Formic acid, zinc salt(2:1) supplier

Name
ZINC FORMATE
EINECS 209-176-5
CAS No. 557-41-5
Article Data29
CAS DataBase
Density 2.21 g/cm³
Solubility soluble in water
Melting Point >250°C (dec.)
Formula C₂H₂O₄Zn
Boiling Point 100.6 °C at 760 mmHg
Molecular Weight 155.425
Flash Point 29.9 °C
Transport Information
Appearance white crystalline solid
Safety 26-36/37/39
Risk Codes 20/21/22
Molecular Structure
Hazard Symbols
Synonyms Formicacid, zinc salt (8CI,9CI);Zinc formate (6CI,7CI);Zinc diformate;
PSA 52.60000
LogP 0.51670

Synthetic route

: 64-18-6
formic acid

: 743369-26-8
zinc(II) carbonate

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
In water for 2h; Reflux;	90%
In not given prepn. from ZnCO3 and carboxylic acid in molar ratio 1:2;
In water prepn. by adding 2 mol/L formic acid to freshly pptd. metal carbonate;
In water at 100℃; for 3h;

: 21790-68-1
Zn(NH3)2(OH)2

: 201230-82-2
carbon monoxide

: 7732-18-5
water

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
In water on react. of Zn(NH3)2(OH)2, water, CO at 160°C and 20atm;;	12.5%
In water on react. of Zn(NH3)2(OH)2, water, CO at 160°C and 20atm;;	12.5%

...Expand

: 201230-82-2
carbon monoxide

: 7732-18-5
water

: zinc(II) hydroxide

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
In water on react. of Zn(OH)2, water, CO at 160°C and 20atm;;	3.5%
In water on react. of Zn(OH)2, water, CO at 160°C and 20atm;;	3.5%

...Expand

: 201230-82-2
carbon monoxide

: 7732-18-5
water

: zinc(II) oxide

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
In water on react. of ZnO, water, CO at 160°C and 20atm;;	1.4%
In water on react. of ZnO, water, CO at 160°C and 20atm;;	1.4%

...Expand

: 544-17-2
calcium diformate

: 557-41-5
zinc(II) formate

: 64-18-6
formic acid

: zinc(II) oxide

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
In water at 110 - 120℃; for 0.0833333 - 0.333333h; Product distribution / selectivity;
In not given reacting of the oxide with the corresponding amt. of the acid;

: 64-18-6
formic acid

: 583-91-5
2-hydroxy 4-methylthiobutyric acid

: zinc(II) oxide

A: DL-2-hydroxy-4-methylsulfanylbutanoate zinc salt

B: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
In water at 20 - 70℃; for 0.333333 - 1.16667h; Product distribution / selectivity;

...Expand

: 64-18-6
formic acid

: 7646-85-7
zinc(II) chloride

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
on slow react. with anhyd. HCOOH;;
on slow react. with anhyd. HCOOH;;

: 743369-26-8
zinc(II) carbonate

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
With formic acid In formic acid metal carbonate dissoln. in formic acid; recrystn. twice;

: 5970-62-7, 14519-97-2, 16788-41-3, 88242-86-8
zinc(II) formate dihydrate

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
Kinetics; byproducts: H2O; 95-115°C; IR;
In solid Kinetics; byproducts: H2O; dehydration under 5E-4 to 6.0 torr water vapour pressure at 70-100°C to amorphous or cryst. zinc formate; detn. by X-ray powder diffraction;
In neat (no solvent) byproducts: H2O; on heating at 140°C;;

: 107-31-3
Methyl formate

: 557-34-6
zinc diacetate

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: methyl acetate; autoclave, presence of phenol, 448-453 K, 6 MPa, 3 h; GC analysis;

: 107-31-3
Methyl formate

: 553-72-0
zinc benzoate

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: methyl benzoate; autoclave, presence of phenol, 448-453 K, 6 MPa, 3 h; GC analysis;

: 7440-66-6
zinc

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
on drying of lacs on Zn metal;;
on drying of lacs on Zn metal;;

