Product Name

  • Name

    4-(Trifluoromethylthio)phenol

  • EINECS 620-583-0
  • CAS No. 461-84-7
  • Article Data24
  • CAS DataBase
  • Density 1.45 g/cm3
  • Solubility
  • Melting Point 57-60 °C(lit.)
  • Formula C7H5F3OS
  • Boiling Point 170.4 °C at 760 mmHg
  • Molecular Weight 194.177
  • Flash Point 56.9 °C
  • Transport Information
  • Appearance Colorless or primrose yellow crystal
  • Safety 26-36
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 461-84-7 (4-(Trifluoromethylthio)phenol)
  • Hazard Symbols IrritantXi
  • Synonyms Phenol,p-[(trifluoromethyl)thio]- (7CI,8CI);4-Trifluoromethylmercaptophenol;4-Trifluoromethylsulfanylphenol;p-[(Trifluoromethyl)thio]phenol;
  • PSA 45.53000
  • LogP 3.00410

Synthetic route

Bromotrifluoromethane
75-63-8

Bromotrifluoromethane

bis(4-hydroxyphenyl)disulfide
15015-57-3

bis(4-hydroxyphenyl)disulfide

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
With disodium hydrogenphosphate; rongalite In water; N,N-dimethyl-formamide at 20℃; under 9000.9 Torr; for 2.5h;86%
N,4-dimethyl-N-[(trifluoromethyl)-sulfanyl]benzene-1-sulfonamide

N,4-dimethyl-N-[(trifluoromethyl)-sulfanyl]benzene-1-sulfonamide

phenol
108-95-2

phenol

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
Stage #1: N,4-dimethyl-N-[(trifluoromethyl)-sulfanyl]benzene-1-sulfonamide; phenol In 1,2-dichloro-ethane at 20℃; for 0.0166667h; Sealed tube;
Stage #2: With trifluorormethanesulfonic acid In 1,2-dichloro-ethane at 80℃; for 18h; Sealed tube;		82%
With trifluorormethanesulfonic acid In 1,2-dichloro-ethane at 80℃; for 18h; Sealed tube;82%
2-((trifluoromethyl)thio)benzo[d]isothiazol-3(2H)-one 1,1-dioxide

2-((trifluoromethyl)thio)benzo[d]isothiazol-3(2H)-one 1,1-dioxide

phenol
108-95-2

phenol

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
With trifluorormethanesulfonic acid; bis(4-methoxyphenyl)selenide In chloroform at 20℃; for 0.5h; Reagent/catalyst;81%
With trifluorormethanesulfonic acid In dichloromethane at 60℃; for 8h; Schlenk technique;75%
With methanesulfonic acid In dichloromethane at 60℃; for 8h; Reagent/catalyst; Solvent; Temperature; Green chemistry;75%
N-[(trifluoromethyl)sulfanyl]aniline
1045821-71-3

N-[(trifluoromethyl)sulfanyl]aniline

phenol
108-95-2

phenol

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In dichloromethane at 20℃; Reagent/catalyst; regioselective reaction;77%
thioorthocarbonotrifluoridic acid 4-amino-phenyl ester
372-16-7

thioorthocarbonotrifluoridic acid 4-amino-phenyl ester

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
With uranyl acetate monohydrate; water; trifluoroacetic acid for 60h; Irradiation; Inert atmosphere;73%
4-sulfanylphenol
637-89-8

4-sulfanylphenol

Langlois reagent
2926-29-6

Langlois reagent

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
With dipotassium peroxodisulfate; silver nitrate In water; acetonitrile at 80℃; for 24h; Inert atmosphere;72%
With tetrabutylammonium tetrafluoroborate; sodium bromide In acetonitrile at 20℃; for 10h; Electrolysis; Inert atmosphere;16%
1-methyl-4-{[(trifluoromethyl)sulfanyl]sulfonyl}benzene
15223-20-8

