Triethoxyvinylsilane supplier

Name
Triethoxyvinylsilane
EINECS 201-081-7
CAS No. 78-08-0
Article Data41
CAS DataBase
Density 0.904 g/cm³
Solubility decomposes
Melting Point <0 °C
Formula C₈H₁₈O₃Si
Boiling Point 160.5 °C at 760 mmHg
Molecular Weight 190.315
Flash Point 34.4 °C
Transport Information UN 1993 3/PG 3
Appearance Colorless transparent liquid
Safety 26-36
Risk Codes 10-36/37
Molecular Structure
Hazard Symbols Xi
Synonyms Silane,triethoxyvinyl- (6CI,8CI);A 151;AH 151;DL 151;Dynasylan VTEO;DynasylanVTEU;EB 151;Ethenyltriethoxysilane;GF 56;Geniosil GF 56;JH-V 151;KBE1003;KH 151;KH 858;LS 2300;NQ 71;NSC 151;NV 1107;Polyscience VTES;S220;SCA 1613;Si 255;Sila-Ace S 220;Silane A 151;Silquest A 151;TM 12;TSL8311;Tri(ethoxo)(vinyl)silane;Silane,ethenyltriethoxy-;UC-A 151;Unisilan 612;Unisilan U 612;V 4910;VP-Si 225;VTES;VTS-E;Vinyltriethoxysilane;WD 20;WD20 (silane);YGO 1203;
PSA 27.69000
LogP 1.76000

Synthetic route

: 64-17-5
ethanol

: 75-94-5
trichlorovinylsilane

: 78-08-0
Triethoxyvinylsilane

Conditions

Conditions	Yield
In dichloromethane at 50 - 80℃; for 3h;	99%
In dichloromethane at 50℃;	78%
With tin(IV) chloride; cyclohexene for 1h; Ambient temperature;	73.4%

: 998-30-1
Triethoxysilane

: 74-86-2
acetylene

: 78-08-0
Triethoxyvinylsilane

Conditions

Conditions	Yield
at 90℃; under 225.023 - 375.038 Torr; Temperature;	96.7%
With acetylacetonatodicarbonylrhodium(l) for 2h; the temperature did not rise above 45 deg C;	70%
With cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate at 25℃; for 2h;	95 %Spectr.
With platinum on activated charcoal at 130℃; under 14710.2 Torr;

: 78-10-4
tetraethoxy orthosilicate

: 75-94-5
trichlorovinylsilane

A: 78-08-0
Triethoxyvinylsilane

B: 18187-22-9
vinyldi(ethoxy)chlorosilane

C: 56124-75-5
vinyl(ethoxy)dichlorosilane

Conditions

Conditions	Yield
at 20 - 22℃; for 150h;	A 2% B 95% C 1%

...Expand

: 64-17-5
ethanol

: 75-94-5
trichlorovinylsilane

A: 78-08-0
Triethoxyvinylsilane

B: 3682-26-6
1,3-diivinyl-1,1,3,3-tetraethoxydisiloxane

Conditions

Conditions	Yield
In diethyl ether at 45 - 80℃; for 3h; Product distribution; different chlorosilanes, alcohols, solvents and reaction temperatures;	A 92.9% B 5.5%

...Expand

: 74-85-1
ethene

: 998-30-1
Triethoxysilane

A: 78-07-9
ethyltriethoxy silane

B: 78-08-0
Triethoxyvinylsilane

Conditions

Conditions	Yield
With FeBr2(iPrPQpy); lithium triethylborohydride In toluene at 70℃; under 1520.1 Torr; for 2h; Inert atmosphere; Glovebox; Schlenk technique;	A 10% B 90%
With lithium triethylborohydride In toluene at 70℃; under 1520.1 Torr; for 2h; Inert atmosphere; Glovebox; Schlenk technique;	A 60% B 40%
With FeBr2(iPrPQpy); sodium triethylborohydride In toluene at 70℃; under 1520.1 Torr; for 2h; Catalytic behavior; Reagent/catalyst; Cooling;

