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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product specif

Kresoxim-methyl

Cas:143390-89-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Kresoxim-Methyl supplier in China

Cas:143390-89-0

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

huge stock TC Fungicide Kresoxim-methyl 143390-89-0 GLP Manufacturer

Cas:143390-89-0

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

Kresoxim-Methyl

Cas:143390-89-0

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality Kresoxim-methyl

Cas:143390-89-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Kresoxim-methyl

Cas:143390-89-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

chengdu and import and export trade co., LTD., who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do res

Kresoxim-methyl

Cas:143390-89-0

Min.Order:1 Metric Ton

FOB Price: $50.0 / 200.0

Type:Trading Company

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Hubei DiBo chemical co., LTD

Name:Kresoxim-methyl Name:Kresoxim-methyl CAS no:143390-89-0 Grade:Medical chemical industry Molecular formula:C18H19NO4 Molecular weight: 313.3478 Product Quality 12 years of chemical raw materials Mature operation of the indust

Kresoxim-methyl /cas:143390-89-0 /raw material/high-quality

Cas:143390-89-0

Min.Order:25 Kilogram

FOB Price: $1.0 / 2.0

Type:Other

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

Kresoxim-methyl

Cas:143390-89-0

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 143390-89-0 with best quality

Cas:143390-89-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

Kresoxim-methyl

Cas:143390-89-0

Min.Order:1 Kilogram

FOB Price: $50.0 / 56.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name: Kresoxim-methyl CAS: 143390-89-0 Molecular formula C18H19NO4 EINECS No.:

Kresoxim-methyl

Cas:143390-89-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Kresoxim-methyl 143390-89-0

Cas:143390-89-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Kresoxim-methyl CAS:143390-89-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermed

Kresoxim-methyl CAS:143390-89-0

Cas:143390-89-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Kresoxim-methyl

Cas:143390-89-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Kresoxim-methyl

Cas:143390-89-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Rely Chemicals Ltd.

Best quality/price/service Professional manufacturing FAO Standards Appearance:white and inodorous crystal Package:Solid:50g,100g,200g,250g,400g,500g,1kg,10kg bag ,20kg, 25kg,40kg bag,50kg,600kg, 900kg; Aluminum Foil Bag,plastic bag, fiber bag

95%TC,50%WDG fungicide kresoxim-methyl CAS No.: 143390-89-0

Cas:143390-89-0

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Kresoxim-methyl

Cas:143390-89-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Kresoxim-methyl/High quality/Best price

Cas:143390-89-0

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Kresoxim-Methyl

Cas:143390-89-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: Kresoxim-methyl Synonyms: STROBY;ALLEGRO;alpha-(Methoxyimino)-2-{(2-methylphenoxy)methyl}-benzeneacetic acid (E)-methyl ester;MENTOR;KRESOXIM-METHYL;BAS 490F;(E)-α-(methoxyimino)-2-((2-methylphenoxy)methyl)benzeneacetic acid me

TIANFU-CHEM Kresoxim-methyl

Cas:143390-89-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Kresoxim-methyl

Cas:143390-89-0

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Kresoxim-methyl

Cas:143390-89-0

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Kresoxim-methyl

Cas:143390-89-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Kresoxim-methyl

Cas:143390-89-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in

Kresoxim-methyl

Cas:143390-89-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Vanz Pharm Co.,Ltd

ISO/factory/goodqualityAppearance:off white Storage:Dry,cool place Package:drum Application:active pharmaceutical ingredients Transportation:by air/sea/express Port:shenzhen/shanghai

Kresoxim-methyl

Cas:143390-89-0

Min.Order:0

Negotiable

Type:Manufacturers

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Synthetic route

N-methoxylamine hydrochloride
593-56-6

N-methoxylamine hydrochloride

2-oxo-2-(((o-tolyl)oxymethyl)phenyl)acetic acid methyl ester
143211-10-3

2-oxo-2-(((o-tolyl)oxymethyl)phenyl)acetic acid methyl ester

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
In methanol for 6h; Reflux;84.8%
ortho-cresol
95-48-7

ortho-cresol

methyl (E)-2-[2-(bromomethyl)phenyl]-2-(methoxyimino)acetate
133409-72-0

methyl (E)-2-[2-(bromomethyl)phenyl]-2-(methoxyimino)acetate

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
With copper(l) iodide In butanone for 4h; Concentration; Reagent/catalyst; Reflux;80%
N-methoxylamine hydrochloride
593-56-6

