Ethyl furfuryl ether supplier

Name
2-(ETHOXYMETHYL)FURAN
EINECS 228-454-7
CAS No. 6270-56-0
Article Data27
CAS DataBase
Density 0.986 g/cm³
Solubility
Melting Point
Formula C₇H₁₀O₂
Boiling Point 136.5 °C at 760 mmHg
Molecular Weight 126.155
Flash Point 41.2 °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms 2-(Ethoxymethyl)furan;Ethyl furfuryl ether;Furfuryl ethyl ether;NSC 35558;
PSA 22.37000
LogP 1.81610

Synthetic route

: 98-00-0
(2-furyl)methyl alcohol

: 64-17-5
ethanol

: 6270-56-0
2-(ethoxymethyl)furan

Conditions

Conditions	Yield
With tin(IV) oxide at 200℃; for 20h; Temperature; Reagent/catalyst;	95%
With arenesulfonic acid and phenyl groups functionalized ethane bridged organosilica nanohybrid at 120℃; for 0.5h; Reagent/catalyst; Autoclave;
With Zr-mesoporous silica (SBA-15) at 100℃; for 5h;
With niobium pentoxide nanowires calcined at 100 ∘C at 100℃; under 6000.6 Torr; for 5h;

: 98-00-0
(2-furyl)methyl alcohol

: 64-17-5
ethanol

A: 6270-56-0
2-(ethoxymethyl)furan

B: 1446756-00-8
4,5,5-triethoxypentan-2-one

C: 539-88-8
4-oxopentanoic acid ethyl ester

Conditions

Conditions	Yield
at 110℃; for 2h; Temperature; Reagent/catalyst; Autoclave; Ionic liquid;	A n/a B n/a C 92%
With hydrothermally treated graphene oxide (GO-HT) at 120℃; for 6h; Autoclave;	A 38.8% B 11.7% C 39.7%

...Expand

: 98-00-0
(2-furyl)methyl alcohol

: 64-17-5
ethanol

A: 6270-56-0
2-(ethoxymethyl)furan

B: 539-88-8
4-oxopentanoic acid ethyl ester

Conditions

Conditions	Yield
With sulfonic acid-functionalized MIL-101(Cr) at 140℃; for 2h; Temperature; Reagent/catalyst; Autoclave;	A n/a B 79.2%
With hierarchical-HZ-5 at 99.84℃; for 4h; Catalytic behavior; Green chemistry;	A 26% B 73%
With hierarchical-HZ-5 at 99.84℃; for 4h; Catalytic behavior; Green chemistry;	A 49% B 41%

...Expand

: 13529-27-6
2-(diethoxymethyl)furan

A: 98-01-1
furfural

B: 6270-56-0
2-(ethoxymethyl)furan

C: 614-99-3
Ethyl 2-furoate

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In 1,2-dichloro-ethane at 0℃; for 0.25h;	A 19% B 54% C 15%
With boron trifluoride diethyl etherate In 1,2-dichloro-ethane at 0℃; for 0.25h; Mechanism;	A 19% B 54% C 15%
monoaluminum phosphate at 150℃; Product distribution; other catalysts ( γ-alumina, γ-aluminium sulphate), other temperatures, other (substituted) furaldehyde acetals;

...Expand

: 98-00-0
(2-furyl)methyl alcohol

: 64-17-5
ethanol

A: 6270-56-0
2-(ethoxymethyl)furan

B: 13529-27-6
2-(diethoxymethyl)furan

C: 539-88-8
4-oxopentanoic acid ethyl ester

Conditions

Conditions	Yield
With silica-supported nickel phosphide at 180℃; under 750.075 Torr; for 3h; Temperature; Inert atmosphere; Autoclave;	A 53.7% B 7.4% C 35.3%

