Cyclodecanone supplier | CasNO.1502-06-3

Name
Cyclodecanone
EINECS 216-119-8
CAS No. 1502-06-3
Article Data68
CAS DataBase
Density 0.886 g/cm³
Solubility
Melting Point 21-24 °C(lit.)
Formula C₁₀H₁₈O
Boiling Point 232.1 °C at 760 mmHg
Molecular Weight 154.252
Flash Point 82.2 °C
Transport Information
Appearance
Safety 26
Risk Codes 36
Molecular Structure
Hazard Symbols Xi
Synonyms NSC 90293;
PSA 17.07000
LogP 3.08000

Synthetic route

: 1502-05-2
cyclodecanol

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
With nickel In benzene for 7h; Heating;	98%
With sodium bromate; 1-n-butyl-3-methylimidazolim bromide at 70℃; for 150h;	88%
With ferredoxin reductase; [2Fe–2S] ferredoxin; cytochrome P450 enzyme CYP101C1 In aq. buffer pH=7.4; Enzymatic reaction;	25%

: 2-iodo-cyclodecanone

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
With triethyl borane; ytterbium(III) triflate; allyl-trimethyl-silane In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;	95%

: 4885-02-3
Dichloromethyl methyl ether

: 116232-75-8
B-methoxyborecane

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
	79%
In not given IR, PMR, mass spectral data, GLC;;	79%

: 87307-15-1
6-bromocyclododecanone

A: 1502-06-3
cyclodecanone

B: 1654-87-1
trans-decal-9-ol

C: 3574-58-1
cis-9-decalol

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene at 60℃; for 15h;	A 4% B 20% C 75%

...Expand

: 935-31-9
(Z)-cyclodecene

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
With (phthalocyaninato)iron(II); zirconium phosphate; oxygen; hydroquinone; palladium dichloride In water; N,N-dimethyl-formamide at 20℃; under 760 Torr; for 3h; Wacker oxidation;	51%

: methyl cis-11-oxabicyclo[8.1.0]undecane-1-carboxylate

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
Stage #1: methyl cis-11-oxabicyclo[8.1.0]undecane-1-carboxylate With methanol; water; sodium hydroxide for 5h; Reflux; Stage #2: With hydrogenchloride; methanol; water for 1h; Reflux;	47%

: 6244-48-0
1-vinyl-1-cyclooctanol

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
at 650℃; under 0.75006 - 3.00024 Torr;	30%
Multi-step reaction with 2 steps 1: 37 percent / iodine, yellow HgO / toluene / Heating 2: 12 percent / AIBN, tri-n-butyltin hydride / benzene / Heating View Scheme

: 293-96-9
cyclodecane

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
With dihydrogen peroxide; vanadium phosphorus oxide In acetonitrile at 70℃; for 20h;	28%
With dihydrogen peroxide; iron(III) chloride In pyridine; acetic acid Mechanism;
With cis-VI(6,6'-Cl2bpy)2O2> In tetrachloromethane; acetonitrile at 20℃; for 0.5h; Oxidation;	75 % Chromat.

: 101999-59-1
10-Iodo-dec-1-en-3-one

A: 1502-06-3
cyclodecanone

B: 928-80-3
decan-3-one

C: 56606-79-2
dec-1-en-3-one

D: 38734-07-5
cycloeicosane-1,11-dione

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene for 3h; Heating; Yields of byproduct given;	A 15% B n/a C n/a D n/a
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene for 3h; Heating; Yield given. Yields of byproduct given;

...Expand

: 101999-59-1
10-Iodo-dec-1-en-3-one

A: 1502-06-3
cyclodecanone

B: 56606-79-2
dec-1-en-3-one

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene Heating;	A 12% B 6%
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene at 80℃; for 3h;	A 15 % Chromat. B 27 % Chromat.