N-methoxylamine hydrochloride

2-oxo-2-(((o-tolyl)oxymethyl)phenyl)acetic acid methyl ester
143211-10-3

2-oxo-2-(((o-tolyl)oxymethyl)phenyl)acetic acid methyl ester

A

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

B

methyl (Z)-O-methyloximino-2-[(2-methyl)phenoxymethyl]phenylacetate
248582-68-5

methyl (Z)-O-methyloximino-2-[(2-methyl)phenoxymethyl]phenylacetate

Conditions
ConditionsYield
In pyridine at 20℃; for 17.5h; Condensation;A 63%
B 28%
methyl (Z)-O-methyloximino-2-[(2-methyl)phenoxymethyl]phenylacetate
248582-68-5

methyl (Z)-O-methyloximino-2-[(2-methyl)phenoxymethyl]phenylacetate

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
With iodine In benzene at 63℃; for 120h; Isomerization; UV-irradiation;
2-(2-methylphenoxymethyl)phenylzinc chloride

2-(2-methylphenoxymethyl)phenylzinc chloride

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 61 percent / Pd(PPh3)4 / tetrahydrofuran / 4 h / 0 °C
2: 63 percent / pyridine / 17.5 h / 20 °C
View Scheme
Multi-step reaction with 3 steps
1: 61 percent / Pd(PPh3)4 / tetrahydrofuran / 4 h / 0 °C
2: 28 percent / pyridine / 17.5 h / 20 °C
3: I2 / benzene / 120 h / 63 °C / UV-irradiation
View Scheme
2-oxo-2-(((o-tolyl)oxymethyl)phenyl)acetic acid methyl ester
143211-10-3

2-oxo-2-(((o-tolyl)oxymethyl)phenyl)acetic acid methyl ester

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 28 percent / pyridine / 17.5 h / 20 °C
2: I2 / benzene / 120 h / 63 °C / UV-irradiation
View Scheme
methyl 2-(2-methylphenoxymethyl)phenylglyoxylate dimethyl acetal
143390-88-9

methyl 2-(2-methylphenoxymethyl)phenylglyoxylate dimethyl acetal

N-methoxylamine hydrochloride
593-56-6

N-methoxylamine hydrochloride

2-oxo-2-(((o-tolyl)oxymethyl)phenyl)acetic acid methyl ester
143211-10-3

2-oxo-2-(((o-tolyl)oxymethyl)phenyl)acetic acid methyl ester

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
With hydrogenchloride In methanol; dichloromethane
methyl E-2-(2-methylphenoxymethyl)phenylglyoxylate oxime
150869-72-0

methyl E-2-(2-methylphenoxymethyl)phenylglyoxylate oxime

methylene chloride
74-87-3

methylene chloride

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
With sodium methylate In 1-methyl-pyrrolidin-2-one; methanol; diethyl ether
(E)-methyl 2-(2-(chloromethyl)phenyl)-2-(methoxyimino)acetate
189813-45-4

(E)-methyl 2-(2-(chloromethyl)phenyl)-2-(methoxyimino)acetate

ortho-cresol
95-48-7

ortho-cresol

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20 - 50℃; for 64h;
2-[(2-methylphenoxy)methyl]benzoic acid
108475-90-7

2-[(2-methylphenoxy)methyl]benzoic acid

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: thionyl chloride / 3 h / Reflux
2.1: tetrabutylammomium bromide / toluene / 2.5 h / 20 - 35 °C
3.1: hydrogenchloride; acetic anhydride / tert-butyl methyl ether / 10 h / -5 - 30 °C
3.2: 5 h / Reflux
4.1: methanol / 6 h / Reflux
View Scheme
2-[(2-methylphenoxy)methyl]benzoyl chloride
143211-21-6

