Tetrapropylammonium tetraoxoruthenate supplier

Name
TETRAPROPYLAMMONIUM PERRUTHENATE
EINECS
CAS No. 114615-82-6
Article Data8
CAS DataBase
Density g/cm³
Solubility Insoluble in water.
Melting Point ~160 °C (dec.)(lit.)
Formula C₁₂H₂₈O₄PRu
Boiling Point °Cat760mmHg
Molecular Weight 351.429
Flash Point °C
Transport Information
Appearance
Safety Hazard Codes O,Xi
Risk Statements 5-8-36/37/38
Safety Statements 17-26-36
RIDADR UN 1479 5.1/PG 2

WGK Germany 3

F 3-10
HazardClass 5.1
PackingGroup III
Risk Codes 5-8-36/37/38
Molecular Structure
Hazard Symbols
Synonyms TETRAPROPYLAMMONIUM PERRUTHENATE;TETRA-N-PROPYLAMMONIUM PERRUTHENATE;TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII);TPAP;Tetrapropylammoniumperruthenate,min.97%TPAP;1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-);Tetrapropylammonium Perruthenate (TPAP);Tetra-n-propylammonium perruthenate(VII), 98+%
PSA 74.27000
LogP 2.96800

Synthetic route

: rhodium(III) chloride hydrate

: 4499-86-9
tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
Stage #1: rhodium(III) chloride hydrate With sodium bromate; sodium carbonate In water at 30 - 40℃; for 5h; Stage #2: tetrapropylammonium hydroxide at 30℃; for 5h; Temperature;	99.7%
Stage #1: rhodium(III) chloride hydrate With sodium bromate; sodium carbonate In water at 20℃; for 2h; Stage #2: tetrapropylammonium hydroxide In water at 20℃; for 0.05h;	67%

: sodium bromate

: ruthenium trichloride hydrate

: tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
With sodium carbonate In water mixt. of RuCl3 and NaBrO3, Na2CO3 in water stirred until color changed to yellow green, addn. of n-Pr4NOH with stirring, deep green pptn.; extd. with alcohol free CH2Cl2, dried over anhydrous Na2CO3, concd. in vac., recrystd. from CCl4; elem. anal.;	99%

...Expand

: 20427-56-9
ruthenium tetroxide

: tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
With K2CO3 stirred at 0°C for 3 h; washed with ice-cold H2O, dried in vac.; elem. anal.;	96%

: 7790-28-5
sodium periodate

: ruthenium trichloride hydrate

: tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
In water stirring of hydrated RuCl3 and NaIO4 in H2O overnight; addn. to an aq. soln. of n-Pr4NOH containing NaOH at 0-5°C under an atmosphere of O2;; ppt. was removed every 20 min, washed with ice-cold water, and dried under vac.;;	87%

...Expand

: 7790-28-5
sodium periodate

: ruthenium(III) chloride trihydrate

: 4499-86-9
tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
Stage #1: tetrapropylammonium hydroxide With sodium hydroxide In water Stage #2: sodium periodate; ruthenium(III) chloride trihydrate In water at 20℃; for 16h;	33%

...Expand

: ruthenium(III) trichloride hydrate

: 4499-86-9
tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
With sodium periodate; sodium hydroxide In water at 20℃; for 16h;	33%

: sodium bromate

: tetrapropylammonium hydroxide

: ruthenium dioxide hydrate

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
With sodium carbonate In water mixt. of RuO2 and NaBrO3, Na2CO3 in water stirred until color changed to yellow green, addn. of n-Pr4NOH with stirring, deep green pptn.; extd. with alcohol free CH2Cl2, dried over anhydrous Na2CO3, concd. in vac., recrystd. from CCl4;

...Expand

: ruthenium(III) chloride trihydrate

: 4499-86-9
tetrapropylammonium hydroxide

: 114615-82-6
tetrapropylammonium perruthennate

Conditions

Conditions	Yield
Stage #1: ruthenium(III) chloride trihydrate With sodium bromate; sodium carbonate In water at 20℃; for 2h; Stage #2: tetrapropylammonium hydroxide In water at 20℃; for 0.05h;

: 114615-82-6
tetrapropylammonium perruthennate

: 3618-04-0, 75877-66-6, 17159-80-7
4-hydroxycyclohexyl carboxylic acid ethyl ester