: 502-49-8
cycloactanone

: 615-53-2
ethyl N-methyl-N-nitrosocarbamate

A: 3350-30-9
cyclononanone

B: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
With methanol; potassium carbonate at 7℃;

...Expand

: 3350-30-9
cyclononanone

: 615-53-2
ethyl N-methyl-N-nitrosocarbamate

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
With methanol; sodium carbonate at 20℃;

: 71172-36-6
1,11-undecanedinitrile

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
With etheric solution; sodium-<N-alkyl-anilide> anschliessendes Behandeln mit Wasser und Kochen der in Aether loeslichen Anteile des Reaktionsprodukts mit 40prozentig. wss. Schwefelsaeure;

: 96-00-4
2-hydroxycyclodecanone

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
With acetic acid; zinc und konz. wss. HCl;

: 30572-96-4
cis-cyclodecane-1,2-diol

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
With pyridine; p-toluenesulfonyl chloride

: 3468-78-8
(Z)-5-Cyclodecenone

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
With acetic acid; platinum Hydrogenation;
With methanol; palladium on activated charcoal

: 73674-34-7
2-(2-Methylamino-phenylsulfonyl)-cyclodecanon

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
With aluminium amalgam In tetrahydrofuran; water for 0.666667h; Heating;

: 4296-15-5
2-iodo-1-methoxyethane

: 77857-64-8
(2S)-(-)-(N-cyclodecylidine)-1-methoxy-3-phenyl-2-propylamine

A: 1502-06-3
cyclodecanone

B: 77857-84-2
(S)-2-(2-methoxyethyl)cyclodecanone

C: 77857-84-2
(R)-(-)-2-(2-methoxyethyl)cyclodecanone

Conditions

Conditions	Yield
With lithium diisopropyl amide Product distribution; multistep reaction: 1.) THF, reflux, 1 h, 2.) -78 deg C, 2.5 h; temperature conditions effect on enatiomeric excess; enantioselective alkylation of cyclic ketones; role of (E)- ans (Z)-lithioenamines; thermodynamic and kinetic products;

...Expand

: 77857-64-8
(2S)-(-)-(N-cyclodecylidine)-1-methoxy-3-phenyl-2-propylamine

: 74-88-4
methyl iodide

A: 1502-06-3
cyclodecanone

B: 73674-38-1, 77857-78-4
(R)-2-methylcyclodecanone

C: 77857-78-4
(S)-(-)-2-methylcyclodecanone

Conditions

Conditions	Yield
With lithium diisopropyl amide Product distribution; multistep reaction: 1.) THF, reflux, 1 h, 2.) -78 deg C, 2.5 h; temperature conditions effect on enatiomeric excess; enantioselective alkylation of cyclic ketones; role of (E)- ans (Z)-lithioenamines; thermodynamic and kinetic products;

...Expand

: 1502-05-2
cyclodecanol

: 502-42-1
cycloheptanone

A: 1502-06-3
cyclodecanone

B: 502-41-0
cycloheptanol

Conditions

Conditions	Yield
With aluminum isopropoxide In benzene at 80℃; Equilibrium constant; Thermodynamic data; -ΔG (reaction), -ΔGox (rel. cyclohexanone);

...Expand

(+-)-2-hydroxy-cyclodecanone-(1): (+-)-2-hydroxy-cyclodecanone-(1)

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
With hydrogenchloride; acetic acid; zinc at 80℃;
With aluminum oxide unter vermindertem Druck und katalytische Hydrierung des Reaktionsprodukts;

thorium salt of/the/ nonane-dicarboxylic acid-(1.9): thorium salt of/the/ nonane-dicarboxylic acid-(1.9)

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
at 350 - 500℃; Erhitzen im Vakuum;
at 350 - 500℃; Erhitzen im Vakuum;

yttrium salt of/the/ nonane-dicarboxylic acid-(1.9): yttrium salt of/the/ nonane-dicarboxylic acid-(1.9)

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
at 350 - 500℃; Erhitzen im Vakuum;
at 350 - 500℃; Erhitzen im Vakuum;

: 7647-01-0
hydrogenchloride

: 96-00-4
2-hydroxycyclodecanone

: 64-19-7
acetic acid

zinc: zinc

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
at 100℃;

...Expand

: 2198-20-1
trans-cyclodecene

A: 1502-06-3
cyclodecanone

B: 32453-08-0, 91108-69-9, 125226-48-4
trans-cyclodecane-1,6-diol

C C10H18O2: C10H18O2

Conditions

Conditions	Yield
at 63℃;

...Expand

: 110-86-1
pyridine

: 30572-96-4
cis-cyclodecane-1,2-diol

: 98-59-9
p-toluenesulfonyl chloride

A: 1502-06-3
cyclodecanone

B cis-1--cyclodecanol-(2): cis-1--cyclodecanol-(2)

