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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Amino-2-methyl-3-phenylpropionic acid

Cas:1132-26-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--1132-26-9--High purity 2-Amino-2-methyl-3-phenylpropionic acid in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had establ

TIANFUCHEM--1132-26-9--High purity 2-Amino-2-methyl-3-phenylpropionic acid in stock

Cas:1132-26-9

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

2-Amino-2-methyl-3-phenylpropionic acid CAS 1132-26-9

Cas:1132-26-9

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 1132-26-9 with competitive price

Cas:1132-26-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

2-Amino-2-methyl-3-phenylpropionic acidCAS1132-26-9

Cas:1132-26-9

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:white powder Storage:R T Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Any port in China

Cheap Price Ready Stock 2-Amino-2-methyl-3-phenylpropionic acid

Cas:1132-26-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the

Phenylalanine, a-methyl-/ LIDE PHARMA- Factory supply / Best price

Cas:1132-26-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Phenylalanine, a-methyl-

Cas:1132-26-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-Amino-2-methyl-3-phenylpropionic acid CAS:1132-26-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qu

2-Amino-2-methyl-3-phenylpropionic acid CAS:1132-26-9

Cas:1132-26-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Phenylalanine, a-methyl-

Cas:1132-26-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Phenylalanine, a-methyl-

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Alpha-Methyl-dl-phenylalanine

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Amino-2-methyl-3-phenylpropionic acid

Cas:1132-26-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply 2-Amino-2-methyl-3-phenylpropionic acid

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:White powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used to make other

Phenylalanine, a-methyl-

Cas:1132-26-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Human Pain-Relieving Drug Phenacet with Safetest Delivery Phenacet

Cas:1132-26-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2-Amino-2-methyl-3-phenylpropionic acid

Cas:1132-26-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Human Pain-Relieving Drug Phenacet with Safetest Delivery Phenacet

Cas:1132-26-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Human Pain-Relieving Drug Phenacet with Safetest Delivery Phenacet

Cas:1132-26-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis:

alpha-Methyl-DL-phenylalanine

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/2-amino-2-methyl-3-phenylpropanoic acid

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

2-Amino-2-methyl-3-phenylpropionic acid

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Human Pain-Relieving Drug Phenacet with Safetest Delivery Phenacet

Cas:1132-26-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

alpha-Methyl-DL-phenylalanine

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratoryAppearance:White to off-white solid Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

alpha-Methyl-DL-phenylalanine cas no. 1132-26-9 98%

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Alpha-Methyl-DL-Phenylalanine

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-Amino-2-methyl-3-phenylpropionic acid

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

alpha-Methyl-dl-phenylalanine

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

2-Amino-2-methyl-3-phenylpropionic acid

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

factory?direct?sale Application:healing drugs

Phenylalanine, a-methyl-

Cas:1132-26-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

benzyl bromide
100-39-0

benzyl bromide

C16H13N3O3(2-)*Ni(2+)

C16H13N3O3(2-)*Ni(2+)

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
With potassium hydroxide; C-9 In dichloromethane at 20℃;95%
benzyl bromide
100-39-0

benzyl bromide

ethyl N-<(4-chlorophenyl)methylene>-DL-alanate
117470-83-4

ethyl N-<(4-chlorophenyl)methylene>-DL-alanate

A

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

B

rac-Ala-OH
302-72-7

rac-Ala-OH

Conditions
ConditionsYield
With tetrabutylammomium bromide; potassium carbonate In acetonitrile for 48h; Product distribution; Heating; further alkylation method;A 94%
B 7%
benzyl bromide
100-39-0

benzyl bromide

isopropyl 2-[(E)-1-phenylmethylideneamino]propanoate
126402-81-1

isopropyl 2-[(E)-1-phenylmethylideneamino]propanoate

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
Stage #1: benzyl bromide; isopropyl 2-[(E)-1-phenylmethylideneamino]propanoate With cesium hydroxide; (R,R)-TADDOL In toluene at 15 - 20℃; for 12h; Alkylation; benzylation;
Stage #2: With hydrogenchloride In water; toluene Hydrolysis; Heating;
94%
(+/-)-N-(tert-butoxycarbonyl)-α-methylphenylalanine
86778-91-8