1-methyl-4-{[(trifluoromethyl)sulfanyl]sulfonyl}benzene

4-amino-phenol
123-30-8

4-amino-phenol

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
Stage #1: 4-amino-phenol With tetrafluoroboric acid In water
Stage #2: With sodium nitrite In water at 0 - 25℃; for 0.5h;
Stage #3: 1-methyl-4-{[(trifluoromethyl)sulfanyl]sulfonyl}benzene With dichlorotris( 1,10-phenanthroline)ruthenium(II) hydrate In dimethyl sulfoxide at 25℃; for 16h; Irradiation; Inert atmosphere;		53%
(4-(allyloxy)phenyl)(trifluoromethyl)sulfane
653578-27-9

(4-(allyloxy)phenyl)(trifluoromethyl)sulfane

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
Stage #1: (4-(allyloxy)phenyl)(trifluoromethyl)sulfane With C12H37NiP4(1+)*C2F6NO4S2(1-) In tetrahydrofuran at 20℃; for 0.5h; Glovebox; Schlenk technique; Inert atmosphere;
Stage #2: With toluene-4-sulfonic acid In tetrahydrofuran for 15h; Glovebox; Schlenk technique; Reflux; Inert atmosphere;		34%
4-thiocyanato-phenol
3774-52-5

4-thiocyanato-phenol

potassium trifluoroacetate
2923-16-2

potassium trifluoroacetate

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
With iron(II) chloride In N,N-dimethyl-formamide at 140℃; for 16h; Inert atmosphere;29%
iodotrifluoromethane
2314-97-8

iodotrifluoromethane

4-sulfanylphenol
637-89-8

4-sulfanylphenol

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
In ammonia Irradiation;
With tris(2,2'-bipyridyl)ruthenium dichloride; triethylamine In acetonitrile at 20℃; for 1h; Time; Irradiation;
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

phenol
108-95-2

phenol

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
With pyridine
With pyridine In chloroform
With pyridine
diazotized 4-trifluoromethylsulfanyl-aniline

diazotized 4-trifluoromethylsulfanyl-aniline

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
With water
phenol
108-95-2

phenol

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aluminum (III) chloride / acetonitrile / 12 h / 25 °C / Inert atmosphere
2: caesium carbonate / acetonitrile / 12 h / 20 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: aluminum (III) chloride / acetonitrile / 60 °C / Inert atmosphere
2: iron(II) chloride / N,N-dimethyl-formamide / 16 h / 140 °C / Inert atmosphere
View Scheme
4-thiocyanato-phenol
3774-52-5

4-thiocyanato-phenol

(trifluoromethyl)trimethylsilane
81290-20-2

(trifluoromethyl)trimethylsilane

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
With caesium carbonate In acetonitrile at 20℃; for 12h; Inert atmosphere;163 mg
(2,2'-bipyride-kN1,kN1')(1,1,1-trifluoromethanethiolato-kS)-copper
1413732-47-4

(2,2'-bipyride-kN1,kN1')(1,1,1-trifluoromethanethiolato-kS)-copper

(p-hydroxyphenyl)boronic acid
71597-85-8

(p-hydroxyphenyl)boronic acid

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
With oxygen In 1-methyl-pyrrolidin-2-one at 20℃; for 1h;92 %Spectr.
C11H12F3O3S(1+)

C11H12F3O3S(1+)

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Conditions
ConditionsYield
With diethylamine In acetonitrile Inert atmosphere;14.8 mg
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

1-(tert-butoxycarbonyl)piperidin-4-yl methanesulfonate
141699-59-4

1-(tert-butoxycarbonyl)piperidin-4-yl methanesulfonate

4-(4-trifluoromethylsulfanyl-phenoxy)-piperidine-1-carboxylic Acid tert-butyl Ester
474711-20-1

4-(4-trifluoromethylsulfanyl-phenoxy)-piperidine-1-carboxylic Acid tert-butyl Ester

Conditions
ConditionsYield
With sodium hydroxide In diethyl ether; diethylene glycol dimethyl ether; ethyl acetate100%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

