CAS No.7440-66-6,Zinc Suppliers,MSDS download

: 143-66-8
sodium tetraphenyl borate

: 13395-16-9
copper(II) acetylacetonate

: 14024-63-6
zinc(II) acetylacetonate

A: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

B: 7440-66-6
zinc

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratios NaBPh4 : Zn(acac)2 : Cu(acac)2 = 20 : 7 : 3; irradn. (254 nm) for 18 h gave deposition only of Cu;	A 100% B 0%

...Expand

: 143-66-8
sodium tetraphenyl borate

: zinc(II) iodide

: 7440-66-6
zinc

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratio NaBPh4 : ZnI2 = 2 : 1; irradn. (254 nm) for 2 h gave deposition of Zn; deposit sepd., washed with acetone and water, and dried in vac. to give pure Zn;	100%

: 143-66-8
sodium tetraphenyl borate

: zinc dibromide

: 7440-66-6
zinc

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratio NaBPh4 : ZnBr2 = 2 : 1; irradn. (254 nm) for 4 h gave deposition of Zn; deposit sepd., washed with acetone and water, and dried in vac. to give pure Zn;	99%

: [ZnBr(Si(SiMe3)3)(THF)]2

A: 5089-31-6
tris(trimethylsilyl)silyl bromide

B: 7440-66-6
zinc

Conditions

Conditions	Yield
at 225℃; for 4h; Inert atmosphere;	A 93 %Spectr. B 99%
at 225℃; for 4h;	A 77 %Spectr. B n/a

: [ZnI(Si(SiMe3)3)(THF)]2

A: 26245-35-2
Tris(trimethylsilyl)iodsilan

B: 7440-66-6
zinc

Conditions

Conditions	Yield
at 250℃; for 4h; Inert atmosphere;	A 94 %Spectr. B 99%

: willemite

: 7440-66-6
zinc

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) redn. on react. with excess C (beech-wood coal, 400% excess) in hard porcelain tube in a stream of N2 at 995°C after 240min;;	98.4%
With C In neat (no solvent) redn. on react. with excess C (beech-wood coal, 400% excess) in hard porcelain tube in a stream of N2 at 995°C after 240min;;	98.4%
With pyrographite In neat (no solvent) redn. on react. with excess C (beech-wood coal, 400% excess) in hard porcelain tube in a stream of N2 at 920°C after 180min;;	97.7%

: lithium tetra-tert-butoxytitanate * THF

: 7646-85-7
zinc(II) chloride

A: titanium(IV) tetrabutoxide

B: 7440-66-6
zinc

Conditions

Conditions	Yield
In tetrahydrofuran Ar atmosphere; mixing of solns. (-78°C), warming to 20°C (stirring), pptn.; collection of pptd. Zn (filtn.), solvent removal, distn.;	A 79.8% B 97%

...Expand

: 562810-64-4
[ZnCl(Si(SiMe3)3)(THF)]2

A: 5565-32-2
chlorotris(trimethylsilyl)silane

B: 7440-66-6
zinc

Conditions

Conditions	Yield
at 210℃; for 4h; Inert atmosphere;	A 91 %Spectr. B 96%

: zinc(II) sulfide

: 75-20-7
calcium carbide

A: calcium(II) sulfide

B: 7440-66-6
zinc

Conditions

Conditions	Yield
sodium chloride In neat (no solvent) atm. pressure (inert gas), 800°C;; pure Zn;;	A n/a B 95%
sodium chloride In neat (no solvent) begin of reaction in vac. or H2 atmosphere at 700-800°C, fast reaction between 800-900°C;; pure Zn;;

