Conditions | Yield |
---|---|
With diphenyl sulfide; palladium 10% on activated carbon; hydrogen In methanol at 20℃; for 24h; | 94% |
With N-benzylammonium trifluoroacetate; 1,4-dihydro-2,6-dimethyl-3,5-bis<(methylamino)carbonyl>pyridine In tetrahydrofuran at 70℃; for 16h; Sealed tube; | 93% |
With palladium on activated charcoal; hydrogen; acetic acid In ethanol at 20℃; under 760.051 Torr; | 87% |
(E)-4-(4-hydroxy-3-methoxyphenyl)but-3-ene-2-one
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
With Rh/Al2O3; hydrogen In methanol at 20℃; under 750.075 Torr; for 2h; | 100% |
With palladium 10% on activated carbon; hydrogen In methanol at 25℃; for 4h; Time; | 97% |
With palladium 10% on activated carbon; hydrogen In methanol at 20℃; | 97% |
(E)-4-(4-hydroxy-3-methoxyphenyl)but-3-ene-2-one
A
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
B
3-hydroxy-1-(4-hydroxy-3-methoxyphenyl)butane
Conditions | Yield |
---|---|
With sodium tetrahydroborate; nickel(II) chloride hexahydrate; hydrogen In methanol at 0 - 30℃; under 760.051 Torr; Reflux; Inert atmosphere; | A 98% B 2% |
With diphenyl diselenide; hypophosphorous acid In glycerol at 90℃; for 0.5h; Inert atmosphere; chemoselective reaction; | A 68% B 19% |
With hydrogen; palladium on activated charcoal In ethyl acetate |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 63 percent / aq. NaOH / 48 h / Ambient temperature 2: 43 percent / H2 / 10percent Pd/C / 3 h / Ambient temperature View Scheme | |
Multi-step reaction with 2 steps 1: aq. NaOH 2: H2 / Pd-C / CHCl3 View Scheme | |
Multi-step reaction with 2 steps 1: aq. alkali 2: H2 / Raney-Ni View Scheme |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride; zinc(II) chloride In tetrahydrofuran; toluene at 20℃; for 0.75h; | 70% |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: aq. NaOH / 20 °C 2: aq. HCl / 20 °C 3: H2; AcOH / Pd/C / ethanol View Scheme | |
Multi-step reaction with 2 steps 1: NaOH; water / 20 °C 2: H2 / Pd/C / ethyl acetate View Scheme | |
Multi-step reaction with 2 steps 1: 83 percent / NaOH / H2O / 3 h 2: H2 / 10 percent Pd/C / ethyl acetate View Scheme |
Dehydrozingerone
A
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
B
3-hydroxy-1-(4-hydroxy-3-methoxyphenyl)butane
Conditions | Yield |
---|---|
With palladium 10% on activated carbon; hydrogen; acetic acid In methanol at 20℃; for 24h; | A 58% B 37% |
With ethanol; palladium Hydrogenation; |
methyl vinyl ketone
2-methoxy-phenol
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
With amberlyst-15 In toluene at 20 - 40℃; | 36.6% |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
With trifluoroacetic acid In dichloromethane at 20℃; for 24h; Inert atmosphere; solid phase reaction; | 12 mg |
4-(4-hydroxyphenyl-3-methoxy)-4-hydroxy-2-butanone
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: aq. HCl / 20 °C 2: H2; AcOH / Pd/C / ethanol View Scheme |
4-[4-(benzyloxy)-3-methoxyphenyl]butan-2-one
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
With hydrogen; palladium on activated charcoal In methanol |
4-(4-((tert-butyldimethylsiloxy)-methyl)-3-methoxyphenyl)-but-3-ene-2-one
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: tetrabutylammonium fluoride / tetrahydrofuran 2: H2 / Pd/C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: imidazole 2: MnO2 / pentane 3: tetrabutylammonium fluoride / tetrahydrofuran 4: H2 / Pd/C View Scheme |
