Product Name

  • Name

    BENZO(J)FLUORANTHENE

  • EINECS
  • CAS No. 205-82-3
  • Article Data41
  • CAS DataBase
  • Density 1.286g/cm3
  • Solubility 2.5ug/L(temperature not stated)
  • Melting Point 166°C
  • Formula C20H12
  • Boiling Point 467.5°Cat760mmHg
  • Molecular Weight 252.315
  • Flash Point 228.6°C
  • Transport Information
  • Appearance
  • Safety Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.
  • Risk Codes 45-50/53-63-43-36/37/38-23/24/25
  • Molecular Structure Molecular Structure of 205-82-3 (BENZO(J)FLUORANTHENE)
  • Hazard Symbols
  • Synonyms 10,11-Benzofluoranthene;7,8-Benzfluoranthene; Benzo-12,13-fluoranthene; Dibenzo[a,jk]fluorene
  • PSA 0.00000
  • LogP 5.64040

Synthetic route

8-hydroxy-1-(1-naphtyl)naphthalene triflate
146746-41-0

8-hydroxy-1-(1-naphtyl)naphthalene triflate

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride; bis(triphenylphosphine)palladium(II)-chloride In N,N-dimethyl-formamide at 140℃; for 10h;93%
(+/-)-1,2,3,6b,7,8-hexahydrobenzofluoranthene
18522-48-0

(+/-)-1,2,3,6b,7,8-hexahydrobenzofluoranthene

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
palladium on activated charcoal In various solvent(s) for 5h; Heating;92%
(+/-)-cis,syn-4,5,6,6a,6b,7,8,12b,octahydrobenzofluoranthene
74983-82-7

(+/-)-cis,syn-4,5,6,6a,6b,7,8,12b,octahydrobenzofluoranthene

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
palladium on activated charcoal for 84h; Heating;92%
2-(2-formylphenyl)acenaphthylene-1-carbaldehyde

2-(2-formylphenyl)acenaphthylene-1-carbaldehyde

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With tetrahydrofuran; pyridine; titanium tetrachloride; zinc for 4h; McMurry Reaction; Reflux;83%
7-(methylthio)benzo[j]fluoranthene

7-(methylthio)benzo[j]fluoranthene

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
Raney Ni (W2) In ethanol for 7h; Heating;57%
azuleno<1,2-a>acenaphthylene
33084-86-5

azuleno<1,2-a>acenaphthylene

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
In benzene at 600℃;A 14%
B 28%
[1,2′-binaphthalen]-8-yl nonafluorobutanesulfonate

[1,2′-binaphthalen]-8-yl nonafluorobutanesulfonate

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); 1-Adamantanecarboxylic acid In N,N-dimethyl acetamide at 110℃; for 24h; Inert atmosphere;A 26%
B 8%
tetrachloromethane
56-23-5

tetrachloromethane

N-Bromosuccinimide
128-08-5

N-Bromosuccinimide

4,5,6,6a,6b,7,8,12b-octahydro-benzo[j]fluoranthene
19390-93-3, 23672-05-1, 23756-78-7, 74983-82-7

4,5,6,6a,6b,7,8,12b-octahydro-benzo[j]fluoranthene

dibenzoyl peroxide
94-36-0

dibenzoyl peroxide

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

N-Bromosuccinimide
128-08-5

N-Bromosuccinimide

1,2,3,6b,7,8,12b,12c-octahydro-benzo[j]fluoranthene
18511-30-3

1,2,3,6b,7,8,12b,12c-octahydro-benzo[j]fluoranthene

dibenzoyl peroxide
94-36-0

dibenzoyl peroxide

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

benzo[j]fluoranthen-1-ol
62393-33-3

benzo[j]fluoranthen-1-ol

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With hydrogen; zinc
1,2,3,6b,7,8,12b,12c-octahydro-benzo[j]fluoranthene
18511-30-3

1,2,3,6b,7,8,12b,12c-octahydro-benzo[j]fluoranthene

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With selenium at 320 - 340℃;
With N-Bromosuccinimide; dibenzoyl peroxide zuletzt Kochen unter Zusatz von Natriumacetat und Eisessig, und Behandeln des Reaktionsprodukts mit siedender aethanol. Natriumaethylat-Loesung;
6b,7,8,12b-tetrahydro-benzo[j]fluoranthene
61322-64-3

6b,7,8,12b-tetrahydro-benzo[j]fluoranthene

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With palladium on activated charcoal at 330℃;
4,5,6,6a,6b,7,8,12b-octahydro-benzo[j]fluoranthene
19390-93-3, 23672-05-1, 23756-78-7, 74983-82-7

4,5,6,6a,6b,7,8,12b-octahydro-benzo[j]fluoranthene

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With N-Bromosuccinimide; dibenzoyl peroxide zuletzt Kochen unter Zusatz von Natriumacetat und Eisessig, und Behandeln des Reaktionsprodukts mit siedender aethanol. Natriumaethylat-Loesung;
With selenium at 320 - 340℃;
benzo[j]fluoranthene-4,5-dicarboxylic acid-anhydride
412037-51-5

benzo[j]fluoranthene-4,5-dicarboxylic acid-anhydride

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With calcium oxide
3,4-dihydronaphthalene-1(2H)-one
529-34-0