...Expand

: 293-96-9
cyclodecane

A: 111-20-6
1,10-decanedioic acid

B: 1502-06-3
cyclodecanone

C: 1502-05-2
cyclodecanol

Conditions

Conditions	Yield
With oxygen; N–hydroxysaccharin; cobalt(III) acetylacetonate In various solvent(s) at 100℃; under 760.051 Torr; for 5h;

...Expand

: 502-49-8
cycloactanone

: 1502-06-3
cyclodecanone

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: CeCl3 / tetrahydrofuran / 0.5 h / 20 °C 1.2: tetrahydrofuran / 0.5 h / 25 °C 2.1: 30 percent / 650 °C / 0.75 - 3 Torr View Scheme
Multi-step reaction with 4 steps 1: boron trifluoride diethyl etherate / diethyl ether / 16.25 h / 0 - 20 °C / Inert atmosphere 2: dimethyl sulfoxide; water / 16 h / 160 °C 3: boron trifluoride diethyl etherate / diethyl ether / 16.25 h / 0 - 20 °C / Inert atmosphere 4: dimethyl sulfoxide; water / 160 °C View Scheme

: 1502-06-3
cyclodecanone

: 1576-35-8
toluene-4-sulfonic acid hydrazide

: 2749-65-7
N'-cyclodecylidene-4-methylbenzenesulfonohydrazide

Conditions

Conditions	Yield
In ethanol at 100℃; for 1h;	100%
In ethanol at 100℃; for 1.66667h; Inert atmosphere;	100%
With hydrogenchloride In methanol at 20℃;
With hydrogenchloride In methanol at 20℃; for 18h;

: 1502-06-3
cyclodecanone

: 50635-71-7, 50635-72-8, 31350-93-3
1-chloroethyl p-tolyl sulfoxide

: 1-[1-chloro-1-(p-tolylsulfinyl)ethyl]-1-cyclodecanol

Conditions

Conditions	Yield
at -70℃;	100%
Stage #1: 1-chloroethyl p-tolyl sulfoxide With lithium diisopropyl amide In tetrahydrofuran at -70℃; for 0.166667h; Stage #2: cyclodecanone In tetrahydrofuran at -70℃; for 0.5h;	35%

: 1502-06-3
cyclodecanone

: 2972-01-2
cyclodecanone oxime

Conditions

Conditions	Yield
With hydroxylamine; sodium acetate In methanol at 20℃; for 1h;	98%

: 1502-06-3
cyclodecanone

: 76066-35-8
2-bromo-cyclodecanone

Conditions

Conditions	Yield
With bromine In tetrachloromethane; water Heating; Irradiation;	95%

: 1502-06-3
cyclodecanone

: 316-46-1
5-fluorouridine

: 1251763-84-4
5-fluoro-1-[(3a'R,4'R,6'R,6a'R)-3a',4',6',6a'-tetrahydro-6'-(hydroxymethyl)spiro[cyclodecane-1,2'-furo[3,4-d][1,3]dioxol]-4'-yl]pyrimidine-2,4(1H,3H)-dione

Conditions

Conditions	Yield
With hydrogenchloride; orthoformic acid triethyl ester In 1,4-dioxane; N,N-dimethyl-formamide at 20℃; for 24h;	95%

: 1502-06-3
cyclodecanone

: 107-02-8
acrolein

: 916853-89-9
2-(1-hydroxy-allyl)-cyclodecanone

Conditions

Conditions	Yield
Stage #1: cyclodecanone With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at 0℃; Stage #2: acrolein In tetrahydrofuran; hexane at -78℃; Further stages.;	94%
Stage #1: cyclodecanone With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at 0℃; for 1h; Stage #2: acrolein In tetrahydrofuran; hexane at -78℃; for 0.0166667h;	90%

: 1502-06-3
cyclodecanone

: 96-00-4
2-hydroxycyclodecanone

Conditions

Conditions	Yield
With ferredoxin reductase; [2Fe–2S] ferredoxin; cytochrome P450 enzyme CYP101C1 In aq. buffer pH=7.4; Kinetics; Catalytic behavior; Enzymatic reaction; regioselective reaction;	90%

