Product Name

  • Name

    meso-Tetra(4-carboxyphenyl)porphine

  • EINECS
  • CAS No. 14609-54-2
  • Article Data103
  • CAS DataBase
  • Density 1.463 g/cm3
  • Solubility
  • Melting Point >300 °C
  • Formula C48H30N4O8
  • Boiling Point
  • Molecular Weight 790.788
  • Flash Point
  • Transport Information
  • Appearance purple powder
  • Safety 22-24/25
  • Risk Codes
  • Molecular Structure Molecular Structure of 14609-54-2 (meso-Tetra(4-carboxyphenyl)porphine)
  • Hazard Symbols
  • Synonyms Benzoicacid, 4,4',4'',4'''-(5,10,15,20-porphinetetrayl)tetra- (8CI);4,4',4'',4'''-(21H,23H-Porphine-5,10,15,20-tetrayl)tetrakis(benzoicacid);5,10,15,20-Tetrakis(4-carboxyphenyl)porphine;5,10,15,20-Tetrakis(4-carboxyphenyl)porphyrin;TCPP;TCPP (porphinederivative);Tetra(4-carboxyphenyl)porphine;Tetra(4-carboxyphenyl)porphyrin;Tetra(p-carboxyphenyl)porphyrin;Tetrakis(4-carboxyphenyl)porphine;Tetrakis(4-carboxyphenyl)porphyrin;Tetrakis(p-carboxyphenyl)porphine;Tetrakis(p-carboxyphenyl)porphyrin;meso-Tetra(4-carboxyphenyl)porphine;meso-Tetra(p-carboxyphenyl)porphine;meso-Tetra(p-carboxyphenyl)porphyrin;meso-Tetrakis(4-carboxyphenyl)porphine;meso-Tetrakis(4-carboxyphenyl)porphyrin;meso-Tetrakis(p-carboxyphenyl)porphine;meso-Tetrakis(p-carboxyphenyl)porphyrin;a,b,g,d-Tetrakis(4-carboxyphenyl)porphine;
  • PSA 205.50000
  • LogP 5.65900

Synthetic route

5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin
22112-83-0

5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

Conditions
ConditionsYield
With potassium hydroxide In tetrahydrofuran; water at 75℃; for 16h;98%
With potassium hydroxide In tetrahydrofuran; ethanol at 70℃; for 24h;96.8%
With potassium hydroxide In tetrahydrofuran; methanol; water for 24h; Reflux;96%
pyrrole
109-97-7

pyrrole

4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

Conditions
ConditionsYield
Stage #1: pyrrole; 4-Carboxybenzaldehyde In N,N-dimethyl-formamide at 100℃; for 0.166667h; Inert atmosphere;
Stage #2: With toluene-4-sulfonic acid In N,N-dimethyl-formamide at 150℃; for 1h; Inert atmosphere;		75%
In propionic acid for 2h; Reflux;55%
With propionic acid at 20℃; for 2h; Reflux;55%
pyrrole
109-97-7

pyrrole

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

Conditions
ConditionsYield
Stage #1: pyrrole; methyl 4-formylbenzoate With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 1.5h; Darkness;
Stage #2: With chloranil In dichloromethane
Stage #3: With sodium hydroxide		35%
Stage #1: pyrrole; methyl 4-formylbenzoate With propionic acid at 160℃; for 12h;
Stage #2: With potassium hydroxide In tetrahydrofuran; methanol; water at 80℃; for 12h;
Stage #1: pyrrole; methyl 4-formylbenzoate With propionic acid at 140℃; for 12h;
Stage #2: With potassium hydroxide In tetrahydrofuran; methanol; water at 80℃; for 12h;
pyrrole
109-97-7

pyrrole

4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

propionic acid
802294-64-0

propionic acid

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

Conditions
ConditionsYield
for 2h; Reflux;26%
...Expand
pyrrole
109-97-7

pyrrole

C8H6O3*H3N

C8H6O3*H3N

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

Conditions
ConditionsYield
Stage #1: pyrrole; C8H6O3*H3N With propionic acid for 3h; Heating / reflux;
Stage #2: With sodium hydrogencarbonate In water
Stage #3: With hydrogenchloride In water pH=< 6;
5,10,15,20-tetrakis(4-cyanophenyl)porphirin
14609-51-9

