Conditions | Yield |
---|---|
With sulfolane; sodium fluoride at 150℃; Reagent/catalyst; Large scale; | 97% |
With tetrabutyl ammonium fluoride In dimethyl sulfoxide at 60℃; for 6h; Temperature; Solvent; | 95% |
With 1-methyl-pyrrolidin-2-one; hydrogen fluoride; triethylamine at 20 - 25℃; for 0.5h; | 90% |
1,3,5-trichloro-2,4,6-triazine
antimony(III) fluoride
trifluoro-[1,3,5]triazine
Conditions | Yield |
---|---|
With antimony(III) chloride; chlorine 160-180°C, 10 mol SbF3, 1 mol SbCl3, 3 mol Cl2; | 91% |
With antimony(III) chloride; chlorine 160-180°C, 10 mol SbF3, 1 mol SbCl3, 3 mol Cl2; | 91% |
With chlorine at 100°C, exclusion of H2O; destillation; | 71.4% |
4-N,N-dichloroamino-2,3,5,6-tetrafluoropyridine
A
trifluoro-[1,3,5]triazine
B
4-chloro-2,3,5,6-tetrafluoropyridine
C
Pentafluoropyridine
D
trichlorofluoromethane
E
2-chloro-3,3-difluoro-acrylonitrile
F
tetrafluoropyrazine
Conditions | Yield |
---|---|
at 550℃; under 2 Torr; Mechanism; vacuum pyrolysis, other fluoropyridine compounds; | A n/a B 75% C n/a D n/a E n/a F n/a |
1,2,3-trifluoro-4,5,6-triazine
perfluoro-4,6-di-isopropyl-1,2,3-triazine
A
trifluoro-[1,3,5]triazine
B
perfluoro-2,4-di-isopropylpyridine
C
perfluoro-2,4,6,8-tetraisopropyl-1,5-diazatricyclo<4.2.0.02,5>octa-3,7-diene
Conditions | Yield |
---|---|
In 1,1,2-Trichloro-1,2,2-trifluoroethane for 24h; Irradiation; | A 0.01 g B 53% C 11% |
In 1,1,2-Trichloro-1,2,2-trifluoroethane for 24h; Irradiation; | A 0.01 g B 4% C 11 g |
In 1,1,2-Trichloro-1,2,2-trifluoroethane for 24h; Mechanism; Irradiation; | A 0.01 g B 0.17 g C 0.03 g |
1,3,5-trichloro-2,4,6-triazine
A
trifluoro-[1,3,5]triazine
B
2-chloro-4,6-difluoro-[1,3,5]triazine
C
2,4-dichloro-6-fluoro-[1,3,5]triazine
Conditions | Yield |
---|---|
With potassium fluoride at 300℃; for 2h; Product distribution; C3Cl3N3/KF = 16 x 10 E-2, other temperatures, other times, other molar ratios; | A n/a B n/a C 48% |
With cesium fluoride; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 80℃; |
1,3,5-trichloro-2,4,6-triazine
sulfur tetrafluoride
trifluoro-[1,3,5]triazine
Conditions | Yield |
---|---|
in 1:6 molar ratio, at 250°C, in autoclave; | 40% |
nitrogen trifluoride
cyanogen chloride
A
trifluoro-[1,3,5]triazine
B
cis-hexafluoroazomethane
C
Perfluoro-2-azapropen
Conditions | Yield |
---|---|
In not given at 500°C, in Ni-tube, in excess of NF3; | A 40% B 30% C 30% |
trifluoro-1,2,4-triazine
A
trifluoro-[1,3,5]triazine
B
Perfluoro-2-azapropen
Conditions | Yield |
---|---|
at 500℃; for 42h; | A 32% B 12% C n/a |
1,3,5-trichloro-2,4,6-triazine
A
trifluoro-[1,3,5]triazine
B
2-chloro-4,6-difluoro-[1,3,5]triazine
Conditions | Yield |
---|---|
With antimonypentachloride; antimony(III) fluoride | |
With antimonypentachloride; antimony(III) fluoride melting, heating, 1 h distn.; fractionated distn.; | |
With SbF3; SbCl5 melting, heating, 1 h distn.; fractionated distn.; |
1,3,5-trichloro-2,4,6-triazine
antimony(III) fluoride
antimony(III) chloride
chlorine
trifluoro-[1,3,5]triazine
1,3,5-trichloro-2,4,6-triazine
hydrogen fluoride
A
trifluoro-[1,3,5]triazine
B
2-chloro-4,6-difluoro-[1,3,5]triazine
C
2,4-dichloro-6-fluoro-[1,3,5]triazine
Conditions | Yield |
---|---|
auch unter Zusatz von Sb2O3 oder SbCl5; | |
With SbCl5 |
1,3,5-trichloro-2,4,6-triazine
A
trifluoro-[1,3,5]triazine
B
2-chloro-4,6-difluoro-[1,3,5]triazine
C
2,4-dichloro-6-fluoro-[1,3,5]triazine
Conditions | Yield |
---|---|
auch unter Zusatz von Sb2O3 oder SbCl5; | |
auch unter Zusatz von Sb2O3 oder SbCl5; |
