No. 3 Gasoline Additive Specification CAS: 5961-59-1 Parameter Standard Appearance Crystalline light-yellow content by wt., %
Cas:5961-59-1
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inquiryDayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
Cas:5961-59-1
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inquiryProduct Description Product Name N-Methyl-4-anisidine CAS No. 5961-59-1 Appearance
Cas:5961-59-1
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inquiryhigh quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:5961-59-1
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inquiryStock products, own laboratory Product number 35634 English Name N-METHYL-P-ANISIDINE CAS Number 5961-59-1 Purity 98% Mol
Cas:5961-59-1
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inquiryOur advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva
Cas:5961-59-1
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:5961-59-1
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inquiryName N-Methyl-4-anisidine/4-Methoxy-N-methylaniline CAS NO. 5961-59-1 Molecular Formula C8H11NO Molecular Weight 137.18 EINECS 227
We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED
Cas:5961-59-1
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inquiryProduct Name: N-METHYL-P-ANISIDINE Synonyms: N-METHYL-PARA-ANISIDINE;4-Methoxy-N-methylaniline,N-Methyl-p-anisidine;1-Methylamino-4-methoxybenzene;4-Methoxy-N-methylbenzenamine;N-(4-Methoxyphenyl)-N-methylamine;N-Methyl-4-methoxyaniline;N-Methy
Cas:5961-59-1
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inquiry1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ
Cas:5961-59-1
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inquiryN-METHYL-P-ANISIDINE CAS:5961-59-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inter
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:5961-59-1
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inquiryAppearance:white powder/crystal Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common products:Sea/Ai
Cas:5961-59-1
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Cas:5961-59-1
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inquiryPacking: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd
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inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:5961-59-1
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inquirySuperior quality, moderate price & quick delivery. Appearance:white to greyish-brown crystal. low melting mass Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:100g/bottle,1kg/bottle,25kg/drum or as per your re
Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.
Cas:5961-59-1
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inquiryZhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed
Cas:5961-59-1
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inquiryWe are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Cas:5961-59-1
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inquiry4-Methoxy-N-methylanilineAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier
Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea
Cas:5961-59-1
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inquiryHunan chemfish Pharmaceutical co.,Ltd a comprehensive enterprise, is located in High-Tech Science Park,Changsha,Chia . Specializing in R&D, manufacture and marketing, we provide a wide range of products and the most professional services to meet the