5,10,15,20-tetrakis(4-cyanophenyl)porphirin

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran; methanol
methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: propionic acid / 1 h / 80 - 140 °C
2: potassium hydroxide / tetrahydrofuran / 24 h / Reflux
View Scheme
Multi-step reaction with 2 steps
1: propionic acid / 1.5 h / 140 °C
2: potassium hydroxide / tetrahydrofuran; water / 48 h / 66 °C
View Scheme
Multi-step reaction with 2 steps
1: propionic acid / 12 h / Reflux
2: sodium hydroxide / water; tetrahydrofuran; methanol / 12 h / Reflux
View Scheme
pyrrole
109-97-7

pyrrole

terephthalaldehyde,
623-27-8

terephthalaldehyde,

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

Conditions
ConditionsYield
In propionic acid for 0.833333h; Reflux; Inert atmosphere;
pyrrole
109-97-7

pyrrole

propionic acid
802294-64-0

propionic acid

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

Conditions
ConditionsYield
Reflux;
...Expand
4-(10,15,20-tris(4-(methoxycarbonyl)phenyl)porphyrin-5-yl)benzoic acid

4-(10,15,20-tris(4-(methoxycarbonyl)phenyl)porphyrin-5-yl)benzoic acid

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

Conditions
ConditionsYield
With water; potassium hydroxide In tetrahydrofuran; methanol at 120℃; for 12h;
pyrrole
109-97-7

pyrrole

terephthalic acid
100-21-0

terephthalic acid

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

Conditions
ConditionsYield
With propionic acid for 1.5h; Reflux;
tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

tetrakis(p-chloroformylphenyl)porphyrin

tetrakis(p-chloroformylphenyl)porphyrin

Conditions
ConditionsYield
With oxalyl dichloride In dichloromethane for 1h;100%
With thionyl chloride for 10h; Substitution; Heating;87%
With thionyl chloride for 2h; Heating;
O-tert-butyl-L-serine methyl ester hydrochloride
17114-97-5

O-tert-butyl-L-serine methyl ester hydrochloride

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

C80H90N8O16

C80H90N8O16

Conditions
ConditionsYield
With benzotriazol-1-yloxyl-tris-(pyrrolidino)-phosphonium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide for 18h; Inert atmosphere;100%
tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

[5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrinato]-Pd(II)

[5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrinato]-Pd(II)

Conditions
ConditionsYield
With palladium dichloride In N,N-dimethyl-formamide at 155℃; for 0.25h;98%
tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

5,10,15,20-tetrakis(4'-carboxamidophenyl)porphyrin

5,10,15,20-tetrakis(4'-carboxamidophenyl)porphyrin

Conditions
ConditionsYield
With thionyl chloride for 1h; Reflux;98%
tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

5,10,15,20-tetrakis (4-carboxyphenyl)porphyrin tetrasodium salt

5,10,15,20-tetrakis (4-carboxyphenyl)porphyrin tetrasodium salt

Conditions
ConditionsYield
With sodium hydroxide98%
(S)-tert-butyl 2-(2-amino-4-tert-butoxy-4-oxobutanoyl)hydrazinecarboxylate

(S)-tert-butyl 2-(2-amino-4-tert-butoxy-4-oxobutanoyl)hydrazinecarboxylate

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

tert-butyl 3-{[4-(7,12-bis{4-[(-3-(tert-butoxy)-1-{N′-[(tert-butoxy)carbonyl]hydrazinecarbonyl}-3-oxopropyl)-carbamoyl]phenyl}-17-{4-[(3-(tert-butoxy)-1-{N′-[(tertbutoxy)carbonyl]hydrazinecarbonyl}-3-oxopropyl)carbamoyl]-phenyl}-21,22,23,24-tetraazapentacyclo[16.2.1.13,6.18,11.113,16]-tetracosa-1,3(24),4,6,8,10,12,14,16(22),17,19-undecaen-2-yl)phenyl]formamido}-3-{N′-[(tert-butoxy)carbonyl]hydrazinecarbonyl}propanoate

tert-butyl 3-{[4-(7,12-bis{4-[(-3-(tert-butoxy)-1-{N′-[(tert-butoxy)carbonyl]hydrazinecarbonyl}-3-oxopropyl)-carbamoyl]phenyl}-17-{4-[(3-(tert-butoxy)-1-{N′-[(tertbutoxy)carbonyl]hydrazinecarbonyl}-3-oxopropyl)carbamoyl]-phenyl}-21,22,23,24-tetraazapentacyclo[16.2.1.13,6.18,11.113,16]-tetracosa-1,3(24),4,6,8,10,12,14,16(22),17,19-undecaen-2-yl)phenyl]formamido}-3-{N′-[(tert-butoxy)carbonyl]hydrazinecarbonyl}propanoate

