D-galactose pentaacetate
D-Galactose
Conditions | Yield |
---|---|
With methanol; sodium bromide; silver(l) oxide at 20℃; | 100% |
With guanidine nitrate In ethanol; dichloromethane deacetylation; | |
With methanol; sodium methylate at 20℃; Reagent/catalyst; | 100 %Spectr. |
1,2:3,4-di-O-isopropylidene-α-D-galactopyranose
D-Galactose
Conditions | Yield |
---|---|
With phosphotungstic acid; water In acetonitrile at 20℃; for 3h; | 100% |
Multi-step reaction with 3 steps 1.1: sodium hydride; tetrabutylammomium bromide / N,N-dimethyl-formamide; mineral oil / 0.75 h / 0 - 20 °C 1.2: 16 h / 0 - 20 °C 2.1: trifluoroacetic acid / water / 0 - 20 °C 3.1: water / 0.33 h / Irradiation View Scheme |
1,2,3,4,6-Penta-O-benzoyl-α-D-galactopyranose
D-Galactose
Conditions | Yield |
---|---|
With methanol; sodium bromide; silver(l) oxide at 20℃; | 100% |
With methanol; sodium methylate at 20℃; Reagent/catalyst; | 100 %Spectr. |
D-Galactose
Conditions | Yield |
---|---|
With water for 0.333333h; Irradiation; | 100% |
penta-O-acetyl-α-D-galactopyranose
D-Galactose
Conditions | Yield |
---|---|
With lipase A from Aspergillus niger In aq. phosphate buffer; acetonitrile at 25℃; for 30h; pH=7; Enzymatic reaction; | 99% |
D-Galactose
Conditions | Yield |
---|---|
With hexaaquaruthenium(II) tosylate In water-d2 at 50℃; for 24h; Inert atmosphere; | 95% |
D-Galactose
Conditions | Yield |
---|---|
With acetyl chloride In methanol at 20℃; Reagent/catalyst; Inert atmosphere; | 93% |
β-D-galactose peracetate
D-Galactose
Conditions | Yield |
---|---|
With methanol; potassium cyanide for 0.333333h; Ambient temperature; | 88% |
With lipase A from Aspergillus niger In aq. phosphate buffer; acetonitrile at 25℃; for 139h; pH=7; Enzymatic reaction; | 80% |
alpha-lactose monohydrate
A
D-Galactose
B
lactulose
C
D-tagatose
Conditions | Yield |
---|---|
With triethylammonium borate In water at 70℃; for 4h; Yields of byproduct given; | A n/a B 87% C n/a |
With triethylammonium borate In water at 70℃; for 4h; Product distribution; various pH, tertiary amines; | A n/a B 87% C n/a |
Conditions | Yield |
---|---|
With acetate buffer for 6h; Ambient temperature; β-galactosidase, pH 4.5; | A n/a B 79% |
2,4,6-tri-O-benzyl-α,β-D-galactopyranose
D-Galactose
Conditions | Yield |
---|---|
With hydrogen; palladium on activated charcoal In ethanol; ethyl acetate under 760 Torr; | 78% |
With hydrogen; palladium on activated charcoal In ethanol; ethyl acetate at 20℃; under 760 Torr; for 54h; | 78% |
Conditions | Yield |
---|---|
With sulfuric acid at 100℃; for 1h; | A n/a B 68% |
With grape snail enzymes | |
With rhamnodiastase |
phenyl-β-D-galactopyranoside
D-Galactose
Conditions | Yield |
---|---|
With naphthalene-1,4-dicarbonitrile In acetonitrile for 24h; Irradiation; | 60% |
4-nitrophenyl α-D-galactoside
A
D-Galactose
B
4-nitrophenyl (α-D-galactopyranosyl)-(1->3)-α-D-galactopyranoside
C
4-nitrophenyl (α-D-galactopyranosyl)-(1->6)-α-D-galactopyranoside
Conditions | Yield |
---|---|
With α-galactosidase Aga B from Bacillus stearothermophilus In phosphate buffer at 25℃; for 3.2h; pH=7.0; Product distribution; Kinetics; Further Variations:; Reagents; Temperatures; Condensation; | A n/a B 4% C 53% |