...Expand

: 998-30-1
Triethoxysilane

: 74-86-2
acetylene

A: 78-08-0
Triethoxyvinylsilane

B: 16068-37-4
1,2-bis(triethoxysilyl)ethane

Conditions

Conditions	Yield
With bis(triphenylphosphine)platinum(II) dichloride In benzene at 80℃; for 10h; Product distribution; other hydrosilanes; var. group-VIII metal phosphine complexes as catalysts, var. solvents, var. conc., var. temperatures and times;	A 86% B 3 % Chromat.
With bis(triphenylphosphine)platinum(II) dichloride In benzene at 80℃; for 10h;	A 86% B 3 % Chromat.
With dihydrogen hexachloroplatinate In benzene at 40℃; for 1h;	A 36% B 30%

...Expand

: 74-85-1
ethene

: 1873-88-7
1,1,1,3,5,5,5-heptamethyltrisiloxan

A: 78-07-9
ethyltriethoxy silane

B: 78-08-0
Triethoxyvinylsilane

Conditions

Conditions	Yield
With CoCl2(iPrPQpy); lithium triethylborohydride In toluene at 70℃; under 1520.1 Torr; for 2h; Inert atmosphere; Glovebox; Schlenk technique;	A 86% B 14%

...Expand

: 75-94-5
trichlorovinylsilane

: 78-08-0
Triethoxyvinylsilane

Conditions

Conditions	Yield
With C2H5OH; pyridine	60.1%
With C2H5OH	50.4%

: 998-30-1
Triethoxysilane

: 74-86-2
acetylene

A: 78-08-0
Triethoxyvinylsilane

B: 91458-95-6
(E)-1,2-bis(triethoxysilyl)ethylene

Conditions

Conditions	Yield
With {palladium-dichloro-(P(C3H7)3)2} In xylene at 80℃; for 3h;	A 54% B 9%

...Expand

: 78-10-4
tetraethoxy orthosilicate

: 75-94-5
trichlorovinylsilane

A: 1825-82-7
trichloroethoxysilane

B: 4667-38-3
dichlorodiethoxysilane

C: 4667-99-6
chlorotriethoxysilane

D: 78-08-0
Triethoxyvinylsilane

E: 18187-22-9
vinyldi(ethoxy)chlorosilane

F: 56124-75-5
vinyl(ethoxy)dichlorosilane

Conditions

Conditions	Yield
N,N-dimethyl-formamide at 90℃; for 5.5h; Product distribution; Thermodynamic data; Equilibrium constant; ΔG0, ΔH0;

...Expand

: 64-17-5
ethanol

: 75-94-5
trichlorovinylsilane

A: 1825-62-3
ethyl trimethylsilyl ether

B: 78-08-0
Triethoxyvinylsilane

C: 18187-22-9
vinyldi(ethoxy)chlorosilane

D: 56124-75-5
vinyl(ethoxy)dichlorosilane

Conditions

Conditions	Yield
With chloro-trimethyl-silane for 1h; Ambient temperature; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 64-17-5
ethanol

: 75-94-5
trichlorovinylsilane

A: 78-08-0
Triethoxyvinylsilane

B: 18187-22-9
vinyldi(ethoxy)chlorosilane

C: 56124-75-5
vinyl(ethoxy)dichlorosilane

Conditions

Conditions	Yield
With chloro-trimethyl-silane for 1h; Product distribution; Ambient temperature; various educt ratios;

...Expand

: 998-30-1
Triethoxysilane

: 74-86-2
acetylene

platinum/charcoal: platinum/charcoal

A: 78-08-0
Triethoxyvinylsilane

B: 16068-37-4
1,2-bis(triethoxysilyl)ethane

Conditions

Conditions	Yield
at 130℃; under 14710.2 Torr;

...Expand

: 64-17-5
ethanol

: 18187-22-9
vinyldi(ethoxy)chlorosilane

: 78-08-0
Triethoxyvinylsilane

Conditions

Conditions	Yield
at 20℃; Kinetics; Equilibrium constant;

: 2-Aminoethoxydiethoxyvinylsilan

: Di-(2-aminoethoxy)-ethoxyvinylsilan

A: 78-08-0
Triethoxyvinylsilane

B: 15942-83-3
tris(2-aminoethoxy)(vinyl)silane

Conditions

Conditions	Yield
at 60℃; Equilibrium constant;

...Expand

: 998-30-1
Triethoxysilane

: 74-86-2
acetylene

A: 78-07-9
ethyltriethoxy silane

B: 78-08-0
Triethoxyvinylsilane

C: 16068-37-4
1,2-bis(triethoxysilyl)ethane

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex at 5℃; for 6h;	A 7 %Spectr. B 70 %Spectr. C 15 %Spectr.

