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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

CIS-9-HEXADECENOL

Cas:10378-01-5

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 10378-01-5 with competitive price

Cas:10378-01-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine chemicals, ph

Palmitoleyl alcohol

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

CIS-9-HEXADECENOL CAS:10378-01-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interm

CIS-9-HEXADECENOL CAS:10378-01-5

Cas:10378-01-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

9-Hexadecen-1-ol, (9Z)-

Cas:10378-01-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

9-Hexadecen-1-ol, (9Z)-

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

CIS-9-HEXADECENOL CAS:10378-01-5

Cas:10378-01-5

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

9-Hexadecen-1-ol, (9Z)-

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Palmitoleyl alcohol

Cas:10378-01-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

Hangzhou Fandachem Co.,Ltd, a China-based chemical company, specialize in exporting Palmitoleyl alcohol , CAS NO: 10378-01-5 Please contact us by email freely. We are leading exporter in China. If you really need this cargo, plea

Palmitoleyl alcohol , CAS NO: 10378-01-5

Cas:10378-01-5

Min.Order:1 Kilogram

Negotiable

Type:Other

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

10378-01-5

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

CIS-9-HEXADECENOL

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

CIS-9-HEXADECENOL

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

9-Hexadecen-1-ol, (9Z)-

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

DB BIOTECH CO., LTD

best seller Application:API

CIS-9-HEXADECENOL

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Trading Company

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

CIS-9-HEXADECENOL

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

10378-01-5

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

HANGZHOU TIANYE CHEMICALS Co.LTD , Located in Eastern Science and Innovation Park Hangzhou .We are a high-tech enterprise specialized in technical research and development, production, development and trade of chemical products. We supply Multiple so

CIS-9-HEXADECENOL

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Muhuang Technology Co., Ltd

best seller Application:API

CIS-9-HEXADECENOL

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

CIS-9-HEXADECENOL

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

suzhou BetterBioChem Co., Ltd.

Betterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in

9Z-Hexadecen-1-ol

Cas:10378-01-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

HuBei Ipure Biotech CO.,ltd

HuBei ipure is a diversified product production and operation enterprise, with API, pharma intermediates, and other fine chemicals as well as R&D and pigments development and sales as one of the large enterprises, with more than 130 acres of pl

Vitamin E nicotinate Manufacturer/High. quality/Best price/In stock

Cas:10378-01-5

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

U-Chemo Holding Co.,Limited

U-CHEMO Holding Co.,Limited is a very fast developing high-technology enterprise combining with manufacture and sales.U-CHEMO supply high quality products and excellent service to our customers.We make the insect pheromones, censor in the quality con

9Z-16OH

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

9-Hexadecen-1-ol, (9Z)-

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chungking Joyinchem Co., Ltd.

Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

9-Hexadecen-1-ol, (9Z)-

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Run-Biotech Co., Ltd.

Shanghai, Run-Biotech Co., Ltd is a leading domestic pharmaceutical, biopharmaceutical, and health care products R & D outsourcing services company. As an innovation-driven and customer-focused company, Run Biotech provides a broad and integrated por

CIS-9-HEXADECENOL

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Nanjing Raymon Biotech Co., Ltd.

9-Hexadecen-1-ol, (9Z)- Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/Shenzhen

9-Hexadecen-1-ol, (9Z)-

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Ingredients Technology Co., Ltd.

Good QualityCompetitive priceFirst-class service Application:pesticide

CIS-9-HEXADECENOL CAS NO.10378-01-5

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Other

inquiry

Esuccess Material Limited

High quality, Competitive price & Excellent service Application:Chemical,Organic Intermediates

Cis-9-Hexadecenol

Cas:10378-01-5

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

10378-01-5

Cas:10378-01-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

cis-9-hexadecenoic acid
373-49-9

cis-9-hexadecenoic acid

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; Reflux;98%
With lithium aluminium tetrahydride In diethyl ether at 20℃; for 24h;97%
Multi-step reaction with 2 steps
1: 0.19 g / conc. H2SO4 / 6 h / Heating
2: 0.14 g / LiAlH4 / tetrahydrofuran / 24 h / Ambient temperature
View Scheme
9-hexadecyn-1-ol
88109-73-3

