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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

Bis(dicyclohexylphosphino)methane CAS NO.137349-65-6

Cas:137349-65-6

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Qingdao Greenchem international Trading Co.,Ltd. is the commercial company which is invested by BeiJing Greenchem Technology Co.,Ltd. in Qingdao. It takes charge of export and production promotion, as well as imports and selling relevant production

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:1 Gram

Negotiable

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.

TIANFU CHEM BIS(DICYCLOHEXYLPHOSPHINO)METHANE

Cas:137349-65-6

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 137349-65-6 with best quality

Cas:137349-65-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

BIS(DICYCLOHEXYLPHOSPHINO)METHANE/High quality/Best price

Cas:137349-65-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply BIS(DICYCLOHEXYLPHOSPHINO)METHANE

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Other

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Shanghai Minstar Chemical Co., Ltd

BIS(DICYCLOHEXYLPHOSPHINO)METHANE Basic information Product Name: BIS(DICYCLOHEXYLPHOSPHINO)METHANE Synonyms: METHYLENEBIS(DICYCLOHEXYLPHOSPHINE);BIS(DICYCLOHEXYLPHOSPHINO)METHANE;1,2-Bis(dicyclohexylphosphino)methane;Bis(dicyclohexylphosphino

BIS(DICYCLOHEXYLPHOSPHINO)METHANE

Cas:137349-65-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

BIS(DICYCLOHEXYLPHOSPHINO)METHANE

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Manufacturers

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SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Bis(dicyclohexylphosphino)methane cas no. 137349-65-6 98%

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

DB BIOTECH CO., LTD

Q1: Are you a manufacturer Answer: Yes, we are factory founded on 2012.Q2: How to contact with us Click "contact supplier" And then send us message the product you interest in, you will get reply within 12 hours.Q3:Which kind of payment terms do you

BIS(DICYCLOHEXYLPHOSPHINO)METHANE

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Bis(dicyclohexylphosphino)Methane

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

BIS(DICYCLOHEXYLPHOSPHINO)METHANE 137349-65-6

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Ocean Chemical Co., Ltd.

★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

Bis(dicyclohexylphosphino)methane Application:Bis(dicyclohexylphosphino)methane

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Other

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. is focused on customization, research and development and production of APIs and advanced intermediates, which can effectively compensate for the deficiencies of traditional CRO and CMO. Priority of high-tech barri

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Newgreat Chemical Co., Ltd

Wuhan Xinweiye Chemical Co., Ltd. is mainly engaged in the process development and production of customized synthesis and pharmaceutical intermediates. We have professional researchers in organic synthesis, analytical chemistry and production process

Bis(dicyclohexylphosphino)methane

Cas:137349-65-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Synthetic route

bis-diphenylphosphinomethane
2071-20-7

bis-diphenylphosphinomethane

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

Conditions
ConditionsYield
With Nb(OC6H3Ph2-2,6)2(CH2C6H4-4Me)3; hydrogen In cyclohexane at 100℃; under 62057.8 Torr; for 96h;96%
With hydrogen In cyclohexane; water96%
dichloromethane
75-09-2

dichloromethane

Cd(2+)*2C12H22P(1-)

Cd(2+)*2C12H22P(1-)

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

Conditions
ConditionsYield
at 70℃; for 12h;95%
dicyclohexylphosphane
829-84-5

dicyclohexylphosphane

1,2-dibromomethane
74-95-3

1,2-dibromomethane

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

Conditions
ConditionsYield
Stage #1: dicyclohexylphosphane With cesiumhydroxide monohydrate In N,N-dimethyl-formamide at 20℃; for 1h; Molecular sieve; Inert atmosphere;
Stage #2: 1,2-dibromomethane In N,N-dimethyl-formamide at 20℃; for 38h; Inert atmosphere; Molecular sieve;
85%
chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