3,4-dihydronaphthalene-1(2H)-one

1-naphthylmagnesiumbromide
703-55-9

1-naphthylmagnesiumbromide

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With diethyl ether Erhitzen des erhaltenen Reaktionsprodukts mit P2O5 und anschliessend mit Palladium/Kohle;
1-(naphthalen-2-yl)naphthalene
4325-74-0

1-(naphthalen-2-yl)naphthalene

A

naphthalene
91-20-3

naphthalene

B

2,2'-binaphthalene
612-78-2

2,2'-binaphthalene

C

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With 9H-fluorene; [1,1';4',1'']terphenyl at 440℃; Product distribution; Rate constant; other biaryl hydrocarbons as H-donor;
3,3',4,4'-tetrahydro-1,1'-binaphthalene
5405-96-9

3,3',4,4'-tetrahydro-1,1'-binaphthalene

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With sulfur; palladium on activated charcoal at 300 - 310℃;
1,2,3,6b,7,8,12b,12c-Octahydrobenzofluoranthen

1,2,3,6b,7,8,12b,12c-Octahydrobenzofluoranthen

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With sulfur at 230℃;
2-(1-chloroethenyl)benzo[c]phenanthrene
190385-64-9

2-(1-chloroethenyl)benzo[c]phenanthrene

A

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

B

benzo[l]acephenanthrylene
95690-49-6

benzo[l]acephenanthrylene

Conditions
ConditionsYield
at 1100℃; under 0.01 Torr;
at 900℃; under 0.01 Torr;
6-(1-chloroethenyl)chrysene
190385-66-1

6-(1-chloroethenyl)chrysene

A

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

B

benzacephenanthrylene
216-48-8

benzacephenanthrylene

Conditions
ConditionsYield
at 1100℃; under 0.01 Torr;
at 1000℃; under 0.01 Torr;
Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

A

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

B

Benzacephenanthrylene
212-41-9

Benzacephenanthrylene

Conditions
ConditionsYield
at 1200℃; under 0.01 Torr; flash vacuum thermolysis;A 11 % Chromat.
B 5 % Chromat.
polystyrene

polystyrene

A

1,1'-bisnaphthalene
604-53-5

1,1'-bisnaphthalene

B

1-(naphthalen-2-yl)naphthalene
4325-74-0

1-(naphthalen-2-yl)naphthalene

C

2,2'-binaphthalene
612-78-2

2,2'-binaphthalene

D

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With air at 900℃; Condensation; combustion; pyrolysis; PAH formation; Formation of xenobiotics; Further byproducts given. Title compound not separated from byproducts;A 0.294 mg
B 0.395 mg
C 0.316 mg
D 1.289 mg
tetrachloromethane
56-23-5

tetrachloromethane

1,2-Dihydronaphthalene
447-53-0

1,2-Dihydronaphthalene

sulfuric acid
7664-93-9

sulfuric acid

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
Destillation ueber PbO;
tetralin
119-64-2

tetralin

1,2-Dihydronaphthalene
447-53-0

1,2-Dihydronaphthalene

sulfuric acid
7664-93-9

sulfuric acid

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
Destillation ueber PbO;
1,2-Dihydronaphthalene
447-53-0

1,2-Dihydronaphthalene

sulfuric acid
7664-93-9

sulfuric acid

benzene
71-43-2

benzene

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
Destillation ueber PbO;
binaphthyl-(1.2')

binaphthyl-(1.2')

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With chromium corundum at 500℃;
1-(naphthalen-2-yl)naphthalene
4325-74-0

1-(naphthalen-2-yl)naphthalene

chromium oxide-aluminium oxide

chromium oxide-aluminium oxide

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
at 500℃;
4,5,6,6a,6b,7,8,12b-octahydro-(6ar,6bc,12bc)-benzo<j>fluoranthene

4,5,6,6a,6b,7,8,12b-octahydro-(6ar,6bc,12bc)-benzo<j>fluoranthene

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With palladium on activated charcoal
4,5,6,6a,6b,7,8,12b-octahydro-(6ar,6bt,12bt)-benzo<j>fluoranthene

4,5,6,6a,6b,7,8,12b-octahydro-(6ar,6bt,12bt)-benzo<j>fluoranthene

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With chloranil; xylene
Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

(+/-)-cis,syn-4,5,6,6a,6b,7,8,12b,octahydrobenzofluoranthene
74983-82-7

(+/-)-cis,syn-4,5,6,6a,6b,7,8,12b,octahydrobenzofluoranthene

Conditions
ConditionsYield
With sodium; isopropyl alcohol
Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

PERYLENE
198-55-0

PERYLENE

C

cyclopenta[c,d]pyrene
27208-37-3

cyclopenta[c,d]pyrene

D

benzo[ghi]fluoranthene
203-12-3

benzo[ghi]fluoranthene

Conditions
ConditionsYield
at 1200℃; under 0.01 Torr; flash vacuum thermolysis; Further byproducts given;A 15 % Chromat.
B 7 % Chromat.
C 7 % Chromat.
D 4 % Chromat.
Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