...Expand

: 998-30-1
Triethoxysilane

: 74-86-2
acetylene

A: 78-07-9
ethyltriethoxy silane

B: 78-08-0
Triethoxyvinylsilane

C: 16068-37-4
1,2-bis(triethoxysilyl)ethane

D: 87061-56-1
1,2-bis(triethoxysilyl)ethylene

Conditions

Conditions	Yield
With hexachloroplatinic(IV) acid hydrate at 25℃; for 3h;	A 8 %Spectr. B 49 %Spectr. C 19 %Spectr. D 5 %Spectr.

...Expand

: 998-30-1
Triethoxysilane

: 74-86-2
acetylene

A: 78-08-0
Triethoxyvinylsilane

B: 87061-56-1
1,2-bis(triethoxysilyl)ethylene

Conditions

Conditions	Yield
With chloro(1,5-cyclooctadiene)rhodium(I) dimer at 25℃; for 18h;	A 74 %Spectr. B 7 %Spectr.

...Expand

: 91458-95-6
(E)-1,2-bis(triethoxysilyl)ethylene

: 111-92-2
dibutylamine

A: 78-08-0
Triethoxyvinylsilane

B: N-(triethoxysilyl)dibutylamine

Conditions

Conditions	Yield
With carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) In toluene at 120℃; for 17h; Inert atmosphere; Schlenk technique;	A n/a B 88 %Chromat.

...Expand

: 91458-95-6
(E)-1,2-bis(triethoxysilyl)ethylene

: 109-89-7
diethylamine

A: 78-08-0
Triethoxyvinylsilane

B: 35077-00-0
N-(triethoxysilyl)diethylamine

Conditions

Conditions	Yield
With carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) In toluene at 120℃; for 24h; Inert atmosphere; Schlenk technique;	A n/a B 86 %Chromat.

...Expand

: 110-89-4
piperidine

: 91458-95-6
(E)-1,2-bis(triethoxysilyl)ethylene

A: 78-08-0
Triethoxyvinylsilane

B: C11H25NO3Si

Conditions

Conditions	Yield
With carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) In toluene at 120℃; for 24h; Inert atmosphere; Schlenk technique;	A n/a B 88 %Chromat.

...Expand

: 91458-95-6
(E)-1,2-bis(triethoxysilyl)ethylene

: 103-69-5
N-ethyl-N-phenylamine

A: 78-08-0
Triethoxyvinylsilane

B: C14H25NO3Si

Conditions

Conditions	Yield
With carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) In toluene at 120℃; for 48h; Inert atmosphere; Schlenk technique;	A n/a B 90 %Chromat.

...Expand

: 91458-95-6
(E)-1,2-bis(triethoxysilyl)ethylene

: 62-53-3
aniline

A: 78-08-0
Triethoxyvinylsilane

B: 18027-61-7
N-phenyl-1,1,1-triethoxysilanamine

Conditions

Conditions	Yield
With carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) In toluene at 120℃; for 48h; Inert atmosphere; Schlenk technique;	A n/a B 95 %Chromat.

...Expand

: 91458-95-6
(E)-1,2-bis(triethoxysilyl)ethylene

: 75-31-0
isopropylamine

A: 78-08-0
Triethoxyvinylsilane

B: N-(triethoxysilyl)isopropylamine

Conditions

Conditions	Yield
With carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) In toluene at 120℃; for 17h; Inert atmosphere; Schlenk technique;	A n/a B 94 %Chromat.

...Expand

: 5813-64-9
2,2-dimethylpropylamine

: 91458-95-6
(E)-1,2-bis(triethoxysilyl)ethylene

A: 78-08-0
Triethoxyvinylsilane

B: (tert-butylamino) triethoxysilane

Conditions

Conditions	Yield
With carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) In toluene at 120℃; for 24h; Inert atmosphere; Schlenk technique;	A n/a B 92 %Chromat.