7-Desoxy-7-nitro-L-glycero-L-galacto-heptitol
A
D-Galactose
B
1-amino-1-deoxy-D-glycero-L-manno-heptitol hydrochloride
Conditions | Yield |
---|---|
With Dowex 50WX8 (H(1+)); ammonia; iron(II) sulfate In water 1) 10 min, reflux, 2) 0.5 h, RT; | A 0.6 g B 26% |
acacetin 7-O-β-D-galactopyranoside
A
D-Galactose
B
5,7-dihydroxy-2-(4'-methoxyphenyl)-4H-1-benzopyran-4-one
Conditions | Yield |
---|---|
With hydrogenchloride In ethanol for 2h; on steam bath; | A n/a B 18% |
Lactose
A
D-Glucose
B
D-Galactose
C
β-D-galactopyranosyl-(1->3)-α-D-galactopyranosyl-(1->4)-α/β-D-glucopyranose
Conditions | Yield |
---|---|
With Streptococcus thermophylus DN-001065 galactosylation; Enzymatic reaction; | A 15% B 4% C 16% |
diazomethane
3-O-β-D-galactopyranosyl-(1->2)-<β-D-xylopyranosyl-(1->3)>-β-D-glucuronopyranosyl quillaic acid 28-O-β-D-apiofuranosyl-(1->3)-β-D-xylopyranosyl-(1->4)-<β-D-glucopyranosyl-(1->3)>-α-L-rhamnopyranosyl-(1->2)-β-D-fucopyranoside.
A
D-Xylose
B
D-Galactose
Conditions | Yield |
---|---|
In methanol; diethyl ether ice cooling then Rt, 1 h; |
diazomethane
A
D-Xylose
B
D-Galactose
Conditions | Yield |
---|---|
In methanol; diethyl ether ice cooling then Rt, 1 h; |
formaldehyd
A
D-Glucose
B
D-Galactose
C
D-Mannose
E
L(+)-sorbose
Conditions | Yield |
---|---|
calcium oxide In water at 55℃; Product distribution; |
formaldehyd
A
D-Galactose
B
alpha-D-glucopyranose
C
β-D-mannose
D
XYLITOL
E
D-Ribose
F
glycerol
Conditions | Yield |
---|---|
With zeolite of type A under 1 Torr; for 144h; Product distribution; Irradiation; other objects of study: dependence of product distribution on time of irradiation; |
Lactose
A
D-Galactose
B
lactulose
C
3-β-D-galactopyranosyloxy-7-<2-(β-D-galactopyranosyloxy)-1,3,4-trihydroxybutyl>-4,8,9-trihydroxy-2-hydroxymethyl-1,6-dioxaspiro<4.4>nonane
Conditions | Yield |
---|---|
With boric acid | A n/a B n/a C 11.4 g |
Lactose
A
D-Galactose
B
gluconic acid
Conditions | Yield |
---|---|
With ammonia; ammonium chloride; potassium hexacyanoferrate(III) Rate constant; Kinetics; Thermodynamic data; Variations of substrate, reagents and aq.methanol concentrations, dielectric constant and ionic strenght at different temperature. Activation parameters: A, ΔE, ΔS, and ΔF.; |
D-melibiose
D-Galactose
Conditions | Yield |
---|---|
With citrate buffer; sodium azide; α-D-galactosidase from Turbo cornutus In water at 25℃; specific activity; |
D-melibiose
A
D-Galactose
B
gluconic acid
Conditions | Yield |
---|---|
With ammonia; potassium hexacyanoferrate(III) Rate constant; Kinetics; Thermodynamic data; Effect of NH3 concentration; activation parameters: A, ΔE, ΔS, and ΔF at two temperature; |
4-O-(α-D-Glucopyranosyl-uronsaeure)-D-galactose
A
D-Galactose
Conditions | Yield |
---|---|
With trifluoroacetic acid for 20h; Yield given. Yields of byproduct given; |
kaempferol 3-O-galactoside
A
D-Galactose
B
kaempferol
Conditions | Yield |
---|---|
With acid hydrolysis | |
With sulfuric acid | |
With hydrogenchloride In ethanol |
syringetin-3-O-β-D-galactopyranoside
A
D-Galactose
B
syringetin
Conditions | Yield |
---|---|
With oxonium Product distribution; |
D-galactose-acetylhydrazone
D-Galactose
Conditions | Yield |
---|---|
With sulfuric acid at 35℃; for 1h; Yield given; |