...Expand

: zinc(II) oxide

: 7440-66-6
zinc

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) redn. in electric furnace without fusion of residues;; whole yield;;	92.6%
With C In neat (no solvent) redn. in electric furnace without fusion of residues;; whole yield;;	92.6%
With sodium hydroxide; sodium cyanide In not given Electrolysis; electrolytical deposition of zinc from soln. of alkali cyanide; bath composition (in g/l): 45 ZnO, 100 NaCN, 38 NaOH, 7 MoO3; deposition conditions: 161 - 753 A/m*m;;

: 91-22-5
quinoline

: 29777-16-0
2-methyl-2-propenylzinc bromide

A: zinc dibromide

B: 7440-66-6
zinc

C: 4-(2-methylallyl)quinoline

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: H2; the mixt. was refluxed at 65°C for 6 h, cooled to 0°C; filtered;	A n/a B n/a C 90%

...Expand

: 7646-85-7
zinc(II) chloride

: 7440-66-6
zinc

Conditions

Conditions	Yield
In melt Electrolysis;	84%
Stage #1: zinc(II) chloride With thionyl chloride Heating; Stage #2: With naphthalene; lithium; Benzo[b]thiophene In tetrahydrofuran for 1h;	46%
With magnesium In diethyl ether byproducts: etherate of ZnCl2; on react. of Mg with anhyd. ZnCl2 at low temp., redn.;;	34.8%

: 143-66-8
sodium tetraphenyl borate

: 14024-63-6
zinc(II) acetylacetonate

: 7440-66-6
zinc

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratio NaBPh4 : Zn(acac)2 = 2 : 1; irradn. (254 nm) for 4 h gave deposition of Zn; deposit sepd., washed with acetone and water, and dried in vac. to give pure Zn;	80%

: 143-66-8
sodium tetraphenyl borate

: zinc(II) iodide

: 7789-45-9
copper(ll) bromide

A: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

B: 7440-66-6
zinc

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratios NaBPh4 : ZnI2 : CuBr2 = 8 : 1 : 3; irradn. (254 nm) for 8 h gave deposition of Zn and Cu; examn. of the Zn-Cu powder by ESCA measurement showed that more than 60% of the sample consisted of a Zn-Cu alloy and that the balance of the particles were Zn and Cu metals;	A 74% B 24%

...Expand

: zinc dibromide

: 7440-66-6
zinc

Conditions

Conditions	Yield
With magnesium In diethyl ether redn. in abs. ether soln. by Mg at room temp.;;	43%
With Mg In diethyl ether redn. in abs. ether soln. by Mg at room temp.;;	43%
With lithium In tetrahydrofuran Sonication; reduction with Li powder and ultrasound at room temp. in THF, reduction was complete within 40 min; workup was performed in air;

: 15658-08-9
dicyclohexylzinc(II)

: 7440-66-6
zinc

Conditions

Conditions	Yield
With water In further solvent(s) (Ar); heating a soln. of zinc compd. in anisole contg. traces of water at 130°C in a Fischer-Porter bottle for 3 h; filtration, washing with anisole, drying in vac.;	30%
With water; polyvinylpyrrolidone In further solvent(s) (Ar); heating a soln. of zinc compd. in anisole contg. traces of water at 130°C in a Fischer-Porter bottle for 3 h; filtration, washing with anisole, drying in vac.;	30%

: zinc(II) sulfate heptahydrate

: 7440-66-6
zinc

Conditions

Conditions	Yield
In not given Electrolysis; Zn deposition from solution of ZnSO47H2O and thiosulfate; bath composition (in g/l): 60 ZnSO47H2O, 200 Na2S2O35H2O, 25 - 50 NH4Cl or 120 ZnSO47H2O, 400 Na2S2O35H2O, 25 - 50 NH4Cl, 75°C, 1 - 2 A/dmdm, Fe cathode, Zn anode;;	3%
In not given Electrolysis; Zn deposition from solution of ZnSO47H2O and thiosulfate; bath composition (in g/l): 60 ZnSO47H2O, 200 Na2S2O35H2O, 25 - 50 NH4Cl or 120 ZnSO47H2O, 400 Na2S2O35H2O, 25 - 50 NH4Cl, 75°C, 1 - 2 A/dmdm, Fe cathode, Zn anode;;	3%
In not given Electrolysis; Zn deposition from acidic ZnSO4 soln.; bath composition (g/l): 400 ZnSO4*7H2O, 70 K-Al-sulfate, 24 MgSO4, 20 H3BO3, pH = 3.9, 25 °C;;