9-hexadecyn-1-ol

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
With hydrogen; ethylendiamine poisoned P-2 Ni In ethanol97%
With hydrogen; Ni-P288%
With bis(cyclopentadienyl)titanium dichloride; di-iso-butylmagnesium; ammonium chloride 1.) Et2O, 20 deg C, 30 min, 2.) H2O; Yield given. Multistep reaction;
(Z)-9-hexadecenoic acid methyl ester
1120-25-8

(Z)-9-hexadecenoic acid methyl ester

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at -10 - 20℃; for 5h;96%
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 2h;92%
With lithium aluminium tetrahydride In tetrahydrofuran for 24h; Ambient temperature;0.14 g
With lithium aluminium tetrahydride In diethyl ether for 2h; Reflux;2.3 g
9-tetradecyn-1-ol
60037-69-6

9-tetradecyn-1-ol

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
With hydrogen; P2Ni86%
(Z)-hexadec-9-en-1-yl acetate
34010-20-3

(Z)-hexadec-9-en-1-yl acetate

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether at 20℃; for 5h;82%
With sodium hydroxide In methanol
(Z)-tert-butyl(hexadec-9-en-1-yloxy)dimethylsilane

(Z)-tert-butyl(hexadec-9-en-1-yloxy)dimethylsilane

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran at 0 - 20℃; for 3h;82%
heptanal
111-71-7

heptanal

(9-hydroxynonyl)(triphenyl)phosphonium bromide
73945-70-7

(9-hydroxynonyl)(triphenyl)phosphonium bromide

A

trans-hexadec-9-en-1-ol
64437-47-4

trans-hexadec-9-en-1-ol

B

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
With sodium hydride; dimethyl sulfoxide In tetrahydrofuran for 0.5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
(Z)-16-(1-Ethoxy-ethoxy)-hexadec-7-ene

(Z)-16-(1-Ethoxy-ethoxy)-hexadec-7-ene

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In methanol; water at 20℃; for 15h; Yield given;
2-[((Z)-Hexadec-9-enyl)oxy]-tetrahydro-pyran
99159-88-3

2-[((Z)-Hexadec-9-enyl)oxy]-tetrahydro-pyran

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In methanol for 3h; Heating; Yield given;
With toluene-4-sulfonic acid In methanol at 20℃; for 16h;
(Z)-4-undecene-1-ol
21676-07-3

(Z)-4-undecene-1-ol

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 96 percent / triphenylphosphine, Br2 / CCl4 / 16 h / Ambient temperature
2: 1.) cuprous iodide, 2,2' bipyridyl / 1.) THF, 2 deg C, 10 min, 2.) THF, a) 2 deg C, 2 h, b) RT, 15 h
3: p-toluenesulfonic acid / methanol; H2O / 15 h / 20 °C
View Scheme
Multi-step reaction with 3 steps
1: 82 percent / PBr3, pyridine / diethyl ether / 1) rt, overnight, 2) reflux, 2 h
2: 1) Mg / 3) Li2CuCl4 / 1) THF, 2) THF, -10 deg C, 30 min, 3) a) 0 to -10 deg C, 6 h, b) rt, overnight
3: p-toluenesulphonic acid / methanol / 3 h / Heating
View Scheme
(Z)-4-undecenal
68820-32-6

(Z)-4-undecenal

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 95 percent / diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C
2: 96 percent / triphenylphosphine, Br2 / CCl4 / 16 h / Ambient temperature
3: 1.) cuprous iodide, 2,2' bipyridyl / 1.) THF, 2 deg C, 10 min, 2.) THF, a) 2 deg C, 2 h, b) RT, 15 h
4: p-toluenesulfonic acid / methanol; H2O / 15 h / 20 °C
View Scheme
(Z)-4-undecenyl bromide
109523-23-1

(Z)-4-undecenyl bromide

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1.) cuprous iodide, 2,2' bipyridyl / 1.) THF, 2 deg C, 10 min, 2.) THF, a) 2 deg C, 2 h, b) RT, 15 h
2: p-toluenesulfonic acid / methanol; H2O / 15 h / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: 1) Mg / 3) Li2CuCl4 / 1) THF, 2) THF, -10 deg C, 30 min, 3) a) 0 to -10 deg C, 6 h, b) rt, overnight
2: p-toluenesulphonic acid / methanol / 3 h / Heating
View Scheme
1,1-dimethoxy-8-tosyloxy-(4Z)-octene
82861-01-6