...Expand

: 98-00-0
(2-furyl)methyl alcohol

: 64-17-5
ethanol

A: 6270-56-0
2-(ethoxymethyl)furan

B: 1446756-00-8
4,5,5-triethoxypentan-2-one

Conditions

Conditions	Yield
With graphene oxide at 80℃; for 6h; Autoclave;	A 22.2% B 12.3%

...Expand

: 617-88-9
2-Chloromethylfuran

: 64-17-5
ethanol

: 6270-56-0
2-(ethoxymethyl)furan

Conditions

Conditions	Yield
With potassium hydroxide; diethyl ether at 75 - 80℃;

: 117680-17-8
2-(Iodomethyl)tetrahydrofuran

: 64-17-5
ethanol

: 6270-56-0
2-(ethoxymethyl)furan

Conditions

Conditions	Yield
With potassium hydroxide; diethyl ether

: 98-00-0
(2-furyl)methyl alcohol

: 75-03-6
ethyl iodide

: 6270-56-0
2-(ethoxymethyl)furan

Conditions

Conditions	Yield
With potassium hydroxide

: 688-73-3
tri-n-butyl-tin hydride

: 81932-19-6
2-(furan-2-yl)-1,3-oxathiolane

A: 6270-56-0
2-(ethoxymethyl)furan

B: 127084-52-0
C19H36O2SSn

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In benzene Product distribution; Heating;

...Expand

: 98-00-0
(2-furyl)methyl alcohol

: 6270-56-0
2-(ethoxymethyl)furan

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: absolute diethyl ether; phosphorus triiodide 2: KOH-solution; diethyl ether View Scheme
Multi-step reaction with 2 steps 1: pyridine; diethyl ether; thionyl chloride 2: KOH-solution; diethyl ether / 75 - 80 °C View Scheme

: 98-01-1
furfural

: 64-17-5
ethanol

A: 110-00-9
furan

B: 534-22-5
2-methylfuran

C: 98-00-0
(2-furyl)methyl alcohol

D: 6270-56-0
2-(ethoxymethyl)furan

E: furan 2-(2-furanylmethyl)-5-methyl

Conditions

Conditions	Yield
With Ru/RuO2/C; hydrogen at 180℃; for 5h; Inert atmosphere;

...Expand

: 98-00-0
(2-furyl)methyl alcohol

: 64-17-5
ethanol

A: 6270-56-0
2-(ethoxymethyl)furan

B: 60-29-7
diethyl ether

C: 1446756-00-8
4,5,5-triethoxypentan-2-one

D: 539-88-8
4-oxopentanoic acid ethyl ester

Conditions

Conditions	Yield
With hierarchical-HZ-5 at 99.84℃; for 2h; Catalytic behavior; Green chemistry;

...Expand

: 98-00-0
(2-furyl)methyl alcohol

: 64-17-5
ethanol

A: 6270-56-0
2-(ethoxymethyl)furan

B: 4,5-diethoxy-5-hydroxypentan-2-one

C: 539-88-8
4-oxopentanoic acid ethyl ester

Conditions

Conditions	Yield
With 12.1PW12/ZrO2 bifunctionalized organosilica nanotubes at 120℃; Autoclave; High pressure;

...Expand

: 98-00-0
(2-furyl)methyl alcohol

: 64-17-5
ethanol

A: 591-11-7
5-methyl-5H-furan-2-one

B: 591-12-8
5-methyl-2-furanone

C: 6270-56-0
2-(ethoxymethyl)furan

D: 539-88-8
4-oxopentanoic acid ethyl ester

Conditions

Conditions	Yield
With zeolite H-beta at 110℃; for 1.5h; Autoclave;	A n/a B n/a C 14.4 %Chromat. D 23.3 %Chromat.