(2E)-3-[4-[[tert-butyldimethylsilyl]oxy]-3-methoxyphenyl]acrylaldehyde
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: MnO2 / pentane 2: tetrabutylammonium fluoride / tetrahydrofuran 3: H2 / Pd/C View Scheme |
4-[4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-phenyl]-but-3-en-2-ol
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: MnO2 / pentane 2: tetrabutylammonium fluoride / tetrahydrofuran 3: H2 / Pd/C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 82 percent / 10percent aq. sodium hydroxide / 96 h 2: 86 percent / H2 / Raney nickel / acetone View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: NaBH4 / methanol 2: PBr3 / diethyl ether 3: (i) nBuLi, THF, (ii) /BRN= 2130929/, (iii) aq. NaIO4, MeOH 4: H2 / Pd-C / methanol View Scheme |
1-(benzyloxy)-4-(bromomethyl)-2-methoxybenzene
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: (i) nBuLi, THF, (ii) /BRN= 2130929/, (iii) aq. NaIO4, MeOH 2: H2 / Pd-C / methanol View Scheme |
4-benzyloxy-3-methoxybenzyl alcohol
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: PBr3 / diethyl ether 2: (i) nBuLi, THF, (ii) /BRN= 2130929/, (iii) aq. NaIO4, MeOH 3: H2 / Pd-C / methanol View Scheme |
(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 6 steps 1.1: thionyl chloride / tetrahydrofuran / 2.5 h / 20 °C / Inert atmosphere 2.1: N-ethyl-N,N-diisopropylamine / tetrahydrofuran; dichloromethane / 24 h / 0 - 20 °C / Inert atmosphere 3.1: trimethylaluminum / dichloromethane; toluene / 15 h / 20 °C / Inert atmosphere 3.2: 2 h / 20 °C / Inert atmosphere 4.1: tetrahydrofuran / -78 °C / Inert atmosphere 5.1: hydrogenchloride / tetrahydrofuran; water / 5 h / Reflux 6.1: hydrogen; Rh/Al2O3 / methanol / 2 h / 20 °C / 750.08 Torr View Scheme |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: tetrahydrofuran / -78 °C / Inert atmosphere 2: hydrogenchloride / tetrahydrofuran; water / 5 h / Reflux 3: hydrogen; Rh/Al2O3 / methanol / 2 h / 20 °C / 750.08 Torr View Scheme |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: hydrogenchloride / tetrahydrofuran; water / 5 h / Reflux 2: hydrogen; Rh/Al2O3 / methanol / 2 h / 20 °C / 750.08 Torr View Scheme |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1.1: N-ethyl-N,N-diisopropylamine / tetrahydrofuran; dichloromethane / 24 h / 0 - 20 °C / Inert atmosphere 2.1: trimethylaluminum / dichloromethane; toluene / 15 h / 20 °C / Inert atmosphere 2.2: 2 h / 20 °C / Inert atmosphere 3.1: tetrahydrofuran / -78 °C / Inert atmosphere 4.1: hydrogenchloride / tetrahydrofuran; water / 5 h / Reflux 5.1: hydrogen; Rh/Al2O3 / methanol / 2 h / 20 °C / 750.08 Torr View Scheme |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: trimethylaluminum / dichloromethane; toluene / 15 h / 20 °C / Inert atmosphere 1.2: 2 h / 20 °C / Inert atmosphere 2.1: tetrahydrofuran / -78 °C / Inert atmosphere 3.1: hydrogenchloride / tetrahydrofuran; water / 5 h / Reflux 4.1: hydrogen; Rh/Al2O3 / methanol / 2 h / 20 °C / 750.08 Torr View Scheme |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: dmap / toluene / Inert atmosphere; Reflux 2: zinc(II) chloride; tetrabutyl ammonium fluoride / toluene; tetrahydrofuran / 0.75 h / 20 °C View Scheme |
4-{[(tert-butyl)(diphenyl)silyl]oxy}-3-methoxybenzaldehyde
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: sodium tetrahydroborate / dichloromethane; ethanol / 0.75 h / 0 °C 2: dmap / toluene / Inert atmosphere; Reflux 3: zinc(II) chloride; tetrabutyl ammonium fluoride / toluene; tetrahydrofuran / 0.75 h / 20 °C View Scheme |