D-Galactose
1-amino-1-deoxy-β-D-galactose
Conditions | Yield |
---|---|
With ammonium hydroxide; ammonium bicarbonate at 42℃; for 36h; | 100% |
With ammonia In methanol at 20℃; for 48h; | 63% |
With ammonia In methanol at 20℃; for 24h; | 39.5% |
With ammonium bicarbonate In water at 30℃; for 192h; | 70 % Turnov. |
With ammonia In methanol at 20℃; for 10h; |
Conditions | Yield |
---|---|
With indium(III) triflate at 30℃; for 0.00277778h; | 100% |
With toluene-4-sulfonic acid In acetonitrile at 0 - 20℃; for 18h; | 100% |
With pyridine; dmap at 20℃; for 16h; | 100% |
Conditions | Yield |
---|---|
With acetyl chloride for 0.583333h; Heating; microwave irradiation; | 100% |
Amberlite IR-120 (H+) resin for 24h; Heating; | 55% |
With hydrogenchloride | |
With Amberlite IR 120 (H+ form) for 0.333333h; Reflux; Microwave irradiation; | |
With acetyl chloride for 12h; Inert atmosphere; Reflux; |
D-Galactose
trityl chloride
(3R,4S,5R,6R)-6-(trityloxymethyl)tetrahydropyran-2,3,4,5-tetrol
Conditions | Yield |
---|---|
With pyridine at 50℃; for 48h; Inert atmosphere; | 100% |
With 1,4-diaza-bicyclo[2.2.2]octane for 15h; | 47% |
With triethylamine In N,N-dimethyl-formamide Ambient temperature; |
chloro-trimethyl-silane
D-Galactose
1,2,3,4,6-penta-O-trimethylsilyl-α-D-galactose
Conditions | Yield |
---|---|
With pyridine at 0℃; for 1h; Substitution; | 100% |
With pyridine; 1,1,1,3,3,3-hexamethyl-disilazane at 75℃; for 1h; Inert atmosphere; | 94.5% |
With 1H-imidazole In N,N-dimethyl-formamide at 20℃; for 3h; | 92% |
D-Galactose
acetic anhydride
1,2,4,6-tetra-O-acetyl-3-O-methyl-α-D-galactopyranoside
Conditions | Yield |
---|---|
With trifluoroacetic acid at 25℃; for 20h; | 100% |
Conditions | Yield |
---|---|
With Pasteurella multocida inorganic pyrophosphatase; Bifidobacterium longum UDP-sugar pyrophosphorylase; Escherichia coli galactokinase; Neisseria meningitidis LgtB 1-4-galatosyltransferase; UTP; ATP; magnesium chloride In aq. buffer at 37℃; for 94h; pH=7.5; Enzymatic reaction; | 100% |
Conditions | Yield |
---|---|
With Pasteurella multocida inorganic pyrophosphatase; Bifidobacterium longum UDP-sugar pyrophosphorylase; Escherichia coli galactokinase; Neisseria meningitidis LgtB 1-4-galatosyltransferase; UTP; ATP; magnesium chloride In aq. buffer at 37℃; for 74h; pH=7.5; Enzymatic reaction; | 100% |
D-Galactose
benzoyl chloride
1,2,3,4,6-Penta-O-benzoyl-α-D-galactopyranose
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere; | 99.5% |
With pyridine In chloroform at 20℃; Inert atmosphere; Cooling with ice; | 93% |
With aluminum oxide In acetonitrile at 20℃; for 12h; | 92% |
D-Galactose
acetic anhydride
penta-O-acetyl-α-D-galactopyranose
Conditions | Yield |
---|---|
With sulfuric acid; acetic acid for 72h; Ambient temperature; | 99% |
With zinc(II) chloride microwave irradiation; | 78% |
With pyridine at 20℃; for 24h; Inert atmosphere; | 74% |
D-Galactose
1,6-anhydro-β-D-galactopyranose
Conditions | Yield |
---|---|
With 2-chloro-1,3-dimethylimidazolinium chloride; triethylamine In water at 0℃; for 0.25h; | 99% |
D-Galactose
toluene-4-sulfonic acid hydrazide
Conditions | Yield |
---|---|
With acetic acid In water; N,N-dimethyl-formamide for 72h; | 99% |
