #2: chloro-trimethyl-silane In diethyl ether; hexane at -78 - 20℃;	85%
With hydrogenchloride In diethyl ether; magnesium	56%

: 626-39-1
1,3,5-trisbromobenzene

: 226065-32-3
tert-butyl 1-(4-cyanophenyl)hydrazine-1-carboxylate

: N'-{3,5-bis-[N'-tert-butoxycarbonyl-N'-(4-cyano-phenyl)-hydrazino]-phenyl}-N-(4-cyano-phenyl)-hydrazinecarboxylic acid tert-butyl ester

Conditions

Conditions	Yield
With caesium carbonate; palladium diacetate; tri-tert-butyl phosphine In hexane; toluene at 20 - 110℃; for 2.5h;	99%

: 626-39-1
1,3,5-trisbromobenzene

: 226065-39-0
N-(4-benzoyl-phenyl)-hydrazinecarboxylic acid tert-butyl ester

: N-(4-benzoyl-phenyl)-N'-{3,5-bis-[N'-(4-benzoyl-phenyl)-N'-tert-butoxycarbonyl-hydrazino]-phenyl}-hydrazinecarboxylic acid tert-butyl ester

Conditions

Conditions	Yield
With caesium carbonate; palladium diacetate; tri-tert-butyl phosphine In hexane; toluene at 20 - 110℃; for 3.5h;	99%

: 626-39-1
1,3,5-trisbromobenzene

: 380383-87-9
N-(2-methoxy-phenyl)-hydrazinecarboxylic acid tert-butyl ester

: 681815-56-5
N'-[3,5-bis-(N'-tert-butoxycarbonyl-N'-(2-methoxy-phenyl)-hydrazino)-phenyl]-N-(2-methoxy-phenyl)-hydrazinecarboxylic acid tert-butyl ester

Conditions

Conditions	Yield
With caesium carbonate; palladium diacetate; tri-tert-butyl phosphine In hexane; toluene at 20 - 110℃; for 2.5h;	99%
With palladium diacetate; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate In toluene for 2h; Heating;	99%

: 626-39-1
1,3,5-trisbromobenzene

: 360045-13-2
1-tert-butoxycarbonyl-1-(4-phenylphenyl)hydrazine

: N-(biphenyl-4-yl)-N'-[3,5-bis(N'-(biphenyl-4-yl)-N'-tert-butoxycarbonylhydrazino)phenyl]hydrazinecarboxylic acid tert-butyl ester

Conditions

Conditions	Yield
With caesium carbonate; palladium diacetate; tri-tert-butyl phosphine In hexane; toluene at 20 - 110℃; for 3.5h;	99%

: 626-39-1
1,3,5-trisbromobenzene

: N-(4-hexyl-phenyl)-hydrazinecarboxylic acid tert-butyl ester

: N'-{3,5-bis-[N'-tert-butoxycarbonyl-N'-(4-hexyl-phenyl)-hydrazino]-phenyl}-N-(4-hexyl-phenyl)-hydrazinecarboxylic acid tert-butyl ester

Conditions

Conditions	Yield
With caesium carbonate; palladium diacetate; tri-tert-butyl phosphine In hexane; toluene at 20 - 110℃; for 2.5h;	99%

: 626-39-1
1,3,5-trisbromobenzene

: 10365-98-7
3-methoxyphenylboronic acid

: 132361-34-3
3,3''-dimethoxy-5'-(3-methoxyphenyl)-1,1':3',1''-terphenyl

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran at 80℃; for 48h;	99%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 48h; Suzuki coupling; Inert atmosphere; Reflux;

: 626-39-1
1,3,5-trisbromobenzene

: 18595-16-9
2-amino-5-methylbenzoic acid methyl ester

: 1305155-04-7
1,3,5-tris(2-carbomethoxy-4-methylphenylamino)benzene

Conditions

Conditions	Yield
With tri-tert-butyl phosphine; palladium diacetate; caesium carbonate In toluene for 72h; Inert atmosphere; Reflux;	99%

: 626-39-1
1,3,5-trisbromobenzene

: methyl 5-dodecyloxy-2-amino-benzoate

: 1,3,5-tris(2-carbomethoxy-4-dodecyloxyphenylamino)benzene

Conditions

Conditions	Yield
With tri-tert-butyl phosphine; palladium diacetate; caesium carbonate In toluene for 72h; Inert atmosphere; Reflux;	99%

: 626-39-1
1,3,5-trisbromobenzene

: 124-41-4
sodium methylate

: 74137-36-3
3,5-dibromoanisole

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 90℃; for 12h;	98%
In N,N-dimethyl-formamide at 80℃; for 8h;	70%
In N,N-dimethyl-formamide at 80℃; for 28h; Inert atmosphere;	48.9%
In pyridine; methanol at 115℃; Rate constant; Product distribution;
In N,N-dimethyl-formamide at 90℃; for 0.25h;