: 7529-22-8
4-methylmorpholine N-oxide

: 17159-79-4
ethyl 4-oxocyclohexane-1-carboxylate

Conditions

Conditions	Yield
In ethyl acetate; acetonitrile	98%
In dichloromethane	13.46 g (85%)

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 277334-43-7
(2Z)-3-(4-hydroxy-2-buten-2-yl)-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-(n-propyloxy)naphthalene

: 180861-54-5
(2Z)-3-[5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-(n-propyloxy)naphthalen-3-yl]but-2-en-1-al

Conditions

Conditions	Yield
With 4-methylmorpholine N-oxide In dichloromethane	98%

: 224309-64-2
tert-butyl N-(4-hydroxycyclohexyl)carbamate

: 114615-82-6
tetrapropylammonium perruthennate

: 7529-22-8
4-methylmorpholine N-oxide

: 179321-49-4
N-(tert-butoxycarbonyl)-4-aminocyclohexanone

Conditions

Conditions	Yield
molecular sieves In dichloromethane; ethyl acetate	96%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 7529-22-8
4-methylmorpholine N-oxide

: 220367-72-6
(4S)-4-(2-methyl-3(RS)-hydroxybut-2-yl)-2,2-dimethyl[1,3]dioxane

: 220367-71-5
(4S)-4-(2-methyl-3-oxobut-2-yl)-2,2-dimethyl[1,3]dioxane

Conditions

Conditions	Yield
molecular sieve In dichloromethane	94.5%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 558442-58-3
4-(1,3-dioxoisoindolin-2-yl)-3-hydroxybutyl acetate

: 7529-22-8
4-methylmorpholine N-oxide

: 558443-82-6
4-(1,3-dioxoisoindolin-2-yl)-3-oxobutyl acetate

Conditions

Conditions	Yield
SiO2 In dichloromethane	92%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 566924-79-6
1-(2-Hydroxy-3-methoxymethoxy-butyl)-2-oxo-6-m-tolyl-4-trifluoromethyl-1,2-dihydro-pyridine-3-carbonitrile

: 566926-43-0
1-(3-Methoxymethoxy-2-oxo-butyl)-2-oxo-6-m-tolyl-4-trifluoromethyl-1,2-dihydro-pyridine-3-carbonitrile

Conditions

Conditions	Yield
With 4-methylmorpholine N-oxide; silica gel In 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran	90%

silica-gel: silica-gel

: 114615-82-6
tetrapropylammonium perruthennate

Å molecular sieves: Å molecular sieves

: 179420-68-9
4-hydroxymethyl-4-(5-benzyloxy-3-fluorophenyl)-3,4,5,6-tetrahydro-2H-pyran

: 4-›3-(Benzyloxy)-5-fluorophenyl›-4-formyl-3,4,5,6-tetrahydro-2H-pyran

Conditions

Conditions	Yield
With 4-methylmorpholine N-oxide In hexane; ethyl acetate	86%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 24424-99-5
di-tert-butyl dicarbonate

: 27489-62-9
trans-4-hydroxycyclohexylamine

: 50910-54-8
trans-4-aminocyclohexanol hydrochloride

: 7529-22-8
4-methylmorpholine N-oxide

: 179321-49-4
N-(tert-butoxycarbonyl)-4-aminocyclohexanone

Conditions

Conditions	Yield
molecular sieves In tetrahydrofuran; sodium hydroxide; dichloromethane	84%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 2-t-butyldiphenylsilyloxymethyl-2-propene-1-ol

: 2-t-butyldiphenylsilyloxymethyl-2-propenal

Conditions

Conditions	Yield
silica gel In dichloromethane; 4-methylmorpholine N-oxide	83%

: 114615-82-6
tetrapropylammonium perruthennate

: 623906-43-4
8-(hydroxymethyl)dibenzo[b,f][1,4]oxazepin-11(10H)-one

: 623906-45-6
11-oxo-10,11-dihydrodibenzo[b,f][1,4]oxazepine-8-carbaldehyde

Conditions

Conditions	Yield
With hydrogenchloride; silica gel In ethyl acetate; acetonitrile	83%