1,1-dimethoxy-8-tosyloxy-(4Z)-octene

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: 63 percent / dilithium tetrachlorocuprate / tetrahydrofuran / 1.) -78 deg C, 2 h, 2.) RT, 15 h
2: 99 percent / 5percent HCl / acetone / 6 h / Ambient temperature
3: 95 percent / diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C
4: 96 percent / triphenylphosphine, Br2 / CCl4 / 16 h / Ambient temperature
5: 1.) cuprous iodide, 2,2' bipyridyl / 1.) THF, 2 deg C, 10 min, 2.) THF, a) 2 deg C, 2 h, b) RT, 15 h
6: p-toluenesulfonic acid / methanol; H2O / 15 h / 20 °C
View Scheme
1,1-dimethoxy-(4Z)-undecene
104187-94-2

1,1-dimethoxy-(4Z)-undecene

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 99 percent / 5percent HCl / acetone / 6 h / Ambient temperature
2: 95 percent / diisobutylaluminum hydride / diethyl ether; toluene / 1.5 h / -10 °C
3: 96 percent / triphenylphosphine, Br2 / CCl4 / 16 h / Ambient temperature
4: 1.) cuprous iodide, 2,2' bipyridyl / 1.) THF, 2 deg C, 10 min, 2.) THF, a) 2 deg C, 2 h, b) RT, 15 h
5: p-toluenesulfonic acid / methanol; H2O / 15 h / 20 °C
View Scheme
methyl aleuritate

methyl aleuritate

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: 60.91 percent / aq. NaIO4 / acetonitrile / 0.5 h / 5 °C
2.1: sodium amide / tetrahydrofuran; hexamethylphosphoric acid triamide / 1.5 h / 20 °C
2.2: 91.52 percent / tetrahydrofuran; hexamethylphosphoric acid triamide / -73 - 20 °C
3.1: 92 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 0 °C
View Scheme
methyl ester of azelaic acid aldehyde
1931-63-1

methyl ester of azelaic acid aldehyde

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: sodium amide / tetrahydrofuran; hexamethylphosphoric acid triamide / 1.5 h / 20 °C
1.2: 91.52 percent / tetrahydrofuran; hexamethylphosphoric acid triamide / -73 - 20 °C
2.1: 92 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 0 °C
View Scheme
Multi-step reaction with 2 steps
1: 1.) NaNH2 / 1.) THF, RT, 1 h, 2.) THF, from -10 deg C to RT
2: 96 percent / LAH / tetrahydrofuran / 5 h / -10 - 20 °C
View Scheme
Multi-step reaction with 2 steps
1: potassium carbonate / toluene / 4 h / Reflux
2: lithium aluminium tetrahydride / diethyl ether / 2 h / Reflux
View Scheme
triphenylheptylphosphonium bromide
13423-48-8

triphenylheptylphosphonium bromide

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: sodium amide / tetrahydrofuran; hexamethylphosphoric acid triamide / 1.5 h / 20 °C
1.2: 91.52 percent / tetrahydrofuran; hexamethylphosphoric acid triamide / -73 - 20 °C
2.1: 92 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 0 °C
View Scheme
Multi-step reaction with 2 steps
1: 1.) sodium bis(trimethylsilyl)amide / 1.) THF, from 50 to 55 deg C, 60 min, 2.) THF, a) -78 deg C, 30 min, b) 20 deg C, 12 h
2: 82 percent / LiAlH4 / diethyl ether / 5 h / 20 °C
View Scheme
(+)-threo-9,10,16-trihydroxyhexadecanoic acid

(+)-threo-9,10,16-trihydroxyhexadecanoic acid

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: 97.95 percent / aq. H2SO4 / 0.11 h / microwave irradiation
2.1: 60.91 percent / aq. NaIO4 / acetonitrile / 0.5 h / 5 °C
3.1: sodium amide / tetrahydrofuran; hexamethylphosphoric acid triamide / 1.5 h / 20 °C
3.2: 91.52 percent / tetrahydrofuran; hexamethylphosphoric acid triamide / -73 - 20 °C
4.1: 92 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 0 °C
View Scheme
8-Bromo-1-octene
2695-48-9

8-Bromo-1-octene

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 87 percent / NH3
2: 1) 9-BBN, 2) H2O2, AcONa
3: 88 percent / H2 / Ni-P2
View Scheme
1-octynyllithium
21433-45-4

