Product Name

  • Name

    cobalt trichloride

  • EINECS 233-574-8
  • CAS No. 10241-04-0
  • Density g/cm3
  • Solubility
  • Melting Point
  • Formula Cl3Co
  • Boiling Point °Cat760mmHg
  • Molecular Weight 165.352
  • Flash Point °C
  • Transport Information
  • Appearance
  • Safety
  • Risk Codes
  • Molecular Structure Molecular Structure of 10241-04-0 (cobalt trichloride)
  • Hazard Symbols
  • Synonyms Cobalttrichloride; Cobaltic chloride
  • PSA 0.00000
  • LogP -8.98800

Synthetic route

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Conditions
ConditionsYield
With Cl2 In ethanol oxidation at -60°C;;
With HCl In ethanol Electrochem. Process; anodic oxidation of CoCl2, dissolved in cold alcoholic HCl, formation of a green soln.;;
With HCl; Cl2 In ethanol oxidation of CoCl2, dissolved in cold alcoholic HCl, by chlorination, formation of a green soln.;;
potassium hexacyanocobaltate(III)

potassium hexacyanocobaltate(III)

ammonium chloride

ammonium chloride

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Conditions
ConditionsYield
In neat (no solvent) calcination with NH4Cl;;
In neat (no solvent) calcination with NH4Cl;;
hydrogenchloride
7647-01-0

hydrogenchloride

cobalt(III) oxide

cobalt(III) oxide

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Conditions
ConditionsYield
In diethyl ether suspension of freshly prepared Co2O3 is treated at -5°C in the dark with dry HCl-gas;;
In diethyl ether suspension of Co2O3 in ether is treated in the dark with HCl-gas;;
In diethyl ether suspension of freshly prepared Co2O3 is treated at -5°C in the dark with dry HCl-gas;;
In diethyl ether suspension of Co2O3 in ether is treated in the dark with HCl-gas;;
hydrogenchloride
7647-01-0

hydrogenchloride

(x)Co2O3*(x)H2O

(x)Co2O3*(x)H2O

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Conditions
ConditionsYield
In ethanol gaseous HCl is passed into a suspension of Co2O3*xH2O in abs. alcohol;; solution is concentrated in vacuum at -15 - -20°C to a small volume and stored over CaCl2, P2O5 and NaOH at low temperatures;;
hydrogenchloride
7647-01-0

hydrogenchloride

cobalt
7440-48-4

cobalt

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Conditions
ConditionsYield
In diethyl ether Electrolysis; solution of HCl in ether is electrolyzed with Co-anode and Cu-cathode at 0°C in the dark;;
In diethyl ether Electrolysis; solution of HCl in ether is electrolyzed with Co-anode and Cu-cathode at 0°C in the dark;;
hydrogenchloride
7647-01-0

hydrogenchloride

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Conditions
ConditionsYield
With CaCl2 In ethanol -70°C;;
chlorine
7782-50-5

chlorine

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Conditions
ConditionsYield
In neat (no solvent) CoCl2 is treated with Cl2 at ambient temperatures;;
In neat (no solvent) at higher temperatures;;
In neat (no solvent) at higher temperatures;;
In neat (no solvent) CoCl2 is treated with Cl2 at ambient temperatures;;
In ethanol -60°C;;
perdeuteriopyridine
7291-22-7

perdeuteriopyridine

C(2)H3C(NO(2)H)C(NO(2)H)C(2)H3

C(2)H3C(NO(2)H)C(NO(2)H)C(2)H3

2-bromo-[1,1,1,2,3,3,3-2H7]-propane
39091-63-9

2-bromo-[1,1,1,2,3,3,3-2H7]-propane

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Co(C(2)H(C(2)H3)2)(NC5(2)H5)(NOCC(2)H3CC(2)H3NO(2)H)2

Co(C(2)H(C(2)H3)2)(NC5(2)H5)(NOCC(2)H3CC(2)H3NO(2)H)2

Conditions
ConditionsYield
With deuteriated sodium hydroxide In d(4)-methanol CoCl3 and glyoxime were dissolved in MeOD containing NaOD and pyridine-d5 under N2, then isopropyl bromide was added under D2 and stirred; neutralized with DCl, the soln. was diluted with D2O and filtered, the crystals were washed with D2O, petroleum ether and ether, then dissolved in CDCl3/MeOD, and pptd. by D2O, drying;86%
cobalt(III) chloride
10241-04-0

cobalt(III) chloride

4-(2-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)hydrazono)-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothioamide
624746-31-2

