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  • Frankland-Duppa Reaction

    Frankland-Duppa Reaction E. Frankland, Ann. 126, 109 (1863); E. Frankland, B. F. Duppa, Ann. 135, 25 (1865). Formation of α-hydroxycarboxylic este

  • Duff Reaction

    Duff Reaction J. C. Duff, E. J. Bills, J. Chem. Soc. 1932, 1987; 1934, 1305; 1941, 547; 1945, 276. Formylation of phenols or aromatic amines with hexame

  • Dötz Reaction

    Dötz Reaction K. H. Dötz, Angew. Chem. Int. Ed. 14, 644 (1975). Three component cyclization of an aromatic or vinylic alkoxy pentacarbonyl chr

  • Doering-LaFlamme Allene Synthesis

    Doering-LaFlamme Allene Synthesis W. von E. Doering, P. M. LaFlamme, Tetrahedron 2, 75 (1958); US 2933544 (1960). Treatment of an olefin with bromoform

  • Doebner Reaction

    Doebner Reaction O. Doebner, Ann. 242, 265 (1887); Ber. 20, 277 (1887); 27, 352, 2020 (1894). Formation of substituted cinchoninic acids from aromatic a

  • Knoevenagel Condensation

    Knoevenagel Condensation; Doebner Modification E. Knoevenagel Ber. 31, 2596 (1898); O. Doebner, Ber. 33, 2140 (1900). Condensation of aldehydes or keton

  • Dimroth Rearrangement

    Dimroth Rearrangement O. Dimroth, Ann. 364, 183 (1909); 459, 39 (1927). Rearrangement whereby exo- and endocyclic heteroatoms on a heterocyclic ring are

  • Dienone-Phenol Rearrangement

    Dienone- Rearrangement K. von Auwers, K. Ziegler, Ann. 425, 217 (1921). Transformation of a 4,4-disubstituted cyclohexadienone into a 3,4-disubstituted

  • Dieckmann Reaction

    Dieckmann Reaction W. Dieckmann, Ber. 27, 102, 965 (1894); 33, 595, 2670, (1900); Ann. 317, 51, 93, (1901). Base-catalyzed cyclization of dicarboxylic a

  • Dess-Martin Oxidation

    Dess-Martin Oxidation D. B. Dess, J. C. Martin, J. Org. Chem. 48, 4155 (1983). Mild oxidation of primary and secondary alcohols to aldehydes and ketones

  • Demjanov Rearrangement

    Demjanov Rearrangement N. J. Demjanov, M. Lushnikov, J. Russ. Phys. Chem. Soc. 35, 26 (1903); Chem. Zentr. 1903, 1, 828. Deamination of primary amines b

  • Tiffeneau-Demjanov Rearrangement

    Tiffeneau-Demjanov Rearrangement M. Tiffeneau et al., Compt. Rend. 205, 54 (1937). Rearrangement of β-amino alcohols upon diazotization with nitrou

  • Delépine Reaction

    Delépine Reaction (Delépine Amine Synthesis) M. Delépine, Compt. Rend. 120, 501 (1895); 124, 292 (1897). Preparation of primary ami

  • de Mayo Reaction

    de Mayo Reaction P. de Mayo et al., Proc. Chem. Soc. London 1962, 119; P. de Mayo, H. Takeshita, Can. J. Chem. 41, 440 (1963). Synthesis of 1,5-diketone

  • Darzens-Nenitzescu Synthesis of Ketones

    Darzens-Nenitzescu Synthesis of Ketones G. Darzens, Compt. Rend. 150, 707 (1910); C. D. Nenitzescu, I. P. Cantuniari, Ann. 510, 269 (1934); C. D. Nenitzescu, C. Cioranescu

  • Darzens Synthesis of Tetralin Derivatives

    Darzens Synthesis of Tetralin Derivatives G. Darzens, Compt. Rend. 183, 748 (1926). Cyclization of α-benzyl-α-allylacetic acid type compound

  • Dakin-West Reaction

    Dakin-West Reaction H. D. Dakin, R. West, J. Biol. Chem. 78, 91, 745, 757 (1928). Reaction of α-amino acids with acetic anhydride in the presence

  • Dakin Reaction

    Dakin Reaction H. D. Dakin, Am. Chem. J. 42, 477 (1909). Replacement of the formyl or acetyl groups in phenolic aldehydes or ketones by a hydroxyl group

  • D-Homo Rearrangement of Steroids

    L. Ruzicka, H. Meldahl, Helv. Chim. Acta 21, 1760 (1938); 22, 421 (1939). Originally discovered in 17β-hydroxy-20-ketosteroids, but thoroughly stu

  • Curtius Rearrangement

    Curtius Rearrangement; Curtius Reaction T. Curtius, Ber. 23, 3023 (1890); idem, J. Prakt. Chem. [2] 50, 275 (1894). Formation of isocyanates by thermal

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