...Expand

: 98-01-1
furfural

: 64-17-5
ethanol

A: 98-00-0
(2-furyl)methyl alcohol

B: 6270-56-0
2-(ethoxymethyl)furan

Conditions

Conditions	Yield
With formic acid at 100℃; for 5h; Sealed tube;
With hydrogen at 60℃; under 2250.23 Torr; for 2h; Catalytic behavior; Pressure;

...Expand

: 98-01-1
furfural

: 64-17-5
ethanol

A: 96-47-9
2-methyltetrahydrofuran

B: 97-99-4
Tetrahydrofurfuryl alcohol

C: 98-00-0
(2-furyl)methyl alcohol

D: 6270-56-0
2-(ethoxymethyl)furan

E: 90755-37-6
2-(diethoxymethyl)tetrahydrofuran

Conditions

Conditions	Yield
With hydrogen at 80℃; under 3750.38 Torr; for 2h;

...Expand

: 98-01-1
furfural

: 64-17-5
ethanol

A: 97-99-4
Tetrahydrofurfuryl alcohol

B: 98-00-0
(2-furyl)methyl alcohol

C: 6270-56-0
2-(ethoxymethyl)furan

Conditions

Conditions	Yield
With hydrogen at 60℃; under 2250.23 Torr; for 2h; Reagent/catalyst;

...Expand

: 98-01-1
furfural

: 64-17-5
ethanol

A: 6270-56-0
2-(ethoxymethyl)furan

B: 13529-27-6
2-(diethoxymethyl)furan

Conditions

Conditions	Yield
With hydrogen at 60℃; under 750.075 Torr; for 2h;

...Expand

: 98-01-1
furfural

: 64-17-5
ethanol

A: 6270-56-0
2-(ethoxymethyl)furan

B: 13529-27-6
2-(diethoxymethyl)furan

C: 90755-37-6
2-(diethoxymethyl)tetrahydrofuran

Conditions

Conditions	Yield
With hydrogen at 60℃; under 2250.23 Torr; for 2h;

...Expand

: 98-01-1
furfural

: 64-17-5
ethanol

A: 98-00-0
(2-furyl)methyl alcohol

B: 6270-56-0
2-(ethoxymethyl)furan

C: 13529-27-6
2-(diethoxymethyl)furan

Conditions

Conditions	Yield
With hydrogen at 60℃; under 2250.23 Torr; for 2h; Reagent/catalyst; Temperature; Pressure;

...Expand

: 98-01-1
furfural

: 64-17-5
ethanol

A: 98-00-0
(2-furyl)methyl alcohol

B: 6270-56-0
2-(ethoxymethyl)furan

C: 90755-37-6
2-(diethoxymethyl)tetrahydrofuran

Conditions

Conditions	Yield
With hydrogen at 60℃; under 2250.23 Torr; for 2h;

...Expand

: 13529-27-6
2-(diethoxymethyl)furan

A: 98-00-0
(2-furyl)methyl alcohol

B: 6270-56-0
2-(ethoxymethyl)furan

C: 90755-37-6
2-(diethoxymethyl)tetrahydrofuran

Conditions

Conditions	Yield
With hydrogen In ethanol at 60℃; under 2250.23 Torr; for 2h;

...Expand

: 98-01-1
furfural

A: 6270-56-0
2-(ethoxymethyl)furan

B: 90755-37-6
2-(diethoxymethyl)tetrahydrofuran

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: hydrogen; / 2 h / 60 °C / 2250.23 Torr 2: hydrogen; / ethanol / 2 h / 60 °C / 2250.23 Torr View Scheme
Multi-step reaction with 2 steps 1: hydrogen; / 2 h / 60 °C / 750.08 Torr 2: hydrogen; / ethanol / 2 h / 60 °C / 2250.23 Torr View Scheme
Multi-step reaction with 2 steps 1: hydrogen; / 2 h / 60 °C / 2250.23 Torr 2: hydrogen; / ethanol / 2 h / 60 °C / 2250.23 Torr View Scheme
Multi-step reaction with 2 steps 1: hydrogen; / 2 h / 60 °C / 2250.23 Torr 2: hydrogen; / ethanol / 2 h / 60 °C / 2250.23 Torr View Scheme

