2-(1-methoxycarbonyl-1-methylethylazo)-2-methylpropionic acid methyl ester
propylene glycol methyl ether acetate
Conditions | Yield |
---|---|
In methanol; hexane; butanone | 60% |
In methanol; hexane; water; butanone | 60% |
sodium methylate
acetic anhydride
methyloxirane
propylene glycol methyl ether acetate
Conditions | Yield |
---|---|
(i), (ii) /BRN= 385737/; Multistep reaction; |
Conditions | Yield |
---|---|
at 98℃; under 130.002 Torr; Concentration; |
Conditions | Yield |
---|---|
With dimethyl sulfate |
Conditions | Yield |
---|---|
With dimethyl sulfate |
1-methoxy-2-propanol
sec-Butyl acetate
propylene glycol methyl ether acetate
Conditions | Yield |
---|---|
With sodium methylate at 135℃; for 5h; |
propylene glycol methyl ether acetate
A
methyl (Z)-prop-1-enyl ether
B
(E)-1-Methoxy-1-propen
C
methylallylether
Conditions | Yield |
---|---|
at 500℃; |
propylene glycol methyl ether acetate
A
methyl (Z)-prop-1-enyl ether
B
methylallylether
Conditions | Yield |
---|---|
at 500℃; |
propylene glycol methyl ether acetate
A
(E)-1-Methoxy-1-propen
B
methylallylether
Conditions | Yield |
---|---|
at 500℃; |
propylene glycol methyl ether acetate
A
(S)-1-Methoxy-propan-2-ol
B
(R)-1-methoxy-2-propanol
Conditions | Yield |
---|---|
With sodium phosphate buffer; esterase B from Candida antarctica In water at 37℃; for 1h; pH=7.3; Product distribution; Further Variations:; Reagents; |
2-methyl-2-propenoic acid 2-hydroxyethyl ester
poly(methacrylic acid)
(S)-Ethyl lactate
propylene glycol methyl ether acetate
benzyl methacrylate
Conditions | Yield |
---|---|
With 2,2'-azobis-(2,4-dimethylvaleronitrile) at 65℃; for 10h; |
tris[2-(methoxymethoxy)ethyl]amine
propylene glycol methyl ether acetate
cyclohexanone
tris[2-(methoxymethoxy)ethyl]amine
propylene glycol methyl ether acetate
tris[2-(methoxymethoxy)ethyl]amine
propylene glycol methyl ether acetate
propylene glycol methyl ether acetate
propylene glycol methyl ether acetate
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; 4-methoxy-phenol at 90℃; for 12h; |
Conditions | Yield |
---|---|
In toluene at 80℃; for 4h; |
Conditions | Yield |
---|---|
With 2,2'-azobis-(2,4-dimethylvaleronitrile) In toluene at 80℃; for 6h; |
Conditions | Yield |
---|---|
With 2,2'-azobis-(2,4-dimethylvaleronitrile); 3-mercaptopropionic acid at 80℃; for 6h; |
Conditions | Yield |
---|---|
With 2,2'-azobis-(2,4-dimethylvaleronitrile) In toluene at 80℃; for 6h; |
Conditions | Yield |
---|---|
With 2,2'-azobis-(2,4-dimethylvaleronitrile) In toluene at 75℃; for 6h; |
1-methoxy-2-propanol
poly(methacrylic acid)
propylene glycol methyl ether acetate
2,3-Epoxypropyl methacrylate
methacrylic acid methyl ester
2-methyl-butyl acrylate
Conditions | Yield |
---|---|
Stage #1: 1-methoxy-2-propanol; poly(methacrylic acid); methacrylic acid methyl ester; 2-methyl-butyl acrylate With 2,2'-azobis(isobutyronitrile); 2-hydroxyethanethiol at 90℃; for 4h; Stage #2: propylene glycol methyl ether acetate at 100℃; for 1.5h; Stage #3: 2,3-Epoxypropyl methacrylate With tetrabutylammomium bromide; 4-methoxy-phenol at 80℃; for 8h; |
Triethoxysilane
propylene glycol methyl ether acetate
triethoxyphenylsilane
Conditions | Yield |
---|---|
In water |
3-hydroxy-1-adamantyl methacrylate
ethyl 2-hydroxypropionate
diphenylether
propylene glycol methyl ether acetate
3,5-bis(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)cyclohexyl methacrylate
2-isopropyl-2-adamantyl methacrylate
potassium nonaflate
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In methanol; dichloromethane; water; acetonitrile |
The International Agency for Research on Cancer (IARC) has not evaluated the carcinogenicity of PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE.
DFG MAK: 50 ppm
The 1-Methoxy-2-propyl acetate, with the CAS registry number 108-65-6,is also known as 1,2-Propanediol monomethyl ether acetate; Propylene glycol methyl ether acetate; MPA. It belongs to the product categories of Solvent Bottles;Solvent Packaging Options;Solvents.This chemical's molecular formula is C6H12O3 and molecular weight is 132.16. What's more,Its systematic name is 2-Methoxy-1-methylethyl acetate.It is colourless liquid,which is stable,flammable,incompatible with strong oxidizing agents,acids,bases.
Physical properties about 1-Methoxy-2-propyl acetate are:
(1)ACD/LogP: 0.481; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.48; (4)ACD/LogD (pH 7.4): 0.48; (5)ACD/BCF (pH 5.5): 1.37; (6)ACD/BCF (pH 7.4): 1.37; (7)ACD/KOC (pH 5.5): 43.49; (8)ACD/KOC (pH 7.4): 43.49; (9)#H bond acceptors: 3; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 4; (12)Index of Refraction: 1.399; (13)Molar Refractivity: 33.325 cm3; (14)Molar Volume: 137.797 cm3; (15)Surface Tension: 26.5 dyne/cm; (16)Density: 0.959 g/cm3; (17)Flash Point: 47.856 °C; (18)Enthalpy of Vaporization: 39.154 kJ/mol; (19)Boiling Point: 154.79 °C at 760 mmHg; (20)Vapour Pressure: 3.125 mmHg at 25°C.
You can still convert the following datas into molecular structure:
(1)SMILES:O=C(OC(C)COC)C;
(2)Std. InChI:InChI=1S/C6H12O3/c1-5(4-8-3)9-6(2)7/h5H,4H2,1-3H3;
(3)Std. InChIKey:LLHKCFNBLRBOGN-UHFFFAOYSA-N.
Uses of 1-Methoxy-2-propyl acetate:
1-Methoxy-2-propyl acetateis used as a solvent in the manufacture of coating polymers such as cellulose acetate butyrate, epoxy resins, nitrocellulose, and phenoxy resins; cosmetic formulations, agricultural products, ink formulations, textile and adhesive products. It is also used as retarder solvent in lacquers, baking elements etc.
Safety Information of 1-Methoxy-2-propyl acetate:
The 1-Methoxy-2-propyl acetate is flammable ,so it need far away from the combustion source.It is irritating to the eyes ,avoid contact with eyes.And it may cause harm to the unborn child.In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .Avoid exposure - obtain special instruction before use.
The toxicity data of 1-Methoxy-2-propyl acetate as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intraperitoneal | 750mg/kg (750mg/kg) | National Technical Information Service. Vol. AD691-490, | |
rabbit | LD50 | skin | > 5gm/kg (5000mg/kg) | Dow Chemical Company Reports. Vol. MSD-1582, | |
rat | LD50 | oral | 8532mg/kg (8532mg/kg) | Dow Chemical Company Reports. Vol. MSD-1582, |
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