Conditions | Yield |
---|---|
Stage #1: vanillin; acetone With sodium hydroxide at 20℃; for 12h; Stage #2: With hydrogen |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
With diethyl ether; hydrogen; platinum |
(E)-ethyl 2-(4-hydroxy-3-methoxybenzylidene)-3-oxo-butanoate
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
With sodium hydroxide; sodium amalgam erwaermt man das Reaktionsprodukt mit konz. Natronlauge und erhitzt die erhaltene Saeure im Vakuum; |
Conditions | Yield |
---|---|
With 1:1 copper and nickel alloy on γ-Al2O3 at 245℃; for 3h; Activation energy; Temperature; Reagent/catalyst; Inert atmosphere; Autoclave; | 45.8% |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
3-hydroxy-1-(4-hydroxy-3-methoxyphenyl)butane
Conditions | Yield |
---|---|
With sodium tetrahydroborate In methanol at 20℃; for 2.5h; Solvent; Enzymatic reaction; | 100% |
With sodium tetrahydroborate In methanol at 20℃; for 1.5h; | 96.6% |
With sodium tetrahydroborate In ethanol | 91% |
With hydrogen; palladium on activated charcoal In ethyl acetate | |
Multi-step reaction with 2 steps 1: 84 percent / phenol, hexamethyldisilazane / benzene / Heating 2: 1.) lithium di-isopropylamide, hexanal, 2.) 2M HCl / 1.) -78 deg C, 1 h, THF, 2.) ether View Scheme |
3,4-dihydro-2H-pyran
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
4-(3-methoxy-4-(tetrahydro-2H-pyran-2-yloxy)phenyl)butan-2-one
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane at 20℃; for 24h; | 99% |
With pyridinium p-toluenesulfonate In dichloromethane |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
(2-aminophenyl)(phenyl)methanone
2-methoxy-4-((2-methyl-4-phenylquinolin-3-yl)methyl)phenol
Conditions | Yield |
---|---|
With trifluoroacetic acid at 100℃; for 0.5h; | 96% |
caprinaldehyde
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
5-hydroxy-1-(4-hydroxy-3-methoxyphenyl)tetradecan-3-one
Conditions | Yield |
---|---|
With n-butyllithium; lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 6h; | 95% |
Stage #1: 4-(4-hydroxy-3-methoxyphenyl)-2-butanone With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 1h; Stage #2: caprinaldehyde In tetrahydrofuran at -78℃; for 3h; Time; | 32% |
With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; |
Octanal
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
5-hydroxy-1-(4-hydroxy-3-methoxyphenyl)dodecan-3-one
Conditions | Yield |
---|---|
With n-butyllithium; lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 6h; | 95% |
Stage #1: 4-(4-hydroxy-3-methoxyphenyl)-2-butanone With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 1h; Stage #2: Octanal In tetrahydrofuran at -78℃; for 3h; Time; | 32% |
With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
hexanal
(+/-)-[6]-gingerol
Conditions | Yield |
---|---|
With n-butyllithium; lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 6h; | 95% |
With potassium tert-butylate In tetrahydrofuran at -78℃; for 1.5h; | 76% |
Stage #1: 4-(4-hydroxy-3-methoxyphenyl)-2-butanone With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 1h; Stage #2: hexanal In tetrahydrofuran at -78℃; for 3h; Time; | 47% |
With potassium tert-butylate In tetrahydrofuran at -78℃; for 1.5h; Inert atmosphere; | 30.73% |
With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
methyl iodide
4-(3,4-dimethoxy-phenyl)-butan-2-one
Conditions | Yield |