: 6Zn(H2NC2H4NH2)3(2+)*Cu5(CN)17(12-)*8.4H2O=[Zn(H2NC2H4NH2)3]6[Cu5(CN)17]*8.4H2O

A: 20654-08-4
zinc(II) cyanimide

B: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

C: 7440-66-6
zinc

Conditions

Conditions	Yield
In neat (no solvent) sample heating at 4 K/min in Ar to 900°C, temp. keeping for 3 h; XRD;	A n/a B n/a C 1%

...Expand

: zinc(II) oxide

A: 80937-33-3
oxygen

B: 7440-66-6
zinc

: zinc ferrite

A: 7439-89-6
iron

B: 7440-66-6
zinc

Conditions

Conditions	Yield
With H2 In neat (no solvent) sample heating in TG apparatus in 25% H2/He (50 ml/min) at 5 K/min up to800°C; TG;

: zinc ferrite

: 7440-66-6
zinc

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) Kinetics; redn. of ZnO at 1050°C;;
With carbon monoxide; pyrographite redn.;;
With anthracite In neat (no solvent) byproducts: CO, CO2; redn.;;	>99

: Zn(ClO4)2·2H2O

: 7440-66-6
zinc

Conditions

Conditions	Yield
In further solvent(s) Electrolysis; electrolysis of soln. of Zn(CLO4)2*2H2O in monoethylether of ethylen glycole, no deposition of Zn at Cu cathode; generation of gas at anode and cathode;;	0%
In further solvent(s) Electrolysis; electrolysis of soln. of Zn(CLO4)2*2H2O in monoethylether of ethylen glycole, no deposition of Zn at Cu cathode; generation of gas at anode and cathode;;	0%

: zinc pyrophosphate

: 7440-66-6
zinc

Conditions

Conditions	Yield
With K4P2O7; KNO3 In water Electrochem. Process; deposited on electrode; not isolated;

: iron(III) oxide

: 7440-44-0
pyrographite

: zinc sulfide

A: 75-15-0
carbon disulfide

B: 201230-82-2
carbon monoxide

C: 7439-89-6
iron

D: 7440-66-6
zinc

Conditions

Conditions	Yield
technical prepartion of Zn, effect of presence of iron;;

...Expand

: iron(III) oxide

: 7440-44-0
pyrographite

: zinc sulfide

A: iron sulfide

B: 201230-82-2
carbon monoxide

C: 7440-66-6
zinc

Conditions

Conditions	Yield
direct smelting of sulfide ores, smelting of zinc blende with iron ore and coal;;

...Expand

: 557-21-1
zinc(II) cyanide

: 7440-66-6
zinc

Conditions

Conditions	Yield
In further solvent(s) Electrolysis; electrolysis of soln. of 0.117g Zn(CN)2 / 10 g acetamide at 100°C and 0.05 A/cm*cm; Cu cathode, Pt anode, stirred soln.; at some positions of cathode deposition of Zn; on addn. of 1 ml H2O to soln., excellent deposit;;
With sodium hydroxide; sodium cyanide; sodium carbonate In water Electrolysis; from aq. soln. of Zn(CN)2, NaCN, NaOH, Na2CO3, NaF, dextrose, gum arabic; temp. lower than 35°C; current density lower 8.6 A/dm**2; Mg cathode; then heating to 257-427°C for 1-4 min;; pptn. on Mg;;
With sodium hydroxide; sodium cyanide In not given Electrolysis; zinc plating from cyanide soln. of different compositions (Zn(CN)2, NaOH, NaCN in alternating ratio), current density of 1.5 - 4 A/dm*dm; Zn casting anode with addn. of Al, Hg; steel cathode; structure of deposits;;

