Product Name

  • Name

    Heptafluoroisopropyl iodide

  • EINECS 211-643-3
  • CAS No. 677-69-0
  • Article Data34
  • CAS DataBase
  • Density 2.189 g/cm3
  • Solubility insoluble in water
  • Melting Point -58 °C
  • Formula C3F7I
  • Boiling Point 40.8 °C at 760 mmHg
  • Molecular Weight 295.926
  • Flash Point 4.7 °C
  • Transport Information UN 2810
  • Appearance clear colorless to yellowish liquid
  • Safety 26-36-37/39
  • Risk Codes 20-36/37/38
  • Molecular Structure Molecular Structure of 677-69-0 (Heptafluoroisopropyl iodide)
  • Hazard Symbols HarmfulXn, IrritantXi, ToxicT
  • Synonyms 2-Iodoheptafluoropropane;2-Iodoperfluoropropane;Bis(trifluoromethyl)fluoroiodomethane;Fluoro(iodo)bis(trifluoromethyl)methane;Heptafluoro-2-iodopropane;Propane,1,1,1,2,3,3,3-heptafluoro-2-iodo-;Isoheptafluoropropyliodide;Perfluoro-2-iodopropane;Perfluoroisopropyl iodide;Propane,heptafluoro-2-iodo- (6CI,7CI,8CI);1,1,1,2,3,3,3-Heptafluoro-2-iodopropane;
  • PSA 0.00000
  • LogP 3.21180

Synthetic route

perfluoropropylene
116-15-4

perfluoropropylene

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

Conditions
ConditionsYield
With hydrogen fluoride; boron trifluoride; Iodine monochloride at 50℃; for 18h;79%
With iodine; antimony(III) fluoride; iodine pentafluoride at 20℃; Rate constant; Kinetics; var. temp.;
(i) CF3CO2Ag, CsF, (ii) I2; Multistep reaction;
perfluoropropylene
116-15-4

perfluoropropylene

iodotrifluoromethane
2314-97-8

iodotrifluoromethane

A

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane
754-34-7

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B

perfluoroisobutylene
382-21-8

perfluoroisobutylene

C

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

D

2-trifluoromethyl-perfluoropropyl iodide
1542-18-3

2-trifluoromethyl-perfluoropropyl iodide

E

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

F

1,1,1,2-Tetrafluoro-2-iodo-butane

1,1,1,2-Tetrafluoro-2-iodo-butane

Conditions
ConditionsYield
at 360℃; Product distribution; nickel reactor; other temperatures, influence of reactor material;
perfluoropropylene
116-15-4

perfluoropropylene

iodotrifluoromethane
2314-97-8

iodotrifluoromethane

A

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

B

2-trifluoromethyl-perfluoropropyl iodide
1542-18-3

2-trifluoromethyl-perfluoropropyl iodide

C

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

D

1,1,1,2-Tetrafluoro-2-iodo-butane

1,1,1,2-Tetrafluoro-2-iodo-butane

Conditions
ConditionsYield
at 360℃; Yield given. Further byproducts given. Yields of byproduct given;
perfluoropropylene
116-15-4

perfluoropropylene

A

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

B

2-hydrohexafluoropropyl fluorosulfate
684-35-5

2-hydrohexafluoropropyl fluorosulfate

C

2-iodo-hexafluoropropyl fluorosulfate
77570-01-5

2-iodo-hexafluoropropyl fluorosulfate

Conditions
ConditionsYield
With iodine; antimony pentafluoride; fluorosulphonic acid at 20℃; for 72h;A 11 g
B 6 g
C 4.5 g
perfluoroisopropyl radical
3248-60-0

perfluoroisopropyl radical

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

Conditions
ConditionsYield
With iodine In gas at 286.9 - 426.9℃; under 30 - 300 Torr; Equilibrium constant;
1,1,1,2,3,3,3-Heptafluoro-2-(1,2,2,2-tetrafluoro-1-iodo-ethoxy)-propane
127629-28-1