4-(2-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)hydrazono)-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothioamide

[Co(N-(3-methyl 1-thiocarbamyl-5-oxo-2-pyrazolin-4-ylene)-N'-(4'-antipyrine)hydrazine)Cl3]
624746-09-4

[Co(N-(3-methyl 1-thiocarbamyl-5-oxo-2-pyrazolin-4-ylene)-N'-(4'-antipyrine)hydrazine)Cl3]

Conditions
ConditionsYield
In ethanol; water refluxing soln. metal salt in aq. EtOH and soln. ligand in EtOH for 1 h; react. mixt. was cooled, ppt. was filtered, washed with EtOH and benzene, and dried over P4O10; elem. anal.;65%
cobalt(III) chloride
10241-04-0

cobalt(III) chloride

1,2-dicyano-4,5-diheptylbenzene
142557-68-4

1,2-dicyano-4,5-diheptylbenzene

(2,3,9,10,16,17,23,24-octaheptylphthalocyaninato)cobalt(II)
165285-38-1

(2,3,9,10,16,17,23,24-octaheptylphthalocyaninato)cobalt(II)

Conditions
ConditionsYield
In ethylene glycol refluxing (24 h); cooling, pouring into MeOH (pptn.), centrifugation, washing (acetone), drying, chromy. (silica gel/toluene), collection of blue fraction, evapn.; elem. anal.;63%
bis-(biacetylmonoxime)carbohydrazone
144934-93-0

bis-(biacetylmonoxime)carbohydrazone

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

{Co(OC(NHNC(CH3)C(CH3)NO)2)Cl}
145393-95-9

{Co(OC(NHNC(CH3)C(CH3)NO)2)Cl}

Conditions
ConditionsYield
In ethanol refluxing, 8h; evapn.; cooling; addn. of Et2O; pptn.; drying (vac., CaCl2); elem. anal.;62%
3,6-diheptylphthalodinitrile
119931-43-0

3,6-diheptylphthalodinitrile

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

(1,4,8,11,15,18,22,25-octaheptylphthalocyaninato)cobalt(II)
165285-37-0

(1,4,8,11,15,18,22,25-octaheptylphthalocyaninato)cobalt(II)

Conditions
ConditionsYield
In ethylene glycol refluxing (24 h); cooling, pouring into MeOH (pptn.), centrifugation, washing (acetone), drying, chromy. (silica gel/toluene), collection of blue fraction, evapn.; elem. anal.;58%
ammonium thiocyanate

ammonium thiocyanate

2-((2-((o-hydroxy-α-methylbenzylidene)amino)ethyl)amino)ethanol
99899-09-9

2-((2-((o-hydroxy-α-methylbenzylidene)amino)ethyl)amino)ethanol

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

2-(2-Aminoethylamino)ethanol
111-41-1

2-(2-Aminoethylamino)ethanol

Co(2-(1-[2-(2-hydroxyethylamino)ethylimino]ethyl)phenolate)(2-(2-aminoethylamino)ethanol)(thiocyanate)

Co(2-(1-[2-(2-hydroxyethylamino)ethylimino]ethyl)phenolate)(2-(2-aminoethylamino)ethanol)(thiocyanate)

Conditions
ConditionsYield
In methanol MeOH soln. of CoCl3 (0.1 mmol) added to MeOH soln. of HOC6H4CH(CH3)NCH2CH2NCH2CH2OH (0.1 mmol), 2-(2-aminoethylamino)ethanol (0.1 mmol) and NH4NCS (0.1 mmol), stirred at ambient temp. for 30 min; allowed to slowly evaporated in air for 13 d, filtrated, washed with MeOH, dried in air; elem. anal., XRD;32%
water
7732-18-5

water

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

cobalt(II) chloride hexahydrate

cobalt(II) chloride hexahydrate

Conditions
ConditionsYield
In water decomposition in excessive water;;
In water
water
7732-18-5