1-chloro-2-methyl-4-nitrobenzene
13290-74-9

1-chloro-2-methyl-4-nitrobenzene

3-methyl-4-(4-((trifluoromethyl)thio)phenyl)oxy-1-nitrobenzene

3-methyl-4-(4-((trifluoromethyl)thio)phenyl)oxy-1-nitrobenzene

Conditions
ConditionsYield
With potassium carbonate; dimethyl sulfoxide In toluene at 125 - 135℃; for 4h; Temperature; Large scale;98.1%
With potassium carbonate In dimethyl sulfoxide; toluene at 125 - 135℃; for 4h; Temperature; Large scale;97.1%
Stage #1: (4-trifluoromethylthio)phenol With potassium carbonate In dimethyl sulfoxide at 70℃; for 20h; Inert atmosphere;
Stage #2: 1-chloro-2-methyl-4-nitrobenzene In dimethyl sulfoxide at 70℃; for 18h; Inert atmosphere;		60%
With potassium carbonate In dimethyl sulfoxide at 90 - 130℃; for 5h;155.9 g
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

methyl iodide
74-88-4

methyl iodide

4-methoxyphenyl trifluoromethylsulfide
78914-94-0

4-methoxyphenyl trifluoromethylsulfide

Conditions
ConditionsYield
With [bmim]BF4; potassium carbonate In water at 20℃; for 0.166667h;98%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

2,6-dichloro-5-hydroxyphenyl trifluoromethylsulfide

2,6-dichloro-5-hydroxyphenyl trifluoromethylsulfide

Conditions
ConditionsYield
With [bmim]BF4; trichloroisocyanuric acid; water at 20℃; for 0.0833333h;96%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

2-chloro-4-(trifluoromethylsulfanyl)phenol
70783-74-3

2-chloro-4-(trifluoromethylsulfanyl)phenol

Conditions
ConditionsYield
With diisobutylamine; sulfuryl dichloride In toluene at 25℃; for 2h;95%
With diisobutylamine; sulfuryl dichloride In toluene at 20℃; for 1h;78%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

(4-(4-bromobenzyloxy)phenyl)(trifluoromethyl)sulfane

(4-(4-bromobenzyloxy)phenyl)(trifluoromethyl)sulfane

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 80℃;95%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

2,6-dibromo-4-(trifluoromethylthio)phenol
457-25-0

2,6-dibromo-4-(trifluoromethylthio)phenol

Conditions
ConditionsYield
With N-Bromosuccinimide; 1-butyl-3-methylimidazolium Tetrafluoroborate at 20℃; for 0.333333h;94%
With bromine; acetic acid
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

1-(6-bromopyridin-3-yl)propan-1-one
1194020-10-4

1-(6-bromopyridin-3-yl)propan-1-one

1-(6-(4-((trifluoromethyl)thio)phenoxy)pyridin-3yl)propan-1-one

1-(6-(4-((trifluoromethyl)thio)phenoxy)pyridin-3yl)propan-1-one

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 130℃; for 5h; Inert atmosphere;92%
With potassium carbonate In N,N-dimethyl-formamide at 130℃; for 5h; Inert atmosphere;92%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

2,6-diiodo-4-(trifluoromethylthio)phenol

2,6-diiodo-4-(trifluoromethylthio)phenol

Conditions
ConditionsYield
With N-iodo-succinimide; 1-butyl-3-methylimidazolium Tetrafluoroborate at 20℃; for 0.333333h;90%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

1-(4-(bromomethyl)phenyl)propan-1-one
95889-09-1

1-(4-(bromomethyl)phenyl)propan-1-one

1-(4-((4-((trifluoromethyl)thio)phenoxy)methyl)phenyl)propan-1-one

1-(4-((4-((trifluoromethyl)thio)phenoxy)methyl)phenyl)propan-1-one

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 3h; Inert atmosphere;90%
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 10h;
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

4-chlorobenzonitrile
100-00-5

4-chlorobenzonitrile

4-(4-nitrophenoxy)-(trifluoromethylthio)benzene
1244974-58-0

4-(4-nitrophenoxy)-(trifluoromethylthio)benzene

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 195℃; for 0.166667h; Microwave irradiation;87%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

