D-(-)-Arabinose supplier | CasNO.10323-20-3

Name
beta-D-(-)-Arabinose
EINECS 233-708-5
CAS No. 10323-20-3
Article Data186
CAS DataBase
Density 1.757 g/cm³
Solubility Soluble in water.
Melting Point 156-160 °C
Formula C₅H₁₀O₅
Boiling Point 415.462 °C at 760 mmHg
Molecular Weight 150.131
Flash Point 219.215 °C
Transport Information
Appearance White to off-white powder
Safety 26-36
Risk Codes 20/21/22-36/37/38
Molecular Structure
Hazard Symbols Xn
Synonyms Arabinose,D- (8CI);(-)-Arabinose;Anhydroarabinose;D-Arabinose;
PSA 97.99000
LogP -2.73970

Synthetic route

: 7-(tert-butyl-diphenyl-silanyloxy)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-ol

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With hydrogenchloride; water at 18℃; for 18h;	68%

: 3391-82-0, 4688-50-0, 6027-86-7, 6622-52-2, 14933-21-2, 18404-69-8, 45079-02-5, 69617-74-9, 71074-87-8, 90010-62-1, 121929-17-7, 299-28-5
calcium gluconate

A: 10323-20-3
D-Arabinose

B: 583-50-6
D-erythrose

Conditions

Conditions	Yield
With dihydrogen peroxide; FAU(2.4); copper In water at 19.85℃; for 3.5h; pH=6.5; Product distribution; Further Variations:; Catalysts; Ruff degradation;	A 63% B 9%

: 73080-26-9
5,6-dihydro-6-(S)-(1,3-dithian-2-yl)-1-β-D-arabinofuranosyluracil

A: 10323-20-3
D-Arabinose

B: 73080-27-0, 76222-45-2
5,6-dihydro-6-(S)-(1,3-dithian-2-yl)uracil

Conditions

Conditions	Yield
With hydrogenchloride at 70℃; for 4h;	A n/a B 62%

deacetylated Scutellaria baicalensis water-soluble polysaccharide: deacetylated Scutellaria baicalensis water-soluble polysaccharide

A: 10323-20-3
D-Arabinose

B: 50-99-7
D-glucose

C: 59-23-4
D-Galactose

D partially hydrolysed deacetylated Scutellaria baicalensis water-soluble polysaccharide: partially hydrolysed deacetylated Scutellaria baicalensis water-soluble polysaccharide

E: galactobiose

Conditions

Conditions	Yield
With sulfuric acid; water at 100℃; for 0.0833333h;	A n/a B n/a C n/a D 56.2% E n/a

...Expand

: 50-69-1
D-ribose

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With molybdic acid In water for 0.05h; Bilik reaction; microwave irradiation;	45%

: 367261-89-0
2-C-(hydroxymethyl)-D-glycero-D-gulo-heptose

A: 10323-20-3
D-Arabinose

B: 96-26-4
dihydroxyacetone

C: 1016606-96-4
D-glycero-D-ido-oct-2-ulose

Conditions

Conditions	Yield
With molybdic acid In water at 85℃; for 8h;	A n/a B n/a C 40%

...Expand

: 110-86-1
pyridine

: 488-84-6
D-ribulose

A: 10323-20-3
D-Arabinose

B: 50-69-1
D-ribose

...Expand

: 110-86-1
pyridine

: 551-84-8
xylulose

A: 58-86-6
D-xylose

B: 10323-20-3
D-Arabinose

C: 50-69-1
D-ribose

...Expand

: 69-65-8
mannitol

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With lead(IV) acetate; oxalic acid; acetic acid Erwaermen des Reaktionsprodukts mit Wasser;
With periodic acid

: 15909-68-9
D-arabinonic acid methyl ester

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With sodium amalgam; sulfuric acid; water

: 3416-24-8
2-amino-2-deoxyglucose

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With sodium hypochlorite; water
With water; chloroamine-T

: 50-99-7
D-glucose

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With water; bromine; barium benzoate Erwaermen des Reaktionsprodukts mit Calciumcarbonat und Wasser und anschliessend mit wss.Wasserstoffperoxid unter Zusatz von Bariumacetat und Eisen(II)-sulfat;
With sodium hypochlorite; water anfangs bei pH 11,zuletzt bei pH 5;
With perchloric acid; ammonium vanadate In water at 50℃; under 750.06 Torr; Rate constant; Mechanism; activation volume; further pressures;
With cerium(IV) perchlorate In perchloric acid at 25 - 50℃; Kinetics; Product distribution; variation of the concentration;

