Tetrasulfide,di-2-propen-1-yl supplier

Name
diallyl tetrasulphide
EINECS 219-485-7
CAS No. 2444-49-7
Article Data8
CAS DataBase
Density 1.211 g/cm³
Solubility
Melting Point
Formula C₆H₁₀S₄
Boiling Point 279.2 °C at 760 mmHg
Molecular Weight 210.409
Flash Point 120.9 °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Allyltetrasulfide (7CI);Tetrasulfide, di-2-propenyl (9CI);Tetrasulfide, diallyl(8CI);Diallyl tetrasulfide;ICD 1585;
PSA 101.20000
LogP 4.03620

Synthetic route

: 107-05-1
3-chloroprop-1-ene

A: 2050-87-5
diallyl trisulfide

B: 2444-49-7
diallyl tetrasulfide

Conditions

Conditions	Yield
With sulfur; potassium hydroxide; water In tetrahydrofuran for 2h; Ambient temperature;	A 30% B 10%

: 870-23-5
prop-2-ene-1-thiol

: 2444-49-7
diallyl tetrasulfide

Conditions

Conditions	Yield
With diethyl ether; sodium ethanolate beim Behandeln anschliessend mit Dischwefeldichlorid in Petrolaether;

: 2179-57-9
diallyl disulphide

A: 62488-53-3
3-vinyl-4H-<1,2>-dithiin

B: 592-88-1
diallyl sulphide

C: 2050-87-5
diallyl trisulfide

D: 2444-49-7
diallyl tetrasulfide

Conditions

Conditions	Yield
at 50℃; for 168h; Further byproducts given;	A 0.7 % Chromat. B 3 % Chromat. C 9.7 % Chromat. D 0.47 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 820-30-4
5-methyl-4,7-dithiadeca-1,9-diene

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.45 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 80028-57-5
2‐ethenyl‐4H‐1,3‐dithiine

Conditions

Conditions	Yield
at 50℃; for 168h; Further byproducts given;	A 3 % Chromat. B 9.7 % Chromat. C 0.47 % Chromat. D 0.3 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 4-methyl-1,2,3-trithiolane

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.68 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 5-methyl-1,2,3,4-tetrathiane

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.42 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 7-methyl-4,5,8-trithiaundeca-1,10-diene

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.86 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 7-methyl-4,5,6,9,10-pentathiatrideca-1,12-diene

Conditions

Conditions	Yield
at 80℃; for 240h; Yield given. Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D n/a

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 8-methyl-4,5,6,9,10-pentathiatrideca-1,12-diene

Conditions

Conditions	Yield
at 80℃; for 240h; Yield given. Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D n/a

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 2-(2',3'-dithia-5'-hexenyl)-3,4-dihydro-2H-thiopyran

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 2.3 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 2-(2'-<3',4'-dihydro-2H-thiopyranyl>)-4H-<1,3>-dithiin

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.2 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 2-(2',3',4'-trithia-6'-heptenyl)-3,4-dihydro-2H-thiopyran

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.7 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 3-(2',3',4'-trithia-6'-heptenyl)-3,4-dihydro-2H-thiopyran

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.25 % Chromat.

...Expand

: 106-95-6
allyl bromide

A: 2179-57-9
diallyl disulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

Conditions

Conditions	Yield
With polysulfide; tetraethylammonium perchlorate In N,N-dimethyl-formamide in situ electrochemical generation of polysulfide from carbon-sulfur cathode; Title compound not separated from byproducts;

...Expand

: 107-05-1
3-chloroprop-1-ene

A: 2179-57-9
diallyl disulphide

B: 592-88-1
diallyl sulphide

C: 2050-87-5
diallyl trisulfide

D: 2444-49-7
diallyl tetrasulfide

Conditions

Conditions	Yield
Stage #1: With sodium sulfide; sodium hydroxide; sulfur; polyethylene glycol In water at 45 - 60℃; under 1173.78 Torr; Stage #2: 3-chloroprop-1-ene In water at 45 - 50℃; under 915.2 - 4897.34 Torr; Product distribution / selectivity; continuous process;
Stage #1: With sodium sulfide; sodium hydroxide; sulfur In water at 45 - 60℃; under 1173.78 Torr; Stage #2: 3-chloroprop-1-ene In water at 45 - 50℃; under 915.2 - 4897.34 Torr; Product distribution / selectivity; continuous process;

...Expand

: 539-86-6
allicin

A: 2179-57-9
diallyl disulphide

B: 592-88-1
diallyl sulphide

C: 2050-87-5
diallyl trisulfide

D: 2444-49-7
diallyl tetrasulfide

E: 118686-45-6
bis-2-propenyl pentasulfide

Conditions

Conditions	Yield
With sulfur; dibutylamine at 60 - 70℃; for 1h; Product distribution / selectivity;

...Expand

: 539-86-6
allicin

A: 2179-57-9
diallyl disulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

Conditions

Conditions	Yield
at 60 - 70℃; for 1h; Product distribution / selectivity;