Conditions
ConditionsYield
With benzotriazol-1-yloxyl-tris-(pyrrolidino)-phosphonium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide for 18h; Inert atmosphere;97%
1-hydroxy-pyrrolidine-2,5-dione
6066-82-6

1-hydroxy-pyrrolidine-2,5-dione

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

C64H42N8O16

C64H42N8O16

Conditions
ConditionsYield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane; dimethyl sulfoxide at 20℃; for 50h; Cooling with ice;96%
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In tetrahydrofuran for 48h; Reflux;
indium(III) nitrate monohydrate

indium(III) nitrate monohydrate

water
7732-18-5

water

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

[In2(OH)2(4-tetracarboxyphenylporphyrin)]*3DMF*4H2O

[In2(OH)2(4-tetracarboxyphenylporphyrin)]*3DMF*4H2O

Conditions
ConditionsYield
at 120℃; for 48h;96%
...Expand
zinc(II) acetate tetrahydrate

zinc(II) acetate tetrahydrate

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinatozinc(II)

5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinatozinc(II)

Conditions
ConditionsYield
In methanol at 20℃;94%
histamine
51-45-6

histamine

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

C68H58N16O4

C68H58N16O4

Conditions
ConditionsYield
Stage #1: tetrakis(4-carboxyphenyl)porphyrin With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In water; N,N-dimethyl-formamide for 0.5h;
Stage #2: histamine With dmap In water; N,N-dimethyl-formamide for 0.333333h; Sonication;		90%
zinc(II) acetate dihydrate
5970-45-6

zinc(II) acetate dihydrate

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

zinc 5,10,15,20-tetrakis (4-carboxyphenyl)porphyrin tetrasodium salt

zinc 5,10,15,20-tetrakis (4-carboxyphenyl)porphyrin tetrasodium salt

Conditions
ConditionsYield
Stage #1: zinc(II) acetate dihydrate; tetrakis(4-carboxyphenyl)porphyrin In N,N-dimethyl-formamide for 0.75h; Reflux;
Stage #2: With sodium hydroxide In N,N-dimethyl-formamide		90%
tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

zinc(II) chloride
7646-85-7

zinc(II) chloride

5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinatozinc(II)

5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinatozinc(II)

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 12h;90%
In N,N-dimethyl-formamide at 140℃; for 4h;
In N,N-dimethyl-formamide at 175℃; for 0.0833333h; Microwave irradiation;
1-n-butyl-3-methylimidazolim bromide
85100-77-2

1-n-butyl-3-methylimidazolim bromide

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

2C8H15N2(1+)*2C48H26N4O8(4-)*4H2O*3Ca(2+)

2C8H15N2(1+)*2C48H26N4O8(4-)*4H2O*3Ca(2+)

Conditions
ConditionsYield
With water; nitric acid; calcium chloride In N,N-dimethyl-formamide at 110℃; for 72h; Autoclave;90%
cobalt(II) chloride hexahydrate

cobalt(II) chloride hexahydrate

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

[[meso-tetra(4-carboxyphenyl)porphyrinato]cobalt(III)]Cl·7H2O

[[meso-tetra(4-carboxyphenyl)porphyrinato]cobalt(III)]Cl·7H2O

Conditions
ConditionsYield
Stage #1: cobalt(II) chloride hexahydrate; tetrakis(4-carboxyphenyl)porphyrin In dimethyl sulfoxide for 24h; Reflux;
Stage #2: With hydrogenchloride In water		89%
In dimethyl sulfoxide for 24h; Reflux;80%
manganese(II) chloride tetrahydrate

manganese(II) chloride tetrahydrate

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

manganase(II)-5,10,15,20-tetra(4-carboxyphenyl)porphine

manganase(II)-5,10,15,20-tetra(4-carboxyphenyl)porphine

Conditions
ConditionsYield
Stage #1: manganese(II) chloride tetrahydrate; tetrakis(4-carboxyphenyl)porphyrin In N,N-dimethyl-formamide for 12h; Reflux;
Stage #2: With sodium hydroxide In tetrahydrofuran; water at 20℃; for 72h;		88%
galium(III) nitrate monohydrate

galium(III) nitrate monohydrate

water
7732-18-5

water

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

[Ga2(OH)2(4-tetracarboxyphenylporphyrin)]*3DMF*3H2O

[Ga2(OH)2(4-tetracarboxyphenylporphyrin)]*3DMF*3H2O

Conditions
ConditionsYield
at 120℃; for 48h;87%
...Expand
tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

copper dichloride

copper dichloride

5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin copper(II)