: 114615-82-6
tetrapropylammonium perruthennate

: 1217527-96-2
(6S)-N-benzyl-2-azabicyclo[2.2.2]octan-6-ol

: 7529-22-8
4-methylmorpholine N-oxide

: 41959-26-6
2-benzyl-2-azabicyclo[2.2.2]octan-6-one

Conditions

Conditions	Yield
In ethyl acetate; acetonitrile	81%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 1134916-40-7
2-(2-Chloro-5-methoxy-phenyl)-1-(2-chloro-pyridin-4-yl)-propan-1-ol

: 7529-22-8
4-methylmorpholine N-oxide

: 1134916-41-8
2-(2-chloro-5-methoxy-phenyl)-1-(2-chloro-pyridin-4-yl)-propan-1-one

Conditions

Conditions	Yield
silica gel In dichloromethane	81%

...Expand

: 1074-85-7
(1H-indol-4-yl)methanol

: 114615-82-6
tetrapropylammonium perruthennate

: 1074-86-8
4-formyl indole

Conditions

Conditions	Yield
With 4-methylmorpholine N-oxide; silica gel In dichloromethane	80%

: 114615-82-6
tetrapropylammonium perruthennate

3,16α-Bis(dimethylthexylsilyl ether): 3,16α-Bis(dimethylthexylsilyl ether)

: 50-27-1
Estriol

: 566-76-7
16α-hydroxyestrone

Conditions

Conditions	Yield
In dichloromethane	76%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 73842-99-6
3-tert-butyldimethylsilyloxy-1-propanol

: 89922-82-7
3-(tert-butyldimethylsilanyloxy)propionaldehyde

Conditions

Conditions	Yield
With 4-methylmorpholine N-oxide; silica gel In dichloromethane; acetonitrile	66%
With 4-methylmorpholine N-oxide; silica gel In dichloromethane; acetonitrile	66%

: 114615-82-6
tetrapropylammonium perruthennate

: 7529-22-8
4-methylmorpholine N-oxide

: 121278-43-1, 121278-44-2, 121278-49-7
2-(3,4-dihydro-1(2H)-benzopyran-4-yl)ethanol

: 150515-77-8
2-(3,4-dihydro-2H-1-benzopyran-4-yl)ethanal

Conditions

Conditions	Yield
silica gel In dichloromethane; ethyl acetate	64%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 529508-87-0
1-{4-[1-(3-Fluoro-benzyl)-1H-indazol-5-ylamino]-pyrrolo[2,1 f][1,2,4]triazin-5-ylmethyl}-(3R)-pyrrolidin-3-ol

: 529509-31-7
1-{4[1-(3-Fluoro-benzyl)-1H-indazol-5-ylamino]-pyrrolo[2,1-f][1,2,4]triazin-5-ylmethyl}-pyrrolidin-3-one

Conditions

Conditions	Yield
With 4-methylmorpholine N-oxide; silica gel In 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran; ethyl acetate	61%

: 114615-82-6
tetrapropylammonium perruthennate

: ethyl 1-(p-chlorophenyl)-β-hydroxy-cyclopropanepropionate

: 7529-22-8
4-methylmorpholine N-oxide

: ethyl 1-(p-chlorophenyl)-β-oxo-cyclopropanepropionate

Conditions

Conditions	Yield
In Å molecular sieves; diethyl ether; ethyl acetate; acetonitrile	55%
In diethyl ether; silica gel; ethyl acetate; acetonitrile	55%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 459-89-2
(3E,7E)-homofarnesol

: 7529-22-8
4-methylmorpholine N-oxide

: 29484-45-5
homofarnesaldehyde

Conditions

Conditions	Yield
silica gel In acetonitrile	50%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 177587-14-3
methyl 5-(3-hydroxypropyl)-4-methylthiophene-2-carboxylate

Å molecular sieves: Å molecular sieves

: 7529-22-8
4-methylmorpholine N-oxide

: 177587-15-4
methyl 4-methyl-5-(3-oxopropyl) thiophene-2-carboxylate

Conditions

Conditions	Yield
In dichloromethane	49%

...Expand

: 110-86-1
pyridine

: 114615-82-6
tetrapropylammonium perruthennate

: cobalt(II) acetate monohydrate

: C23H27Co3N3O13Ru

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 16h; Inert atmosphere;	45%

...Expand

: 4606-65-9
3-(hydroxymethy)piperidine

: 114615-82-6
tetrapropylammonium perruthennate

: 24424-99-5
di-tert-butyl dicarbonate

: 7529-22-8
4-methylmorpholine N-oxide

: 118156-93-7
3-formylpiperidine-1-carboxylic acid tert-butyl ester

Conditions

Conditions	Yield
molecular sieves In tetrahydrofuran; dichloromethane	43%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: (3RS,4RS)-3-[N-((1-naphthyloxy)acetyl)valinyl]amino-5-fluoro-4-hydroxypentanoic acid, tert-butyl ester