: 110-91-8
morpholine

: 626-39-1
1,3,5-trisbromobenzene

: 16857-97-9
1,3,5-trimorpholinobenzene

Conditions

Conditions	Yield
With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 100℃; for 24h;	98%
With potassium tert-butylate In 5,5-dimethyl-1,3-cyclohexadiene at 130℃; for 7h; Buchwald-Hartwig coupling reaction;	86%
With potassium tert-butylate In 5,5-dimethyl-1,3-cyclohexadiene at 130℃; for 7h; Reagent/catalyst; Buchwald-Hartwig Coupling; Glovebox;	86%

: 92-54-6
4-phenyl-1-piperazine

: 626-39-1
1,3,5-trisbromobenzene

: C36H42N6

Conditions

Conditions	Yield
With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 100℃; for 24h;	98%

: 626-39-1
1,3,5-trisbromobenzene

: 245507-96-4
C9H15ClMg

: 1,3,5-tris(3-tert-butylbicyclo[1.1.1]pent-1-yl)benzene

Conditions

Conditions	Yield
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In 1,4-dioxane at 20℃; for 48h; Grignard reaction;	98%

: 626-39-1
1,3,5-trisbromobenzene

: 124-41-4
sodium methylate

: 621-23-8
1,2,3-trimethoxybenzene

Conditions

Conditions	Yield
With methanol; Methyl formate; copper(l) chloride at 115℃; for 2h; Autoclave; Green chemistry;	98%
With copper(I) chloride In N,N-dimethyl-formamide at 130℃; for 6h;	91%

: 626-39-1
1,3,5-trisbromobenzene

: 98-80-6
phenylboronic acid

: 612-71-5
1,3,5-triphenylbenzene

Conditions

Conditions	Yield
With {2,6-bis[(di-1-piperidinylphosphino)amino]phenyl}palladium(II) chloride; potassium carbonate In 1,4-dioxane; water; butan-1-ol at 100℃; for 1h; Suzuki-Miyaura reaction;	98%
With sodium carbonate; palladium diacetate In water; N,N-dimethyl-formamide at 60℃; for 12h; Suzuki;	97%
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0); tri-tert-butyl phosphine In 1,1,1,2,3,3,3-Heptafluoropropane; ethanol; 1,1,1,3,3-pentafluorobutane at 20℃; for 24h; Inert atmosphere;	96%

: 626-39-1
1,3,5-trisbromobenzene

: 226065-37-8
N-phenyl-hydrazine carboxylic acid tert-butyl ester

: 681815-36-1
N'-[3,5-bis-(N'-tert-butoxycarbonyl-N'-phenyl-hydrazino)-phenyl]-N-phenylhydrazinecarboxylic acid tert-butyl ester

Conditions

Conditions	Yield
With caesium carbonate; palladium diacetate; tri-tert-butyl phosphine In hexane; toluene at 20 - 110℃; for 2.5h;	98%
With palladium diacetate; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate In toluene for 2h; Heating;	98%

: 626-39-1
1,3,5-trisbromobenzene

: 497064-60-5
tert-butyl 1-p-tolylhydrazinecarboxylate

: N'-[3,5-bis(N'-tert-butoxycarbonyl-N'-p-tolylhydrazino)phenyl]-N-p-tolylhydrazinecarboxylic acid tert-butyl ester

Conditions

Conditions	Yield
With caesium carbonate; palladium diacetate; tri-tert-butyl phosphine In hexane; toluene at 20 - 110℃; for 2.5h;	98%

: 626-39-1
1,3,5-trisbromobenzene

: 321903-29-1
1,1-dimethyl-1,3-dihydrobenzo[c][1,2]oxasilole

: 1239354-49-4
(3,5-dibromophenyl)[2-(hydroxymethyl)phenyl]dimethylsilane

Conditions

Conditions	Yield
Stage #1: 1,3,5-trisbromobenzene With n-butyllithium In diethyl ether; hexane at -78℃; for 2.5h; Stage #2: 1,1-dimethyl-1,3-dihydrobenzo[c][1,2]oxasilole In diethyl ether; hexane at -78 - 20℃;	98%

: 626-39-1
1,3,5-trisbromobenzene

: 73183-34-3
bis(pinacol)diborane

: 365564-05-2
1,3,5-tris(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene

Conditions

Conditions	Yield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In N,N-dimethyl-formamide at 90℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere;	98%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In N,N-dimethyl-formamide at 90℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere;	98%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In N,N-dimethyl-formamide at 90℃; for 24h; Inert atmosphere;	96%

: 626-39-1
1,3,5-trisbromobenzene

: 620-93-9
di-p-tolylamine

: 134257-64-0
N1,N1,N3,N3,N5,N5-hexakis(4-methylphenyl)-1,3,5-benzenetriamine

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 60℃; for 7h; Inert atmosphere; Schlenk technique;	98%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 60℃; for 7h; Inert atmosphere;	98%