PERYLENE
198-55-0

PERYLENE

C

cyclopenta[c,d]pyrene
27208-37-3

cyclopenta[c,d]pyrene

D

cyclopentacepyrylene
98791-43-6

cyclopentacepyrylene

Conditions
ConditionsYield
at 1200℃; under 0.01 Torr; flash vacuum thermolysis; Further byproducts given;A 15 % Chromat.
B 7 % Chromat.
C 7 % Chromat.
D 6 % Chromat.
at 1200℃; under 0.01 Torr; flash vacuum thermolysis; Further byproducts given;A 15 % Chromat.
B 13 % Chromat.
C 7 % Chromat.
D 6 % Chromat.
Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

PERYLENE
198-55-0

PERYLENE

C

benzo[ghi]fluoranthene
203-12-3

benzo[ghi]fluoranthene

D

benzacephenanthrylene
216-48-8

benzacephenanthrylene

Conditions
ConditionsYield
at 1200℃; under 0.01 Torr; flash vacuum thermolysis; Further byproducts given;A 15 % Chromat.
B 7 % Chromat.
C 4 % Chromat.
D 4 % Chromat.
Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

PERYLENE
198-55-0

PERYLENE

C

benzacephenanthrylene
216-48-8

benzacephenanthrylene

D

cyclopentacepyrylene
98791-43-6

cyclopentacepyrylene

Conditions
ConditionsYield
at 1200℃; under 0.01 Torr; flash vacuum thermolysis; Further byproducts given;A 15 % Chromat.
B 7 % Chromat.
C 4 % Chromat.
D 6 % Chromat.

Benzo(j)fluoranthene Chemical Properties

 Benzo(j)fluoranthene with CAS number of 205-82-3 is called for 10,11-Benzfluoranthene ; 10,11-benzofluoranthene ; 7,8-Benzofluoranthene ; B(j)F ; Benz(j)fluoranthene ; Benzo(l)fluoranthene ; Benzo[l]fluoranthene ; Dibenzo(a,jk)fluorene ,and so on. Benzo(j)fluoranthene is usually yellow crystals.
CAS: 205-82-3
Molecular Formula: C20H12
Molecular Weight: 252.31
Molecular structure:
EINECS: 205-910-3
Storage temp.:  2-8°C
ACD/LogD (pH 5.5): 6.4 
ACD/LogD (pH 7.4): 6.4 
ACD/BCF (pH 5.5): 43177 
ACD/BCF (pH 7.4): 43177 
ACD/KOC (pH 5.5): 72359.67 
ACD/KOC (pH 7.4): 72359.67 
H bond acceptors: 0 
H bond donors: 0 
Freely Rotating Bonds: 0 
Index of Refraction: 1.887 
Molar Refractivity: 90.3 cm3 
Molar Volume: 196 cm3 
Polarizability: 35.8×10-24cm3 
Surface Tension: 63.4 dyne/cm 
Density: 1.286 g/cm3 
Flash Point: 228.6 °C 
Enthalpy of Vaporization: 70.16 kJ/mol 
Boiling Point: 467.5 °C at 760 mmHg 
Vapour Pressure: 1.81E-08 mmHg at 25°C

Benzo(j)fluoranthene Uses

 Benzo(j)fluoranthene (CAS No.205-82-3) is supposed to be used as chemical reagent.

Benzo(j)fluoranthene Toxicity Data With Reference

1.    

mma-sat 10 µg/plate

    CNREA8    Cancer Research. 40 (1980),4258.
2.    

dnd-mus-skn 3760 nmol/kg

    PAACA3    Proceedings of the American Association for Cancer Research. 25 (1984),121.

Benzo(j)fluoranthene Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Limited Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 3 (1973),p. 82.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 32 (1983),p. 155.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) .

Benzo(j)fluoranthene Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.

Hazard Codes:  T,N  
Risk Statements:  45-50/53-63-43-36/37/38-23/24/25 (R45:May cause cancer. R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R63:Possible risk of harm to the unborn child. R43:May cause sensitization by skin contact. R36/37/38:Irritating to eyes, respiratory system and skin. R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.)
Safety Statements:  45-53-61-60-36/37-24/25-23 (S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S53:Avoid exposure - obtain special instructions before use. S61:Avoid release to the environment. Refer to special instructions / safety data sheets. S60:This material and its container must be disposed of as hazardous waste. S36/37:Wear suitable protective clothing and gloves. S24/25:Avoid contact with skin and eyes. S23:Do not breathe vapour.)
RIDADR:  3077
HazardClass:  6.1(b)
PackingGroup:  III

Benzo(j)fluoranthene Specification

Removal in wastewater treatment of Benzo(j)fluoranthene (CAS No.205-82-3) can be stated as follows:
Total removal:90.94  percent
Total biodegradation:0.76  percent
Total sludge adsorption:90.18  percent
Total to Air:0.00  percent
(using 10000 hr Bio P,A,S)

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