: (3RS)-3-[N-((1-Naphthyloxy)Acetyl)Valinyl]Amino-5-Fluoro-4-Oxopentanoic Acid

Conditions

Conditions	Yield
With 4-methylmorpholine N-oxide; silica gel In dichloromethane	40%

: 620-08-6
4-methoxypyridine

: 114615-82-6
tetrapropylammonium perruthennate

: cobalt(II) acetate monohydrate

: C26H33Co3N3O16Ru

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 16h; Inert atmosphere;	38%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 345964-18-3
2-cyclopropyl-6-hydroxymethyl-4,4-dimethyl-1,2,3,4-tetrahydroisoquinoline

molecular sieves powder: molecular sieves powder

: 7529-22-8
4-methylmorpholine N-oxide

: 345964-19-4
2-cyclopropyl-4,4-dimethyl-1,2,3,4-tetrahydroisoquinoline-6-carbaldehyde

Conditions

Conditions	Yield
In hexane; dichloromethane; acetonitrile	37%
In hexane; dichloromethane; acetonitrile	37%

...Expand

: 114615-82-6
tetrapropylammonium perruthennate

: 3796-24-5
4-trifluoromethylpyridine

: cobalt(II) acetate monohydrate

: C26H24Co3F9N3O13Ru

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 16h; Inert atmosphere;	36%

...Expand

Tetrapropylammonium tetraoxoruthenate Chemical Properties

Molecular Structure of Tetrapropylammonium tetraoxoruthenate (CAS No.114615-82-6):

Molecular Formula: C₁₂H₂₈N.RuO₄
Molecular Weight: 351.425
CAS No: 114615-82-6
H bond acceptors: 5
H bond donors: 1
Freely Rotating Bonds: 8
Polar Surface Area: 74.27 Å²
InChI: InChI=1/C₁₂H₂₈N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;/rC12H28N.O4Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;1-5(2,3)4/h5-12H2,1-4H3;/q+1;-1
InChIKey: NQSIKKSFBQCBSI-DQAXOFGLAB
Std. InChI: InChI=1S/C₁₂H₂₈N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;
Std. InChIKey: NQSIKKSFBQCBSI-UHFFFAOYSA-N
Product Categories: Boron, Nitrile, Thio, TM-Cpds;Ammonium Polyhalides, etc. (Quaternary);Catalysts for Organic Synthesis;Classes of Metal Compounds;Environmentally-friendly Oxidation;Homogeneous Catalysts;Metal Complexes;Oxidation;Quaternary Ammonium Compounds;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Complexes (Environmentally-friendly Oxidation);Transition Metal Compounds
Systematic Name: Oxido-trioxo-ruthenium ; Etrapropylammonium

Tetrapropylammonium tetraoxoruthenate Safety Profile

Hazard Codes: Oxidizing O, Irritant Xi
Risk Statements: 5-8-36/37/38
R5 :Heating may cause an explosion.
R8 :Contact with combustible material may cause fire.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 17-26-36
S17:Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
RIDADR: UN 1479 5.1/PG 2
WGK Germany: 3
F: 3-10
HazardClass: 5.1
PackingGroup: III

Tetrapropylammonium tetraoxoruthenate Specification

Tetrapropylammonium tetraoxoruthenate (CAS No.114615-82-6), its synonyms are Tetrapropylammonium perruthenate ; N,N,N-Tripropylpropan-1-aminium oxido(trioxo)ruthenium .

Product Name

TETRAPROPYLAMMONIUM PERRUTHENATE

Synthetic route

Tetrapropylammonium tetraoxoruthenate Chemical Properties

Tetrapropylammonium tetraoxoruthenate Safety Profile

Tetrapropylammonium tetraoxoruthenate Specification

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Hazard Codes	O,Xi
Risk Statements	5-8-36/37/38
Safety Statements	17-26-36
RIDADR	UN 1479 5.1/PG 2
WGK Germany	3
F	3-10
HazardClass	5.1
PackingGroup	III