1,1,1,2,3,3,3-Heptafluoro-2-(1,2,2,2-tetrafluoro-1-iodo-ethoxy)-propane

A

iodotrifluoromethane
2314-97-8

iodotrifluoromethane

B

trifluoroacetyl fluoride
354-34-7

trifluoroacetyl fluoride

C

perfluoro(2,3-dimethylbutane)
354-96-1

perfluoro(2,3-dimethylbutane)

D

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

Conditions
ConditionsYield
at 250℃; under 7500.6 Torr; Pyrex tube;
1,1,1,2,3,3,3-Heptafluoro-2-(1,2,2,2-tetrafluoro-1-iodo-ethoxy)-propane
127629-28-1

1,1,1,2,3,3,3-Heptafluoro-2-(1,2,2,2-tetrafluoro-1-iodo-ethoxy)-propane

A

trifluoroacetyl fluoride
354-34-7

trifluoroacetyl fluoride

B

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

Conditions
ConditionsYield
at 250℃; under 7500.6 Torr; Pyrex tube;
C3F17IO2Te2
105062-54-2

C3F17IO2Te2

A

tetradecafluorohexane
355-42-0

tetradecafluorohexane

B

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

C

Hexafluoroacetone
684-16-2

Hexafluoroacetone

Conditions
ConditionsYield
at 120℃; for 10h;
1,1,1,2,2,4,5,5,5-nonafluoro-3-pentafluoroethyl-3,4-bis-trifluoromethyl-pentane
50285-19-3

1,1,1,2,2,4,5,5,5-nonafluoro-3-pentafluoroethyl-3,4-bis-trifluoromethyl-pentane

A

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

B

1,1,1,2,2,4,4,5,5,5-Decafluoro-3-iodo-3-trifluoromethyl-pentane

1,1,1,2,2,4,4,5,5,5-Decafluoro-3-iodo-3-trifluoromethyl-pentane

Conditions
ConditionsYield
With iodine at 201℃; for 48h;
With iodine at 201℃; for 48h; Rate constant; Thermodynamic data; other temp., activation energy;
perfluoro-2,4-dimethyl-3-ethylpentane
50285-18-2

perfluoro-2,4-dimethyl-3-ethylpentane

A

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

B

1,1,1,2,2,3,4,5,5,5-decafluoro-3-iodo-4-trifluoromethyl-pentane
60340-52-5

1,1,1,2,2,3,4,5,5,5-decafluoro-3-iodo-4-trifluoromethyl-pentane

Conditions
ConditionsYield
With iodine at 261℃; for 48h;
perfluoro-2,3,3-trimethylpentane
127678-98-2

perfluoro-2,3,3-trimethylpentane

A

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

B

F-2-iodo-2-methyl-butane

F-2-iodo-2-methyl-butane

Conditions
ConditionsYield
With iodine at 261℃; for 48h;
perfluoro-2,3,3,4-tetramethylpentane
120615-52-3

perfluoro-2,3,3,4-tetramethylpentane

A

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

B

1,1,1,2,4,4,4-Heptafluoro-3-iodo-2,3-bis-trifluoromethyl-butane

1,1,1,2,4,4,4-Heptafluoro-3-iodo-2,3-bis-trifluoromethyl-butane

Conditions
ConditionsYield
With iodine at 161℃; for 48h;
With iodine at 161℃; for 48h; Rate constant; Thermodynamic data; other temp., activation energy;
1,1,1,2,3,5,5,5-Octafluoro-2,3,4,4-tetrakis-trifluoromethyl-pentane
122432-75-1

1,1,1,2,3,5,5,5-Octafluoro-2,3,4,4-tetrakis-trifluoromethyl-pentane

A

Perfluoro-2-iodo-3-methylbutane
7626-45-1

Perfluoro-2-iodo-3-methylbutane

B

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

C

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

D

1,1,1,2,4,4,4-Heptafluoro-2-iodo-3,3-bis-trifluoromethyl-butane

1,1,1,2,4,4,4-Heptafluoro-2-iodo-3,3-bis-trifluoromethyl-butane

Conditions
ConditionsYield
With iodine at 161℃; for 48h;
With iodine at 201℃; for 48h;
With iodine at 201℃; for 48h; Rate constant; Thermodynamic data; other temp., activation energy;
(CF3)2CFNi(CH3CN)2I