4-Hydroxyphenyltrifluoromethylsulphone
432-84-8

4-Hydroxyphenyltrifluoromethylsulphone

Conditions
ConditionsYield
With ruthenium trichloride; sodium periodate In water; 1,2-dichloro-ethane; acetonitrile at 20℃; for 22h; Cooling with ice;85%
With sodium tungstate (VI) dihydrate; dihydrogen peroxide at 70 - 80℃; for 7.5h;10.81 g
With 2-Ethylhexanoic acid; sulfuric acid; dihydrogen peroxide at 10 - 70℃; for 8.5h; Reagent/catalyst; Temperature;19.1 g
With sodium tungstate (VI) dihydrate; dihydrogen peroxide In water at 75℃; for 37h; Reagent/catalyst;45.1 g
Stage #1: (4-trifluoromethylthio)phenol With sodium tungstate (VI) dihydrate; dihydrogen peroxide; acetic acid at 65℃;
Stage #2: With sodium disulfite; water; sodium hydroxide pH=8;
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

3-nitrobenzene-1,2-dicarbonitrile
51762-67-5

3-nitrobenzene-1,2-dicarbonitrile

3-(4-(trifluoromethylthio)phenoxy)phthalonitrile

3-(4-(trifluoromethylthio)phenoxy)phthalonitrile

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 40℃; for 72h; Inert atmosphere;85%
With potassium carbonate In N,N-dimethyl-formamide at 40℃; for 72h; Inert atmosphere;
1-oxyl-4-carboxyl-2,2,6,6-tetramethylpiperidine
37149-18-1

1-oxyl-4-carboxyl-2,2,6,6-tetramethylpiperidine

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

C17H21F3NO3S

C17H21F3NO3S

Conditions
ConditionsYield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In 2-methyltetrahydrofuran at 0 - 20℃; Steglich Esterification; Inert atmosphere;84%
N-methoxyethylpiperidine-4-fluorophenylsulfone ethyl ester
226396-34-5

N-methoxyethylpiperidine-4-fluorophenylsulfone ethyl ester

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

C24H28F3NO6S2
226400-93-7

C24H28F3NO6S2

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 90℃; for 24h;81%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

1-(4-iodo-3-methylphenyl)-3-methyl-1,3,5-triazine-2,4,6-trione

1-(4-iodo-3-methylphenyl)-3-methyl-1,3,5-triazine-2,4,6-trione

toltrazuril
69004-03-1

toltrazuril

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; N-(2-phenylphenyl)-N′-benzyl oxalamide In acetonitrile at 90℃; for 24h; Inert atmosphere;80.6%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

tert-butyl 4-(4-((methylsulfonyloxy)methyl)cyclohexyl)piperazine-1-carboxylate
1403676-88-9

tert-butyl 4-(4-((methylsulfonyloxy)methyl)cyclohexyl)piperazine-1-carboxylate

tert-butyl 4-((1r,4r)-4-((4-(trifluoromethylthio)phenoxy)methyl)cyclohexyl)piperazine-1-carboxylate

tert-butyl 4-((1r,4r)-4-((4-(trifluoromethylthio)phenoxy)methyl)cyclohexyl)piperazine-1-carboxylate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 90℃;79%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

benzoyl chloride
98-88-4

benzoyl chloride

4-((trifluoromethyl)thio)phenyl benzoate

4-((trifluoromethyl)thio)phenyl benzoate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 23℃; for 16h; Inert atmosphere;73%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

allyl bromide
106-95-6

allyl bromide

(4-(allyloxy)phenyl)(trifluoromethyl)sulfane
653578-27-9

(4-(allyloxy)phenyl)(trifluoromethyl)sulfane

Conditions
ConditionsYield
With potassium carbonate In acetone Reflux;70%
With caesium carbonate In N,N-dimethyl-formamide at 50℃; for 2h;
4'-Bromopropiophenone
10342-83-3