: 557-21-1
zinc(II) cyanide

: 7440-23-5
sodium

A: Zn4Na

B: 7440-66-6
zinc

Conditions

Conditions	Yield
In ammonia
In ammonia NH3 (liquid);

...Expand

: 80937-33-3
oxygen

: 7440-66-6
zinc

: zinc(II) oxide

Conditions

Conditions	Yield
In neat (no solvent) Zn films, obtained on corroded or polished Cu base by vapor metallizing, are showing no changing of positions of electron interferences on heating in vacuum; between 250 - 440°C, oxidation of Zn to ZnO completely;;	100%
In neat (no solvent) Zn films, obtained on corroded or polished Cu base by vapor metallizing, are showing no changing of positions of electron interferences on heating in vacuum; between 250 - 440°C, oxidation of Zn to ZnO completely;;	100%
With air; NH4NH3 In neat (no solvent, gas phase) Zn, NH4NH3 (0-18 wt.%) mixed; pressed; placed into reactor; combustion react. ignited in air by heating for several s up to 1850°C; powerturned off after ignition; O2 available in closed chamber approx. 3 tim es; SEM; TEM; XRD;	90%

: 189207-85-0
3,3,5-trimethyl-6-ethoxycarbonyl-8-chlorothiochroman-4-one-1,1-dioxide

: 7440-66-6
zinc

: 3,3,5-trimethyl-4-hydroxy-6-carboxythiochroman-1,1-dioxide

Conditions

Conditions	Yield
With hydrogenchloride; sodium hydroxide In ethanol; water	100%

: 2042-37-7
o-cyanobromobenzene

: 7440-66-6
zinc

A: 4341-02-0
biphenyl-2,2'-dicarbonitrile

B: 100-47-0
benzonitrile

C: 131379-17-4
2-cyanophenylzinc bromide

Conditions

Conditions	Yield
With trifluoroacetic acid; cobalt(II) bromide; zinc dibromide In acetonitrile the mixt. in CH3CN was stirred at room temp., then arylbromide was added, stirred at room temp.; GC analysis;	A 0% B 0% C 100%

...Expand

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: 639-58-7
triphenyltin chloride

: 7440-66-6
zinc

: Ph3SnZnCl * N,N,N',N'-tetramethylethylenediamine

Conditions

Conditions	Yield
In acetonitrile; benzene Electrolysis; absence of oxygen and moisture; W-cathode, Zn suspended on Pt-anode, 30 V, 25 mA, 3.0 h, Et4NClO4 electrolyte; sepn. of pptd. product (further crop on addn. of petroleum ether), washing (petroleum ether), drying (vac.); elem. anal.;	100%

...Expand

: 7647-01-0
hydrogenchloride

: tungstic acid

: 7440-66-6
zinc

: 13470-13-8
tungsten(IV) chloride

Conditions

Conditions	Yield
strong HCl;	100%
strong HCl;	100%

...Expand

: 91-15-6
phthalonitrile

: 7440-66-6
zinc

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
With sodium methylate In methanol Sonication; Zn added to a methanol soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30% soln of CH3ONa in methanol; flask put into an ultrasonic cleaner and maintained at 50°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97%; elem. anal.;	100%
With sodium methylate In further solvent(s) Sonication; Zn added to an 1-octanol soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30% soln of CH3ONa in methanol; flask put intoan ultrasonic cleaner and maintained at 50°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97%; elem. anal.;	100%
With sodium methylate In methanol Sonication; Zn added to a methanol soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30% soln of CH3ONa in methanol; flask put into an ultrasonic cleaner and maintained at 40°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97%; elem. anal.;	85%