(+/-)-N-(tert-butoxycarbonyl)-α-methylphenylalanine

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran for 2h; Ambient temperature;89%
With ammonium hydroxide; silica gel; trifluoroacetic acid 1.) MeOH; Yield given. Multistep reaction;
benzyl bromide
100-39-0

benzyl bromide

N-benzylidene-D,L-alanine isopropyl ester

N-benzylidene-D,L-alanine isopropyl ester

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
Stage #1: benzyl bromide; N-benzylidene-D,L-alanine isopropyl ester With sodium hydroxide; tetraethylammonium bromide; (R,R)-TADDOL In toluene at 15 - 20℃; for 12h; Substitution;
Stage #2: With hydrogenchloride In water for 0.25h; Hydrolysis; Further stages.;
83%
benzyl bromide
100-39-0

benzyl bromide

ethyl 2-(diphenylmethyleneamino)propanoate
69555-16-4

ethyl 2-(diphenylmethyleneamino)propanoate

A

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

B

rac-Ala-OH
302-72-7

rac-Ala-OH

Conditions
ConditionsYield
With tetrabutylammomium bromide; potassium carbonate In acetonitrile for 48h; Product distribution; Heating; further alkylation method;A 23%
B 63%
4-benzyl-2-phenyl-2-oxazolin-5-one
5874-61-3, 21453-79-2, 51127-19-6, 75658-67-2

4-benzyl-2-phenyl-2-oxazolin-5-one

methyl iodide
74-88-4

methyl iodide

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
(i) iPr2NEt, (ii) aq. HCl, AcOH; Multistep reaction;
methyl-2-benzylideneamino-2-methyl-3-phenylpropanoate
64298-85-7

methyl-2-benzylideneamino-2-methyl-3-phenylpropanoate

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
With hydrogenchloride 1.) ether, 12 h, room temp.; 2.) reflux, 4 h; Yield given. Multistep reaction;
α-methyl-α-carbethoxy-β-phenethylamine
46438-07-7

α-methyl-α-carbethoxy-β-phenethylamine

A

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

B

ethyl (S)-2-amino-2-methyl-3-phenylpropanoate
164453-67-2

ethyl (S)-2-amino-2-methyl-3-phenylpropanoate

C

ethyl (R)-2-amino-2-methyl-3-phenylpropanoate
22435-99-0

ethyl (R)-2-amino-2-methyl-3-phenylpropanoate

Conditions
ConditionsYield
With phosphate buffer; Humicola amino esterase Ambient temperature; Title compound not separated from byproducts;
5-benzyl-5-methyl-imidazolidine-2,4-dione
27993-44-8

5-benzyl-5-methyl-imidazolidine-2,4-dione

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
With sodium hydroxide Heating;
rac-4-benzyl-4-methyl-2-phenyl-1,3-oxazol-5(4H)-one
55686-06-1

rac-4-benzyl-4-methyl-2-phenyl-1,3-oxazol-5(4H)-one

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
With hydrogenchloride; acetic acid at 95℃; for 5.5h; Heating; Yield given;
(+-)-4-methyl-4-benzyl-imidazolidinedione-(2.5)

(+-)-4-methyl-4-benzyl-imidazolidinedione-(2.5)

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
With barium dihydroxide; water
hexamethylenetetramine
100-97-0

hexamethylenetetramine

(+-)-2-chloro-2-methyl-3-phenyl-propionic acid

(+-)-2-chloro-2-methyl-3-phenyl-propionic acid

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
With 1,4-dioxane
potassium cyanide
151-50-8

potassium cyanide

1-phenyl-acetone
103-79-7

1-phenyl-acetone

A

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

B

(+-)-2-amino-2-methyl-3-phenyl-propionitrile hydrochloride

(+-)-2-amino-2-methyl-3-phenyl-propionitrile hydrochloride

Conditions
ConditionsYield
With water; ammonium chloride at 55 - 60℃; Behandeln der in Aether loeslichen Anteile des Reaktionsprodukts mit HCl;
benzyl bromide
100-39-0

benzyl bromide

2-{[1-(2-Hydroxy-phenyl)-meth-(E)-ylidene]-amino}-propionic acid benzyl ester

2-{[1-(2-Hydroxy-phenyl)-meth-(E)-ylidene]-amino}-propionic acid benzyl ester

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
Stage #1: 2-{[1-(2-Hydroxy-phenyl)-meth-(E)-ylidene]-amino}-propionic acid benzyl ester With (R,R)-dicyclohexyl tartrate; lithium diisopropyl amide In tetrahydrofuran at -60℃; for 0.5h;
Stage #2: benzyl bromide In tetrahydrofuran at 25℃; for 12h;
Stage #3: With hydrogenchloride In tetrahydrofuran; water for 10h; Heating;
98 % Chromat.
benzyl bromide
100-39-0