water

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

cobalt(II) chloride dihydrate

cobalt(II) chloride dihydrate

Conditions
ConditionsYield
In water small amount of water;;
In water small amount of water;;
ammonium sulfite

ammonium sulfite

water
7732-18-5

water

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

3 ammonium sulfite * cobalt(III) sulfite * 2 H2O

3 ammonium sulfite * cobalt(III) sulfite * 2 H2O

Conditions
ConditionsYield
In not given a moderately concd. CoCl3 soln. mixed with a great excess of (NH4)2SO3;; crystn.;;
In not given a moderately concd. CoCl3 soln. mixed with a great excess of (NH4)2SO3;; crystn.;;
sodium stearate
822-16-2

sodium stearate

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Co(C17H35COO)2F
125171-18-8

Co(C17H35COO)2F

Conditions
ConditionsYield
With hydrogen fluoride In water Na stearate is added to an aq. soln. of CoCl3, after 2 h stirring the formed ppt. of Co stearate intermediate is filtered; an aq. 10% soln. of HF is added to the Co stearate; After 2 d the liq. phase is decanted and the residue dried in air;
cobalt(III) chloride
10241-04-0

cobalt(III) chloride

sodium nitrite
7632-00-0

sodium nitrite

trisodium hexanitrocobaltate(III)

trisodium hexanitrocobaltate(III)

Conditions
ConditionsYield
In diethyl ether byproducts: NaCl;
In diethyl ether byproducts: NaCl;
cobalt(III) chloride
10241-04-0

cobalt(III) chloride

cobalt(II) chloride dihydrate

cobalt(II) chloride dihydrate

Conditions
ConditionsYield
With air In neat (no solvent)
With air In neat (no solvent)
cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Co(2+)*2{CoCl3(H2O)3}(1-)=Co{CoCl3(H2O)3}2

Co(2+)*2{CoCl3(H2O)3}(1-)=Co{CoCl3(H2O)3}2

Conditions
ConditionsYield
With water In neat (no solvent) excessive CoCl3;;
With H2O In neat (no solvent) excessive CoCl3;;
cobalt(III) chloride
10241-04-0

cobalt(III) chloride

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: Cl2; on light or in vacuum;;
In neat (no solvent) byproducts: Cl2; on light or in vacuum;;
ammonia
7664-41-7

ammonia

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

hexammine cobalt(III) chloride

hexammine cobalt(III) chloride

Conditions
ConditionsYield
In diethyl ether 0°C;;
In diethyl ether 0°C;;
cobalt(III) chloride
10241-04-0

cobalt(III) chloride

H(1+)*{CoCl3(H2O)3}(1-)=H{CoCl3(H2O)3}

H(1+)*{CoCl3(H2O)3}(1-)=H{CoCl3(H2O)3}

Conditions
ConditionsYield
With humid air
1-(3-hydroxy-2-naphthoyl)-4-phenyl-3-thiosemicarbazide
54417-21-9

1-(3-hydroxy-2-naphthoyl)-4-phenyl-3-thiosemicarbazide

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Co(2+)*HOC10H6CONNCSNHC6H5(2-)={Co(C18H13N3O2S)}

Co(2+)*HOC10H6CONNCSNHC6H5(2-)={Co(C18H13N3O2S)}

Conditions
ConditionsYield
With sodium acetate In ethanol refluxing of equimolar amts. of H2NPTS and CoCl3 in presence of sodium acetate in abs. ethanol for 2 h;; filtration; washing with ethanol and diethyl ether for several times; drying in a vacuum desiccator over anhydrous CaCl2; elem. anal.;;
1-(3-hydroxy-2-naphthoyl)-4-phenyl-3-thiosemicarbazide
54417-21-9

1-(3-hydroxy-2-naphthoyl)-4-phenyl-3-thiosemicarbazide

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Co(2+)*2OC10H6CONHNHCSNHC6H5(1-)={Co(C18H14N3O2S)2}