C13H24LiP
563539-93-5

C13H24LiP

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

Conditions
ConditionsYield
In tetrahydrofuran at -78 - 20℃;83%
Cy2PCH2SnPh3

Cy2PCH2SnPh3

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

Conditions
ConditionsYield
at 240℃; for 0.333333h; Substitution;80%
bis-diphenylphosphinomethane
2071-20-7

bis-diphenylphosphinomethane

A

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

B

{Cyclohexyl-[(dicyclohexylphosphanyl)-methyl]-phosphanyl}-benzene

{Cyclohexyl-[(dicyclohexylphosphanyl)-methyl]-phosphanyl}-benzene

C

CyPCH2PPh2
83291-39-8

CyPCH2PPh2

D

C25H28P2

C25H28P2

E

C25H34P2

C25H34P2

Conditions
ConditionsYield
With n-butyllithium; hydrogen; tris(2,6-diisopropylphenoxy) dichloroniobium(V) In hexane; benzene at 60℃; under 62057.8 Torr; Kinetics;
cyclohexyl chloride
542-18-7

cyclohexyl chloride

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: Mg / diethyl ether / 2.5 h / Heating
2: PCl3 / diethyl ether
3: diethyl ether; pentane
4: tert-BuLi / heptane
5: 83 percent / tetrahydrofuran / -78 - 20 °C
View Scheme
Multi-step reaction with 3 steps
1: Mg / diethyl ether / 2.5 h / Heating
2: PCl3 / diethyl ether
3: 83 percent / tetrahydrofuran / -78 - 20 °C
View Scheme
dicyclohexylmethylphosphine
50420-46-7

dicyclohexylmethylphosphine

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tert-BuLi / heptane
2: 83 percent / tetrahydrofuran / -78 - 20 °C
View Scheme
cyclohexylmagnesiumchloride
931-51-1

cyclohexylmagnesiumchloride

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: PCl3 / diethyl ether
2: diethyl ether; pentane
3: tert-BuLi / heptane
4: 83 percent / tetrahydrofuran / -78 - 20 °C
View Scheme
Multi-step reaction with 2 steps
1: PCl3 / diethyl ether
2: 83 percent / tetrahydrofuran / -78 - 20 °C
View Scheme
chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: diethyl ether; pentane
2: tert-BuLi / heptane
3: 83 percent / tetrahydrofuran / -78 - 20 °C
View Scheme
Multi-step reaction with 3 steps
1: diethyl ether / 2 h / 0 - 20 °C / Inert atmosphere
2: ethylmagnesium bromide / tetrahydrofuran / 0 - 20 °C
3: 12 h / 70 °C
View Scheme
diethyl-dicyclohexylphosphino-amine
65768-05-0

diethyl-dicyclohexylphosphino-amine

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: ethylmagnesium bromide / tetrahydrofuran / 0 - 20 °C
2: 12 h / 70 °C
View Scheme
cobalt(II) chloride hexahydrate

cobalt(II) chloride hexahydrate

dichloromethane
75-09-2

dichloromethane

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[CoCl3(Cy2PCH2Cy2PH)]*0.5CH2Cl2

[CoCl3(Cy2PCH2Cy2PH)]*0.5CH2Cl2

Conditions
ConditionsYield
In methanol; toluene to a methanol-soln. of CoCl2*6H2O was added a toluene-soln. of diphosphine, the soln. was stirred for 12 h; stripped to dryness, dissolved in degased CH2Cl2, placed in a freezer; elem. anal.;99.2%
(dimethyl sulfoxide)(2,6-diphenylpyridinate(2-))platinum(II)
224195-09-9

(dimethyl sulfoxide)(2,6-diphenylpyridinate(2-))platinum(II)

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[Pt2((C6H4)2C5H3N)2(μ-bis(dicyclohexylphosphino)methane)]
350045-85-1

[Pt2((C6H4)2C5H3N)2(μ-bis(dicyclohexylphosphino)methane)]

Conditions
ConditionsYield
In chloroform mixt. stirred for 12 h under N2 at room temp.; soln. evapd. to dryness; purifn. by chromy. (Al, CH2Cl2 as eluent); elem. anal.;99%
PdCl2(COD)

PdCl2(COD)