5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin copper(II)

Conditions
ConditionsYield
In methanol; acetone for 24h; Inert atmosphere; Reflux;86%
In N,N-dimethyl-formamide for 12h; Reflux;
In N,N-dimethyl-formamide at 175℃; for 0.0833333h; Microwave irradiation;
tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

copper dichloride

copper dichloride

[5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinato]Fe(III)Chloride

[5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinato]Fe(III)Chloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 5h; Reflux;86%
zinc diacetate
557-34-6

zinc diacetate

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

5,10,15,20-tetra(p-carboxylphenyl)porphyrinatozinc

5,10,15,20-tetra(p-carboxylphenyl)porphyrinatozinc

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 5h; Reflux;86%
tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

C-[8-(tert-butyl-diphenyl-silanyloxymethyl)-1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidin-2-yl]-methylamine; hydrochloride

C-[8-(tert-butyl-diphenyl-silanyloxymethyl)-1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidin-2-yl]-methylamine; hydrochloride

C148H170N20O8Si4(4+)*4Cl(1-)

C148H170N20O8Si4(4+)*4Cl(1-)

Conditions
ConditionsYield
With pyridine; dmap; dicyclohexyl-carbodiimide In N,N-dimethyl-formamide at 20℃;85%
3,5-bis[(S)-3,7-dimethyloctyloxy]aniline

3,5-bis[(S)-3,7-dimethyloctyloxy]aniline

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

C152H210N8O12

C152H210N8O12

Conditions
ConditionsYield
Stage #1: tetrakis(4-carboxyphenyl)porphyrin With oxalyl dichloride In chloroform; N,N-dimethyl-formamide at 20℃; for 3h; Inert atmosphere;
Stage #2: 3,5-bis[(S)-3,7-dimethyloctyloxy]aniline In chloroform at 20℃; for 24h; Inert atmosphere; Alkaline conditions;		85%
methyl (2S)-2-amino-3-phenylpropanoate hydrochloride
7524-50-7

methyl (2S)-2-amino-3-phenylpropanoate hydrochloride

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

5,10,15,20-tetrakis([N-(1-methoxycarbonyl-2-phenyl)ethyl]-4-carboxamido phenyl)porphyrin

5,10,15,20-tetrakis([N-(1-methoxycarbonyl-2-phenyl)ethyl]-4-carboxamido phenyl)porphyrin

Conditions
ConditionsYield
With dmap; benzotriazol-1-ol; dicyclohexyl-carbodiimide In tetrahydrofuran at 20℃; for 18h; Condensation;84%
cobalt(II) diacetate tetrahydrate
6147-53-1

cobalt(II) diacetate tetrahydrate

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

cobalt(II) 4,4',4'',4'''-(porphyrin-5,10,15,20-tetrayl)tetrabenzoic acid

cobalt(II) 4,4',4'',4'''-(porphyrin-5,10,15,20-tetrayl)tetrabenzoic acid

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 2h; Reflux;84%
In N,N-dimethyl-formamide for 1h; Reflux;80.7%
In methanol; dichloromethane Reflux;
In N,N-dimethyl-formamide for 2h; Reflux;
In N,N-dimethyl-formamide for 12h; Reflux;222 mg
zirconium oxide chloride octahydrate

zirconium oxide chloride octahydrate

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

2C48H26N4O8(4-)*6Zr(4+)*5.5HO(1-)*4.5O(2-)*20H2O*1.5Cl(1-)

2C48H26N4O8(4-)*6Zr(4+)*5.5HO(1-)*4.5O(2-)*20H2O*1.5Cl(1-)

Conditions
ConditionsYield
Stage #1: zirconium oxide chloride octahydrate; tetrakis(4-carboxyphenyl)porphyrin In N,N-dimethyl-formamide at 130℃; for 15h;
Stage #2: In N,N-dimethyl-formamide for 2h; Reflux;		83%
tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

tert-butyl {2-[2-(2-aminoethoxy)ethoxy]ethyl}carbamate
153086-78-3

tert-butyl {2-[2-(2-aminoethoxy)ethoxy]ethyl}carbamate

C92H118N12O20

C92H118N12O20

Conditions
ConditionsYield
Stage #1: tetrakis(4-carboxyphenyl)porphyrin With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide for 0.5h; Cooling with ice;
Stage #2: tert-butyl {2-[2-(2-aminoethoxy)ethoxy]ethyl}carbamate In N,N-dimethyl-formamide at 20℃; for 24h; Cooling with ice;		83%
formic acid
64-18-6

formic acid

yttrium(lll) nitrate hexahydrate

yttrium(lll) nitrate hexahydrate

water
7732-18-5

water

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

2C48H26N4O8(4-)*3C3H7NO*H2O*CHO2(1-)*3Y(3+)