1,3,5-trichloro-2,4,6-triazine
A
trifluoro-[1,3,5]triazine
B
2-chloro-4,6-difluoro-[1,3,5]triazine
C
2,4-dichloro-6-fluoro-[1,3,5]triazine
Conditions | Yield |
---|---|
auch unter Zusatz von Sb2O3 oder SbCl5; | |
auch unter Zusatz von Sb2O3 oder SbCl5; |
1,3,5-trichloro-2,4,6-triazine
A
trifluoro-[1,3,5]triazine
B
2-chloro-4,6-difluoro-[1,3,5]triazine
C
2,4-dichloro-6-fluoro-[1,3,5]triazine
Conditions | Yield |
---|---|
auch unter Zusatz von Sb2O3 oder SbCl5; | |
auch unter Zusatz von Sb2O3 oder SbCl5; |
Trifluoromethylsulfenyl chloride
1,3,5-Trichlor-2,2,4,4,6,6-hexafluor-1,3,5-triazinan
A
trifluoro-[1,3,5]triazine
B
Bis(trifluoromethyl)disulfid
C
trifluoromethanesulfinyl fluoride
Conditions | Yield |
---|---|
byproducts: Cl2; at 20°C (1 h); | |
byproducts: Cl2; at 20°C (1 h); |
cis-hexafluoroazomethane
A
trifluoro-[1,3,5]triazine
B
carbon tetrafluoride
C
N,N-Bis(trifluoromethyl)amine
D
Perfluoro-2-azapropen
E
tetrakis(trifluoromethyl)hydrazine
Conditions | Yield |
---|---|
heating in autoclave at 483°C; further product; | |
heating in autoclave at 483°C; further product; |
Conditions | Yield |
---|---|
at ambient temp. quick polimn.; | |
room temp., polymerisation; | |
at ambient temp. quick polimn.; |
2,2,2-trifluoro-1-oxoethanesulphenylchloride
1,3,5-Trichlor-2,2,4,4,6,6-hexafluor-1,3,5-triazinan
A
trifluoro-[1,3,5]triazine
B
2,2,2-trifluoro-1-oxoethanesulfenyl fluoride
Conditions | Yield |
---|---|
byproducts: Cl2; | |
byproducts: Cl2; |
1,3,5-trichloro-2,4,6-triazine
A
trifluoro-[1,3,5]triazine
B
2-chloro-4,6-difluoro-[1,3,5]triazine
C
2,4-dichloro-6-fluoro-[1,3,5]triazine
D
Hexafluormethandiamin
E
cycloperfluoro dimethylenediamine
Conditions | Yield |
---|---|
With fluorine 125°C, under N2; |
Conditions | Yield |
---|---|
other products, in N2, at 125°C; |
2-chloro-4,6-difluoro-[1,3,5]triazine
2,4-dichloro-6-fluoro-[1,3,5]triazine
1,3,5-trichloro-2,4,6-triazine
trifluoro-[1,3,5]triazine
Conditions | Yield |
---|---|
With Sb2O3; KHF2 In benzene | |
With KF | |
With KHF2 |
cyanuric bromide
trifluoro-[1,3,5]triazine
Conditions | Yield |
---|---|
With ZnF2 | |
With KF; Sb2O3 |
dichloromethylene-trifluoromethylmercaptoamine
A
trifluoro-[1,3,5]triazine
C
bis(trifluoromethylmercapto)-trifluoromethylamine
Conditions | Yield |
---|---|
byproducts: AgCl; 130°C; 21 h;; detected by IR and Mass spectr.; | |
byproducts: AgCl; 130°C; 21 h;; detected by IR and Mass spectr.; |
manganese(III) fluoride
cyanogen chloride
A
trifluoro-[1,3,5]triazine
B
carbon tetrafluoride
C
chlorotrifluoromethane
D
pentafluoro chloro azomethane
Conditions | Yield |
---|---|
byproducts: Cl2; at 160-190°C; |
nitrogen trifluoride
cyanogen chloride
A
trifluoro-[1,3,5]triazine
B
carbon tetrafluoride
C
cis-hexafluoroazomethane
D
trichlorofluoromethane
E
Perfluoro-2-azapropen
Conditions | Yield |
---|---|
With chlorine In not given at 450-500°C, in Ni-tube, in excess of NF3; |
Conditions | Yield |
---|---|
In not given ClCN/NF3 = 1:1; |
trifluoro-[1,3,5]triazine
tris(dimethylamino)sulfonium trimethylsilyldifluoride
Conditions | Yield |
---|---|
In acetonitrile at -196 - -40℃; for 0.75h; | 100% |
trifluoro-[1,3,5]triazine
(2R)-2-({formyl[(phenylmethyl)oxy]amino}methyl)hexanoic acid
(2R)-2-({formyl[(phenylmethyl)oxy]amino}methyl)hexanoyl fluoride
Conditions | Yield |
---|---|
With pyridine | 100% |
trifluoro-[1,3,5]triazine
6-chloro-2-(ethylamino)pyridine-3-carboxylic acid
6-chloro-2-(ethylamino)pyridine-3-carbonyl fluoride