...Expand

: 997-11-5
N-deuterio-diethylamine

: 91458-95-6
(E)-1,2-bis(triethoxysilyl)ethylene

A: 74-85-1
ethene

B: 78-08-0
Triethoxyvinylsilane

Conditions

Conditions	Yield
With carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) In (2)H8-toluene; toluene

...Expand

: 64-17-5
ethanol

: 3682-26-6
1,3-diivinyl-1,1,3,3-tetraethoxydisiloxane

: 78-08-0
Triethoxyvinylsilane

Conditions

Conditions	Yield
With potassium hydroxide at 240℃; for 3h; Autoclave; Molecular sieve;

: 88-15-3
2-Acetylthiophene

: 78-08-0
Triethoxyvinylsilane

: 161467-61-4
2-acetyl-3-<2-(triethoxysilyl)ethyl>thiophene

Conditions

Conditions	Yield
With sodium formate; triphenylphosphine; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 In toluene at 140℃; for 2h; Murai reaction;	100%
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; sodium formate; triphenylphosphine In toluene at 140℃; for 2h;	100%
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene for 1h; Heating;	93%
With rhodium(III) chloride hydrate; sodium formate; tris(para-trifluoromethyl)phenyl phosphine In 1,4-dioxane at 80℃; for 20h; Inert atmosphere;	90%
With [RhCl2(p-cymene)]2; sodium formate; triphenylphosphine In isopropyl alcohol; acetone at 80℃; Inert atmosphere;	70%

: 941-98-0
1'-naphthacetophenone

: 78-08-0
Triethoxyvinylsilane

: 161467-57-8
2'-<2-(triethoxysilyl)ethyl>-1'-acetonaphthone

Conditions

Conditions	Yield
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; sodium formate; triphenylphosphine In toluene at 140℃; for 0.3h;	100%
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene for 6h; Heating;	67%
With bis(1,5-cyclooctadiene)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; C38H28P2 In 1,3-dioxane at 130℃; for 24h; Reagent/catalyst; regioselective reaction;	45%

: 78-08-0
Triethoxyvinylsilane

: 529-34-0
3,4-dihydronaphthalene-1(2H)-one

: 154735-94-1
8-(2-triethoxysilyl-ethyl)-3,4-dihydro-2H-naphthalen-1-one

Conditions

Conditions	Yield
With sodium formate; triphenylphosphine; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 In toluene at 140℃; Murai reaction;	100%
With (HCHO+4PPh3)-Ru(II) supported on CeO2 In toluene at 140℃; for 0.5h; Inert atmosphere; Schlenk technique;	99%
With carbonyldihydridotris(triphenylphosphine)ruthenium(II) In toluene at 125℃; for 0.5h; Inert atmosphere;	96%

: 78-08-0
Triethoxyvinylsilane

: 577-16-2, 122382-54-1
2-Methylacetophenone

: 157557-78-3
1-[6-methyl-2-(2-(triethoxysilyl)ethyl)phenyl]-ethanone

Conditions

Conditions	Yield
[Ru(H2)(CO)(PPh3)3] In toluene at 135℃; for 2h; Addition;	100%
carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene for 2h; Heating; other catalysts: Ru(CO)2(PPh3)3, RuH2(PPh3)4, Ru(CO)3(PPh3)2;	93%
With rhodium(III) chloride hydrate; sodium formate; tris(para-trifluoromethyl)phenyl phosphine In 1,4-dioxane at 80℃; for 20h; Inert atmosphere;	67%

: 78-08-0
Triethoxyvinylsilane

: 120820-40-8
1-(2-(((1,1-dimethylethyl)dimethylsilyl)oxy)phenyl)ethanone

: 1-(6-(2-(triethoxysilyl)ethyl)-2-(((1,1-dimethylethyl)dimethylsilyl)oxy)phenyl)ethanone

Conditions

Conditions	Yield
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) for 12h;	100%
carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene for 12h; Heating;	100%

: 78-08-0
Triethoxyvinylsilane

: 40751-52-8
2-Isopropyl-1-benzonitrile

: C18H29NO3Si

Conditions

Conditions	Yield
carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene at 135℃; for 24h; Addition;	100%

: 78-08-0
Triethoxyvinylsilane

: 104-85-8
para-methylbenzonitrile

: C24H43NO6Si2

Conditions

Conditions	Yield
carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene at 135℃; for 24h; Addition;	100%