---|---|
With potassium carbonate In acetone Reflux; | 95% |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
(E)-4-(4-hydroxy-3-methoxyphenyl)but-3-ene-2-one
Conditions | Yield |
---|---|
With oxygen; palladium diacetate; trifluoroacetic acid In dimethyl sulfoxide at 80℃; for 9h; Sealed tube; | 95% |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
2-aminoacetophenone
4-((2,4-dimethylquinolin-3-yl)methyl)-2-methoxyphenol
Conditions | Yield |
---|---|
With trifluoroacetic acid at 100℃; for 0.5h; | 90% |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
With ammonia; hydrogen In tetrahydrofuran at 120℃; for 15h; | 89% |
With nickel(II) tetrafluoroborate hexahydrate; ammonia; hydrogen; bis(2-diphenylphosphinoethyl)phenylphosphine In 2,2,2-trifluoroethanol at 120℃; for 24h; chemoselective reaction; | 87% |
With ammonia; hydrogen In methanol at 90℃; under 15001.5 Torr; for 4h; Autoclave; | 99 %Spectr. |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
2-Amino-5-chlorobenzophenone
4-((6-chloro-2-methyl-4-phenylquinolin-3-yl)methyl)-2-methoxyphenol
Conditions | Yield |
---|---|
With trifluoroacetic acid at 100℃; for 0.5h; | 86% |
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0 - 20℃; for 13h; | 85% |
chloro-trimethyl-silane
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
4-(3-methoxy-4-trimethylsilyloxyphenyl)butan-2-one
Conditions | Yield |
---|---|
With 1,1,1,3,3,3-hexamethyl-disilazane; phenol In benzene Heating; | 84% |
4-Nitrophthalonitrile
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide for 48h; Inert atmosphere; | 84% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 0℃; for 2h; | 84% |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
hexanal
[6]-shogaol
Conditions | Yield |
---|---|
With DIMCARB at 25℃; | 80% |
With DIMCARB at 20℃; for 72h; | 55% |
Stage #1: 4-(4-hydroxy-3-methoxyphenyl)-2-butanone With pyrrolidine In dichloromethane at 20℃; for 0.25h; Stage #2: hexanal In dichloromethane for 18h; | 45.52 g |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
4-chlorobenzylamine
4-(3-(4-chlorobenzylamino)butyl)-2-methoxyphenol
Conditions | Yield |
---|---|
Stage #1: 4-(4-hydroxy-3-methoxyphenyl)-2-butanone; 4-chlorobenzylamine In toluene for 16h; Reflux; Inert atmosphere; Stage #2: With methanol; sodium tetrahydroborate In toluene at 0℃; for 16.5h; Reflux; | 75% |
Stage #1: 4-(4-hydroxy-3-methoxyphenyl)-2-butanone; 4-chlorobenzylamine With sodium tetrahydroborate In toluene at 0℃; for 16h; Inert atmosphere; Dean-Stark; Reflux; Stage #2: With sodium tetrahydroborate In methanol; toluene for 16.5h; Reflux; Inert atmosphere; | 75% |
Stage #1: 4-(4-hydroxy-3-methoxyphenyl)-2-butanone; 4-chlorobenzylamine In toluene for 16h; Reflux; Inert atmosphere; Dean-Stark; Stage #2: With sodium tetrahydroborate In methanol; toluene at 0℃; for 16.5h; Reflux; | 75% |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
p-Trifluoromethylbenzylamine
2-methoxy-4-(3-(4-(trifluoromethyl)benzylamino)butyl)phenol
Conditions | Yield |
---|---|
Stage #1: 4-(4-hydroxy-3-methoxyphenyl)-2-butanone; p-Trifluoromethylbenzylamine In toluene for 16h; Reflux; Inert atmosphere; Stage #2: With methanol; sodium tetrahydroborate In toluene at 0℃; for 16.5h; Reflux; | 74% |
Stage #1: 4-(4-hydroxy-3-methoxyphenyl)-2-butanone; p-Trifluoromethylbenzylamine In toluene at 0℃; for 16h; Inert atmosphere; Reflux; Dean-Stark; Stage #2: With sodium tetrahydroborate In methanol; toluene for 16.5h; Reflux; Inert atmosphere; | 74% |