With acetic acid |
D-Galactose
O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-(1->3)-O-(β-D-galactopyranosyl)-(1->4)-D-glucopyranoside
lacto-N-neo-tetraose
Conditions | Yield |
---|---|
With Pasteurella multocida inorganic pyrophosphatase; Bifidobacterium longum UDP-sugar pyrophosphorylase; Escherichia coli galactokinase; Neisseria meningitidis β1−4-galactosyltransferase; UTP; ATP; magnesium chloride In aq. buffer at 37℃; for 30h; pH=8.0; Enzymatic reaction; | 99% |
With Pasteurella multocida inorganic pyrophosphatase; Bifidobacterium longumuridine 5'-diphosphate-sugarpyrophosphorylase; Echerichia coli galactokinase; Neisseris meningitidis β1-4-galactosyltransferase; adenosine-5'-triphosphate; UTP; magnesium chloride In aq. buffer at 37℃; for 30h; pH=8; Enzymatic reaction; | 92% |
D-Galactose
(2S,3R,4S,5R,6R)-2-(((2R,3S,4R,5R,6R)-6-(allyloxy)-4,5-dihydroxy-2-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol
Conditions | Yield |
---|---|
With galactokinase; pyrophosphatase; pyruvate kinase; phosphoenolpyruvic acid; α-1,4-galactosyltransferase; UDP-sugar pyrophosphorylase; UTP; ATP; magnesium chloride In aq. buffer at 16 - 50℃; pH=7.5; pH-value; Temperature; Enzymatic reaction; | 99% |
Conditions | Yield |
---|---|
With Bifidobacterium longum UDP-sugar pyrophosphorylase; Escherichia coli galactokinase; Neisseria meningitidis β1–4-galactosyltransferase; ATP; magnesium chloride; uridine-5'-triphosphate In aq. phosphate buffer at 37℃; for 5h; pH=8; Enzymatic reaction; | 99% |
D-Galactose
Lactose
α-D-galactopyranosyl-(1->3)-β-D-galactopyranosyl-(1->4)-β-D-glucose
Conditions | Yield |
---|---|
With Pasteurella multocida inorganic pyrophosphatase; Bifidobacterium longum UDP-sugar pyrophosphorylase; Escherichia coli galactokinase; recombinant bovine α1−3GalT; UTP; ATP; magnesium chloride; manganese(ll) chloride In aq. buffer at 37℃; pH=7.5; Enzymatic reaction; | 99% |
D-Galactose
β-D-galactopyranosyl-(1→3)-(2-acetamido-2-deoxy-β-D-galactopyranosyl)-(1→4)-(5-acetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2→3)-β-D-galactopyranosyl-(1→4)-β-D-glucopyranosyl-(1→1)-(2S,3R,4E)-2-amino-4-octadecene-1,3-diol
Conditions | Yield |
---|---|
With Pasteurella multocida inorganic pyrophosphatase; Bifidobacterium longum UDP-sugar pyrophosphorylase; Escherichia coli galactokinase; campylobacter jejuni β1–3-galactosyltransferase; UTP; ATP; magnesium chloride In aq. buffer at 30℃; for 48h; pH=7.5; Enzymatic reaction; | 99% |
Conditions | Yield |
---|---|
Stage #1: D-Galactose With inorganic pyrophosphatase; galactokinase from Meiothermus taiwanensis; glucose-1-phosphate thymidylyltransferase from Aneurinibacillus thermoaerophilus; UTP; ATP; magnesium chloride In aq. buffer at 55℃; for 6h; pH=8.3; Green chemistry; Enzymatic reaction; Stage #2: C41H51F17N6O16S With β-1,4-galactosyltransferase from Neisseria meningitidis; D,L-dithiothreitol In aq. buffer at 25℃; for 6h; Enzymatic reaction; Green chemistry; | 99% |
Conditions | Yield |
---|---|