: 109-80-8
1.3-propanedithiol

: 7440-66-6
zinc

: 16526-94-6
Zn(S2C3H6-1,3)

Conditions

Conditions	Yield
In acetonitrile byproducts: H2; Electrolysis; electrochemical cell with a platinum cathode and a Zn-anode attached to a platinum wire, in presence of Et4NClO4, N2 bubbled slowly through the soln., reaction time: 2.5 h, 10 V; filtered, washed with CH3CN, dried in vac.; elem. anal.;	100%

: 4532-64-3
butane-2,3-dithiol

: 7440-66-6
zinc

: 116271-09-1
Zn(S2C4H8-2,3)

Conditions

Conditions	Yield
In acetonitrile byproducts: H2; Electrolysis; electrochemical cell with a platinum cathode and a Zn-anode attached to a platinum wire, in presence of Et4NClO4, N2 bubbled slowly through the soln., reaction time: 3.5 h, 10 V; filtered, washed with CH3CN, dried in vac.; elem. anal.;	100%

: 1191-08-8
1,4-Butanedithiol

: 7440-66-6
zinc

: Zn(S2C4H8-1,4)

Conditions

Conditions	Yield
In acetonitrile byproducts: H2; Electrolysis; electrochemical cell with a platinum cathode and a Zn-anode attached to a platinum wire, in presence of Et4NClO4, N2 bubbled slowly through the soln., reaction time: 2.5 h, 10 V; filtered, washed with CH3CN, dried in vac.; elem. anal.;	100%

: 1191-43-1
1,6-dimercaptohexane

: 7440-66-6
zinc

: Zn(S2C6H12-1,6)

Conditions

Conditions	Yield
In acetonitrile byproducts: H2; Electrolysis; electrochemical cell with a platinum cathode and a Zn-anode attached to a platinum wire, in presence of Et4NClO4, N2 bubbled slowly through the soln., reaction time: 3 h, 10 V; filtered, washed with CH3CN, dried in vac.; elem. anal.;	100%

: (CH3CO2)2Sn(CH2CH2CO2(C4H9))2

: 7440-66-6
zinc

: 72305-70-5
tetra(2-n-butoxycarbonylethyl)tin

Conditions

Conditions	Yield
In toluene powdered Zn adding to Sn deriv. in toluene under N2, refluxing for 8 h, cooling to room temp., filtering, filtrate washing with H2O, drying over MgSO4 and concg.; identified by NMR spectrum;	100%

: 111-24-0
1,5-dibromo-pentane

: 7440-66-6
zinc

: pentamethylenebis(zinc bromide)

Conditions

Conditions	Yield
In tetrahydrofuran Br(CH2)5Br was added to Zn powder in THF in a sealed and evacuated glass apparatus, mixt. was stirred for 5 h at 65°C; detd. by titrn.;	100%

: (Cu(C(N2C4H10)2C(NH2CH2CONCH2CH2)2))(4+)*4Cl(1-)*5H2O=(Cu(C(N2C4H10)2C(NH2CH2CONCH2CH2)2))Cl4*5H2O

: 7440-66-6
zinc

: (Zn(C(N2C4H10)2C(NH2CH2CONCH2CH2)2))(4+)*ZnCl4(2-)*2Cl(1-)*H2O=(Zn(C(N2C4H10)2C(NH2CH2CONCH2CH2)2))(ZnCl4)Cl2*H2O

Conditions

Conditions	Yield
In water excess Zn dust was added to aq. soln. copper complex ad stitrred for 30 min; excess of Zn was filtered off, soln. was evapd., residue was crystd. from water/EtOH; elem. anal.;	100%

: 143-66-8
sodium tetraphenyl borate

: 13395-16-9
copper(II) acetylacetonate

: 14024-63-6
zinc(II) acetylacetonate

A: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

B: 7440-66-6
zinc

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratios NaBPh4 : Zn(acac)2 : Cu(acac)2 = 20 : 7 : 3; irradn. (254 nm) for 18 h gave deposition only of Cu;	A 100% B 0%