: 626-39-1
1,3,5-trisbromobenzene

: 100-61-8
N-methylaniline

: N1,N3,N5-trimethyl-N1,N3,N5-triphenylbenzene-1,3,5-triamine

Conditions

Conditions	Yield
With (6-Dipp)PdCl2-SPhos; sodium t-butanolate In neat (no solvent) at 110℃; for 24h; Buchwald-Hartwig Coupling;	98%

: 626-39-1
1,3,5-trisbromobenzene

: 52921-77-4
deuterated 1,3,5-tribromobenzene

Conditions

Conditions	Yield
With water-d2; silver(l) oxide; 2-(dicyclohexylphosphino)-2'-methylbiphenyl In toluene at 60 - 80℃; Reagent/catalyst;	97.1%
With water-d2; potassium carbonate; silver carbonate; cyclohexyldiphenylphosphine In toluene at 120℃; for 12h;	90%

: 626-39-1
1,3,5-trisbromobenzene

: 3958-47-2
triphenylindium

: 612-71-5
1,3,5-triphenylbenzene

Conditions

Conditions	Yield
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran Heating;	97%
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran for 6h; Heating;	97%

: 626-39-1
1,3,5-trisbromobenzene

: 5720-07-0
4-methoxyphenylboronic acid

: 7509-20-8
1,3,5-tris(4-methoxyphenyl)benzene

Conditions

Conditions	Yield
With sodium carbonate; palladium diacetate In water; N,N-dimethyl-formamide at 60℃; for 12h; Suzuki;	97%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane for 48h; Suzuki Coupling; Inert atmosphere; Reflux;	95%
With potassium carbonate In ethanol; water at 20℃; for 0.333333h; Suzuki-Miyaura Coupling; Green chemistry;	95%

: 626-39-1
1,3,5-trisbromobenzene

: 24424-99-5
di-tert-butyl dicarbonate

: 422569-46-8
tert-butyl 3,5-dibromobenzoate

Conditions

Conditions	Yield
Stage #1: 1,3,5-trisbromobenzene With n-butyllithium; butyl magnesium bromide In tetrahydrofuran; hexane; toluene at -10℃; Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane; toluene at -10℃; Stage #3: With citric acid In tetrahydrofuran; hexane; toluene Further stages.;	97%
Stage #1: 1,3,5-trisbromobenzene With n-butyllithium; butyl magnesium bromide In tetrahydrofuran; hexane; toluene at -5℃; for 1h; Inert atmosphere; Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane; toluene at -5℃; for 2h; Temperature; Inert atmosphere;	97%

1,3,5-Tribromobenzene Chemical Properties

Molecule structure of 1,3,5-Tribromobenzene (CAS NO.626-39-1):

IUPAC Name: 1,3,5-Tribromobenzene
Molecular Formula: C₆H₃Br₃
Molecular Weight: 314.80002 g/mol
Density: 2.281 g/cm³
Melting Point: 117-121 °C(lit.)
Boiling Point: 269.4 °C at 760 mmHg
Flash Point: 115.5 °C
Formula Weight: 314.8 g/mol
Index of Refraction: 1.633
Molar Refractivity: 49.32 cm³
Molar Volume: 137.9 cm³
Surface Tension: 45.6 dyne/cm
Enthalpy of Vaporization: 48.71 kJ/mol
Vapour Pressure: 0.012 mmHg at 25 °C
XLogP3: 4.5
Exact Mass: 313.776441
MonoIsotopic Mass: 311.778488
Canonical SMILES: C1=C(C=C(C=C1Br)Br)Br
InChI: InChI=1S/C6H3Br3/c7-4-1-5(8)3-6(9)2-4/h1-3H
InChIKey: YWDUZLFWHVQCHY-UHFFFAOYSA-N
EINECS: 210-947-3
Product Categories: Aromatic Hydrocarbons (substituted) & Derivatives;Organics;Benzene derivates;Aryl;C6;Halogenated Hydrocarbons

1,3,5-Tribromobenzene Uses

1,3,5-Tribromobenzene (626-39-1) is used as a fundamental raw material for organic synthesis.

1,3,5-Tribromobenzene Safety Profile

Hazard Codes: Irritant Xi
Risk Statements: 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 22-24/25-37/39-26
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
S37/39:Wear suitable gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany: 3
RTECS: DC1957200
HS Code: 29036990

1,3,5-Tribromobenzene Standards and Recommendations

PURITY: 98.5% min
WATER: 0.2% max

1,3,5-Tribromobenzene Specification

1,3,5-Tribromobenzene (CAS NO.626-39-1) is also named as AI3-15483 ; NSC 62439 ; Benzene, 1,3,5-tribromo- . 1,3,5-Tribromobenzene (CAS NO.626-39-1) is Light yellow brown powder. It is insoluble in water, soluble in hot ethanol, glacial acetic acid.

Product Name

Tribromobenzene

Synthetic route

1,3,5-Tribromobenzene Chemical Properties

1,3,5-Tribromobenzene Uses

1,3,5-Tribromobenzene Safety Profile

1,3,5-Tribromobenzene Standards and Recommendations

1,3,5-Tribromobenzene Specification

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