1-octynyllithium

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 87 percent / NH3
2: 1) 9-BBN, 2) H2O2, AcONa
3: 88 percent / H2 / Ni-P2
View Scheme
hexadec-1-en-9-yne
197901-27-2

hexadec-1-en-9-yne

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1) 9-BBN, 2) H2O2, AcONa
2: 88 percent / H2 / Ni-P2
View Scheme
10,11-dibromo-undecanoic acid
6308-96-9

10,11-dibromo-undecanoic acid

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: KOH, PEG 400 / 0.5 h / 150 - 200 °C
2: p-TSA / 12 h / Ambient temperature
3: 96 percent / H2, quinoline / 5percent Pd/BaSO4 / hexane / Ambient temperature
4: 84 percent / O3 / CH2Cl2 / -78 °C
5: 1.) NaNH2 / 1.) THF, RT, 1 h, 2.) THF, from -10 deg C to RT
6: 96 percent / LAH / tetrahydrofuran / 5 h / -10 - 20 °C
View Scheme
10-undecenoic acid
112-38-9

10-undecenoic acid

aqueous KOH-solution

aqueous KOH-solution

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 7 steps
1: 97 percent / Br2 / CCl4 / 1.5 h
2: KOH, PEG 400 / 0.5 h / 150 - 200 °C
3: p-TSA / 12 h / Ambient temperature
4: 96 percent / H2, quinoline / 5percent Pd/BaSO4 / hexane / Ambient temperature
5: 84 percent / O3 / CH2Cl2 / -78 °C
6: 1.) NaNH2 / 1.) THF, RT, 1 h, 2.) THF, from -10 deg C to RT
7: 96 percent / LAH / tetrahydrofuran / 5 h / -10 - 20 °C
View Scheme
9-undecynoic acid
22202-65-9

9-undecynoic acid

hydrogen

hydrogen

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: p-TSA / 12 h / Ambient temperature
2: 96 percent / H2, quinoline / 5percent Pd/BaSO4 / hexane / Ambient temperature
3: 84 percent / O3 / CH2Cl2 / -78 °C
4: 1.) NaNH2 / 1.) THF, RT, 1 h, 2.) THF, from -10 deg C to RT
5: 96 percent / LAH / tetrahydrofuran / 5 h / -10 - 20 °C
View Scheme
9-undecynoic acid methyl ester
18937-76-3

9-undecynoic acid methyl ester

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 96 percent / H2, quinoline / 5percent Pd/BaSO4 / hexane / Ambient temperature
2: 84 percent / O3 / CH2Cl2 / -78 °C
3: 1.) NaNH2 / 1.) THF, RT, 1 h, 2.) THF, from -10 deg C to RT
4: 96 percent / LAH / tetrahydrofuran / 5 h / -10 - 20 °C
View Scheme
(Z)-0-undecenoic acid methyl ester
54299-07-9

(Z)-0-undecenoic acid methyl ester

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 84 percent / O3 / CH2Cl2 / -78 °C
2: 1.) NaNH2 / 1.) THF, RT, 1 h, 2.) THF, from -10 deg C to RT
3: 96 percent / LAH / tetrahydrofuran / 5 h / -10 - 20 °C
View Scheme
2-(8-bromooctyloxy)tetrahydropyran
50816-20-1

2-(8-bromooctyloxy)tetrahydropyran

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 1.) LiNH2, HMPTA / 1.) RT, 1 h, 2.) a) 10 deg C, 1 h, b) RT, 15 h, c) 55 deg C, 10 h
2: 85 percent / p-TsOH / methanol; H2O / 18 h / 20 °C
3: 1.) iso-BuMgBr, 2.) Cp2TiCl2 / 1.) diethyl ether, 0 deg C, 15 min, 2.) diethyl ether, RT, 3 h
View Scheme
Multi-step reaction with 3 steps
1.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -30 - 0 °C / Inert atmosphere
1.2: 16 h / Reflux
2.1: potassium hydroxide; palladium diacetate / N,N-dimethyl-formamide / 16 h / 145 °C / Sealed tube
3.1: toluene-4-sulfonic acid / methanol / 16 h / 20 °C
View Scheme
1,8-Octanediol
629-41-4