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

Pd(dcpm)Cl2
295325-16-5

Pd(dcpm)Cl2

Conditions
ConditionsYield
In toluene (N2); addn. of phosphine to palladium complex in toluene, stirring at 20 °C for 5 min; decantation, washing with petroleum ether, drying under vac.;98%
trans[iodobis(triphenylphosphine)phenylpalladium(II)]

trans[iodobis(triphenylphosphine)phenylpalladium(II)]

dichloromethane
75-09-2

dichloromethane

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

C6H5PdI((C6H11)2PCH2P(C6H11)2)*CH2Cl2

C6H5PdI((C6H11)2PCH2P(C6H11)2)*CH2Cl2

Conditions
ConditionsYield
In toluene (N2); addn. of phosphine soln. in toluene to a soln. of palladium complex in toluene, stirring for 12 h at room temp.; filtration, washing with petroleum ether, recrystn. (CH2Cl2-ether) at -25 °C; elem. anal.;96%
copper(l) iodide
7681-65-4

copper(l) iodide

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[(copper(I))2(μ-bis(dicyclohexylphosphanyl)methane)2]I2

[(copper(I))2(μ-bis(dicyclohexylphosphanyl)methane)2]I2

Conditions
ConditionsYield
In acetone mixt. of Cu and P compds. in acetone stirred for 2 h at room temp.; filtered, recrystd. from CH2Cl2/Et2O, elem. anal.;95%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

[(AuCl)2{μ-(N-butylimidazol-N-yl-2-ylidene)2(CH2)}]

[(AuCl)2{μ-(N-butylimidazol-N-yl-2-ylidene)2(CH2)}]

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

C40H70Au2N4P2(2+)*2F6P(1-)

C40H70Au2N4P2(2+)*2F6P(1-)

Conditions
ConditionsYield
Stage #1: [(AuCl)2{μ-(N-butylimidazol-N-yl-2-ylidene)2(CH2)}]; bis(dicyclohexylphosphino)methane In dichloromethane at 20℃; for 3h;
Stage #2: ammonium hexafluorophosphate In dichloromethane; acetonitrile at 20℃; for 0.5h;
95%
nickel(II) chloride hexahydrate

nickel(II) chloride hexahydrate

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[bis(dicyclohexylphosphino)methaneNiCl2] * C7H8

[bis(dicyclohexylphosphino)methaneNiCl2] * C7H8

Conditions
ConditionsYield
In methanol; toluene stirred, 12 h; elem. anal.;94%
dichlorotetrakis(dimethylsulfoxide)ruthenium(II)

dichlorotetrakis(dimethylsulfoxide)ruthenium(II)

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

trans-RuCl2(bis(dicyclohexylphosphino)methane)2

trans-RuCl2(bis(dicyclohexylphosphino)methane)2

Conditions
ConditionsYield
In ethanol Ar-atmosphere; refluxing for 1 h; evapn., recrystn. (hot EtOH/PhCl=1:1, slow cooling, then standing overnight; two crops), collection (filtration), washing (cold EtOH), drying (vac.);94%
trans-[(Cy3P)2PtCl(InCl2)]

trans-[(Cy3P)2PtCl(InCl2)]

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[(Cy3P)(dcpm)Pt→InI3]

[(Cy3P)(dcpm)Pt→InI3]

Conditions
ConditionsYield
With ortho-difluorobenzene In dichloromethane at 20℃; for 0.5h; Inert atmosphere; Schlenk technique; Sealed tube;94%
bis(cycloocta-1,5-diene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate
404573-66-6

bis(cycloocta-1,5-diene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[Rh(Cy2PCH2PCy2)(cyclooctadiene)] [BArF4]

[Rh(Cy2PCH2PCy2)(cyclooctadiene)] [BArF4]

Conditions
ConditionsYield
In dichloromethane at -78 - 20℃; for 16h; Glovebox; Inert atmosphere; Schlenk technique;93%
(1,5-cyclooctadiene)Rh(η3-CH2Ph)

(1,5-cyclooctadiene)Rh(η3-CH2Ph)

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

(dcypm)Rh(η3-CH2Ph)

(dcypm)Rh(η3-CH2Ph)

Conditions
ConditionsYield
In hexane N2; equimolar amounts; 1h;; filtration; solvent concentration; crystn. at -40 ° C;;92%
silver(I) hexafluorophosphate
26042-63-7

silver(I) hexafluorophosphate

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[Ag2(μ-bis(dicyclohexylphosphino)methane)](PF6)2