: 98-00-0
(2-furyl)methyl alcohol

: 64-17-5
ethanol

A: 591-12-8
5-methyl-2-furanone

B: 6270-56-0
2-(ethoxymethyl)furan

C: 1197-40-6
2,2'-difurylmethane

D: 539-88-8
4-oxopentanoic acid ethyl ester

Conditions

Conditions	Yield
With niobium pentoxide nanowires calcined at 100 ∘C at 160℃; under 6000.6 Torr; for 5h; Temperature;

...Expand

: 98-00-0
(2-furyl)methyl alcohol

: 64-17-5
ethanol

A: 591-12-8
5-methyl-2-furanone

B: 6270-56-0
2-(ethoxymethyl)furan

Conditions

Conditions	Yield
With niobium pentoxide nanowires calcined at 100 ∘C at 120℃; under 6000.6 Torr; for 5h;

...Expand

: 6270-56-0
2-(ethoxymethyl)furan

: 98-01-1
furfural

Conditions

Conditions	Yield
With water; 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate In acetonitrile at 20℃; for 8h;	90%

: 6270-56-0
2-(ethoxymethyl)furan

: 762-42-5
dimethyl acetylenedicarboxylate

: dimethyl 4-(ethoxymethyl)-7-oxabicyclo [2.2.1] hepta-2,5-diene-2,3-dicarboxylate

Conditions

Conditions	Yield
In toluene at 100℃; for 16h; Sealed tube;	64%

: 6270-56-0
2-(ethoxymethyl)furan

: 71-36-3
butan-1-ol

: 2052-15-5
butyl levulinate

Conditions

Conditions	Yield
With bismuth(lll) trifluoromethanesulfonate In water at 117℃; for 2.75h; Concentration;	53%

: 6270-56-0
2-(ethoxymethyl)furan

: 50-00-0
formaldehyd

: 113983-97-4
(5-(ethoxymethyl)furan-2-yl)methanol

Conditions

Conditions	Yield
With acetic acid at 70 - 80℃; for 3h;	46%

: 6270-56-0
2-(ethoxymethyl)furan

: 762-42-5
dimethyl acetylenedicarboxylate

: dimethyl 3-(ethoxymethyl)-6-hydroxy-1,2-benzenedicarboxylate

Conditions

Conditions	Yield
Stage #1: dimethyl acetylenedicarboxylate With scandium tris(trifluoromethanesulfonate) In acetonitrile at 20℃; for 0.166667h; Stage #2: 2-(ethoxymethyl)furan In acetonitrile at 100℃; for 16h; Sealed tube;	32%

: 6270-56-0
2-(ethoxymethyl)furan

A: C7H9(2)HO2

B: C7H9(2)HO2

C: C7H9(2)HO2

Conditions

Conditions	Yield
With sodium methylate In deuteromethanol; toluene at 85℃; for 2h; Product distribution; Heating; other temperature;	A 5% B 16% C 27%

...Expand

: 6270-56-0
2-(ethoxymethyl)furan

: 75-77-4
chloro-trimethyl-silane

: 93271-55-7
2-ethoxymethyl-5-trimethylsilylfuran

Conditions

Conditions	Yield
With n-butyllithium 1)ether in ether,0 deg C, 5 min 2)trimethylchlorosilane, -70 deg C, 30 min 3)room temp. 30 min; Yield given. Multistep reaction;

: 6270-56-0
2-(ethoxymethyl)furan

: 6262-51-7
pentachlorocyclopropane

: 1160560-98-4
(1S*,5S*)-2,3,4,4-tetrachloro-1-ethoxymethyl-8-oxabicyclo-[3.2.1]octa-2,6-diene

Conditions

Conditions	Yield
Stage #1: pentachlorocyclopropane With potassium hydroxide In 1,4-dioxane at 20 - 65℃; for 1h; Stage #2: 2-(ethoxymethyl)furan In 1,4-dioxane at 85 - 90℃; for 16h;