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Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In tetrahydrofuran for 2h; Heating / reflux; | 100% |
With lithium aluminium tetrahydride In tetrahydrofuran at 60℃; | |
With lithium aluminium tetrahydride In diethyl ether Inert atmosphere; Reflux; |
Conditions | Yield |
---|---|
With butyl triphenylphosphonium tetraborate at 20℃; for 0.183333h; | 99% |
With 3 weight% Pd/C; hydrogen In methanol at 80℃; under 3800.26 Torr; Reagent/catalyst; Autoclave; | 94.2% |
Stage #1: formaldehyd; 4-methoxy-aniline With sodium methylate In methanol at 20℃; for 5h; Stage #2: With sodium tetrahydroborate In methanol for 1.75h; Heating; | 80% |
Conditions | Yield |
---|---|
With cesiumhydroxide monohydrate; (1,4-dimethyl-5,7-diphenyl-1,2,3,4-tetrahydro-6H-cyclopenta[b]pyrazin-6-one) irontricarbonyl complex3 at 110℃; Catalytic behavior; Reagent/catalyst; Temperature; Schlenk technique; Inert atmosphere; | 99% |
With potassium tert-butylate; C49H50Cl2Ir2N5O(1+)*F6P(1-) at 130℃; for 4h; | 99% |
With C12H16IrN4O2(1+)*BF4(1-); potassium hydroxide at 120℃; for 5h; Irradiation; Inert atmosphere; Sealed tube; | 95% |
N-(4-methoxyphenyl)-N-methyl-S-phenylthiohydroxylamine
A
diphenyldisulfane
B
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In acetonitrile for 0.166667h; Mechanism; Product distribution; Ambient temperature; various solvents, Lewis acids, and N-methylbenzenesulfenanilide; | A 97% B 40% |
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene; 1-dodecylthiol In water; N,N-dimethyl-formamide for 12h; Inert atmosphere; | 97% |
Conditions | Yield |
---|---|
With C18H37ClMoNO2P2; hydrogen; sodium triethylborohydride In tetrahydrofuran; toluene at 130℃; under 37503.8 Torr; for 24h; Autoclave; Glovebox; | 96% |
With hydrogenchloride In water for 1.5h; Reflux; | 74% |
With water Heating; Yield given; | |
With aluminum oxide; potassium fluoride for 0.333333h; microwave irradiation; |
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With trifluoroacetic acid In dichloromethane at 25℃; | 96% |
With trifluoroacetic acid In dichloromethane at 40℃; for 48h; Inert atmosphere; Schlenk technique; | |
With hydrogenchloride In water at 120℃; |
N-(4-methoxyphenyl)-N-methylacetamide
A
4-methoxy-N-ethyl-N-methylaniline
B
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With triethyl borane; Triethoxysilane; sodium hydroxide In hexane at 80℃; for 6h; Reagent/catalyst; Solvent; Inert atmosphere; Sealed tube; | A 3% B 96% |
With sodium triethylborohydride In tetrahydrofuran at 80℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox; Sealed tube; | A n/a B 72% |
With sodium triethylborohydride In tetrahydrofuran at 80℃; for 6h; Inert atmosphere; Schlenk technique; High pressure; Sealed tube; | A n/a B 72% |
Conditions | Yield |
---|---|
With potassium tert-butylate; C49H50Cl2Ir2N5O(1+)*F6P(1-) at 130℃; for 10h; | 96% |
With [iridium(I)Br(carbonyl)2(κ1C-tBuImCH2PyCH2OMe)]; caesium carbonate at 129.84℃; for 5h; Catalytic behavior; Mechanism; Inert atmosphere; Glovebox; Green chemistry; | 92% |
With rhodium(III) chloride hydrate; potassium tert-butylate at 130℃; for 48h; Sealed tube; High pressure; | 82% |
N-(4-methoxyphenyl)-N-methylacetamide
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
Stage #1: N-(4-methoxyphenyl)-N-methylacetamide With sulfuric acid; water for 2h; Heating / reflux; Stage #2: With sodium hydroxide; water Product distribution / selectivity; | 95.86% |