[Ag2(μ-bis(dicyclohexylphosphino)methane)](PF6)2

Conditions
ConditionsYield
In dichloromethane soln. in CH2Cl2 was stirred at 40°C for 5 h; pptn. by Et2O, recrystn. by diffusion of Et2O into a CH2Cl2 soln.; elem. anal.;92%
[(η(5)-C5H5)Fe(CO)(μ-CN)2Cu(CH3CN)2]2
223596-54-1

[(η(5)-C5H5)Fe(CO)(μ-CN)2Cu(CH3CN)2]2

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[(η(5)-C5H5)Fe(CO)(CN)(μ-CN)Cu(bis(dicyclohexylphosphanyl)methane)]2

[(η(5)-C5H5)Fe(CO)(CN)(μ-CN)Cu(bis(dicyclohexylphosphanyl)methane)]2

Conditions
ConditionsYield
In dichloromethane; acetonitrile all manipulations under Ar atm.; soln. of org. compd. in CH2Cl2 slowly added to soln. of complex in MeCN, stirred for 30 min at ambient temp.; solvent removed in vac.;92%
silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[Ag2(μ-bis(dicyclohexylphosphino)methane)](CF3SO3)2

[Ag2(μ-bis(dicyclohexylphosphino)methane)](CF3SO3)2

Conditions
ConditionsYield
In dichloromethane ssoln. in CH2Cl2 was stirred for 6 h; pptn. by Et2O, recrystn. by diffusion of Et2O into an acetonitrile soln.; elem. anal.;90%
cis-(tungsten tetracarbonyl bipiperidine)
14515-95-8, 56083-13-7

cis-(tungsten tetracarbonyl bipiperidine)

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[W(CO)4(bis(dicyclohexylphosphino)methane)]
1001401-12-2

[W(CO)4(bis(dicyclohexylphosphino)methane)]

Conditions
ConditionsYield
In dichloromethane (N2); reflux of PCy2CH2PCy2 and W(CO)4(NHC5H10)2 in CH2Cl2 for 4.5 h; cooling, filtration, addn. of MeOH; placing of mixt. in the freezer; removal of cryst., concn. of soln. on rotary evaporator; cooling in the freezer; crystn., elem. anal.;90%
cobalt(II) nitrate hexahydrate

cobalt(II) nitrate hexahydrate

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

((C6H11)2PCH2P(C6H11)2O)Co(NO3)2
835605-09-9

((C6H11)2PCH2P(C6H11)2O)Co(NO3)2

Conditions
ConditionsYield
In methanol; dichloromethane; toluene to a methanol soln. of Co-salt was added a toluene-soln. of diphosphine,CH2Cl2 was added to the soln., stirred for 12 h; stripped to dryness, dissolved in degased CH2Cl2, allowed to slow evapn.; elem. anal.;89.4%
tetrakis(acetonitrile)copper(I) perchlorate
14057-91-1

tetrakis(acetonitrile)copper(I) perchlorate

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[(copper(I))2(μ-bis(dicyclohexylphosphanyl)methane)2](ClO4)2

[(copper(I))2(μ-bis(dicyclohexylphosphanyl)methane)2](ClO4)2

Conditions
ConditionsYield
In acetone mixt. of Cu and P compds. in acetone stirred for 1 h at room temp.; solvent removed, Et2O added, recrystd. from CH2Cl2/Et2O, elem. anal.;89%
[Rh(cod)2]+[Al(OC(CF3)3)4]-

[Rh(cod)2]+[Al(OC(CF3)3)4]-

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[Rh(Cy2PCH2PCy2)(cyclooctadiene)][Al{OC(CF3)3}4]

[Rh(Cy2PCH2PCy2)(cyclooctadiene)][Al{OC(CF3)3}4]

Conditions
ConditionsYield
In dichloromethane at -78 - 20℃; for 16h; Glovebox; Inert atmosphere; Schlenk technique;89%
bis(acetonitrile)dichloroplatinum(II)
13869-38-0, 21264-32-4, 13869-42-6

bis(acetonitrile)dichloroplatinum(II)

dichloromethane
75-09-2

dichloromethane

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[Pt(bis(dicyclohexylphosphino)methane)2]Cl2*0.5CH2Cl2