1,8-Octanediol

primary-secondary glycol C8H18O2

primary-secondary glycol C8H18O2

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 75 percent / 48percent HBr / Heating
2: 99 percent / p-toluenesulfonic acid
3: 1.) LiNH2, HMPTA / 1.) RT, 1 h, 2.) a) 10 deg C, 1 h, b) RT, 15 h, c) 55 deg C, 10 h
4: 85 percent / p-TsOH / methanol; H2O / 18 h / 20 °C
5: 1.) iso-BuMgBr, 2.) Cp2TiCl2 / 1.) diethyl ether, 0 deg C, 15 min, 2.) diethyl ether, RT, 3 h
View Scheme
8-bromooctanol
50816-19-8

8-bromooctanol

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 99 percent / p-toluenesulfonic acid
2: 1.) LiNH2, HMPTA / 1.) RT, 1 h, 2.) a) 10 deg C, 1 h, b) RT, 15 h, c) 55 deg C, 10 h
3: 85 percent / p-TsOH / methanol; H2O / 18 h / 20 °C
4: 1.) iso-BuMgBr, 2.) Cp2TiCl2 / 1.) diethyl ether, 0 deg C, 15 min, 2.) diethyl ether, RT, 3 h
View Scheme
Multi-step reaction with 4 steps
1.1: toluene-4-sulfonic acid / dichloromethane / 16.5 h / 0 - 20 °C
2.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -30 - 0 °C / Inert atmosphere
2.2: 16 h / Reflux
3.1: potassium hydroxide; palladium diacetate / N,N-dimethyl-formamide / 16 h / 145 °C / Sealed tube
4.1: toluene-4-sulfonic acid / methanol / 16 h / 20 °C
View Scheme
1-tetrahydropyranyloxy-n-9-hexadecyn
25258-24-6

1-tetrahydropyranyloxy-n-9-hexadecyn

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 85 percent / p-TsOH / methanol; H2O / 18 h / 20 °C
2: 1.) iso-BuMgBr, 2.) Cp2TiCl2 / 1.) diethyl ether, 0 deg C, 15 min, 2.) diethyl ether, RT, 3 h
View Scheme
Multi-step reaction with 2 steps
1: potassium hydroxide; palladium diacetate / N,N-dimethyl-formamide / 16 h / 145 °C / Sealed tube
2: toluene-4-sulfonic acid / methanol / 16 h / 20 °C
View Scheme
palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

(Z)-9-hexadecenal
56219-04-6

(Z)-9-hexadecenal

Conditions
ConditionsYield
With pyridinium chlorochromate In dichloromethane at 20℃; for 2h;98%
With pyridinium chlorochromate In dichloromethane for 1.5h; Ambient temperature;94%
With pyridinium chlorochromate94%
palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

(Z)-hexadec-9-enyl bromide
132538-05-7

(Z)-hexadec-9-enyl bromide

Conditions
ConditionsYield
With bromine; triphenylphosphine In benzene at 20℃; for 3h;97%
With carbon tetrabromide; triphenylphosphine In dichloromethane for 16h; Ambient temperature;94%
With carbon tetrabromide; triphenylphosphine In dichloromethane at 20℃; for 16h;94%
palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

(Z)-16-iodohexadec-7-ene

(Z)-16-iodohexadec-7-ene

Conditions
ConditionsYield
With 1H-imidazole; iodine; triphenylphosphine In toluene at 20℃; for 3h;89%
palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

acetic anhydride
108-24-7

acetic anhydride

(Z)-hexadec-9-en-1-yl acetate
34010-20-3

(Z)-hexadec-9-en-1-yl acetate

Conditions
ConditionsYield
With pyridine for 1h; Ambient temperature;85%
With pyridine for 24h; Ambient temperature;68%
With pyridine for 25h; Ambient temperature;0.1 g
In pyridine at 20℃; for 24h;1.4 g
cholesteryl p-toluenesulfonate
1182-65-6, 3381-56-4

cholesteryl p-toluenesulfonate

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

cholesteryl cis-9'-hexadecenyl ether
74996-37-5

cholesteryl cis-9'-hexadecenyl ether

Conditions
ConditionsYield
at 110℃; for 2.5h;54.1%
palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

palmitoleyl methanesulfonate
93135-85-4

palmitoleyl methanesulfonate

Conditions
ConditionsYield
With pyridine
With pyridine at 0 - 20℃; for 24h;
methanol
67-56-1