With potassium methanolate; C26H32MnN4O4 In butan-1-ol at 135℃; for 45h; | 63% |
With hydrogenchloride In water; ethylene glycol for 24h; Reflux; Inert atmosphere; | |
With hydrogenchloride In water; ethylene glycol at 20℃; for 3h; Inert atmosphere; |
Conditions | Yield |
---|---|
With copper In water at 100℃; for 12h; Ullmann reaction; | 95.3% |
With copper(l) iodide; 6,7-dihydro-5H-quinolin-8-one oxime; potassium hydroxide In water at 85℃; for 24h; Inert atmosphere; | 87% |
With copper(l) iodide; tetrabutylammomium bromide; potassium hydroxide In water at 90℃; for 16h; Ullmann-Goldberg Substitution; Green chemistry; | 63% |
Conditions | Yield |
---|---|
With copper(l) iodide; 6,7-dihydro-5H-quinolin-8-one oxime; potassium hydroxide In water at 25℃; for 24h; Inert atmosphere; | 95% |
With potassium phosphate; copper(II) ferrite at 100℃; for 12h; Sealed tube; chemoselective reaction; | 80% |
With copper In water at 100℃; for 24h; Sealed tube; |
N-methyl-N-(4-methoxyphenyl)-4-nitrobenzene sulphonamide
mercaptoacetic acid
A
2-(4-nitrophenylthio)acetic acid
B
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃; | A n/a B 93% |
Conditions | Yield |
---|---|
With chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2’,4’,6’-triisopropyl-1,1’-biphenyl] [2-(2-aminoethyl)phenyl]palladium(II); sodium t-butanolate In tetrahydrofuran; tert-butyl alcohol at 20℃; for 2h; Inert atmosphere; | 92% |
With sodium t-butanolate; chloro[2-(dicyclohexylphosphino)-3 ,6-dimethoxy-2’,4’, 6’-triisopropyl- 1,1’-biphenyl] [2-(2-aminoethyl)phenyl]palladium(II) In tetrahydrofuran; tert-butyl alcohol at 20℃; for 2h; Inert atmosphere; | 92% |
With Pd2(dba)4; potassium tert-butylate; C40H66P2 In tetrahydrofuran at 20℃; for 1.5h; Buchwald-Hartwig Coupling; Inert atmosphere; Schlenk technique; Glovebox; | 79% |
Conditions | Yield |
---|---|
With hydrogen; sodium hydroxide In methanol at 125℃; under 26252.6 Torr; for 4h; Concentration; Reagent/catalyst; Pressure; Temperature; Time; Autoclave; | 90.7% |
carbon dioxide
p-toluidine
4-chloro-aniline
4-methoxy-aniline
aniline
4-fluoroaniline
4-bromo-aniline
A
N-methyl-p-toluidine
B
4-fluoro-N-methylaniline
C
N-methyl(p-chloroaniline)
D
4-bromo-N-methylaniline
E
N-methylaniline
F
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With methanesulfonic acid; hydrogen; tris(acetylacetonato)ruthenium(III); [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In tetrahydrofuran at 140℃; for 5h; Inert atmosphere; | A 69% B 39% C 15% D 13% E 35% F 90% |
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With 3-azapentane-1,5-diamine at 140℃; for 24h; Sealed tube; | 90% |
Methyl methanesulfonate
4-methoxy-aniline
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In ethanol for 2h; Reflux; Inert atmosphere; Molecular sieve; | 89% |
Conditions | Yield |
---|---|
With sodium bis(2-methoxyethoxy)aluminium dihydride In toluene for 0.166667h; | 88% |
With lithium borohydride | |
With lithium aluminium tetrahydride | |
With dimethylsulfide borane complex In tetrahydrofuran for 3h; Heating; Yield given; | |
Multi-step reaction with 2 steps 1: anhydrous potassium carbonate, sodium hydroxide, tetrabutylammonium hydrogensulphate / benzene / 1 h / 5 - 10 °C / Heating 2: water / Heating View Scheme |
N-methyl-O-(trimethylsilyl)hydroxylamine
p-methoxyphenyllithium
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With CuCN In tetrahydrofuran at -50 - 20℃; for 2h; Arylation; | 88% |