Co(2+)*2OC10H6CONHNHCSNHC6H5(1-)={Co(C18H14N3O2S)2}

Conditions
ConditionsYield
In ethanol refluxing of equimolar amts. of H2NPTS and CoCl3 in abs. ethanol for 2 h;; filtration; washing with ethanol and diethyl ether for several times; drying in a vacuum desiccator over anhydrous CaCl2; elem. anal.;;
p-chloroisonitrosobenzoylacetone
6797-46-2

p-chloroisonitrosobenzoylacetone

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

cobalt(III) tris-p-chloroisonitrosobenzoylacetonate

cobalt(III) tris-p-chloroisonitrosobenzoylacetonate

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water aq. soln. of metal chloride reacted with ethanolic soln. of ligand in 1/3 molar ratio; NaOH added; pH 6;; ppt. washed with EtOH; dried in vacuum; elem. anal.;;
p-bromoisonitrosobenzoylacetone
95732-21-1

p-bromoisonitrosobenzoylacetone

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

cobalt(III) tris-p-bromoisonitrosobenzoylacetonate

cobalt(III) tris-p-bromoisonitrosobenzoylacetonate

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water aq. soln. of metal chloride reacted with ethanolic soln. of ligand in 1/3 molar ratio; NaOH added; pH 6;; ppt. washed with EtOH; dried in vacuum; elem. anal.;;
ethoxythiocarbonyl hydrazide hydrochloride
25645-71-0

ethoxythiocarbonyl hydrazide hydrochloride

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

(Co(NH2NHCSOC2H5)3)(3+)*3Cl(1-)={Co(NH2NHCSOC2H5)3}Cl3

(Co(NH2NHCSOC2H5)3)(3+)*3Cl(1-)={Co(NH2NHCSOC2H5)3}Cl3

Conditions
ConditionsYield
With HCl In ethanol ethanolic solns. of the metal chloride and the hydrazide hydrochloride were mixed, molar ratio 1:3, and some drops HCl added;; after slow evapn. of solvent, the complex was filtered off, washed with EtOH, and dried in vac.; elem. anal.;;
6-methyl-6-(4-amino-2-azabutyl)-1-thia-4-azacycloheptane
150899-98-2

6-methyl-6-(4-amino-2-azabutyl)-1-thia-4-azacycloheptane

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

cis-dichloro-(6-methyl-6-(4-amino-2-azabutyl)-1-thia-4-azacycloheptane)cobalt(III) perchlorate* 0.5hydrate

cis-dichloro-(6-methyl-6-(4-amino-2-azabutyl)-1-thia-4-azacycloheptane)cobalt(III) perchlorate* 0.5hydrate

Conditions
ConditionsYield
In methanol The ligand is dissolved in CH3OH, whilst air is drawn through the soln. a methanol soln. of CoCl3 is added dropwise over 0.5 h.; The air stream is continued for 2 h after completion of addn. followed by filtn., after dilution with water cation excange chromy., solvent is removed under reduced pressure, residue is crystd. from an aq. NaClO4 soln., elem. anal.;
2-(2-carbamothioylhydrazono)butanoic acid
89417-93-6

2-(2-carbamothioylhydrazono)butanoic acid

cobalt(III) chloride
10241-04-0

cobalt(III) chloride

Co(SC(NH2)NHNC(CH2CH3)COO)(SC(NH2)NNC(CH2CH3)COO)

Co(SC(NH2)NHNC(CH2CH3)COO)(SC(NH2)NNC(CH2CH3)COO)

Conditions
ConditionsYield
With NaHCO3 In water soln. od CoCl3 added slowly to H2KBTSC/NaHCO3 in H2O; stirred;; slow evapn.; crystn.; elem. anal.;;

Trichlorocobalt Chemical Properties

IUPAC Name: Trichlorocobalt
CAS: 10241-04-0
The Molecular formula of Trichlorocobalt ( CAS NO.10241-04-0): Cl3Co
The Molecular Weight of Trichlorocobalt ( CAS NO.10241-04-0): 165.2922
Molecular Structure of Trichlorocobalt ( CAS NO.10241-04-0): 
 
Enthalpy of Vaporization: 16.15 kJ/mol 
Vapour Pressure: 33900 mmHg at 25°C 
Water Solubility: 6616(mg/L) at 25 °C

Trichlorocobalt Specification

  The chemical synonyms of Trichlorocobalt ( CAS NO.10241-04-0) are Cobalt trichloride ; Cobaltic Chloride ; Cobalt(III) trichloride ; Trichlorocobalt(III) .
 

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