2C48H26N4O8(4-)*3C3H7NO*H2O*CHO2(1-)*3Y(3+)

Conditions
ConditionsYield
at 120℃; for 48h;82%
...Expand
1,3-di(4-pyridyl)propane
17252-51-6

1,3-di(4-pyridyl)propane

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

C13H14N2*C48H30N4O8

C13H14N2*C48H30N4O8

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide at 120℃; for 8h; Autoclave; High pressure;82%
iridium(III) chloride hexahydrate

iridium(III) chloride hexahydrate

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

C48H30ClIrN4O9

C48H30ClIrN4O9

Conditions
ConditionsYield
In acetone for 24h; Inert atmosphere; Reflux; Schlenk technique;82%
2-ethylhexyl bromide
18908-66-2

2-ethylhexyl bromide

tetrakis(4-carboxyphenyl)porphyrin
14609-54-2

tetrakis(4-carboxyphenyl)porphyrin

C80H94N4O8

C80H94N4O8

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 20h;81%

meso-Tetra(4-carboxyphenyl)porphine Specification

The meso-Tetra(4-carboxyphenyl)porphine with CAS registry number of 14609-54-2 is also known as Benzoicacid, 4,4',4'',4'''-(5,10,15,20-porphinetetrayl)tetra- (8CI). The IUPAC name is 4-[10,15,20-Tris(4-carboxyphenyl)-21,24-dihydroporphyrin-5-yl]benzoic acid. It belongs to product categories of Porphyrins; Synthetic Porphyrins; Analytical Chemistry; Biochemistry; Chelating Reagents; Ligands for Pharmaceutical Research; Magnetic Resonance Imaging (Chelating Reagents); Porphines. In addition, the formula is C48H30N4O8 and the molecular weight is 790.77. When you are using this chemical, do not breathe dust and avoid contact with skin and eyes.

Physical properties about meso-Tetra(4-carboxyphenyl)porphine are: (1)ACD/LogP: 7.54; (2)# of Rule of 5 Violations: 4; (3)#H bond acceptors: 12; (4)#H bond donors: 6; (5)#Freely Rotating Bonds: 8; (6)Polar Surface Area: 206.56Å2; (7)Index of Refraction: 1.734; (8) Molar Refractivity: 216.672 cm3; (9)Molar Volume: 540.517 cm3; (10)Surface Tension: 79.865 dyne/cm; (11)Density: 1.463 g/cm3.

Uses of meso-Tetra(4-carboxyphenyl)porphine: it is used to produce 4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl) tetrakis(benzoic acid chloride). The reaction occurs with reagent thionyl chloride and other condition of heating for 10 hours. The yield is about 87%.

meso-Tetra(4-carboxyphenyl)porphine is used to produce 4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl) tetrakis(benzoic acid chloride).

You can still convert the following datas into molecular structure:
1.SMILES: OC(=O)c1ccc(cc1)c7c2\C=C/c(n2)c(c3nc(cc3)c(c\4nc(/C=C/4)c(c5ccc(cc5)C(O)=O)c6ccc7n6)c8ccc(cc8)C(O)=O)c9ccc(cc9)C(O)=O
2.InChI: InChI=1/C48H30N4O8/c53-45(54)29-9-1-25(2-10-29)41-33-17-19-35(49-33)42(26-3-11-30(12-4-26)46(55)56)37-21-23-39(51-37)44(28-7-15-32(16-8-28)48(59)60)40-24-22-38(52-40)43(36-20-18-34(41)50-36)27-5-13-31(14-6-27)47(57)58/h1-24,49,52H,(H,53,54)(H,55,56)(H,57,58)(H,59,60)/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40- 
3.InChIKey: HHDUMDVQUCBCEY-LWQDQPMZBG
4.Std. InChI: InChI=1S/C48H30N4O8/c53-45(54)29-9-1-25(2-10-29)41-33-17-19-35(49-33)42(26-3-11-30(12-4-26)46(55)56)37-21-23-39(51-37)44(28-7-15-32(16-8-28)48(59)60)40-24-22-38(52-40)43(36-20-18-34(41)50-36)27-5-13-31(14-6-27)47(57)58/h1-24,49,52H,(H,53,54)(H,55,56)(H,57,58)(H,59,60)/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-.

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