benzyl bromide

methyl (E)-N-benzylidenealaninate
120328-90-7

methyl (E)-N-benzylidenealaninate

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
With sodium hydroxide; N,N'-ethylenebis(salicylideneiminato)copper(II) In toluene at 20℃; for 48h;
benzyl bromide
100-39-0

benzyl bromide

CO

CO

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: 70 percent / CF3CO2Ag / CH2Cl2 / 2 h / 0 °C
2: 96 percent / 2,6-dimethylpyridine / CH2Cl2 / 1 h / Ambient temperature
3: 66 percent / CF3CO2H / CH2Cl2 / 2 h / 0 °C
4: KMnO4, dicyclohexano-18-crown-6 ether / CH2Cl2 / 2 h / Ambient temperature
6: 89 percent / aq. HCl / tetrahydrofuran / 2 h / Ambient temperature
View Scheme
(+/-)-5-benzyl-1-(tert-butoxycarbonyl)-2,5-dihydropyrrol-2-one
171898-22-9

(+/-)-5-benzyl-1-(tert-butoxycarbonyl)-2,5-dihydropyrrol-2-one

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 96 percent / 2,6-dimethylpyridine / CH2Cl2 / 1 h / Ambient temperature
2: 66 percent / CF3CO2H / CH2Cl2 / 2 h / 0 °C
3: KMnO4, dicyclohexano-18-crown-6 ether / CH2Cl2 / 2 h / Ambient temperature
5: 89 percent / aq. HCl / tetrahydrofuran / 2 h / Ambient temperature
View Scheme
(+/-)-5-benzyl-1-(tert-butoxycarbonyl)-5-methyl-2,5-dihydropyrrol-2-one
171898-27-4

(+/-)-5-benzyl-1-(tert-butoxycarbonyl)-5-methyl-2,5-dihydropyrrol-2-one

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: KMnO4, dicyclohexano-18-crown-6 ether / CH2Cl2 / 2 h / Ambient temperature
3: 89 percent / aq. HCl / tetrahydrofuran / 2 h / Ambient temperature
View Scheme
2-Benzyl-3,4-dihydroxy-2-methyl-5-oxo-pyrrolidine-1-carboxylic acid tert-butyl ester
1059698-59-7

2-Benzyl-3,4-dihydroxy-2-methyl-5-oxo-pyrrolidine-1-carboxylic acid tert-butyl ester

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
2: 89 percent / aq. HCl / tetrahydrofuran / 2 h / Ambient temperature
View Scheme
5-benzyl-1-(tert-butoxycarbonyl)-2-(tert-butyldimethylsiloxy)pyrrole
171898-25-2

5-benzyl-1-(tert-butoxycarbonyl)-2-(tert-butyldimethylsiloxy)pyrrole

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 66 percent / CF3CO2H / CH2Cl2 / 2 h / 0 °C
2: KMnO4, dicyclohexano-18-crown-6 ether / CH2Cl2 / 2 h / Ambient temperature
4: 89 percent / aq. HCl / tetrahydrofuran / 2 h / Ambient temperature
View Scheme
benzyl chloride
100-44-7

benzyl chloride

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 96 percent / K2CO3, KOH / benzyl triethylammonium chloride / CH2Cl2 / 6 h / Ambient temperature
2: 1.) hydrochloric acid (1N); 2.) hydrochloric acid (6N) / 1.) ether, 12 h, room temp.; 2.) reflux, 4 h
View Scheme
2-amino-3-phenyl-2-methylpropanenitrile
64384-47-0

2-amino-3-phenyl-2-methylpropanenitrile

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
With hydrogenchloride for 3h; Heating;
With hydrogenchloride; water
1-phenyl-acetone
103-79-7

1-phenyl-acetone

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: ammonia
2: hydrogenchloride; water
View Scheme
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