: 544-17-2
calcium diformate

: 7733-02-0
zinc(II) sulfate

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
In water on filtration of CaSO4 from soln. and treating soln. with Ba formate and oxalic acid (for removing of small amt. of CaSO4 and ZnSO4 impurities);;
In water on filtration of CaSO4 from soln. and treating soln. with Ba formate and oxalic acid (for removing of small amt. of CaSO4 and ZnSO4 impurities);;

: zinc(II) nitrate hexahydrate

: 141-53-7
sodium formate

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
In water Kinetics; dissolving both components in distilled water; stoichiometric concentrations: Zn 0.1 - 0.8 M, formate 0.1 - 0.4 M; pH of solution from 4 to 6;; ultrasonic absorptions spectra;;

: 64-18-6
formic acid

: hydrozincite

: 557-41-5
zinc(II) formate

Conditions

Conditions	Yield
With In2O3 In neat (no solvent) byproducts: In(HCOO)3; HCOOH added to a mixt. of In and Zn compd., heated at 80°C; cooled to room temp., filtered, washed (THF), dried under aspiration; obtained as a mixt.;

: 557-41-5
zinc(II) formate

: zinc(II) oxide

Conditions

Conditions	Yield
With water In neat (no solvent) on cautious heating of Zn formate at 250°C in a dry stream of vapor (CO2, H2, N2, CO, air) with larger amt. of H2O in the stream, following react. is proceeding: Zn(HCOO)2 + H2O = ZnO + CO2 + H2;;	90%
With H2O In neat (no solvent) on cautious heating of Zn formate at 250°C in a dry stream of vapor (CO2, H2, N2, CO, air) with larger amt. of H2O in the stream, following react. is proceeding: Zn(HCOO)2 + H2O = ZnO + CO2 + H2;;	90%
In solid thermal decomposition of Zn(HCO2)2 in an air atmosphere;

: triphenyltin molybdate

: 64-17-5
ethanol

: 557-41-5
zinc(II) formate

: 107-15-3
ethylenediamine

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 2C2H8N2*Cu(2+)*2C18H15Sn(1+)*2MoO4(2-)*2C3H7NO*C2H6O

Conditions

Conditions	Yield
for 168h;	81%

...Expand

: 65344-26-5
4-Iododibenzo-[b,d]furan

: 557-41-5
zinc(II) formate

: 51412-72-7
dibenzo-[b,d]furan-4-carbonitrile

Conditions

Conditions	Yield
In hexane	68.8%

0.5% Pd/Al2O3: 0.5% Pd/Al2O3

: 557-41-5
zinc(II) formate

Reaxys ID: 11360997: Reaxys ID: 11360997

Conditions

Conditions	Yield
at 150 - 300℃; for 2h;

: 64-18-6
formic acid

: 876-53-9
1,3-dibromoadamantane

: 557-41-5
zinc(II) formate

A: 869627-12-3
3-bromo-1-formyloxyadamantane

B: 869627-11-2
1,3-diformyloxyadamantane

C: 17933-29-8
7-methylenebicyclo[3.3.1]nonan-3-one

Conditions

Conditions	Yield
Product distribution / selectivity;

...Expand

: 64-18-6
formic acid

: 16104-50-0
1,3-dichloroadamantane

: 557-41-5
zinc(II) formate

A: 869627-10-1
3-chloro-1-formyloxyadamantane

B: 869627-11-2
1,3-diformyloxyadamantane

C: 17933-29-8
7-methylenebicyclo[3.3.1]nonan-3-one

Conditions

Conditions	Yield
Product distribution / selectivity;

...Expand

: sodium azide

: 557-41-5
zinc(II) formate

: Na(1+)*Zn(2+)*2HCO2(1-)*N3(1-)=Na{Zn(HCOO)2N3}

Conditions

Conditions	Yield
In methanol
In methanol

: 7732-18-5
water

: 541-43-5
barium formate

: 557-41-5
zinc(II) formate

: barium zinc formate tetrahydrate

Conditions

Conditions	Yield
In not given crystg. from soln. of Ba and Zn formate;;
In not given formation in solutions containing Zn(HCO2)2 and Ba(HCO2)2;;
In not given crystg. from soln. of Ba and Zn formate;;
In not given formation in solutions containing Zn(HCO2)2 and Ba(HCO2)2;;