: 50-99-7
D-glucose

A: 10323-20-3
D-Arabinose

B: 488-30-2
arabinoic acid

Conditions

Conditions	Yield
With sulfuric acid Elektrolyse an Bleianoden;

: 6748-69-2
D-mannose diethyl dithioacetal

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With 1,4-dioxane; perpropionic acid Behandeln des Reaktionsprodukts mit wss.Ammoniak;

: 55065-39-9
1-Desoxy-1-nitro-D-arabino-pentitol

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With sodium hydroxide anschliessendes Behandeln mit wss.Schwefelsaeure;

: 3118-85-2
D-gluconamide

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With sodium hypochlorite

: 526-95-4
gluconic acid

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
Einw. von anderen Oxydationsmitteln;

: 608-81-1
D-glucose oxime

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With sodium hydrogencarbonate anschliessendes Erwaermen mit 1-Fluor-2,4-dinitro-benzol in Isopropylalkohol;

: 6337-12-8, 35439-42-0, 40732-44-3, 75004-10-3, 83830-73-3, 83830-74-4, 127000-04-8, 127000-05-9, 127000-06-0, 127000-07-1, 132202-32-5, 132202-33-6, 132202-34-7, 132204-32-1, 132204-33-2, 6272-51-1
2,3,4,5,6-pentaacetoxy-D-glucononitrile

: 67-66-3
chloroform

: 124-41-4
sodium methylate

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
anschliessend Behandeln mit Wasser;

...Expand

: 109454-90-2, 109785-30-0
D-arabino-3,4,5,6-tetraacetoxy-1,1-bis-ethanesulfonyl-hex-1-ene

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With methanol; water; hydrazine Erwaermen einer wss.Loesung des Reaktionsprodukts mit Benzaldehyd,wenig Benzoesaeure und Aethanol;

: 67-66-3
chloroform

: 29505-20-2
2,3,4,5,6-penta-O-benzoyl-D-glucononitrile

: 124-41-4
sodium methylate

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
at -5℃;

...Expand

: 67-66-3
chloroform

: 71439-41-3
1,2,3,4,5-penta-O-benzoyl-D-mannonic acid nitrile

: 124-41-4
sodium methylate

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
at -5℃;

...Expand

: 13039-93-5
2,2:4,5-di-O-isopropylidene-D-arabinose

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With sulfuric acid

: 572-30-5
avicularin

A: 10323-20-3
D-Arabinose

B: 117-39-5
quercetol

Conditions

Conditions	Yield
With hydrogenchloride for 2h; Heating;

: 3458-28-4
D-Mannose

A: 10323-20-3
D-Arabinose

B: 583-50-6
D-erythrose

Conditions

Conditions	Yield
With iron(III) chloride In water at 20℃; for 3h; Product distribution; Irradiation;

: 3458-28-4
D-Mannose

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With perchloric acid; ammonium vanadate In water at 55℃; under 750.06 Torr; Rate constant; Mechanism; activation volume; further pressures;
With cerium(IV) perchlorate In perchloric acid at 25 - 50℃; Kinetics; Product distribution; variation of the concentration;

: 50-99-7
D-glucose

A: 453-17-8
D-Glyceraldehyde

B: 10323-20-3
D-Arabinose

C: 583-50-6
D-erythrose

Conditions

Conditions	Yield
With iron(III) chloride In water at 20℃; for 3h; Product distribution; Kinetics; Mechanism; Irradiation; various reaction times.;

...Expand

: 28697-53-2
D-arabinopyranose

: 10323-20-3
D-Arabinose

Conditions

Conditions	Yield
With potassium chloride In water at 25℃; Equilibrium constant; Thermodynamic data; free energy of cyclization ΔG0c;

: 108179-46-0
dimorphoside A

A: 10323-20-3
D-Arabinose

B: 50-99-7
D-glucose

Conditions

Conditions	Yield
With hydrogenchloride In methanol; water Product distribution; Heating; products ratio 1:1;

: 10323-20-3
D-Arabinose

: 98-80-6
phenylboronic acid

: 1218927-63-9
C17H16B2O5

Conditions

Conditions	Yield
In methanol; water at 20℃; for 2h;	100%

: 10323-20-3
D-Arabinose

: 100-46-9
benzylamine

: 70399-59-6, 70399-60-9, 70399-61-0, 74036-10-5, 85280-63-3, 85280-64-4, 108942-11-6, 108942-12-7
N-Benzyl-D-arabinosylamin