(+/-)-N-(tert-butoxycarbonyl)-α-methylphenylalanine
86778-91-8

(+/-)-N-(tert-butoxycarbonyl)-α-methylphenylalanine

Conditions
ConditionsYield
Stage #1: di-tert-butyl dicarbonate; 2-methyl-3-phenylalanine With sodium hydroxide In 1,4-dioxane; water at 0 - 20℃; pH=9;
Stage #2: With hydrogenchloride In 1,4-dioxane; water pH=2;
88%
Stage #1: di-tert-butyl dicarbonate; 2-methyl-3-phenylalanine With sodium hydroxide In 1,4-dioxane; water at 0 - 20℃;
Stage #2: With hydrogenchloride In 1,4-dioxane; water pH=2;
88%
With triethylamine In N,N-dimethyl-formamide at 25℃; for 18h;46%
Stage #1: di-tert-butyl dicarbonate; 2-methyl-3-phenylalanine With sodium hydroxide In 1,4-dioxane; water for 14h;
Stage #2: With hydrogenchloride In 1,4-dioxane; water pH=~ 1;
Stage #1: di-tert-butyl dicarbonate; 2-methyl-3-phenylalanine With sodium hydroxide In 1,4-dioxane; water for 14h;
Stage #2: With hydrogenchloride In 1,4-dioxane; water pH=~ 1;
2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

chloroacetyl chloride
79-04-9

chloroacetyl chloride

N-Chloroacetyl-α-methylphenylalanine
121703-95-5

N-Chloroacetyl-α-methylphenylalanine

Conditions
ConditionsYield
In acetonitrile for 1.5h; Heating;76%
phthalic anhydride
85-44-9

phthalic anhydride

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

α-Methyl-N-phthaloylphenylalanin
21878-65-9

α-Methyl-N-phthaloylphenylalanin

Conditions
ConditionsYield
at 140℃; for 0.5h;75%
2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

2-(boc-oxyimino)-2-phenylacetonitrile

2-(boc-oxyimino)-2-phenylacetonitrile

(+/-)-N-(tert-butoxycarbonyl)-α-methylphenylalanine
86778-91-8

(+/-)-N-(tert-butoxycarbonyl)-α-methylphenylalanine

Conditions
ConditionsYield
With triethylamine In water; N,N-dimethyl-formamide; acetone at 20℃; for 16h;64%
formaldehyd
50-00-0

formaldehyd

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

3-carboxy-3-methyl-1,2,3,4-tetrahydroisoquinoline hydrochloride
100486-34-8

3-carboxy-3-methyl-1,2,3,4-tetrahydroisoquinoline hydrochloride

Conditions
ConditionsYield
With hydrogenchloride 1.) reflux, 1 h, 2.) RT, 16 h;63.3%
2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

2-amino-2-methyl-3-phenylpropan-1-ol
21394-84-3

2-amino-2-methyl-3-phenylpropan-1-ol

Conditions
ConditionsYield
With borane In tetrahydrofuran 1.) 0 deg C, 4 h, 2.) 25 deg C, 17 h;51%
10%
With sodium hydroxide; sodium tetrahydroborate; sulfuric acid 1.) THF, 1 h; 2.) 0 deg C, Et2O, r.t., overnight; 3.) MeOH, 2 h, reflux; Yield given. Multistep reaction;
2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

2-adamantyl chloroformate
53120-53-9

2-adamantyl chloroformate

N-<(2-adamantyloxy)carbonyl>-DL-α-methyl-3-phenylalanine
150871-35-5

N-<(2-adamantyloxy)carbonyl>-DL-α-methyl-3-phenylalanine

Conditions
ConditionsYield
38%
ethanol
64-17-5

ethanol

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

α-methyl-α-carbethoxy-β-phenethylamine
46438-07-7

α-methyl-α-carbethoxy-β-phenethylamine

Conditions
ConditionsYield
With thionyl chloride
methanol
67-56-1

methanol

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

DL-α-methylphenylalanine methyl ester hydrochloride
64665-60-7

DL-α-methylphenylalanine methyl ester hydrochloride

Conditions
ConditionsYield
With thionyl chloride for 20h; Heating;
(S)-2-chloropropionyl chloride
70110-24-6

(S)-2-chloropropionyl chloride

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

2-((S)-2-Chloro-propionylamino)-2-methyl-3-phenyl-propionic acid
113509-63-0

2-((S)-2-Chloro-propionylamino)-2-methyl-3-phenyl-propionic acid

Conditions
ConditionsYield
With potassium hydroxide at -10℃; for 0.166667h;
2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