...Expand

: 539-86-6
allicin

A: 2179-57-9
diallyl disulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 118686-45-6
bis-2-propenyl pentasulfide

Conditions

Conditions	Yield
at 70℃; for 1h; Product distribution / selectivity;
With sulfur at 60 - 70℃; for 1h; Product distribution / selectivity;

...Expand

: 539-86-6
allicin

A: 2179-57-9
diallyl disulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 118686-45-6
bis-2-propenyl pentasulfide

E: 137443-18-6
diallyl hexasulfide

Conditions

Conditions	Yield
With sulfur at 60 - 70℃; for 1h; Product distribution / selectivity;

...Expand

: 539-86-6
allicin

A: 2179-57-9
diallyl disulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 118686-45-6
bis-2-propenyl pentasulfide

E: 137443-18-6
diallyl hexasulfide

F: 139693-24-6
diallyl heptasulfide

Conditions

Conditions	Yield
With sulfur at 70℃; for 1h; Product distribution / selectivity;

...Expand

: 539-86-6
allicin

A: 2050-87-5
diallyl trisulfide

B: 2444-49-7
diallyl tetrasulfide

Conditions

Conditions	Yield
at 70℃; for 1h; Product distribution / selectivity;

: 539-86-6
allicin

A: 2050-87-5
diallyl trisulfide

B: 2444-49-7
diallyl tetrasulfide

C: 118686-45-6
bis-2-propenyl pentasulfide

D: 137443-18-6
diallyl hexasulfide

E: 139693-24-6
diallyl heptasulfide

Conditions

Conditions	Yield
With sulfur at 70℃; for 1h; Product distribution / selectivity;

...Expand

: 539-86-6
allicin

A: 2050-87-5
diallyl trisulfide

B: 2444-49-7
diallyl tetrasulfide

C: 118686-45-6
bis-2-propenyl pentasulfide

D: 139693-24-6
diallyl heptasulfide

Conditions

Conditions	Yield
With sulfur at 70℃; for 1h; Product distribution / selectivity;

...Expand

: 2444-49-7
diallyl tetrasulfide

zinc: zinc

: 592-88-1
diallyl sulphide

: copper(II) bromide dihydrate

: 2444-49-7
diallyl tetrasulfide

: 3CuBr*diallyltetrasulfide

Conditions

Conditions	Yield
In ethanol Electrochem. Process; diallyltetrasulfide added to a soln. of CuBr2*2H2O in EtOH, placed into glass reservoir, copper electrodes mounted via air tight seal, system maintained for 20 h under an applied tension of alternating current (50 Hz, 0.2 V, 0.1 mA); crystn. on electrodes;

Tetrasulfide,di-2-propen-1-yl Specification

The Tetrasulfide,di-2-propen-1-yl, with CAS registry number 2444-49-7, has the systematic name of diprop-2-en-1-yltetrasulfane. Besides this, it is also called Bis(2-propenyl) pertetrasulfide. And the chemical formula of this chemical is C₆H₁₀S₄. What's more, its EINECS is 219-485-7.

Physical properties of Tetrasulfide,di-2-propen-1-yl: (1)ACD/LogP: 5.62; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 5.62; (4)ACD/LogD (pH 7.4): 5.62; (5)ACD/BCF (pH 5.5): 10930.74; (6)ACD/BCF (pH 7.4): 10930.74; (7)ACD/KOC (pH 5.5): 27067.87; (8)ACD/KOC (pH 7.4): 27067.87; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 7; (12)Polar Surface Area: 101.2 Å²; (13)Index of Refraction: 1.623; (14)Molar Refractivity: 61.28 cm³; (15)Molar Volume: 173.6 cm³; (16)Polarizability: 24.29×10^-24cm³; (17)Surface Tension: 45.7 dyne/cm; (18)Density: 1.211 g/cm³; (19)Flash Point: 120.9 °C; (20)Enthalpy of Vaporization: 49.7 kJ/mol; (21)Boiling Point: 279.2 °C at 760 mmHg; (22)Vapour Pressure: 0.00692 mmHg at 25°C.

Preparation: this chemical can be prepared by 3-chloro-propene. This reaction will need reagents S₈, KOH and solvent tetrahydrofuran. The reaction time is 2 hour(s). The yield is about 30%.

Tetrasulfide,di-2-propen-1-yl can be prepared by 3-chloro-propene.

You can still convert the following datas into molecular structure:
(1)SMILES: S(SSSC\C=C)C/C=C
(2)InChI: InChI=1/C6H10S4/c1-3-5-7-9-10-8-6-4-2/h3-4H,1-2,5-6H2
(3)InChIKey: RMKCQUWJDRTEHE-UHFFFAOYAZ
(4)Std. InChI: InChI=1S/C6H10S4/c1-3-5-7-9-10-8-6-4-2/h3-4H,1-2,5-6H2
(5)Std. InChIKey: RMKCQUWJDRTEHE-UHFFFAOYSA-N

Product Name

diallyl tetrasulphide

Synthetic route

Tetrasulfide,di-2-propen-1-yl Specification

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