Conditions

Conditions	Yield
In methanol at 20 - 45℃; for 3h;	100%

: 67-56-1
methanol

: 10323-20-3
D-Arabinose

: 13039-64-0
(2S,3R,4R)-2-(hydroxymethyl)-5-methoxytetrahydrofuran-3,4-diol

Conditions

Conditions	Yield
With hydrogenchloride; acetyl chloride at 0 - 20℃; for 3h;	100%
With acetyl chloride at 0 - 20℃; for 3h;	100%

: 10323-20-3
D-Arabinose

: 75-08-1
ethanethiol

: 1941-50-0
D-arabinose diethyl dithioacetal

Conditions

Conditions	Yield
With hydrogenchloride; zinc(II) chloride	99%
In hydrogenchloride at 0℃; for 0.5h;	91%
	88%

: 10323-20-3
D-Arabinose

: 123-54-6
acetylacetone

: 1-((2S,5R)-3,4-dihydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)propan-2-one

Conditions

Conditions	Yield
With sodium carbonate In water at 10℃; for 12h; stereoselective reaction;	97%

: 10323-20-3
D-Arabinose

: 95-83-0
4-Chloro-1,2-phenylenediamine

: 1609208-14-1
(1R,2S,3R)-2-(1,2,3,4-tetrahydroxybutyl)-1H-6-chlorobenzimidazole

Conditions

Conditions	Yield
With iodine In water; acetic acid at 20℃; for 3h;	97%

: 10323-20-3
D-Arabinose

: 771-97-1
2,3-Diaminonaphthalene

: 1027103-25-8
(1'R,2'S,3'R,)-2-[1',2',3',4'-tetrahydroxybutyl]-1H-naphthimidazole

Conditions

Conditions	Yield
With air; iodine; acetic acid at 20℃; for 3h;	96%

: 10323-20-3
D-Arabinose

: 67533-07-7
phosphoenolpyruvate trianion

: D-arabinose-5-phosphate

Conditions

Conditions	Yield
With sodium hydroxide; pyruvate kinase; potassium chloride; magnesium sulfate; 2-hydroxyethanethiol; hexokinase In water at 20℃; for 46h; pH=7.6; Enzymatic reaction;	95%

: carbonic acid bis(1-isopropylhydrazide) dihydrochloride

: 10323-20-3
D-Arabinose

: 1'R,2'S,3'R-2,4-diisopropyl-6-(1',2',3',4'-tetrahydroxybutyl)-1,2,4,5-tetrazinan-3-one

Conditions

Conditions	Yield
With sodium acetate In water at 20℃;	95%

: 67-56-1
methanol

: 10323-20-3
D-Arabinose

: 79083-42-4
methyl D-arabinofuranoside

Conditions

Conditions	Yield
With hydrogenchloride at 20℃; for 5h;	94%
With acetyl chloride at 20℃; for 18h;	91%
With acetyl chloride for 24h; Inert atmosphere;	82%

: 10323-20-3
D-Arabinose

: 100-53-8
phenylmethanethiol

: 34685-26-2
L-(+)-arabinose dibenzyl thioacetal

Conditions

Conditions	Yield
In hydrogenchloride for 0.5h;	93%
With hydrogenchloride; zinc(II) chloride	81%
With hydrogenchloride
With hydrogenchloride; zinc(II) chloride
With trifluoroacetic acid

: 10323-20-3
D-Arabinose

: 123506-40-1
6-hydrazino-1,3-dimethyl-1H-pyrimidine-2,4-dione

: 69471-90-5
1,3-Dimethyl-6-{N'-[(2R,3S,4R)-2,3,4,5-tetrahydroxy-pent-(Z)-ylidene]-hydrazino}-1H-pyrimidine-2,4-dione

Conditions

Conditions	Yield
In methanol for 5h; Heating;	93%

: 10323-20-3
D-Arabinose

: 1082607-20-2
4-hydrazino-1,3-diphenylpyrazolo[3,4-d]pyrimidine

: D-arabinose N-(1,3-diphenylpyrazolo[3,4-d]pyrimidin-4-y)hydrazone

Conditions

Conditions	Yield
With hydrogenchloride In ethanol; water for 6h; Reflux;	93%

: 10323-20-3
D-Arabinose

: 13437-75-7
N-Phenyl-N'-thiobenzoyl-hydrazin

: (1S,2R,3R)-1-<(2S)-(3,5-diphenyl-2,3-dihydro-<1,3,4>thiadiazol-2-yl)>-butane-1,2,3,4-tetraol