: 78-08-0
Triethoxyvinylsilane

: 86-53-3
1-Cyanonaphthalene

: 251471-74-6
C19H25NO3Si

Conditions

Conditions	Yield
carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene at 135℃; for 16h; Addition;	100%
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II)	100%
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene at 135℃; for 24h; regioselective reaction;	100%

: 78-08-0
Triethoxyvinylsilane

: 712-50-5
Cyclohexyl phenyl ketone

: 1151886-44-0
cyclohexyl-{2-[(2-triethoxysilyl)-ethyl]phenyl}methanone

Conditions

Conditions	Yield
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; sodium formate; triphenylphosphine In toluene at 140℃; for 1h;	100%

: 78-08-0
Triethoxyvinylsilane

: 98-86-2
acetophenone

: 154735-85-0
1-[2-[2-(triethoxysilyl)ethyl]phenyl]ethanone

Conditions

Conditions	Yield
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; sodium formate; triphenylphosphine In toluene at 140℃; for 1h;	100%
With [Ru(OCOH)2PPh3(p-cym)]; triphenylphosphine In isopropyl alcohol at 80℃; Inert atmosphere;	93%

: 78-08-0
Triethoxyvinylsilane

: 1444623-88-4
C11H14BrO4P

: 1444623-89-5
C13H17O4P

Conditions

Conditions	Yield
With palladium diacetate; sodium hydroxide In water at 140℃; for 3h; Reagent/catalyst; Temperature; Concentration; Hiyama Coupling;	100%

: 78-08-0
Triethoxyvinylsilane

: 7215-33-0
diethylphosphine oxide

: C12H29O4PSi

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) at 80℃; for 4h; Inert atmosphere; Reflux;	99.5%

: 119-61-9
benzophenone

: 78-08-0
Triethoxyvinylsilane

: 2,2'-bis<2-(triethoxysilyl)ethyl>benzophenone

Conditions

Conditions	Yield
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene for 4h; Heating;	99%

: 18448-47-0
methyl cyclohex-1-ene-1-carboxylate

: 78-08-0
Triethoxyvinylsilane

: 167967-05-7
methyl 2-(2-(triethoxysilyl)ethyl)cyclohex-1-enecarboxylate

Conditions

Conditions	Yield
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; sodium formate; tris(para-trifluoromethyl)phenyl phosphine In 1,4-dioxane at 20 - 100℃; Inert atmosphere;	99%
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene for 18h;	97%

: allylboronic acid 2,2-dimethyl-1,3-propanediol ester

: 78-08-0
Triethoxyvinylsilane

: C14H29BO5Si

Conditions

Conditions	Yield
[1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(O-isopropoxyphenylmethylene)ruthenium In dichloromethane at 40℃; for 1h;	99%

: 78-08-0
Triethoxyvinylsilane

: 72824-04-5
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: C15H31BO5Si

Conditions

Conditions	Yield
[1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(O-isopropoxyphenylmethylene)ruthenium In dichloromethane at 40℃; for 1h;	99%

: 2879-20-1
1,4-benzodioxan-6-yl methyl ketone

: 78-08-0
Triethoxyvinylsilane

: 200631-17-0
1-[5-(2-triethoxysilyl-ethyl)-2,3-dihydro-benzo[1,4]dioxin-6-yl]ethanone

Conditions

Conditions	Yield
With sodium formate; triphenylphosphine; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 In toluene at 140℃; for 1.5h; Murai reaction;	99%
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; sodium formate; triphenylphosphine In toluene at 140℃; for 1.5h;	99%

: tert-butyl-naphthalen-1-ylmethyleneamine

: 78-08-0
Triethoxyvinylsilane

: 926031-32-5
2-(2-triethoxysilyl-ethyl)naphthalene-1-carbaldehyde

Conditions

Conditions	Yield
With sodium formate; triphenylphosphine; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 In toluene at 140℃;	99%

: 78-08-0
Triethoxyvinylsilane

: 116071-21-7
(E)-N-tert-butyl-2-methyl-2-butenamide

: 1202396-18-6
(Z)-N-tert-butyl-2,3-dimethyl-5-(triethoxysilyl)pent-2-enamide

Conditions

Conditions	Yield
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; sodium formate; tris(para-trifluoromethyl)phenyl phosphine In 1,4-dioxane at 20 - 100℃; Inert atmosphere;	99%