: 6270-56-0
2-(ethoxymethyl)furan

: 1917-65-3
5-(ethoxymethyl)furfural

: 113983-97-4
(5-(ethoxymethyl)furan-2-yl)methanol

Conditions

Conditions	Yield
With hydrogen; Pd on active carbon
With hydrogen

: 108-31-6
maleic anhydride

: 6270-56-0
2-(ethoxymethyl)furan

: 1428945-27-0
1-ethoxymethyl-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride

Conditions

Conditions	Yield
at 20℃; for 36h;
In neat (no solvent) at 15 - 20℃; for 26h; Diels-Alder Cycloaddition;

: 6270-56-0
2-(ethoxymethyl)furan

: 3-(ethoxymethyl)phthalic acid disodium salt

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: 36 h / 20 °C 2.1: sodium methylate / methanol / 18 h / 0 - 20 °C 2.2: 5 h / Reflux View Scheme

: 6270-56-0
2-(ethoxymethyl)furan

: 569-51-7
benzene-1,2,3-tricarboxlic acid

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1.1: 36 h / 20 °C 2.1: sodium methylate / methanol / 18 h / 0 - 20 °C 2.2: 5 h / Reflux 3.1: potassium permanganate / water / 18 h / 20 °C View Scheme

: 6270-56-0
2-(ethoxymethyl)furan

: 67-63-0
isopropyl alcohol

A: 591-11-7
5-methyl-5H-furan-2-one

B: 591-12-8
5-methyl-2-furanone

C: 21884-26-4
isopropyl levulinate

D: 123-76-2
levulinic acid

Conditions

Conditions	Yield
With zeolite H-beta at 110℃; for 1.5h; Autoclave;	A n/a B n/a C 7.7 %Chromat. D 6.4 %Chromat.

...Expand

Ethyl furfuryl ether Specification

The Furan, 2-(ethoxymethyl)-, with the CAS registry number of 6270-56-0, is also known as Ethyl furfuryl ether. Its EINECS registry number is 228-454-7. This chemical's molecular formula is C₇H₁₀O₂ and molecular weight is 126.15. What's more, its IUPAC name is 2-(Ethoxymethyl)furan.

Physical properties about Furan, 2-(ethoxymethyl)- are: (1)ACD/LogP: 1.65; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.65; (4)ACD/LogD (pH 7.4): 1.65; (5)ACD/BCF (pH 5.5): 10.56; (6)ACD/BCF (pH 7.4): 10.56; (7)ACD/KOC (pH 5.5): 188.15; (8)ACD/KOC (pH 7.4): 188.15; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 22.37 Å²; (13)Index of Refraction: 1.451; (14)Molar Refractivity: 34.47 cm³; (15)Molar Volume: 127.9 cm³; (16)Polarizability: 13.66×10^-24 cm³; (17)Surface Tension: 29.1 dyne/cm; (18)Density: 0.986 g/cm³; (19)Flash Point: 41.2 °C; (20)Enthalpy of Vaporization: 35.85 kJ/mol; (21)Boiling Point: 136.5 °C at 760 mmHg; (22)Vapour Pressure: 9.11 mmHg at 25 °C.

Preparation: this chemical is prepared by Furfural-diethylacetal. The reaction needs reagent BF₃O(C₂H₅)₂ and solvent 1, 2-Dichloro-ethane. The reaction time is 15 minutes with reaction temperature of 0 °C. The yield is about 54 %.

Uses: it is used to produce other chemicals. For example, it is used to produce 5-Ethoxymethyl-furfuryl alcohol. This reaction needs reagent Acetic acid. Other condition of this reaction is reaction time of 3 hours at 70-80 °C. The yield is about 46 %.

You can still convert the following datas into molecular structure:
(1) SMILES: O(CC)Cc1occc1
(2) InChI: InChI=1/C7H10O2/c1-2-8-6-7-4-3-5-9-7/h3-5H,2,6H2,1H3
(3) InChIKey: BHGBNDNKYPEAAT-UHFFFAOYAB

Product Name

2-(ETHOXYMETHYL)FURAN

Synthetic route

Ethyl furfuryl ether Specification

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