...Expand

: 557-41-5
zinc(II) formate

: 50-00-0
formaldehyd

Conditions

Conditions	Yield
In neat (no solvent) byproducts: methanol, methyl formate; on cautious heating of Zn formate at 250°C in a dry stream of vapor (CO2, H2, N2, CO, air), formation of formaldehyde (probably primary product), methanol and methyl formate (untill 40% yield );;
In neat (no solvent) byproducts: methanol, methyl formate; on cautious heating of Zn formate at 250°C in a dry stream of vapor (CO2, H2, N2, CO, air), formation of formaldehyde (probably primary product), methanol and methyl formate (untill 40% yield );;
byproducts: methyl formate; at 180°C;;

: 557-41-5
zinc(II) formate

A: 107-31-3
Methyl formate

B: 124-38-9
carbon dioxide

C: 201230-82-2
carbon monoxide

D: 7440-44-0
pyrographite

E: zinc(II) oxide

Conditions

Conditions	Yield
In solid thermal decomposition of Zn(HCO2)2 under N2 at 200-250°C; detd. by XRD and IR;

...Expand

: 557-41-5
zinc(II) formate

: zinc(II) hydroxide

Conditions

Conditions	Yield
With sodium hydroxide In sodium hydroxide equilibration (isomolar components concn. (0.246 M), NaOH>=66.7 mol-%, (20+/-0.05)°C); monitoring by refractive index of liquid phase;

: 557-41-5
zinc(II) formate

: 15959-26-9
dithionic acid

Conditions

Conditions	Yield
With SO2 In water
With sulfur dioxide In water

: 557-41-5
zinc(II) formate

: 5Zn(2+)*8OH(1-)*2HCOO(1-)=Zn5(OH)8(HCOO)2

Conditions

Conditions	Yield
With sodium hydroxide In sodium hydroxide equilibration (isomolar components concn. (0.246 M), up to 60 mol-% NaOH, (20+/-0.05)°C), pptn.; monitoring by refractive index of liquid phase;

: 557-41-5
zinc(II) formate

: 547-68-2
zinc(II) oxalate

Conditions

Conditions	Yield
sodium amide at temp. below melting point of amid, violent react.;;
sodium amide on heating at 200°C;;
sodium amide at temp. below melting point of amid, violent react.;;
sodium amide on heating at 200°C;;

Formic acid, zinc salt(2:1) Specification

This chemical is called Formic acid, zinc salt(2:1), and its IUPAC name is zinc diformate. With the molecular formula of C₂H₂O₄Zn, its product category is Metal Organic. The CAS registry number of this chemical is 557-41-5. In addition, this chemical should be sealed in the cool and dry place. Its superlist classification code is Reportable Quantity (RQ) = 1000 lb.

Other characteristics of the Formic acid, zinc salt(2:1) can be summarised as followings: (1)ACD/LogP: -0.54; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -2.3; (4)ACD/LogD (pH 7.4): -3.94; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 37.3 Å²; (13)Flash Point: 29.9 °C; (14)Enthalpy of Vaporization: 22.69 kJ/mol; (15)Boiling Point: 100.6 °C at 760 mmHg; (16)Vapour Pressure: 36.5 mmHg at 25°C.

Synthesis of this chemcial: Pure zinc carbonate is batches added to the excess 90 % formic acid with slightly hot, so that the resulting carbon dioxide can escape. Filtered and heated at 140 °C to constant weight, the product could be obtained.

Uses of this chemical: The Formic acid, zinc salt(2:1) is used as a catalyst in chemical processing and as a waterproofing agent. It's also use as catalysts for the transesterification reaction and crosslinking reaction.

When you are using this chemical, please be cautious about it as the following: This chemical is harmful to eyes, respiratory system, skin or if swallowed. It may cause corneal opacity, iritis and conjunctivitis. You should wear suitable protective clothing if you use it. In case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
1.SMILES: [Zn+2].[O-]C=O.[O-]C=O
2.InChI: InChI=1/2CH2O2.Zn/c2*2-1-3;/h2*1H,(H,2,3);/q;;+2/p-2
3.InChIKey: XOBMCBQSUCOAOC-NUQVWONBAK

Product Name

ZINC FORMATE

Synthetic route

Formic acid, zinc salt(2:1) Specification

Related Products

Hot Products