: 292638-84-7
styrene

: 78-08-0
Triethoxyvinylsilane

: 65119-09-7, 90260-88-1, 35308-08-8
1-styryltriethoxysilane

Conditions

Conditions	Yield
With [(H2IMes)(OSiMe3)2Ru(=CHC6H4(O-i-Pr)-2)] In dichloromethane for 24h; Reflux; Inert atmosphere;	99%
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 25℃; for 2h;

: 78-08-0
Triethoxyvinylsilane

: C20H19N

: C36H53NO6Si2

Conditions

Conditions	Yield
With dihydridotetrakis(triphenylphosphine)ruthenium In toluene at 140℃; for 24h; Inert atmosphere; Schlenk technique;	99%

: 78-08-0
Triethoxyvinylsilane

: C19H16FN

: C35H50FNO6Si2

Conditions

Conditions	Yield
With dihydridotetrakis(triphenylphosphine)ruthenium In toluene at 140℃; for 24h; Inert atmosphere; Schlenk technique;	99%

: 78-08-0
Triethoxyvinylsilane

: 53441-73-9, 53441-90-0, 125331-38-6
phenyl-N-(1-naphthylethylidene)methanamine

: C35H51NO6Si2

Conditions

Conditions	Yield
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene at 140℃; for 72h; Reagent/catalyst; Inert atmosphere; Schlenk technique;	99%

: 78-08-0
Triethoxyvinylsilane

: (1S,4aS)-7-Acetyl-6-(tert-butyl-dimethyl-silanyloxy)-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydro-phenanthrene-1-carboxylic acid methyl ester

: C34H58O7Si2

Conditions

Conditions	Yield
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) for 36h;	98%

: 78-08-0
Triethoxyvinylsilane

: 173612-84-5
methyl 13-acetyl-12-(((1,1-dimethylethyl)dimethylsilyl)oxy)podocarpa-8,11,13-trien-19-oate

: methyl 13-acetyl-14-[2-(triethoxysilyl)ethyl]-12-{[(1,1-dimethylethyl)dimethylsilyl]oxy}podocarpa-8,11,13-trien-19-oate

Conditions

Conditions	Yield
carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene for 36h; Heating;	98%

: 78-08-0
Triethoxyvinylsilane

: 2182-55-0
vinyl cyclohexyl ether

A: C14H28O4Si

B: C14H28O4Si

Conditions

Conditions	Yield
Grubbs catalyst first generation at 60℃; for 24h; cross-metathesis; Title compound not separated from byproducts;	A n/a B 98%

...Expand

: 78-08-0
Triethoxyvinylsilane

: 107400-39-5
ethyl 5-hydroxy-3-keto-hept-6-enoate

: 880139-84-4
ethyl (6E)-8,8,8-triethoxy-5-hydroxy-3-oxo-8-silaoct-6-enoate

Conditions

Conditions	Yield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane at 45℃; for 1h;	98%

: 5332-24-1
3-bromoquinoline

: 78-08-0
Triethoxyvinylsilane

: 698387-12-1
(E)-1,2-di(quinoline-3-yl)ethene

Conditions

Conditions	Yield
With sodium hydroxide; palladium diacetate In water at 140℃; for 3h;	98%
Stage #1: Triethoxyvinylsilane With sodium hydroxide In water at 20℃; for 0.0833333h; Sealed tube; Stage #2: 3-bromoquinoline With palladium diacetate In water at 120 - 140℃; Sealed tube;	98%
With palladium diacetate; sodium hydroxide In water at 140℃; for 4h; Sealed tube;	91%
With palladium diacetate; sodium hydroxide In water at 140℃; Hiyama Coupling; Sealed tube;	91%
With palladium diacetate; sodium hydroxide In neat (no solvent) at 140℃; for 6h; Hiyama Coupling; Sealed tube;	91%