4'-Bromopropiophenone

(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

1-(4-(4-((trifluoromethyl)thio)phenoxy)phenyl)propan-1-one

1-(4-(4-((trifluoromethyl)thio)phenoxy)phenyl)propan-1-one

Conditions
ConditionsYield
With 2-Picolinic acid; potassium phosphate; copper(l) iodide In dimethyl sulfoxide at 110℃; for 10h; Inert atmosphere;67%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

Diphenyliodonium triflate
66003-76-7

Diphenyliodonium triflate

1-phenoxy-4-[(trifluoromethyl)sulfanyl]benzene
1333415-80-7

1-phenoxy-4-[(trifluoromethyl)sulfanyl]benzene

Conditions
ConditionsYield
Stage #1: (4-trifluoromethylthio)phenol With potassium tert-butylate In tetrahydrofuran at 0℃; for 0.25h; Inert atmosphere;
Stage #2: Diphenyliodonium triflate In tetrahydrofuran at 40℃; for 3h; Inert atmosphere;		64%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

para-bromoacetophenone
99-90-1

para-bromoacetophenone

1-(4-(4-((trifluoromethyl)thio)phenoxy)phenyl)ethanone

1-(4-(4-((trifluoromethyl)thio)phenoxy)phenyl)ethanone

Conditions
ConditionsYield
With 2-Picolinic acid; potassium phosphate; copper(l) iodide In dimethyl sulfoxide at 110℃; for 10h; Inert atmosphere;64%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

2,5-bis-methanesulfonyl-pyridine
85330-63-8

2,5-bis-methanesulfonyl-pyridine

5-(methylsulfonyl)-2-(4-((trifluoromethyl)thio)phenoxy)pyridine

5-(methylsulfonyl)-2-(4-((trifluoromethyl)thio)phenoxy)pyridine

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran; water; dimethyl sulfoxide60%
With potassium tert-butylate In tetrahydrofuran; water; dimethyl sulfoxide60%
(4-trifluoromethylthio)phenol
461-84-7

(4-trifluoromethylthio)phenol

acetic anhydride
108-24-7

acetic anhydride

4-((trifluoromethyl)thio)phenyl acetate

4-((trifluoromethyl)thio)phenyl acetate

Conditions
ConditionsYield
With pyridine In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere;60%

4-(Trifluoromethylthio)phenol Chemical Properties


IUPAC Name: 4-(Trifluoromethylsulfanyl)phenol
Canonical SMILES: C1=CC(=CC=C1O)SC(F)(F)F
InChI: InChI=1S/C7H5F3OS/c8-7(9,10)12-6-3-1-5(11)2-4-6/h1-4,11H
InChIKey: YYCPTWHVKSATQK-UHFFFAOYSA-N
Molecular Weight: 194.17421 [g/mol]
Molecular Formula: C7H5F3OS
XLogP3-AA: 3.3
H-Bond Donor: 1
H-Bond Acceptor: 4 
Product Categories: Aromatic Phenols; Organic Building Blocks; Sulfides / Disulfides; Sulfur Compounds 
Sensitive: Stench 
Index of Refraction: 1.529
Molar Refractivity: 41.28 cm3
Molar Volume: 133.8 cm3
Surface Tension: 39.2 dyne/cm
Density: 1.45 g/cm3
Flash Point: 56.9 °C
Enthalpy of Vaporization: 42.36 kJ/mol
Boiling Point: 170.4 °C at 760 mmHg
Vapour Pressure: 1.11 mmHg at 25 °C
Appearance: Colorless or primrose yellow crystal
Melting Point of Phenol,4-[(trifluoromethyl)thio]- (CAS NO.461-84-7): 57-60 °C(lit.)

4-(Trifluoromethylthio)phenol Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing.
WGK Germany: 3
HazardClass: IRRITANT, STENCH

4-(Trifluoromethylthio)phenol Specification

  Phenol,4-[(trifluoromethyl)thio]- (CAS NO.461-84-7), its Synonyms are 4-Trifluoromethylmercaptophenol ; 4-Trifluoromethylsulfanylphenol ; 4-(Trifluoromethylthio)phenol .

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