(CF3)2CFNi(CH3CN)2I

A

1,1,1,2,3,3,3-Heptafluoropropane
431-89-0

1,1,1,2,3,3,3-Heptafluoropropane

B

perfluoropropylene
116-15-4

perfluoropropylene

C

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

Conditions
ConditionsYield
at 80 - 160℃; under 0.5 Torr;
perfluoroisopropyl radical
3248-60-0

perfluoroisopropyl radical

A

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

B

atomic iodine

atomic iodine

Conditions
ConditionsYield
With iodine In gas at 286.9 - 426.9℃; under 30 - 300 Torr; Equilibrium constant;
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

iodotrifluoromethane
2314-97-8

iodotrifluoromethane

A

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane
754-34-7

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

Conditions
ConditionsYield
With aluminum chlorofluoride at 25 - 30℃; for 16h; Addition; Title compound not separated from byproducts;
perfluoropropylene
116-15-4

perfluoropropylene

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
423-39-2

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

A

octafluoro-2-butene
360-89-4, 172368-67-1

octafluoro-2-butene

B

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

Conditions
ConditionsYield
With aluminum chlorofluoride at 80℃; for 40h; Addition; Elimination;
perfluoropropylene
116-15-4

perfluoropropylene

n-perfluorohexyl iodide
355-43-1

n-perfluorohexyl iodide

A

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

B

perfluoro-2-hexene
67899-37-0

perfluoro-2-hexene

C

cis-F-Hexene-2
71186-97-5

cis-F-Hexene-2

D

trans-perfluoro-3-hexene
81018-66-8

trans-perfluoro-3-hexene

Conditions
ConditionsYield
With aluminum chlorofluoride at 50℃; for 16h; Addition; Elimination; Further byproducts given. Title compound not separated from byproducts;
perfluoropropylene
116-15-4

perfluoropropylene

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
423-39-2

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

Conditions
ConditionsYield
aluminum chlorofluoride
iodine
7553-56-2

iodine

heptafluoroisopropyl silver
22407-25-6

heptafluoroisopropyl silver

A

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

B

silver(I) iodide

silver(I) iodide

heptafluoroisopropyl silver
22407-25-6

heptafluoroisopropyl silver

trans-CF3CFCICF3
108071-78-9

trans-CF3CFCICF3

A

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

B

trans-perfluoro-1-methylpropenylsilver
24703-63-7, 37981-99-0

trans-perfluoro-1-methylpropenylsilver

perfluoropropylene
116-15-4

perfluoropropylene

tetrafluoro-trifluoromethyl-λ5-iodane
38091-67-7

tetrafluoro-trifluoromethyl-λ5-iodane

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

Conditions
ConditionsYield
at 20°C;
3-Methylindole
83-34-1

3-Methylindole

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

C12H8F7N
1638115-68-0

C12H8F7N

Conditions
ConditionsYield
With tris(2,2'-bipyridyl)ruthenium dichloride; N,N,N,N,-tetramethylethylenediamine In acetonitrile at 20℃; for 0.166667h; Flow reactor; Irradiation; Inert atmosphere;99%
1-Decene
872-05-9

1-Decene

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

1,1,1,2-tetrafluoro-4-iodo-2-(trifluoromethyl)dodecane

1,1,1,2-tetrafluoro-4-iodo-2-(trifluoromethyl)dodecane

Conditions
ConditionsYield
With pyrrolidine; Diphenylacetaldehyde In dichloromethane at 20℃; for 16h; Inert atmosphere; Irradiation;99%
With 2',4',5',7'-tetrabromofluorescein; sodium thiosulfate In water; acetonitrile at 20℃; for 1h; Inert atmosphere; Irradiation;64%
perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

4-Phenyl-1-butene
768-56-9

4-Phenyl-1-butene

(E)-(5,6,6,6-tetrafluoro-5-(trifluoromethyl)hex-3-en-1-yl)benzene

(E)-(5,6,6,6-tetrafluoro-5-(trifluoromethyl)hex-3-en-1-yl)benzene

Conditions
ConditionsYield
With (dppf)Ni(o-tol)Cl; sodium t-butanolate In Hexafluorobenzene at 50℃; for 16h; Inert atmosphere; Schlenk technique; Sealed tube;99%
With eosin; caesium carbonate In N,N-dimethyl acetamide at 20℃; for 48h; Inert atmosphere; Sealed tube; Irradiation;87%
4-cyclohexen-1-ylmorpholine
670-80-4