: 78-08-0
Triethoxyvinylsilane

: 99-90-1
para-bromoacetophenone

: 6536-02-3
(E)-1,1'-(ethene-1,2-diylbis(4,1-phenylene))diethanone

Conditions

Conditions	Yield
With sodium hydroxide; palladium diacetate In water at 140℃; for 3h;	98%
Stage #1: Triethoxyvinylsilane With sodium hydroxide In water at 20℃; for 0.0833333h; Sealed tube; Stage #2: para-bromoacetophenone With palladium diacetate In water at 120 - 140℃; Sealed tube;	98%

Triethoxyvinylsilane Chemical Properties

Molecule structure of Triethoxyvinylsilane (CAS NO.78-08-0):

IUPAC Name: Ethenyl(triethoxy)silane
Molecular Weight: 190.31222 g/mol
Molecular Formula: C₈H₁₈O₃Si
Density: 0.904 g/cm³
Melting Point: <0 °C
Boiling Point: 160.5 °C at 760 mmHg
Flash Point: 34.4 °C
Index of Refraction: 1.415
Molar Refractivity: 52.78 cm³
Molar Volume: 210.5 cm³
Surface Tension: 22.3 dyne/cm
Enthalpy of Vaporization: 38.08 kJ/mol
Vapour Pressure: 3.09 mmHg at 25 °C
Storage Temp.: flammables area
Water Solubility: decomposes
Sensitive Moisture: sensitive
H-Bond Acceptor: 3
Rotatable Bond Count: 7
Exact Mass: 190.102521
MonoIsotopic Mass: 190.102521
Topological Polar Surface Area: 27.7
Heavy Atom Count: 12
Canonical SMILES: CCO[Si](C=C)(OCC)OCC
InChI: InChI=1S/C8H18O3Si/c1-5-9-12(8-4,10-6-2)11-7-3/h8H,4-7H2,1-3H3
InChIKey: FWDBOZPQNFPOLF-UHFFFAOYSA-N
EINECS: 201-081-7
Product Categories: Vinyl;Silicone series;Functional Materials;Si (Classes of Silicon Compounds);Silane Coupling Agents;Si-O Compounds;Trialkoxysilanes;Vinyl Silanes (Silane Coupling Agents);Vinylsilanes, Allylsilanes;Adhesion Promoters;Coupling Agents;Surface Modifiers;Silane series

Triethoxyvinylsilane Uses

Triethoxyvinylsilane (CAS NO.78-08-0) is used in silane cross-linked polyethylene cables and pipes. It is also used as hydrophobic agent and the glass fiber surface treatment agent.

Triethoxyvinylsilane Toxicity Data With Reference

1.	skn-rbt 500 mg open MLD	UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 7/10 ,1967.
2.	eye-rbt 500 mg	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
3.	orl-rat LD50:22,500 mg/kg	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
4.	ihl-rat LCLo:4000 ppm/4H	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.

Triethoxyvinylsilane Consensus Reports

Reported in EPA TSCA Inventory.

Triethoxyvinylsilane Safety Profile

Hazard Codes: Irritant Xi
Risk Statements: 10-36/37
R10:Flammable.
R36/37:Irritating to eyes and respiratory system.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
RIDADR: UN 1993 3/PG 3
WGK Germany: 2
RTECS: VV6700000
F: 21
TSCA: Yes
HazardClass: 3
PackingGroup: III
HS Code: 29310095
Mildly toxic by ingestion and inhalation. A skin and eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

Triethoxyvinylsilane Specification

Triethoxyvinylsilane (CAS NO.78-08-0) is also named as 4-04-00-04256 (Beilstein Handbook Reference) ; AI3-51468 ; BRN 1767229 ; CCRIS 2645 ; KBE 1003 ; NV 1107 ; Polyscience VTES ; Silane A 151 ; Silane, vinyl triethoxy 1-151 ;
Triethoxyvinylsilicane ; Union carbide A-151 ; VTES ; VTS-E ; Vinyltriethoxysilane . Triethoxyvinylsilane (CAS NO.78-08-0) is pale yellow to colorless liquid.

Product Name

Triethoxyvinylsilane

Synthetic route

Triethoxyvinylsilane Chemical Properties

Triethoxyvinylsilane Uses

Triethoxyvinylsilane Toxicity Data With Reference

Triethoxyvinylsilane Consensus Reports

Triethoxyvinylsilane Safety Profile

Triethoxyvinylsilane Specification

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