Conditions | Yield |
---|---|
Stage #1: formic acid; 4-methoxy-aniline With sodium methylate In methanol at 20℃; for 17h; Reflux; Stage #2: With sodium tetrahydroborate In methanol for 2.5h; Reflux; | 88% |
4-methoxy-aniline
N,N-dimethyl-formamide
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With trimethylamine-borane; sodium hydride at 80℃; for 1h; Inert atmosphere; | 88% |
Conditions | Yield |
---|---|
Stage #1: 4-methoxy-N,N-dimethylanilne With tert.-butylhydroperoxide In toluene for 0.0333333h; Inert atmosphere; Stage #2: With triethylamine In toluene at 110℃; for 3h; Inert atmosphere; | 85% |
With iodosylbenzene; C25H25FeN5(2+)*2CF3O3S(1-) In acetonitrile at 25℃; for 0.833333h; | 6% |
With 3-Nitrochlorobenzene In benzene for 3h; Irradiation; Yield given; |
methanol
4-methoxy-aniline
A
4-methoxy-N,N-dimethylanilne
B
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With hydrogenchloride; nickel(II) oxide; titanium(IV) oxide In water for 6h; UV-irradiation; | A 81% B 18% |
With zinc oxide-supported iridium catalyst In 1,3,5-trimethyl-benzene at 150℃; under 3750.38 Torr; for 17h; Inert atmosphere; | A 15 %Chromat. B 63 %Chromat. |
N-(4-methoxyphenyl)-N,4-dimethylbenzenesulfonamide
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; potassium tert-butylate In dimethyl sulfoxide at 20℃; for 1h; Inert atmosphere; Schlenk technique; Irradiation; Sealed tube; | 80% |
With sulfuric acid at 150℃; |
Conditions | Yield |
---|---|
Stage #1: methanol; 4-methoxybenzoyl azide at 70℃; for 3h; Inert atmosphere; Stage #2: With C54H43ClN3P2Ru(1+)*F6P(1-); potassium carbonate at 140℃; Inert atmosphere; | 78% |
methyllithium
(Z)-tert-Butyl (4-methoxyphenyl)azo sulfide
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
In diethyl ether at 0 - 25℃; for 0.416667h; | 76% |
Conditions | Yield |
---|---|
With hydrogen In hexane at 160℃; for 24h; Autoclave; | 74% |
formaldehyd
4-methoxy-aniline
A
4-methoxy-N,N-dimethylanilne
B
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With hydrogen In methanol at 80℃; under 3800.26 Torr; Reagent/catalyst; Autoclave; | A n/a B 72.44% |
With calcium hydride; 5%-palladium/activated carbon In toluene at 30℃; for 16h; Sealed tube; | A n/a B 50 %Spectr. |
2-methylmalonyl dichloride
N-methyl-N-(4-methoxyphenyl)amine
N-methyl-N-(4-methoxyphenyl)-α-carbomethoxyacetamide
Conditions | Yield |
---|---|
With triethylamine; citric acid In dichloromethane | 100% |
Conditions | Yield |
---|---|
Stage #1: cyanoacetic acid With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃; for 3h; Stage #2: N-methyl-N-(4-methoxyphenyl)amine With triethylamine In dichloromethane at 0 - 20℃; | 100% |
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0℃; for 1h; Inert atmosphere; Schlenk technique; | 75% |
Stage #1: cyanoacetic acid With oxalyl dichloride In dichloromethane; N,N-dimethyl-formamide at 0 - 20℃; for 3h; Stage #2: N-methyl-N-(4-methoxyphenyl)amine With triethylamine In dichloromethane; N,N-dimethyl-formamide at 0℃; |
carbon dioxide
N-methyl-N-(4-methoxyphenyl)amine
4-methoxy-N,N-dimethylanilne
Conditions | Yield |
---|---|
With proazaphosphatrane; 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran at 90℃; under 750.075 Torr; for 1h; Inert atmosphere; Schlenk technique; chemoselective reaction; | 100% |
With phenylsilane; triphenylphosphine In tetrahydrofuran at 120℃; under 3750.38 Torr; for 24h; Autoclave; Green chemistry; | 99% |