4-cyclohexen-1-ylmorpholine

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

C13H16F7NO

C13H16F7NO

Conditions
ConditionsYield
With caesium carbonate In dichloromethane at 25℃; for 16h; Solvent; Inert atmosphere; Sealed tube;99%
5-Hexen-1-ol
821-41-0

5-Hexen-1-ol

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

7,8,8,8-tetrafluoro-5-iodo-7-(trifluoromethyl)octan-1-ol
1378412-56-6

7,8,8,8-tetrafluoro-5-iodo-7-(trifluoromethyl)octan-1-ol

Conditions
ConditionsYield
With iodine; N-ethyl-N,N-diisopropylamine In water for 1h; Irradiation; regioselective reaction;98%
With rhodamine B; N-ethyl-N,N-diisopropylamine In water at 0 - 20℃; for 1h; Inert atmosphere; Irradiation;90%
With C30H26N6Ru(2+)*2Cl(1-); sodium L-ascorbate In methanol; acetonitrile for 0.5h; Inert atmosphere; Irradiation;81%
With potassium carbonate In N,N-dimethyl-formamide for 24h; Schlenk technique; Inert atmosphere; Irradiation;41%
allylbenzene
300-57-2

allylbenzene

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

1,1,1,2-tetrafluoro-2-(trifluoromethyl)-4-iodo-5-phenylpentane
1025027-36-4

1,1,1,2-tetrafluoro-2-(trifluoromethyl)-4-iodo-5-phenylpentane

Conditions
ConditionsYield
With iodine; N-ethyl-N,N-diisopropylamine In water at 20℃; for 1h; Reagent/catalyst; Irradiation;98%
With rhodamine B; N-ethyl-N,N-diisopropylamine In water at 0 - 20℃; for 1h; Inert atmosphere; Irradiation;86%
With triethylamine In acetonitrile at 20℃; for 0.166667h; Irradiation; Flow reactor;78%
With diethylzinc In hexane; acetonitrile at -20℃; for 16h; Schlenk technique; Inert atmosphere;60%
diallylmalonic acid diethyl ester
3195-24-2

diallylmalonic acid diethyl ester

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

cis-3-[2-(trifluoromethyl)-2,3,3,3-tetrafluoropropyl]-4-(iodomethyl)-1,1-cyclopentandicarboxylic acid diethyl ester

cis-3-[2-(trifluoromethyl)-2,3,3,3-tetrafluoropropyl]-4-(iodomethyl)-1,1-cyclopentandicarboxylic acid diethyl ester

Conditions
ConditionsYield
With iodine; N-ethyl-N,N-diisopropylamine In water at 20℃; for 1h; Irradiation; diastereoselective reaction;98%
Estragole
140-67-0

Estragole

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

1-methoxy-4-(4,5,5,5-tetrafluoro-2-iodo-4-trifluoromethylpentyl)benzene

1-methoxy-4-(4,5,5,5-tetrafluoro-2-iodo-4-trifluoromethylpentyl)benzene

Conditions
ConditionsYield
With iodine; N-ethyl-N,N-diisopropylamine In water for 1h; Irradiation; regioselective reaction;98%
perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

2-methyl-1-phenyl-2-propene
3290-53-7

2-methyl-1-phenyl-2-propene

C13H12F7I

C13H12F7I

Conditions
ConditionsYield
With iodine; N-ethyl-N,N-diisopropylamine In water for 1h; Irradiation; regioselective reaction;98%
perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

bromopentene
1119-51-3

bromopentene

C8H9BrF7I

C8H9BrF7I

Conditions
ConditionsYield
With iodine; N-ethyl-N,N-diisopropylamine In water for 1h; Irradiation; regioselective reaction;98%
Methyl 10-undecenoate
111-81-9