Conditions

Conditions	Yield
With hydrogenchloride In ethanol at 20℃; for 3h;	92%

: 10323-20-3
D-Arabinose

: 98-01-1
furfural

Conditions

Conditions	Yield
With Dowex 50Wx8-100 ion-exchange resin at 100℃; for 6h; Ionic liquid; Sealed tube;	92%
With silicoaluminophosphate-44 In water; toluene at 170℃; for 8h;	63%
With 1-butyl-3-methylimidazolium tetrachloridoferrate(III) In water; butanone at 160℃; for 3h;	50.7%

: 10323-20-3
D-Arabinose

: 3171-45-7
4,5-dimethyl-1,2-phenylenediamine

: (1'R,2'S,3'R)-5,6-dimethyl-2-[1',2',3',4'-tetrahydroxybutyl]-1H-benzimidazole

Conditions

Conditions	Yield
With iodine In water; acetic acid at 20℃; for 3.5h;	92%
With iodine; acetic acid In methanol at 20℃; for 12h;

: 10323-20-3
D-Arabinose

: 876594-46-6
C19H20N4O2

: 1155315-21-1
1-[4-(2-methoxybenzyl)-6-(4-methoxyphenyl)-2H-pyridazin-3-ylidene]-2-(pent-1-ylidene-2,3,4,5-tetraol) hydrazine

Conditions

Conditions	Yield
In ethanol for 5h; Reflux;	92%

: 52-90-4
L-Cysteine

: 10323-20-3
D-Arabinose

: C8H14NO6S(1-)*Na(1+)

Conditions

Conditions	Yield
With sodium hydroxide at 80℃; pH=9.5; Temperature; Flow reactor;	92%

: 104-13-2
4-Butylaniline

: 10323-20-3
D-Arabinose

: 4-butyl-N,N-bis(d-arabinityl)aniline

Conditions

Conditions	Yield
With sodium cyanoborohydride; acetic acid In methanol at 50℃; for 24h;	92%

: 10323-20-3
D-Arabinose

: 60887-36-7, 60933-70-2, 60933-71-3, 80182-97-4
(1RS)-<1-2H1>-D-arabinitol

Conditions

Conditions	Yield
With sodium borodeuteride; potassium hydrogencarbonate In water for 24h;	91%
With sodium borodeuteride at 4℃;

: 10323-20-3
D-Arabinose

: 108-24-7
acetic anhydride

: 106-49-0
p-toluidine

: 123-54-6
acetylacetone

: 1020540-90-2
(6S)-3-acetyl-2-methyl-1-(4-methylphenyl)-1,5,6,7-tetrahydropyrano[3,2-b]pyrrol-6-yl acetate

Conditions

Conditions	Yield
Stage #1: D-Arabinose; p-toluidine; acetylacetone With indium(III) chloride In water at 80℃; for 6.5h; Stage #2: acetic anhydride With dmap In dichloromethane at 20℃; for 1h; Further stages.;	91%

...Expand

: 10323-20-3
D-Arabinose

: 108-24-7
acetic anhydride

: 14268-66-7
benzo[1,3]dioxolo-5-ylamine

: 123-54-6
acetylacetone

: 1020540-92-4
(6S)-3-acetyl-1-(1,3-benzodioxol-5-yl)-2-methyl-1,5,6,7-tetrahydropyrano[3,2-b]pyrrol-6-yl acetate

Conditions

Conditions	Yield
Stage #1: D-Arabinose; benzo[1,3]dioxolo-5-ylamine; acetylacetone With indium(III) chloride In water at 80℃; for 6.5h; Stage #2: acetic anhydride With dmap In dichloromethane at 20℃; for 1h; Further stages.;	91%

...Expand

: 10323-20-3
D-Arabinose

: 2782-09-4
D-arabinono-1,4-lactone

Conditions

Conditions	Yield
With bromine; barium carbonate In water at 0 - 20℃; for 4.3h; Oxidation;	90%
With pseudomonas-saccharophila-cultures
With quinoprotein D-glucose dehydrogenase Enzymatic reaction;

: 10323-20-3
D-Arabinose

: 5397-03-5
hydrazinecarbodithioic acid methyl ester

: N'-[(2R,3S,4R)-2,3,4,5-Tetrahydroxy-pent-(E)-ylidene]-hydrazinecarbodithioic acid methyl ester

Conditions

Conditions	Yield
In methanol; water for 0.166667h; Heating;	90%

: 10323-20-3
D-Arabinose

: 86799-26-0
2-hydrazineyl-6-phenylpyrimidin-4(3H)-one

: 6-Phenyl-2-{N'-[(2R,3S,4R)-2,3,4,5-tetrahydroxy-pent-(E)-ylidene]-hydrazino}-3H-pyrimidin-4-one