With cyclopentadienyl iron(II) dicarbonyl dimer; phenylsilane; triphenylphosphine In acetonitrile at 100℃; under 760.051 Torr; for 36h; Schlenk technique; Sealed tube; | 95% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 19h; | 100% |
chloroacetyl chloride
N-methyl-N-(4-methoxyphenyl)amine
2-chloro-N-(4-methoxy-phenyl)-N-methylacetamide
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In dichloromethane; water Ambient temperature; | 99% |
With pyridine; triethylamine In toluene Ambient temperature; | 67% |
In N,N-dimethyl acetamide at 0 - 20℃; | 67% |
α-bromopropionyl bromide
N-methyl-N-(4-methoxyphenyl)amine
N-(4-methoxyphenyl)-N-methyl-2-bromopropionylamide
Conditions | Yield |
---|---|
In 1,2-dichloro-ethane for 2h; Heating; | 99% |
N-methyl-N-(4-methoxyphenyl)amine
cyclopropylboronic acid
Conditions | Yield |
---|---|
With [2,2]bipyridinyl; oxygen; copper diacetate; sodium carbonate In 1,2-dichloro-ethane at 70℃; for 2h; Chan-Lam reaction; | 99% |
(2-methylquinazolin-4-yl)-4-methylbenzenesulfonate
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
In dichloromethane; isopropyl alcohol at 20℃; for 1h; | 99% |
tert-butyl(5-hexenyloxy)dimethylsilane
N-methyl-N-(4-methoxyphenyl)amine
N-(6-(tert-butyldimethylsilyloxy)-2-methylhexyl)-4-methoxyaniline
Conditions | Yield |
---|---|
With (N-[2,6-diisopropylphenyl]pivalamidate)tetrakis(dimethylamido)tantalum In (2)H8-toluene at 130℃; for 20h; Inert atmosphere; | 99% |
(N-[2,6-diisopropylphenyl]pivalamidate)tetrakis(dimethylamido)tantalum In (2)H8-toluene at 130℃; for 20h; Product distribution / selectivity; | 90% |
With (N-[2,6-diisopropylphenyl]pivalamidate)tetrakis(dimethylamido)tantalum In (2)H8-toluene at 130℃; for 20h; | 90% |
1-bromo-2-(bromomethyl)-4,5-dimethoxybenzene
N-methyl-N-(4-methoxyphenyl)amine
N-(2-bromo-4,5-dimethoxybenzyl)-4-methoxy-N-methylaniline
Conditions | Yield |
---|---|
Stage #1: N-methyl-N-(4-methoxyphenyl)amine With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.0833333h; Inert atmosphere; Stage #2: 1-bromo-2-(bromomethyl)-4,5-dimethoxybenzene In N,N-dimethyl-formamide at 0 - 20℃; for 2h; | 99% |
N-methyl-N-(4-methoxyphenyl)amine
1-Bromo-2-bromomethyl-benzene
N-(2-bromobenzyl)-4-methoxy-N-methylaniline
Conditions | Yield |
---|---|
Stage #1: N-methyl-N-(4-methoxyphenyl)amine With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.0833333h; Inert atmosphere; Stage #2: 1-Bromo-2-bromomethyl-benzene In N,N-dimethyl-formamide at 0 - 20℃; for 2h; | 99% |
carbon dioxide
N-methyl-N-(4-methoxyphenyl)amine
4-methoxy-N-methylformanilide
Conditions | Yield |
---|---|
With phenylsilane; C42H60N6O2Zn(2+)*2Br(1-) at 40℃; under 3750.38 Torr; for 6h; Reagent/catalyst; Autoclave; | 99% |
With phenylsilane; C56H50N2O2P2Zn(2+)*2Br(1-) In neat (no solvent) at 40℃; under 3750.38 Torr; for 6h; Autoclave; chemoselective reaction; | 99% |
With phenylsilane In neat (no solvent) at 35℃; under 7500.75 Torr; for 14h; Autoclave; | 99% |
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0 - 20℃; | 99% |
cyclohexa-1,3-diene
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); trifluoroacetic acid In toluene at 20℃; for 24h; | 98% |
tetrakis(triphenylphosphine) palladium(0); trifluoroacetic acid In toluene at 25℃; for 24h; | 98% |
With tetrakis(triphenylphosphine) palladium(0); trifluoroacetic acid In toluene at 20℃; for 18h; Inert atmosphere; Schlenk technique; | 84% |
2,4-dichloro-6-methoxy-quinazoline