[Pt(bis(dicyclohexylphosphino)methane)2]Cl2*0.5CH2Cl2

Conditions
ConditionsYield
In dichloromethane stirring of CH2Cl2 soln. of Pt(NCMe)2Cl2 (1 equiv.) and PCy2CH2PCy2 (2 equiv.) for 48 h; concd., filtration, drying in vac., elem. anal.;88%
(tetrahydrothiophene)gold(I) chloride
39929-21-0

(tetrahydrothiophene)gold(I) chloride

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[Au2(bis(dicyclohexylphosphanyl)methane)Cl2]
180333-95-3

[Au2(bis(dicyclohexylphosphanyl)methane)Cl2]

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.5h; Inert atmosphere; Schlenk technique;87%
In tetrahydrofuran stoichiometric amounts of Au-complex and phosphine in THF; pptn. with pentane, vac.-filtered;
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[(copper(I))2(μ-bis(dicyclohexylphosphanyl)methane)2](PF6)2

[(copper(I))2(μ-bis(dicyclohexylphosphanyl)methane)2](PF6)2

Conditions
ConditionsYield
In acetone mixt. of Cu and P compds. in acetone stirred for 1 h at room temp.; solvent removed, Et2O added, recrystd. from CH2Cl2/Et2O, elem. anal.;86%
1,3-(μ-propanedithiolato)diironhexacarbonyl

1,3-(μ-propanedithiolato)diironhexacarbonyl

dichloromethane
75-09-2

dichloromethane

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

4[Fe2(CO)4(μ-SCH2CH2CH2S)(μ-bis(dicyclohexylphosphino)methane)]*2CH2Cl2

4[Fe2(CO)4(μ-SCH2CH2CH2S)(μ-bis(dicyclohexylphosphino)methane)]*2CH2Cl2

Conditions
ConditionsYield
In toluene byproducts: CO; (N2); reflux of toluene soln. of Fe2(CO)6(SCH2CH2CH2S) and PCy2CH2PCy2 for 16 h; cooling to room temp., removal of volatiles by rotary evapn., washing with hexane; drying; dissolving in min. of CH2Cl2; chromy. on alumina; eluting with Et2O:hexane (1:9); elem. anal.;84%
(hexafluoroacetylacetonato)(1,5-cyclooctadiene)rhodium(I)

(hexafluoroacetylacetonato)(1,5-cyclooctadiene)rhodium(I)

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

(((C6H11)2P)2CH2)Rh(OC(CF3))2CH
222017-64-3

(((C6H11)2P)2CH2)Rh(OC(CF3))2CH

((((C6H11)2P)2CH2)Rh)2((OC(CF3))2CH)2

((((C6H11)2P)2CH2)Rh)2((OC(CF3))2CH)2

Conditions
ConditionsYield
In tetrahydrofuran Ar-atmosphere; slow phosphine soln. addn.; crystn.; elem. anal.;A 82%
B n/a
bis(bis(trimethylsilyl)amido)zinc(II)

bis(bis(trimethylsilyl)amido)zinc(II)

2,6-di-tert-butylphenol
128-39-2

2,6-di-tert-butylphenol

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

[Zn(2,6-di-tert-butylphenoxide)2]2(bisdicyclohexylphosphinomethane)

[Zn(2,6-di-tert-butylphenoxide)2]2(bisdicyclohexylphosphinomethane)

Conditions
ConditionsYield
In toluene under Ar; toluene soln. of phosphine and substituted phenol (molar ratio 1:2) added to neat Zn compd.; stirred for 0.5 h; volatiles stripped away in vac.;82%
(N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II)

(N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II)

bis(dicyclohexylphosphino)methane
137349-65-6

bis(dicyclohexylphosphino)methane

(bis(dicyclohexylphosphino)methane)dimethylpalladium(II)
343987-35-9

(bis(dicyclohexylphosphino)methane)dimethylpalladium(II)

Conditions
ConditionsYield
In benzene at room temp.; characterized spectroscopically and by single crystal X-ray diffraction;82%

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