Methyl 10-undecenoate

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

(E)-methyl (E)-12,13,13,13-tetrafluoro-12-(trifluoromethyl)tridec-10-enoate

(E)-methyl (E)-12,13,13,13-tetrafluoro-12-(trifluoromethyl)tridec-10-enoate

Conditions
ConditionsYield
With eosin; caesium carbonate In N,N-dimethyl acetamide at 20℃; for 48h; Inert atmosphere; Sealed tube; Irradiation;98%
perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

A

C3F17IO2Te2
105062-54-2

C3F17IO2Te2

B

Cl2, TeF5OH

Cl2, TeF5OH

Conditions
ConditionsYield
With ClOTeF5 at 25℃; for 48h;A 97%
B n/a
2-(1,4-dimethylpentyl)aniline
477738-25-3

2-(1,4-dimethylpentyl)aniline

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

2-(1,4-dimethylpentyl)-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]aniline
477738-26-4

2-(1,4-dimethylpentyl)-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]aniline

Conditions
ConditionsYield
With sodium dithionite; tetra(n-butyl)ammonium hydrogensulfate; sodium hydrogencarbonate In tert-butyl methyl ether; water at 20℃; for 12h;97%
(1,5-cyclooctadiene)dimethylplatinum(II)

(1,5-cyclooctadiene)dimethylplatinum(II)

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

methyl-η4-(1,5-cyclooctadiene)perfluoro(iso-propyl)platinum
887305-17-1

methyl-η4-(1,5-cyclooctadiene)perfluoro(iso-propyl)platinum

Conditions
ConditionsYield
In dichloromethane at 30 - 45℃; for 48h; Time; Concentration; Inert atmosphere; Darkness;97%
In dichloromethane at 35℃; for 120h; Darkness;90%
In further solvent(s) in a Schlenk flask, excess of F-compd. was added and used as solvent, room temp., 3 d shaking; ppt. was collected, washed twice with hexane, recrystn. from Et2O, elem.anal.;85%
perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

o-toluidine
95-53-4

o-toluidine

2-methyl-4-(heptafluoropropan-2-yl)-aniline
238098-26-5

2-methyl-4-(heptafluoropropan-2-yl)-aniline

Conditions
ConditionsYield
With sodium dithionite; sodium carbonate; tetrabutylammonium sulfate In tert-butyl methyl ether; water at 50℃; for 4h;97%
With tetra(n-butyl)ammonium hydrogensulfate; sodium carbonate In tert-butyl methyl ether; water at 50℃; for 4h;97%
With sodium dithionite; tetrabutylammomium bromide; sodium carbonate In tert-butyl methyl ether; water at 5℃; for 24h;89.1%
10-Undecen-1-ol
112-43-6

10-Undecen-1-ol

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

11-(F-isopropyl)-10-iodoundecan-1-ol

11-(F-isopropyl)-10-iodoundecan-1-ol

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) at 70℃; for 26h;96.4%
perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

diethylzinc
557-20-0

diethylzinc

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

Zn(2+)*2C3F7(1-)*2C3H7NO

Zn(2+)*2C3F7(1-)*2C3H7NO

Conditions
ConditionsYield
In hexane; dichloromethane at -78 - 0℃; for 3h; Solvent; Temperature; Inert atmosphere;96%
perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

ortho-ethylaniline
578-54-1

ortho-ethylaniline

2-ethyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]aniline

2-ethyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]aniline

Conditions
ConditionsYield
With sodium dithionite; tetra(n-butyl)ammonium hydrogensulfate; sodium hydrogencarbonate In tert-butyl methyl ether; water at 0 - 25℃;95%
With sodium dithionite; tetrabutylammomium bromide; sodium carbonate In tert-butyl methyl ether; water at 5℃; for 24h;
5-methyl-3-phenyl-1,2,4-oxadiazole
1198-98-7

5-methyl-3-phenyl-1,2,4-oxadiazole

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

C12H7F7N2O

C12H7F7N2O

Conditions
ConditionsYield
With sodium persulfate; cetyltrimethylammonim bromide In tert-butyl methyl ether; water95%
5-ethyl-3-phenyl-[1,2,4]oxadiazole
10364-68-8