N-methyl-N-(4-methoxyphenyl)amine
(2-chloro-6-methoxy-quinazoline-4-yl)-(4-methoxy-phenyl)methylamine
Conditions | Yield |
---|---|
With sodium acetate In tetrahydrofuran; water at 60 - 70℃; for 3h; | 98% |
phenylacetylene
N-methyl-N-(4-methoxyphenyl)amine
(4-methoxyphenyl)(methyl)(1-phenylethyl)amine
Conditions | Yield |
---|---|
With (o-biphenyl)(t-Bu)2PAuCl; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; AgBF4 In tetrahydrofuran at 60℃; for 26h; | 98% |
With tin(II) trifluoromethanesulfonate; ethanol In toluene at 120℃; for 7h; | 83% |
2-bromo-5-methoxybenzyl bromide
N-methyl-N-(4-methoxyphenyl)amine
N-(2-bromo-5-methoxybenzyl)-4-methoxy-N-methylaniline
Conditions | Yield |
---|---|
Stage #1: N-methyl-N-(4-methoxyphenyl)amine With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.0833333h; Inert atmosphere; Stage #2: 2-bromo-5-methoxybenzyl bromide In N,N-dimethyl-formamide at 0 - 20℃; for 2h; | 98% |
5-bromothiophene-2-carbonyl chloride
N-methyl-N-(4-methoxyphenyl)amine
5-bromo-N-(4-methoxyphenyl)-N-methylthiophene-2-carboxamide
Conditions | Yield |
---|---|
With triethylamine at 0℃; for 3h; | 98% |
4-bromobenzenesulfonyl chloride
N-methyl-N-(4-methoxyphenyl)amine
4-bromo-N-(4-methoxyphenyl)-N-methylbenzenesulfonamide
Conditions | Yield |
---|---|
With tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide In dichloromethane; water at 20℃; for 3h; | 98% |
formic acid
N-methyl-N-(4-methoxyphenyl)amine
4-methoxy-N,N-dimethylanilne
Conditions | Yield |
---|---|
With tris(pentafluorophenyl)borate In dibutyl ether at 100℃; Schlenk technique; Inert atmosphere; | 98% |
With phenylsilane; copper diacetate In dibutyl ether at 80℃; for 8h; Schlenk technique; Green chemistry; | 92% |
With platinum on carbon; phenylsilane In toluene at 80℃; for 15h; | 74% |
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With C39H60N4O4; gadolinium(III) trifluoromethanesulfonate In chloroform at 55℃; for 16h; enantioselective reaction; | 98% |
2-Iodobenzoyl chloride
N-methyl-N-(4-methoxyphenyl)amine
2-iodo-N-(4-methoxyphenyl)-N-methylbenzamide
Conditions | Yield |
---|---|
With dmap; triethylamine In dichloromethane Inert atmosphere; Schlenk technique; | 98% |
allyl alcohol
N-methyl-N-(4-methoxyphenyl)amine
N-methyl-N-(3-hydroxyl-1-propyl)-4-methoxyaniline
Conditions | Yield |
---|---|
With C17H16BrMnN2O3S; potassium carbonate In toluene at 100℃; for 12h; Inert atmosphere; chemoselective reaction; | 98% |
With C14H29BrMnNO2P2; sodium triethylborohydride; potassium carbonate In cyclohexane at 60℃; for 24h; Inert atmosphere; | 96% |
With potassium phosphate; [(bis(2-dicyclohexylphosphinoethyl)amine)Fe(CO)Br2]; sodium triethylborohydride In cyclohexane at 80℃; for 12h; Inert atmosphere; Sealed tube; | 94% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl In acetonitrile at 25℃; for 3.5h; Inert atmosphere; | 97.6% |
N-methyl-N-(4-methoxyphenyl)amine
Conditions | Yield |
---|---|
With potassium hexamethylsilazane In toluene at 20℃; for 1.5h; | 97% |
5-bromo-6-bromomethylbenzo[1,3]dioxole
N-methyl-N-(4-methoxyphenyl)amine
N-((6-bromobenzo[d][1,3]dioxol-5-yl)methyl)-4-methoxy-N-methylaniline
Conditions | Yield |
---|---|
Stage #1: N-methyl-N-(4-methoxyphenyl)amine With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.0833333h; Inert atmosphere; Stage #2: 5-bromo-6-bromomethylbenzo[1,3]dioxole In N,N-dimethyl-formamide at 0 - 20℃; for 2h; | 97% |
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