2-acetoxy-2-phenylacetyl chloride
1638-63-7

2-acetoxy-2-phenylacetyl chloride

2-(2-Hydroxy-2-phenyl-acetylamino)-2-methyl-3-phenyl-propionic acid

2-(2-Hydroxy-2-phenyl-acetylamino)-2-methyl-3-phenyl-propionic acid

Conditions
ConditionsYield
With sodium hydroxide for 4h; Ambient temperature;
2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

Di<(R)-(-)-sec-butyl> phosphite
22156-89-4

Di<(R)-(-)-sec-butyl> phosphite

2-[Bis-((R)-sec-butoxy)-phosphorylamino]-2-methyl-3-phenyl-propionic acid
142421-47-4, 142507-05-9

2-[Bis-((R)-sec-butoxy)-phosphorylamino]-2-methyl-3-phenyl-propionic acid

Conditions
ConditionsYield
With triethylamine In tetrachloromethane; ethanol; water at 20℃; for 2h;
2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

2-amino-1-phenylpropane
60-15-1, 156-34-3, 51-64-9, 300-62-9

2-amino-1-phenylpropane

Conditions
ConditionsYield
With NH4OH-NH4Cl buffer; pyridoxal 5'-phosphate at 30℃; for 0.5h; relative rate of CO2 evolution by aromatic L-amino acid decarboxylase from Micrococcus percitreus;
2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

A

2-amino-1-phenylpropane
60-15-1, 156-34-3, 51-64-9, 300-62-9

2-amino-1-phenylpropane

B

1-phenyl-acetone
103-79-7

1-phenyl-acetone

Conditions
ConditionsYield
With pyridixamine phosphate at 30℃; for 20h; pH 9.0. aromatic L-amino acid decarboxylase from Micrococcus percitreus;
2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

2-Bromopropionyl chloride
7148-74-5

2-Bromopropionyl chloride

N-(2-Brompropionyl)-α-methylphenylalanin
84570-56-9

N-(2-Brompropionyl)-α-methylphenylalanin

Conditions
ConditionsYield
With sodium hydroxide Yield given;
2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

(2S,4R)-5,5-Dimethyl-4-phenyl-[1,3,2]dioxaphosphinane 2-oxide
161853-73-2

(2S,4R)-5,5-Dimethyl-4-phenyl-[1,3,2]dioxaphosphinane 2-oxide

2-((2R,4R)-5,5-Dimethyl-2-oxo-4-phenyl-2λ5-[1,3,2]dioxaphosphinan-2-ylamino)-2-methyl-3-phenyl-propionic acid

2-((2R,4R)-5,5-Dimethyl-2-oxo-4-phenyl-2λ5-[1,3,2]dioxaphosphinan-2-ylamino)-2-methyl-3-phenyl-propionic acid

Conditions
ConditionsYield
With water; triethylamine In tetrachloromethane; ethanol for 2h; Ambient temperature;
formic acid
64-18-6

formic acid

2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

2-Benzyl-2-(formylamino)-propionsaeure
23082-21-5

2-Benzyl-2-(formylamino)-propionsaeure

Conditions
ConditionsYield
With acetic anhydride
2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

benzyl alcohol
100-51-6

benzyl alcohol

benzyl 2-amino-2-methyl-3-phenylpropanoate
55456-42-3

benzyl 2-amino-2-methyl-3-phenylpropanoate

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene
2-methyl-3-phenylalanine
1132-26-9

2-methyl-3-phenylalanine

CR 2194
137795-35-8

CR 2194

2-[(R)-5-(8-Aza-spiro[4.5]dec-8-yl)-4-(3,5-dichloro-benzoylamino)-5-oxo-pentanoylamino]-2-methyl-3-phenyl-propionic acid

2-[(R)-5-(8-Aza-spiro[4.5]dec-8-yl)-4-(3,5-dichloro-benzoylamino)-5-oxo-pentanoylamino]-2-methyl-3-phenyl-propionic acid

Conditions
ConditionsYield
With chloroformic acid ethyl ester; triethylamine 1.) THF, -10 deg C, 15 min, 2.) THF, DMF, H2O, a) -10 deg C, 1 h, b) RT, overnight; Multistep reaction;

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