...Expand

: 143-66-8
sodium tetraphenyl borate

: zinc(II) iodide

: 7440-66-6
zinc

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratio NaBPh4 : ZnI2 = 2 : 1; irradn. (254 nm) for 2 h gave deposition of Zn; deposit sepd., washed with acetone and water, and dried in vac. to give pure Zn;	100%

: 143-66-8
sodium tetraphenyl borate

: zinc dibromide

: 7440-66-6
zinc

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratio NaBPh4 : ZnBr2 = 2 : 1; irradn. (254 nm) for 4 h gave deposition of Zn; deposit sepd., washed with acetone and water, and dried in vac. to give pure Zn;	99%

: [ZnBr(Si(SiMe3)3)(THF)]2

A: 5089-31-6
2-bromo-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane

B: 7440-66-6
zinc

Conditions

Conditions	Yield
at 225℃; for 4h; Inert atmosphere;	A 93 %Spectr. B 99%
at 225℃; for 4h;	A 77 %Spectr. B n/a

: [ZnI(Si(SiMe3)3)(THF)]2

A: 26245-35-2
tris(trimethylsilyl)iodosilane

B: 7440-66-6
zinc

Conditions

Conditions	Yield
at 250℃; for 4h; Inert atmosphere;	A 94 %Spectr. B 99%

: willemite

: 7440-66-6
zinc

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) redn. on react. with excess C (beech-wood coal, 400% excess) in hard porcelain tube in a stream of N2 at 995°C after 240min;;	98.4%
With C In neat (no solvent) redn. on react. with excess C (beech-wood coal, 400% excess) in hard porcelain tube in a stream of N2 at 995°C after 240min;;	98.4%
With pyrographite In neat (no solvent) redn. on react. with excess C (beech-wood coal, 400% excess) in hard porcelain tube in a stream of N2 at 920°C after 180min;;	97.7%

: lithium tetra-tert-butoxytitanate * THF

: 7646-85-7
zinc(II) chloride

A: titanium(IV) tetrabutoxide

B: 7440-66-6
zinc

Conditions

Conditions	Yield
In tetrahydrofuran Ar atmosphere; mixing of solns. (-78°C), warming to 20°C (stirring), pptn.; collection of pptd. Zn (filtn.), solvent removal, distn.;	A 79.8% B 97%

...Expand

: 562810-64-4
[ZnCl(Si(SiMe3)3)(THF)]2

A: 5565-32-2
chlorotris(trimethylsilyl)silane

B: 7440-66-6
zinc

Conditions

Conditions	Yield
at 210℃; for 4h; Inert atmosphere;	A 91 %Spectr. B 96%

: zinc(II) sulfide

: 75-20-7
calcium carbide

A: calcium(II) sulfide

B: 7440-66-6
zinc

Conditions

Conditions	Yield
sodium chloride In neat (no solvent) atm. pressure (inert gas), 800°C;; pure Zn;;	A n/a B 95%
sodium chloride In neat (no solvent) begin of reaction in vac. or H2 atmosphere at 700-800°C, fast reaction between 800-900°C;; pure Zn;;

...Expand

: zinc(II) oxide

: 7440-66-6
zinc

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) redn. in electric furnace without fusion of residues;; whole yield;;	92.6%
With C In neat (no solvent) redn. in electric furnace without fusion of residues;; whole yield;;	92.6%
With sodium hydroxide; sodium cyanide In not given Electrolysis; electrolytical deposition of zinc from soln. of alkali cyanide; bath composition (in g/l): 45 ZnO, 100 NaCN, 38 NaOH, 7 MoO3; deposition conditions: 161 - 753 A/m*m;;