5-ethyl-3-phenyl-[1,2,4]oxadiazole

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

C13H9F7N2O

C13H9F7N2O

Conditions
ConditionsYield
With sodium persulfate; cetyltrimethylammonim bromide In tert-butyl methyl ether; water for 2.5h;95%
perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

diethylzinc
557-20-0

diethylzinc

acetonitrile
75-05-8

acetonitrile

Zn(2+)*2CF3CFCF3(1-)*2CH3CN=Zn(CF3CFCF3)2*2CH3CN

Zn(2+)*2CF3CFCF3(1-)*2CH3CN=Zn(CF3CFCF3)2*2CH3CN

Conditions
ConditionsYield
In hexane byproducts: C2H5I, ZnI2, Zn(i-C3F7)i*2THF; dry N2 atm.; cooling (-78°C), stirring (-20°C, 24 h), heating (room temp., 15 min); evapn. (vac.); elem. anal.;94%
perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

5-(4-methoxyphenyl)-1-pentene
51125-16-7

5-(4-methoxyphenyl)-1-pentene

1-methoxy-4-[6,7,7,7-tetrafluoro-4-iodo-6-(trifluoromethyl)-hepta-1-yl]benzene

1-methoxy-4-[6,7,7,7-tetrafluoro-4-iodo-6-(trifluoromethyl)-hepta-1-yl]benzene

Conditions
ConditionsYield
With rhodamine B; N-ethyl-N,N-diisopropylamine In water at 0 - 20℃; for 1h; Inert atmosphere; Irradiation;94%
With iodine; N-ethyl-N,N-diisopropylamine In water for 1h; Irradiation; regioselective reaction;85%
With rhodamine B; N-ethyl-N,N-diisopropylamine In water at 20℃; for 1h; Reagent/catalyst; Solvent; Inert atmosphere; Irradiation;84%
2-diallylamino-malonic acid diethyl ester

2-diallylamino-malonic acid diethyl ester

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

cis-3-[2-(trifluoromethyl)-2,3,3,3-tetrafluoropropyl]-4-(iodomethyl)-1,1-cyclopentandicarboxylic acid, diethyl ester

cis-3-[2-(trifluoromethyl)-2,3,3,3-tetrafluoropropyl]-4-(iodomethyl)-1,1-cyclopentandicarboxylic acid, diethyl ester

Conditions
ConditionsYield
With rhodamine B; N-ethyl-N,N-diisopropylamine In water at 0 - 20℃; for 0.5h; Reagent/catalyst; Inert atmosphere; Irradiation;94%
ethene
74-85-1

ethene

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

1,1,1,2-tetrafluoro-4-iodo-2-(trifluoromethyl)butane
99324-96-6

1,1,1,2-tetrafluoro-4-iodo-2-(trifluoromethyl)butane

Conditions
ConditionsYield
With ethanolamine; copper(l) chloride at 140℃; under 15001.2 - 18751.5 Torr; for 8h;93%
With ethanolamine; copper(l) chloride In various solvent(s) at 150℃; for 18h; Addition;75%
With dibenzoyl peroxide at 100℃; for 6h;33%
1-dodecyne
765-03-7

1-dodecyne

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

(E)-1,1,1,2-Tetrafluoro-4-iodo-2-trifluoromethyl-tetradec-3-ene
125081-24-5

(E)-1,1,1,2-Tetrafluoro-4-iodo-2-trifluoromethyl-tetradec-3-ene

Conditions
ConditionsYield
With triethyl borane In hexane at 25℃; for 8h;92%
perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

1,7-Octadiene
3710-30-3

1,7-Octadiene

9,10,10,10-Tetrafluoro-7-iodo-9-trifluoromethyldec-1-ene
143766-68-1

9,10,10,10-Tetrafluoro-7-iodo-9-trifluoromethyldec-1-ene

Conditions
ConditionsYield
With bis(cyclopentadienyl)titanium dichloride; iron In ethanol at 55℃; for 10h; other per(poly)fluoroalkyl iodides and bromides;92%
With bis(cyclopentadienyl)titanium dichloride; iron In ethanol at 55℃; for 10h;92%
perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

potassium vinyltrifluoroborate

potassium vinyltrifluoroborate

potassium 1-iodo-3,3-bistrifluoromethyl-3-fluoropropyl trifluoroborate

potassium 1-iodo-3,3-bistrifluoromethyl-3-fluoropropyl trifluoroborate

Conditions
ConditionsYield
In acetonitrile at 27℃; for 3h; Inert atmosphere; Sealed tube; Irradiation;92%
With tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; sodium L-ascorbate In acetone at 20℃; for 24h; Irradiation;71%
1-allyl-4-fluorobenzene
1737-16-2