: 1502-06-3
cyclodecanone

: 139343-81-0
(S(S)R)-(+)-3-methyl-2-pivaloyl-2,3-dihydroisothiazole 1-oxide

: 2,2-Dimethyl-N-{(R)-1-[2-((S)-2-oxo-cyclodecanesulfinyl)-phenyl]-ethyl}-propionamide

Conditions

Conditions	Yield
With sodium hexamethyldisilazane In tetrahydrofuran; toluene 1.) -78 deg C, 1 h, 2.) -78 deg C, 1 h; -78 deg C to r.t.;	88%

: 1502-06-3
cyclodecanone

: 10035-97-9
cis-2-cyclodecen-1-one

Conditions

Conditions	Yield
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In fluorobenzene; dimethyl sulfoxide at 75℃; for 9h;	88%
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In dimethyl sulfoxide; toluene at 65℃;

: 1502-06-3
cyclodecanone

: 1155336-35-8
C10H17FO

Conditions

Conditions	Yield
With sodium dodecyl-sulfate; Selectfluor In water at 80℃; Micellar solution; regioselective reaction;	87%

: 108-22-5
Isopropenyl acetate

: 1502-06-3
cyclodecanone

: 50590-91-5
1-cyclodecen-1-yl acetate

Conditions

Conditions	Yield
With toluene-4-sulfonic acid for 31h; Heating;	86%
With toluene-4-sulfonic acid
With toluene-4-sulfonic acid for 24h; Heating;

: 1502-06-3
cyclodecanone

: 15022-08-9
diallylcarbonate

: 307492-98-4
prop-2-enyl 2-oxocyclodecane-1-carboxylate

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran for 4h; Alkylation; Heating;	85%

: 75-77-4
chloro-trimethyl-silane

: 1502-06-3
cyclodecanone

: 74173-15-2
(E)-1-Trimethylsilyloxy-1-cyclodecen

Conditions

Conditions	Yield
With magnesium In N,N-dimethyl-formamide at 15 - 25℃;	84%
With triethylamine In N,N-dimethyl-formamide	59%
With triethylamine In N,N-dimethyl-formamide at 120℃;

: 1502-06-3
cyclodecanone

: 5579-79-3
Oxacycloundecan-2-one

Conditions

Conditions	Yield
With trifluoroacetyl peroxide; camphor-10-sulfonic acid for 12h;	84%
With disodium hydrogenphosphate; urea hydrogen peroxide adduct; trifluoroacetic anhydride at 0 - 20℃; for 48h;	83%
With 3-chloro-benzenecarboperoxoic acid In chloroform Heating;

: 1502-06-3
cyclodecanone

: cyclodecane-1,2-dione monooxime

Conditions

Conditions	Yield
With hydrogenchloride; sodium nitrite In tetrahydrofuran at 20℃; for 5h;	84%

: 1502-06-3
cyclodecanone

: perdeuterated cyclodecanone

Conditions

Conditions	Yield
With water-d2; palladium on activated charcoal at 250℃; for 12h;	83%
With water-d2; palladium on activated charcoal at 250℃; for 12h;

: 1502-06-3
cyclodecanone

: 27367-70-0
(E)-2-hydroxyiminocyclododecanone

Conditions

Conditions	Yield
With hydrogenchloride; methyl nitrite In diethyl ether at 0℃; for 24h;	81%

: 1502-06-3
cyclodecanone

: 24824-93-9
chloromethyl p-tolyl sulfoxide

: 851662-60-7
3'-(p-tolylsulfinyl)spiro[cyclodecane-1,2'-oxirane]

Conditions

Conditions	Yield
Stage #1: chloromethyl p-tolyl sulfoxide With lithium diisopropyl amide In tetrahydrofuran at -78℃; Stage #2: cyclodecanone In tetrahydrofuran at -78℃; Stage #3: With potassium tert-butylate In tetrahydrofuran; tert-butyl alcohol at 0℃;	80%

: 1502-06-3
cyclodecanone

: 15189-27-2
Cyclodec-2-enone

Conditions

Conditions	Yield
With 4-methoxypyridine N-oxide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In dimethyl sulfoxide at 20℃; for 24h;	78%

: 1271-15-4
lithiumferrocene

: 1502-06-3
cyclodecanone

: {Fe(C5H5)(C5H4)C(OH)(CH2)9}

Conditions

Conditions	Yield
In diethyl ether byproducts: ferrocene; reaction at 0°C, 3 hours and hydrolysis;; chromatography (silica gel, benzene); detn. by IR and 1H-NMR; elem. anal.;;	78%