: 91-22-5
quinoline

: 29777-16-0
2-methyl-2-propenylzinc bromide

A: zinc dibromide

B: 7440-66-6
zinc

C: 4-(2-methylallyl)quinoline

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: H2; the mixt. was refluxed at 65°C for 6 h, cooled to 0°C; filtered;	A n/a B n/a C 90%

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: 7646-85-7
zinc(II) chloride

: 7440-66-6
zinc

Conditions

Conditions	Yield
In melt Electrolysis;	84%
Stage #1: zinc(II) chloride With thionyl chloride Heating; Stage #2: With naphthalene; lithium; Benzo[b]thiophene In tetrahydrofuran for 1h;	46%
With magnesium In diethyl ether byproducts: etherate of ZnCl2; on react. of Mg with anhyd. ZnCl2 at low temp., redn.;;	34.8%

: 143-66-8
sodium tetraphenyl borate

: 14024-63-6
zinc(II) acetylacetonate

: 7440-66-6
zinc

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratio NaBPh4 : Zn(acac)2 = 2 : 1; irradn. (254 nm) for 4 h gave deposition of Zn; deposit sepd., washed with acetone and water, and dried in vac. to give pure Zn;	80%

: 143-66-8
sodium tetraphenyl borate

: zinc(II) iodide

: 7789-45-9
copper(ll) bromide

A: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

B: 7440-66-6
zinc

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratios NaBPh4 : ZnI2 : CuBr2 = 8 : 1 : 3; irradn. (254 nm) for 8 h gave deposition of Zn and Cu; examn. of the Zn-Cu powder by ESCA measurement showed that more than 60% of the sample consisted of a Zn-Cu alloy and that the balance of the particles were Zn and Cu metals;	A 74% B 24%

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: zinc dibromide

: 7440-66-6
zinc

Conditions

Conditions	Yield
With magnesium In diethyl ether redn. in abs. ether soln. by Mg at room temp.;;	43%
With Mg In diethyl ether redn. in abs. ether soln. by Mg at room temp.;;	43%
With lithium In tetrahydrofuran Sonication; reduction with Li powder and ultrasound at room temp. in THF, reduction was complete within 40 min; workup was performed in air;

: 15658-08-9
dicyclohexylzinc(II)

: 7440-66-6
zinc

Conditions

Conditions	Yield
With water In further solvent(s) (Ar); heating a soln. of zinc compd. in anisole contg. traces of water at 130°C in a Fischer-Porter bottle for 3 h; filtration, washing with anisole, drying in vac.;	30%
With water; polyvinylpyrrolidone In further solvent(s) (Ar); heating a soln. of zinc compd. in anisole contg. traces of water at 130°C in a Fischer-Porter bottle for 3 h; filtration, washing with anisole, drying in vac.;	30%

: zinc(II) sulfate heptahydrate

: 7440-66-6
zinc

Conditions

Conditions	Yield
In not given Electrolysis; Zn deposition from solution of ZnSO47H2O and thiosulfate; bath composition (in g/l): 60 ZnSO47H2O, 200 Na2S2O35H2O, 25 - 50 NH4Cl or 120 ZnSO47H2O, 400 Na2S2O35H2O, 25 - 50 NH4Cl, 75°C, 1 - 2 A/dmdm, Fe cathode, Zn anode;;	3%
In not given Electrolysis; Zn deposition from solution of ZnSO47H2O and thiosulfate; bath composition (in g/l): 60 ZnSO47H2O, 200 Na2S2O35H2O, 25 - 50 NH4Cl or 120 ZnSO47H2O, 400 Na2S2O35H2O, 25 - 50 NH4Cl, 75°C, 1 - 2 A/dmdm, Fe cathode, Zn anode;;	3%
In not given Electrolysis; Zn deposition from acidic ZnSO4 soln.; bath composition (g/l): 400 ZnSO4*7H2O, 70 K-Al-sulfate, 24 MgSO4, 20 H3BO3, pH = 3.9, 25 °C;;