Conditions

Conditions	Yield
In ethanol; water for 0.25h; Condensation; Heating;	90%

: 1004-40-6
6-Amino-2-thiouracil

: 10323-20-3
D-Arabinose

: 79-11-8
chloroacetic acid

: 7-amino-2-arabinosyl-2,3-dihydro-5H-thiazolo[3,2-a]pyrimidine-3,5-dione

Conditions

Conditions	Yield
With piperidine; pyridine for 8h; Reflux;	90%

...Expand

: 21703-52-6
2-hydrazinyl-4-methylquinoline

: 10323-20-3
D-Arabinose

: (2R,3S,4R)-5-[(4-Methyl-quinolin-2-yl)-hydrazono]-pentane-1,2,3,4-tetraol

Conditions

Conditions	Yield
With acetic acid In ethanol for 0.5h; Heating;	89%

: 10323-20-3
D-Arabinose

: 98-88-4
benzoyl chloride

: 377075-27-9
1,2,3,4-tetra-O-benzoyl-D-arabinopyranose

Conditions

Conditions	Yield
With pyridine; dmap at 0 - 20℃; for 24h;	89%

: 10323-20-3
D-Arabinose

: 100-51-6
benzyl alcohol

: 5329-50-0
(-)-benzyl β-D-arabinopyranoside

Conditions

Conditions	Yield
With acetyl chloride In tert-butyl methyl ether at 35 - 50℃;	88.6%
With hydrogenchloride

: 10323-20-3
D-Arabinose

: 49830-45-7
5-ethyl-3-hydrazino-5H-1,2,4-triazino<5,6-b>indole

: D-arabinose 5-ethyl-1,2,4-triazino[5,6-b]indol-3-ylhydrazone

Conditions

Conditions	Yield
In ethanol; water for 0.25h; Condensation; Heating;	88%

D-(-)-Arabinose Chemical Properties

Molecular Structure of D-(-)-Arabinose (CAS NO.10323-20-3):

IUPAC Name: (2S,3R,4R)-2,3,4,5-Tetrahydroxypentanal
Canonical SMILES: C(C(C(C(C=O)O)O)O)O
Isomeric SMILES: C([C@H]([C@H]([C@@H](C=O)O)O)O)O
InChI: InChI=1S/C5H10O5/c6-1-3(8)5(10)4(9)2-7/h1,3-5,7-10H,2H2/t3-,4-,5+/m1/s1
InChIKey: PYMYPHUHKUWMLA-WDCZJNDASA-N
Molecular Weight: 150.1299 [g/mol]
Molecular Formula: C₅H₁₀O₅
XLogP3: -2.3
H-Bond Donor: 4
H-Bond Acceptor: 5
EINECS: 233-708-5
Index of Refraction: 1.543
Molar Refractivity: 31.41 cm³
Molar Volume: 99.5 cm³
Surface Tension: 81.4 dyne/cm
Density: 1.508 g/cm³
Flash Point: 219.2 °C
Enthalpy of Vaporization: 77.23 kJ/mol
Boiling Point: 415.5 °C at 760 mmHg
Vapour Pressure: 1.22E-08 mmHg at 25 °C
Melting Point: 156-160 °C
Product Categories: CARBOHYDRATE; FINE Chemical & INTERMEDIATES; Carbohydrates; Basic Sugars (Mono & Oligosaccharides); Arabinose; Biochemistry; Sugars; Dextrins、Sugar & Carbohydrates; Base Ingredients; Carbohydrate Sources (Sugars/Extracts); Sugars for Media; Carbohydrates A to; Carbohydrates A-CBiochemicals and Reagents; Monosaccharide; CarbohydrateSpecialty Synthesis; Carbohydrate Synthesis; Metabolic Pathways; Metabolites and Cofactors on the Metabolic Pathways Chart; Monosaccharides; Biochemicals; Molecular Biology; Molecular Biology Reagents

D-(-)-Arabinose Safety Profile

Safety Information of D-(-)-Arabinose (CAS NO.10323-20-3):
Hazard Codes: Harmful Xn
Risk Statements: 20/21/22-36/37/38
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
WGK Germany: 3
F: 3-10

D-(-)-Arabinose Specification

D-(-)-Arabinose (CAS NO.10323-20-3), its Synonyms are Arabinose,d ; D-Arabinose ; beta-D-(-)-Arabinose ; Pentopyranose ; D-Arabinose (9CI) .

Product Name

beta-D-(-)-Arabinose

Synthetic route

D-(-)-Arabinose Chemical Properties

D-(-)-Arabinose Safety Profile

D-(-)-Arabinose Specification

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