Stage #1: 4-(4-hydroxy-3-methoxyphenyl)-2-butanone; p-Trifluoromethylbenzylamine In toluene for 16h; Reflux; Inert atmosphere; Dean-Stark; Stage #2: With sodium tetrahydroborate In methanol; toluene at 0℃; for 16.5h; Reflux; | 74% |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
3-nitrobenzene-1,2-dicarbonitrile
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide for 48h; Inert atmosphere; | 72% |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
2-amino-5-nitrobenzophenone
2-methoxy-4-((2-methyl-6-nitro-4-phenylquinolin-3-yl)methyl)phenol
Conditions | Yield |
---|---|
With trifluoroacetic acid at 100℃; for 1.5h; | 70% |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
3-(3'-methoxy-4'-hydroxyphenyl)propionaldehyde
(E)-1,7-bis(4-hydroxy-3-methoxyphenyl)-4-hepten-3-one
Conditions | Yield |
---|---|
With DIMCARB at 20℃; for 96h; | 70% |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
4,5-dichlorophthalonitrile
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide for 48h; Inert atmosphere; | 68% |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
4,4'-(6,6'-dihydroxy-5,5'-dimethoxy-[1,1'-biphenyl]-3,3'-diyl)bis(butan-2-one)
Conditions | Yield |
---|---|
With methyltri(butyl)ammonium permanganate In dichloromethane at 20℃; | 65% |
With methyltri(butyl)ammonium permanganate In dichloromethane at 20℃; for 1h; Inert atmosphere; | 65% |
With MTBAP In dichloromethane at 20℃; for 1h; | |
With Colletotrichum gloeosporioides In water; dimethyl sulfoxide at 20℃; for 360h; Microbiological reaction; |
4-(4-hydroxy-3-methoxyphenyl)-2-butanone
3,4-dihydroxybenzaldehyde
(E)-1-(3,4-dihydroxyphenyl)-5-(4-hydroxy-3-methoxyphenyl)-pent-1-en-3-one
Conditions | Yield |
---|---|
With pyrrolidine; acetic acid In tetrahydrofuran Reflux; | 63% |
Conditions | Yield |
---|---|
With Amberlyst15; air In water at 20℃; for 24h; Irradiation; Green chemistry; | 60% |
With methanesulfonic acid In acetonitrile at 20℃; for 0.25h; Irradiation; | 52% |
Conditions | Yield |
---|---|
With phosphoric acid In acetonitrile at 20℃; for 12h; Irradiation; | 60% |
Product Name: Vanillyl acetone (122-48-5)
Molecular Formula: C11H14O3
Molecular Weight: 194.23g/mol
Mol File: 122-48-5.mol
Einecs: 204-548-3
Melting Point: 40-41 °C(lit.)
Boiling point: 141 °C0.5 mm Hg(lit.)
Flash Point: >230 °F
Density: 1.14 g/mL at 25 °C(lit.)
Refractive index: n20/D 1.541(lit.)
Product Categories: Miscellaneous Natural Products
Synonyms of Vanillyl acetone (122-48-5): (0)-paradol ; [0]-Paradol ; 3-Methoxy-4-hydroxybenzylacetone ; 3-methoxy-4-hydroxy-benzylacetone ; 4-(3-methoxy-4-hydroxyphenyl)-2-butanone ; 4-(4-hydroxy-3 ; 4-(4-hydroxy-3-methoxyphenyl)-2-butanon ; Gingerone .
Moderately toxic by ingestion. A skin irritant. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rabbit | LD50 | skin | > 5gm/kg (5000mg/kg) | Food and Chemical Toxicology. Vol. 20, Pg. 851, 1982. | |
rat | LD50 | oral | 2580mg/kg (2580mg/kg) | Food and Chemical Toxicology. Vol. 20, Pg. 851, 1982. |
Reported in EPA TSCA Inventory.
Safety Information of Vanillyl acetone (122-48-5):
Risk Statements: 36/37/38
36: Irritating to the eyes
37: Irritating to the respiratory system
38: Irritating to the skin
Safety Statements: 26-36
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
DOT Classification: 3; Label: Flammable Liquid
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