methanol

palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

A

10-Methoxy-hexadecan-1-ol

10-Methoxy-hexadecan-1-ol

B

9-Methoxy-hexadecan-1-ol

9-Methoxy-hexadecan-1-ol

Conditions
ConditionsYield
With sodium tetrahydroborate; mercury(II) diacetate 1.) 48 h, RT; 2.) glacial acetic acid; Multistep reaction;
palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

tert-butyl [4-hydroxy-3-(10(Z)-heptadecenyl)]phenyl carbonate

tert-butyl [4-hydroxy-3-(10(Z)-heptadecenyl)]phenyl carbonate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 97 percent / PPh3; Br2 / benzene / 3 h / 20 °C
2.1: Mg / tetrahydrofuran / 4 h / Heating
2.2: 12 mg / NaH / diethyl ether / 1.5 h / 0 - 20 °C
View Scheme
palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

tert-butyl [2-bromo-3-hydroxy-4-(10(Z)-heptadecenyl)]phenyl carbonate

tert-butyl [2-bromo-3-hydroxy-4-(10(Z)-heptadecenyl)]phenyl carbonate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 97 percent / PPh3; Br2 / benzene / 3 h / 20 °C
2.1: Mg / tetrahydrofuran / 4 h / Heating
2.2: 0.920 g / NaH / diethyl ether / 1.5 h / 0 - 20 °C
View Scheme
palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

(3S,8aR)-5-Bromo-8a-((Z)-heptadec-10-enyl)-3-methyl-8aH-benzo[1,4]dioxine-2,6-dione
903522-41-8

(3S,8aR)-5-Bromo-8a-((Z)-heptadec-10-enyl)-3-methyl-8aH-benzo[1,4]dioxine-2,6-dione

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: 97 percent / PPh3; Br2 / benzene / 3 h / 20 °C
2.1: Mg / tetrahydrofuran / 4 h / Heating
2.2: 0.920 g / NaH / diethyl ether / 1.5 h / 0 - 20 °C
3.1: 92 percent / K2CO3 / dimethylformamide / 6 h / 20 °C
4.1: 93 percent / ZnBr; CH3NO2 / 20 °C
5.1: 55 percent / PhIOTMS(OTf); TMSOTf / CH2Cl2 / 0.25 h / 0 °C
View Scheme
palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

2-(2-bromo-6-heptadec-10-enyl-3-hydroxy-phenoxy)-N-methoxy-N-methyl-propionamide
903522-40-7

2-(2-bromo-6-heptadec-10-enyl-3-hydroxy-phenoxy)-N-methoxy-N-methyl-propionamide

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: 97 percent / PPh3; Br2 / benzene / 3 h / 20 °C
2.1: Mg / tetrahydrofuran / 4 h / Heating
2.2: 0.920 g / NaH / diethyl ether / 1.5 h / 0 - 20 °C
3.1: 92 percent / K2CO3 / dimethylformamide / 6 h / 20 °C
4.1: 93 percent / ZnBr; CH3NO2 / 20 °C
View Scheme
palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

2,2-Dimethyl-propionic acid 2-bromo-4-((Z)-heptadec-10-enyl)-3-[(S)-1-(methoxy-methyl-carbamoyl)-ethoxy]-phenyl ester

2,2-Dimethyl-propionic acid 2-bromo-4-((Z)-heptadec-10-enyl)-3-[(S)-1-(methoxy-methyl-carbamoyl)-ethoxy]-phenyl ester

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: 97 percent / PPh3; Br2 / benzene / 3 h / 20 °C
2.1: Mg / tetrahydrofuran / 4 h / Heating
2.2: 0.920 g / NaH / diethyl ether / 1.5 h / 0 - 20 °C
3.1: 92 percent / K2CO3 / dimethylformamide / 6 h / 20 °C
View Scheme
palmitoleyl alcohol
10378-01-5

palmitoleyl alcohol

2-(10(Z)-heptadecenyl)-1,4-hydroquinone

2-(10(Z)-heptadecenyl)-1,4-hydroquinone

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: 97 percent / PPh3; Br2 / benzene / 3 h / 20 °C
2.1: Mg / tetrahydrofuran / 4 h / Heating
2.2: 12 mg / NaH / diethyl ether / 1.5 h / 0 - 20 °C
3.1: 90 percent / HCl / dioxane / 1.25 h / 80 °C
View Scheme

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