Stage #1: D-Galactose With inorganic pyrophosphatase; galactokinase from Meiothermus taiwanensis; glucose-1-phosphate thymidylyltransferase from Aneurinibacillus thermoaerophilus; UTP; ATP; magnesium chloride In aq. buffer at 55℃; for 6h; pH=8.3; Green chemistry; Enzymatic reaction; Stage #2: C41H51F17N6O18S With β-1,4-galactosyltransferase from Neisseria meningitidis; D,L-dithiothreitol In aq. buffer at 25℃; for 6h; Enzymatic reaction; Green chemistry; | 99% |
Conditions | Yield |
---|---|
With sulfuric acid; copper(II) sulfate | 98% |
With sulfuric acid; zinc(II) chloride at 20℃; for 16h; | 97% |
With nano n-propylsulfonated magnetic γ-Fe2O3 for 2h; Reflux; | 95% |
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In water at 90℃; for 12h; Lubineau's reaction; | 98% |
D-Galactose
Conditions | Yield |
---|---|
With β1–4-galactosyltransferase from Neisseria meningitides; galactokinase from Escherichia coli K-12; pyrophosphorylase from Bifidobacterium longum UDP-sugar; UTP; ATP; magnesium chloride In water at 37℃; pH=7.5; Enzymatic reaction; | 98% |
D-Galactose
(2,4,6-trichlorophenyl)hydrazine
N-(β-D-galactopyranosyl)-N'-(2,4,6-trichlorophenyl)hydrazine
Conditions | Yield |
---|---|
In ethanol for 1h; Heating; | 97% |
D-Galactose
Conditions | Yield |
---|---|
With galactokinase; pyruvate kinase; phosphoenolpyruvic acid monosodium salt; adenosine 5'-triphosphate disodium salt; magnesium chloride at 30℃; for 24h; Enzymatic reaction; | 97% |
With hydrogenchloride; Bifidobacterium infantis ATCC15697 galactokinase; ATP; 2-amino-2-hydroxymethyl-1,3-propanediol; magnesium chloride In water at 37℃; for 2h; pH=6.5; Enzymatic reaction; | 95.2% |
With galactokinase; ATP; magnesium chloride In phosphate buffer at 30℃; pH=7.5; Enzyme kinetics; | |
With galactokinase from bifidobacterium infantis ATCC 15675; ATP In water at 37℃; pH=8; aq. buffer; Enzymatic reaction; | |
With galactokinase immobilized onto PureCube Ni-IDA MagBeads; ATP; magnesium chloride In aq. buffer at 40℃; pH=7.5; Catalytic behavior; Kinetics; Temperature; pH-value; Flow reactor; Enzymatic reaction; |
Conditions | Yield |
---|---|
In methanol at 20 - 65℃; | 97% |
The CAS register number of D-Galactopyranose is 10257-28-0. It also can be called as D-Galactose and the systematic name about this chemical is D-galactopyranose. The molecular formula about this chemical is C6H12O6 and the molecular weight is 180.1559.
Physical properties about D-Galactopyranose are: (1)# of Rule of 5 Violations: 1; (2)ACD/BCF (pH 5.5): 1; (3)ACD/BCF (pH 7.4): 1; (4)ACD/KOC (pH 5.5): 1.053; (5)ACD/KOC (pH 7.4): 1.053; (6)#H bond acceptors: 6; (7)#H bond donors: 5; (8)#Freely Rotating Bonds: 6; (9)Polar Surface Area: 110.38Å2; (10)Index of Refraction: 1.635; (11)Molar Refractivity: 37.254 cm3; (12)Molar Volume: 104.015 cm3; (13)Polarizability: 14.769x10-24cm3; (14)Surface Tension: 81.751 dyne/cm; (15)Flash Point: 202.243 °C; (16)Enthalpy of Vaporization: 76.626 kJ/mol; (17)Boiling Point: 410.797 °C at 760 mmHg.
You can still convert the following datas into molecular structure:
(1)SMILES: C([C@@H]1[C@@H]([C@@H]([C@H](C(O1)O)O)O)O)O
(2)InChI: InChI=1/C6H12O6/c7-1-2-3(8)4(9)5(10)6(11)12-2/h2-11H,1H2/t2-,3+,4+,5-,6?/m1/s1
(3)InChIKey: WQZGKKKJIJFFOK-SVZMEOIVBA
(4)Std. InChI: InChI=1S/C6H12O6/c7-1-2-3(8)4(9)5(10)6(11)12-2/h2-11H,1H2/t2-,3+,4+,5-,6?/m1/s1
(5)Std. InChIKey: WQZGKKKJIJFFOK-SVZMEOIVSA-N
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