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 3h; | 99% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide Inert atmosphere; | 98% |
trifluoro-[1,3,5]triazine
trifluoroethylamine
2-fluoro-4,6-bis<(2,2,2-trifluoroethyl)amino>-1,3,5-triazine
Conditions | Yield |
---|---|
97% |
trifluoro-[1,3,5]triazine
2-fluoro-4,6-bis<(2,2,2-trifluoroethyl)amino>-1,3,5-triazine
Conditions | Yield |
---|---|
97% |
trifluoro-[1,3,5]triazine
Conditions | Yield |
---|---|
With pyridine In dichloromethane | 96% |
trifluoro-[1,3,5]triazine
3-phenyl-4-(trifluoromethyl)isoxazole-5-carboxylic acid
3-phenyl-4-(trifluoromethyl)isoxazole-5-carbonyl fluoride
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 20℃; | 96% |
Conditions | Yield |
---|---|
In tetrahydrofuran hydrolysis at 0°C; | 94% |
In water hydrolysis at 0°C; | >99 |
trifluoro-[1,3,5]triazine
Propargylamine
N2,N4,N6-tri(prop-2-yn-1-yl)-1,3,5-triazine-2,4,6-triamine
Conditions | Yield |
---|---|
In toluene for 20h; Heating; | 93% |
In toluene Reflux; | 83% |
trifluoro-[1,3,5]triazine
trifluoroethylamine
2,4,6-tris<(2,2,2-trifluoroethyl)amino>-1,3,5-triazine
Conditions | Yield |
---|---|
With cesium fluoride In N,N-dimethyl-formamide at 40℃; for 72h; | 91% |
With cesium fluoride In N,N-dimethyl-formamide |
trifluoro-[1,3,5]triazine
N-tert-butoxycarbonyl-3-(2-naphthyl)-L-alanine
Conditions | Yield |
---|---|
With pyridine In dichloromethane at -15℃; for 1h; | 91% |
trifluoro-[1,3,5]triazine
2-[N-(tert-butoxycarbonyl)-N-(2,2,2-trifluoroethyl)aminomethyl]-4-methoxydihydrocinnamic acid
(R)-4-(phenylmethyl)-2-oxazolidinone
Conditions | Yield |
---|---|
With pyridine; n-butyllithium; ammonium chloride In tetrahydrofuran; dichloromethane | 91% |
trifluoro-[1,3,5]triazine
ferrocenylamidoundecanoic acid
ferrocenylamidoundecanoic acid fluoride
Conditions | Yield |
---|---|
With pyridine In dichloromethane (Ar, Schlenk technique); addn. of cyanuric fluoride to suspn. of ferrocene deriv. and pyridine in dry CH2Cl2, stirring for 2 h; addn. of ice cold water, filtration, separating organic layer, washing with cold water, drying over MgSO4, filtration, evapn., elem. anal.; | 91% |
polytetrafluoroethylene
trifluoro-[1,3,5]triazine
tris(perfluoroethyl)-s-triazine
Conditions | Yield |
---|---|
at 140℃; Large scale; | 91% |
trifluoro-[1,3,5]triazine
2-[N-(tert-butoxycarbonyl)-N-(4-trifluoromethylbenzyl)aminomethyl]-4-methoxydihydrocinnamic acid
(R)-4-(phenylmethyl)-2-oxazolidinone
Conditions | Yield |
---|---|
With pyridine; n-butyllithium; ammonium chloride In tetrahydrofuran; dichloromethane | 90% |
With pyridine; n-butyllithium; ammonium chloride In tetrahydrofuran; dichloromethane | 90% |
trifluoro-[1,3,5]triazine
K{Mn(CO)5}
Conditions | Yield |
---|---|
In not given -18°C; sublimed in vacuo (50°C/0.01 Torr), recrystd. from dry hexane; | 90% |
trifluoro-[1,3,5]triazine
perfluoropropylene
perfluoro-2,4,6-triisopropyl-s-triazine
Conditions | Yield |
---|---|
at 140℃; Reagent/catalyst; Temperature; Large scale; | 89% |
trifluoro-[1,3,5]triazine
glycine ethyl ester hydrochloride
2-[(4-[1-(tert-butoxycarbonyl)-4-piperidyl]-2-{2-[1-(tert-butoxycarbonyl)-4-piperidyl]ethyl}butanoyl)amino]acetic acid
Conditions | Yield |
---|---|
With pyridine; hydrogenchloride; lithium hydroxide monohydrate; N-ethyl-N,N-diisopropylamine In tetrahydrofuran; dichloromethane; water | 88% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide | 87% |
In N,N-dimethyl-formamide |
Conditions | Yield |
---|---|