1-allyl-4-fluorobenzene

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

1-fluoro-4-[4,5,5,5-tetrafluoro-2-iodo-4-(trifluoromethyl)pentyl]benzene

1-fluoro-4-[4,5,5,5-tetrafluoro-2-iodo-4-(trifluoromethyl)pentyl]benzene

Conditions
ConditionsYield
With iron(III) trifluoromethanesulfonate; tert-butyl peroxyacetate In tert-butyl methyl ether at 20℃; for 12h; Schlenk technique; Inert atmosphere;92%
(η(5)-cyclopentadienyl)Rh(trimethylphosphane)2

(η(5)-cyclopentadienyl)Rh(trimethylphosphane)2

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

[Ru(η(4)-C5H5CF(CF3)2)(PMe3)2I]
185224-80-0

[Ru(η(4)-C5H5CF(CF3)2)(PMe3)2I]

Conditions
ConditionsYield
In tetrahydrofuran -78°C; elem. anal.;91%
In further solvent(s) (N2); using Schlenk techniques; treatment of RhCp(PMe3)2 with (CF3)2CFI; not isolated;
perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

4-tert-Butylphenylacetylene
772-38-3

4-tert-Butylphenylacetylene

3-(4-(tert-butyl)phenyl)-2-(perfluoropropan-2-yl)-2H-azirine

3-(4-(tert-butyl)phenyl)-2-(perfluoropropan-2-yl)-2H-azirine

Conditions
ConditionsYield
With tert.-butylhydroperoxide; trimethylsilylazide; iron(II) chloride In decane; acetonitrile at 70℃; for 3h; Schlenk technique; Inert atmosphere;91%

Heptafluoroisopropyl iodide Chemical Properties

Structure of Heptafluoroisopropyl iodide (CAS NO.677-69-0):
 
Molecular Formula: C3F7I
Molecular Weight: 295.93
EINECS: 211-643-3
Index of Refraction: 1.361 
Molar Refractivity: 29.96 cm
Molar Volume: 135.1 cm3 
Polarizability: 11.87 10 -24 cm
Surface Tension: 17.7 dyne/cm 
Density: 2.189 g/cm 
Melting Point: -58 °C
Boiling Point: 40.8 °C at 760 mmHg 
Flash Point: 4.7 °C 
Enthalpy of Vaporization: 27.34 kJ/mol 
Vapour Pressure: 429 mmHg at 25°C 
storage temp.: Keep Cold
Water Solubility: insoluble
Product Categories: Organic Fluorides
IUPAC Name: 1,1,1,2,3,3,3-heptafluoro-2-iodopropane
Synonyms: Perfluoroisopropyl iodide ; 1,1,1,2,3,3,3-Heptafluoro-2-iodopropane ; Propane, 1,1,1,2,3,3,3-heptafluoro-2-iodo- 

Heptafluoroisopropyl iodide Safety Profile


The Hazard Codes of Heptafluoroisopropyl iodide (CAS NO.677-69-0): HarmfulXn, IrritantXi , ToxicT
The Risk Statements information of Heptafluoroisopropyl iodide (CAS NO.677-69-0):
20:  Harmful by inhalation
36/37/38:  Irritating to eyes, respiratory system and skin
The Safety Statements information of Heptafluoroisopropyl iodide (CAS NO.677-69-0):
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing
37/39:  Wear suitable gloves and eye/face protection
Hazard Note: Irritant
HazardClass: 6.1(b)
RIDADR: 2810
WGK Germany: 3
RTECS: TZ3925000
F: 8
TSCA: T

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