: 1502-06-3
cyclodecanone

: 1,1-dihydroperoxycyclodecane

Conditions

Conditions	Yield
With dihydrogen peroxide In acetonitrile at 40℃; for 24h;	78%

: 1502-06-3
cyclodecanone

: 3473-63-0
formamidine acetic acid

: 5,6,7,8,9,10,11,12-octahydro-cyclodecapyrimidine

Conditions

Conditions	Yield
In propan-1-ol at 100℃; for 20h;	77%

: 1502-06-3
cyclodecanone

: 105-58-8
Diethyl carbonate

: 4017-58-7
ethyl 2-oxocyclodecane-1-carboxylate

Conditions

Conditions	Yield
With sodium hydride In mineral oil Inert atmosphere;	76%
With ethanol; sodium hydride In xylene
With sodium In benzene
With sodium hydride
Yield given. Multistep reaction;

: 1502-06-3
cyclodecanone

: 104-88-1
4-chlorobenzaldehyde

: 109-77-3
malononitrile

: (E)-2-amino-4-(4-chlorophenyl)-4a,5,6,7,8,9,10,11-octahydrobenzo[10]annulene-1,3,3(4H)-tricarbonitrile

Conditions

Conditions	Yield
With borax In ethanol for 2h; Reflux;	76%

...Expand

: 1502-06-3
cyclodecanone

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

A: 2-chloro-cyclodecanecarbaldehyde

B: 892127-42-3
(Z)-2-chlorocyclodec-1-ene-1-carbaldehyde

Conditions

Conditions	Yield
Stage #1: N,N-dimethyl-formamide With trichlorophosphate In dichloromethane at 20℃; for 30h; Stage #2: cyclodecanone In dichloromethane at 75℃; for 6h; Vilsmeier-Haack formylation;	A 15% B 75%

...Expand

Cyclodecanone Specification

The Cyclodecanone is an organic compound with the formula C₁₀H₁₈O. The IUPAC name of this chemical is Cyclodecanone. With the CAS registry number 1502-06-3, it is also named as Cyclodecan-1-one. The product's categories are C10; Carbonyl Compounds; Ketones. Besides, it should be stored in a dry, well-ventilated, lightproof place.

Physical properties about Cyclodecanone are: (1)ACD/LogP: 3.02; (2)ACD/LogD (pH 5.5): 3.02; (3)ACD/LogD (pH 7.4): 3.02; (4)ACD/BCF (pH 5.5): 116.05; (5)ACD/BCF (pH 7.4): 116.05; (6)ACD/KOC (pH 5.5): 1045.89; (7)ACD/KOC (pH 7.4): 1045.89; (8)#H bond acceptors: 1; (9)Polar Surface Area: 17.07 Å²; (10)Index of Refraction: 1.444; (11)Molar Refractivity: 46.24 cm³; (12)Molar Volume: 173.9 cm³; (13)Polarizability: 18.33×10^-24 cm³; (14)Surface Tension: 29.7 dyne/cm; (15)Density: 0.886 g/cm³; (16)Flash Point: 82.2 °C; (17)Enthalpy of Vaporization: 46.88 kJ/mol; (18)Boiling Point: 232.1 °C at 760 mmHg; (19)Vapour Pressure: 0.06 mmHg at 25 °C.

Uses of Cyclodecanone: it can be used to produce Cyclodecanone oxime at temperature of 20 °C. It will need reagents hydroxylamine; sodium acetate and solvent methanol with reaction time of 1 hour. The yield is about 98%.

When you are using this chemical, please be cautious about it as the following:
It is irritating to the eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)InChI: InChI=1/C10H18O/c11-10-8-6-4-2-1-3-5-7-9-10/h1-9H2
(2)InChIKey: SXOZDDAFVJANJP-UHFFFAOYAD
(3)Std. InChI: InChI=1S/C10H18O/c11-10-8-6-4-2-1-3-5-7-9-10/h1-9H2
(4)Std. InChIKey: SXOZDDAFVJANJP-UHFFFAOYSA-N

Product Name

Cyclodecanone

Synthetic route

Cyclodecanone Specification

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