With triethylamine In diethyl ether at 20℃; for 2.5h; | 87% |
trifluoro-[1,3,5]triazine
boron trifluoride diethyl etherate
2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene
2-(4,6-difluoro-1,3,5-triazin-2-yl)-1,3-diisopropyl-4,5-dimethylimidazolium tetrafluoroborate
Conditions | Yield |
---|---|
In diethyl ether (Ar); imidazolylidene deriv. added to Et2O soln. of cyanuric trifluorideat -70°C; stirred for 12 h at room temp.; BF3*OEt2 added dropwis e; stirred for 4 h at room temp.; ppt. isolated; washed with Et2O; vac. dried; recrystd. from MeCN/Et2O; elem. anal.; | 86% |
trifluoro-[1,3,5]triazine
(R)-4-(phenylmethyl)-2-oxazolidinone
Conditions | Yield |
---|---|
With pyridine; n-butyllithium In tetrahydrofuran; dichloromethane | 85% |
Conditions | Yield |
---|---|
With pyridine In acetonitrile | 85% |
trifluoro-[1,3,5]triazine
2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene
2-(4,6-difluoro-1,3,5-triazin-2-yl)-1,3-diisopropyl-4,5-dimethylimidazolium tetrafluoroborate
Conditions | Yield |
---|---|
Stage #1: trifluoro-[1,3,5]triazine; 2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene In diethyl ether at -70 - 20℃; Inert atmosphere; Stage #2: With boron trifluoride diethyl etherate at 20℃; Inert atmosphere; | 85% |
trifluoro-[1,3,5]triazine
(Sp)-2-formylferrocene-1-carboxylic acid
(Sp)-2-formylferrocenoyl fluoride
Conditions | Yield |
---|---|
With pyridine In dichloromethane pyridine (1.650 ml) and cyanuric fluoride (3.605 ml) added to CH2Cl2 soln. of Fc(CHO)CO2H (10 mmol) at 0°C under Ar, after few min cooling bath removed, mixt. stirred at room temp. for 90 min; crushed ice added, suspn. filtered, organic phase sepd., washed with cold H2O, dried over Na2SO4, filtered, solidified for few min, crystals collected, dried in vac. exicator over P2O5 overnight at room temp.; elem. anal.; | 85% |
trifluoro-[1,3,5]triazine
A
fluorocarbonyl ruthenocene
B
[Ru(η5-C5H5)(η5-C5H4CO)]2O
Conditions | Yield |
---|---|
With pyridine In dichloromethane under N2 or Ar; suspn. of Ru complex and pyridine in CH2Cl2 cooled to 0°C; N3C3F3 added; stirred at 0°C for 2 h; poured into ice-cold H2O; filtered; org. layer collected; concd. in vac.; purified by column chromy. (silica gel, ethyl acetate-hexane 1:5); elem. anal.; | A 82% B 2% |
Conditions | Yield |
---|---|
Stage #1: trifluoro-[1,3,5]triazine; sulfanilamide In acetone at 0℃; for 0.5h; Stage #2: With sodium hydroxide In water; acetone at 20℃; for 1.33333h; | 82% |
Chemical Name: Cyanuric fluoride
IUPAC NAME: 2,4,6-trifluoro-1,3,5-triazine
CAS No.: 675-14-9
EINECS: 211-620-8
RTECS: XZ1750000
Molecular Formula: C3F3N3
Molecular Weight: 135.05 g/mol
Hazard Note: Corrosive/Toxic
Density: 1.652 g/cm3
Melting Point: -38°C
Flash Point: 145 °C
Boiling Point: 316.1 °C at 760 mmHg
2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9) is a colourless, pungent liquid. it is moisture sensitive and incompatible with xoidizing agents.Following is the structure:
The chemical synonymous of 2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9) are 2,4,6-TRIFLUORO-1,3,5-TRIAZINE;CYANURIC FLUORIDE;1,3,5-triazine,2,4,6-trifluoro-;2,4,6-trifluoro-s-triazin;2,4,6-Trifluoro-s-triazine;2,4,6-Trifluorotriazine;2,4,6-trifluro-s-triazin;5-triazine,2,4,6-trifluoro-3.
2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9) is mainly used for preparation of reactive dyes and used in organic synthesis.It has been used as a precursor for fibre-reactive dyes, as a specific reagent for tyrosine residues in enzymes, and as a fluorinating agent.
