Frankland-Duppa Reaction E. Frankland, Ann. 126, 109 (1863); E. Frankland, B. F. Duppa, Ann. 135, 25 (1865). Formation of α-hydroxycarboxylic este
Duff Reaction J. C. Duff, E. J. Bills, J. Chem. Soc. 1932, 1987; 1934, 1305; 1941, 547; 1945, 276. Formylation of phenols or aromatic amines with hexame
Dötz Reaction K. H. Dötz, Angew. Chem. Int. Ed. 14, 644 (1975). Three component cyclization of an aromatic or vinylic alkoxy pentacarbonyl chr
Doering-LaFlamme Allene Synthesis W. von E. Doering, P. M. LaFlamme, Tetrahedron 2, 75 (1958); US 2933544 (1960). Treatment of an olefin with bromoform
Doebner Reaction O. Doebner, Ann. 242, 265 (1887); Ber. 20, 277 (1887); 27, 352, 2020 (1894). Formation of substituted cinchoninic acids from aromatic a
Knoevenagel Condensation; Doebner Modification E. Knoevenagel Ber. 31, 2596 (1898); O. Doebner, Ber. 33, 2140 (1900). Condensation of aldehydes or keton
Dimroth Rearrangement O. Dimroth, Ann. 364, 183 (1909); 459, 39 (1927). Rearrangement whereby exo- and endocyclic heteroatoms on a heterocyclic ring are
Dienone- Rearrangement K. von Auwers, K. Ziegler, Ann. 425, 217 (1921). Transformation of a 4,4-disubstituted cyclohexadienone into a 3,4-disubstituted
Dieckmann Reaction W. Dieckmann, Ber. 27, 102, 965 (1894); 33, 595, 2670, (1900); Ann. 317, 51, 93, (1901). Base-catalyzed cyclization of dicarboxylic a
Dess-Martin Oxidation D. B. Dess, J. C. Martin, J. Org. Chem. 48, 4155 (1983). Mild oxidation of primary and secondary alcohols to aldehydes and ketones
Demjanov Rearrangement N. J. Demjanov, M. Lushnikov, J. Russ. Phys. Chem. Soc. 35, 26 (1903); Chem. Zentr. 1903, 1, 828. Deamination of primary amines b
Tiffeneau-Demjanov Rearrangement M. Tiffeneau et al., Compt. Rend. 205, 54 (1937). Rearrangement of β-amino alcohols upon diazotization with nitrou
Delépine Reaction (Delépine Amine Synthesis) M. Delépine, Compt. Rend. 120, 501 (1895); 124, 292 (1897). Preparation of primary ami
de Mayo Reaction P. de Mayo et al., Proc. Chem. Soc. London 1962, 119; P. de Mayo, H. Takeshita, Can. J. Chem. 41, 440 (1963). Synthesis of 1,5-diketone
Darzens-Nenitzescu Synthesis of Ketones G. Darzens, Compt. Rend. 150, 707 (1910); C. D. Nenitzescu, I. P. Cantuniari, Ann. 510, 269 (1934); C. D. Nenitzescu, C. Cioranescu
Darzens Synthesis of Tetralin Derivatives G. Darzens, Compt. Rend. 183, 748 (1926). Cyclization of α-benzyl-α-allylacetic acid type compound
Dakin-West Reaction H. D. Dakin, R. West, J. Biol. Chem. 78, 91, 745, 757 (1928). Reaction of α-amino acids with acetic anhydride in the presence
Dakin Reaction H. D. Dakin, Am. Chem. J. 42, 477 (1909). Replacement of the formyl or acetyl groups in phenolic aldehydes or ketones by a hydroxyl group
L. Ruzicka, H. Meldahl, Helv. Chim. Acta 21, 1760 (1938); 22, 421 (1939). Originally discovered in 17β-hydroxy-20-ketosteroids, but thoroughly stu
Curtius Rearrangement; Curtius Reaction T. Curtius, Ber. 23, 3023 (1890); idem, J. Prakt. Chem. [2] 50, 275 (1894). Formation of isocyanates by thermal
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