Product Categories about 2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9) is mainly refer to Heterocycles.
rabbit | LD50 | skin | 160mg/kg (160mg/kg) | SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE LUNGS, THORAX, OR RESPIRATION: BRONCHIOLAR CONSTRICTION | American Industrial Hygiene Association Journal. Vol. 33, Pg. 382, 1972. |
rat | LC50 | inhalation | 3100ppb/4H (3.1ppm) | BEHAVIORAL: EXCITEMENT LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA LUNGS, THORAX, OR RESPIRATION: DYSPNEA | American Industrial Hygiene Association Journal. Vol. 33, Pg. 382, 1972. |
Poison by skin contact and inhalation. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits very toxic fumes of F− and NOx. See also FLUORIDES.
Hazard Codes:
T+: Very toxic
T: Toxic
C: Corrosive
Risk Statements about 2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9):
R24 Toxic in contact with skin.
R26 Very toxic by inhalation.
R35 Causes severe burns.
Safety Statements about 2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9):
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 After contact with skin, wash immediately with plenty of soap-suds.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
1. Storage: Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
2. Handling: All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
3. Personal Protection: Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
4. Fire Fighting: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.
5. Reactivity Profile Inorganic oxidizing agents can react with reducing agents to generate heat and products that may be gaseous (causing pressurization of closed containers). The products may themselves be capable of further reactions (such as combustion in the air). The chemical reduction of materials in this group can be rapid or even explosive, but often requires initiation (heat, spark, catalyst, addition of a solvent). Explosive mixtures of inorganic oxidizing agents with reducing agents often persist unchanged for long periods if initiation is prevented. Such systems are typically mixtures of solids, but may involve any combination of physical states. Some inorganic oxidizing agents are salts of metals that are soluble in water; dissolution dilutes but does not nullify the oxidizing power of such materials. Organic compounds, in general, have some reducing power and can in principle react with compounds in this class. Actual reactivity varies greatly with the identity of the organic compound. Inorganic oxidizing agents can react violently with active metals, cyanides, esters, and thiocyanates. Explosives often consist of an inorganic oxidizing agent mixed in intimate contact with a reducing agent. Gunpowder is such a mixture. Other examples are a mixture of sugar (an organic compound) plus sodium chlorate and magnesium (an inorganic reducing agent) plus barium peroxide. Compounds that inherently contain a group that is a reducing agent and an oxidizing agent are classed in both Group 44 (Inorganic Oxidizing Agents) and in Group 45 (Inorganic Reducing Agents; for example, ammonium nitrate). The strongly oxidizing elements oxygen and fluorine are classified here. Inorganic oxidizing agents that are also acids (such as nitric and perchloric acids) are not included in this group. They are in Group 2 (Acids, Inorganic Oxidizing).
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