2-[(2-methylphenoxy)methyl]benzoyl chloride

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: tetrabutylammomium bromide / toluene / 2.5 h / 20 - 35 °C
2.1: hydrogenchloride; acetic anhydride / tert-butyl methyl ether / 10 h / -5 - 30 °C
2.2: 5 h / Reflux
3.1: methanol / 6 h / Reflux
View Scheme
2-[(2-methylphenoxy)methyl]benzoyl cyanide
143211-11-4

2-[(2-methylphenoxy)methyl]benzoyl cyanide

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: hydrogenchloride; acetic anhydride / tert-butyl methyl ether / 10 h / -5 - 30 °C
1.2: 5 h / Reflux
2.1: methanol / 6 h / Reflux
View Scheme
methanol
67-56-1

methanol

2-methoxyimino(2-(o-tolyl)oxymethylphenyl)acetic acid
137169-29-0

2-methoxyimino(2-(o-tolyl)oxymethylphenyl)acetic acid

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Stage #1: 2-methoxyimino(2-(o-tolyl)oxymethylphenyl)acetic acid With thionyl chloride In N,N-dimethyl-formamide at 40 - 45℃; for 8h;
Stage #2: methanol at 60 - 65℃; for 2h;
42.5 g
ortho-cresol
95-48-7

ortho-cresol

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: sodium methylate / methanol / 1 h / 20 °C
1.2: 2 h / 190 °C
2.1: thionyl chloride / 3 h / Reflux
3.1: tetrabutylammomium bromide / toluene / 2.5 h / 20 - 35 °C
4.1: hydrogenchloride; acetic anhydride / tert-butyl methyl ether / 10 h / -5 - 30 °C
4.2: 5 h / Reflux
5.1: methanol / 6 h / Reflux
View Scheme
2-methyl-α-hydroxyiminobenzeneacetonitrile
107960-33-8

2-methyl-α-hydroxyiminobenzeneacetonitrile

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: sodium hydroxide / water / 0.5 h / 11 - 15 °C
2.1: sodium hydroxide / water / 2.5 h / 50 - 65 °C
2.2: 25 °C
3.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
4.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: sodium hydroxide / water / 0.5 h / 11 - 15 °C
2.1: sodium hydroxide / water / 3 h / 70 - 75 °C
2.2: 5 - 10 °C
3.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
4.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: sodium hydroxide / water / 1 h / 7 - 15 °C
2.1: sodium hydroxide / water / 2.5 h / 50 - 65 °C
2.2: 25 °C
3.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
4.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
2-methyl-a-cyanobenzoxime potassium
178983-50-1

2-methyl-a-cyanobenzoxime potassium

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: sodium hydroxide / water / 0.5 h / 8 - 10 °C
2.1: sodium hydroxide / water / 2.5 h / 50 - 65 °C
2.2: 25 °C
3.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
4.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: sodium hydroxide / water / 0.5 h / 8 - 10 °C
2.1: sodium hydroxide / water / 3 h / 70 - 75 °C
2.2: 5 - 10 °C
3.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
4.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: sodium hydroxide / water / 0.5 h / 8 - 10 °C
2.1: sodium carbonate / water / 1.6 h / 80 - 85 °C
2.2: 6 °C
3.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
4.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
2-methyl-a-cyanobenzoxime sodium

2-methyl-a-cyanobenzoxime sodium

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: sodium hydroxide / water / 0.5 h / 8 - 10 °C
2.1: sodium hydroxide / water / 2.5 h / 50 - 65 °C
2.2: 25 °C
3.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
4.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: sodium hydroxide / water / 0.5 h / 8 - 10 °C
2.1: sodium hydroxide / water / 3 h / 70 - 75 °C
2.2: 5 - 10 °C
3.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
4.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: sodium hydroxide / water / 0.5 h / 8 - 10 °C
2.1: sodium carbonate / water / 1.6 h / 80 - 85 °C
2.2: 6 °C
3.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
4.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
2-benzofuran-1(3H)-one
87-41-2

2-benzofuran-1(3H)-one

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: sodium methylate / methanol / 1 h / 20 °C
1.2: 2 h / 190 °C
2.1: thionyl chloride / 3 h / Reflux
3.1: tetrabutylammomium bromide / toluene / 2.5 h / 20 - 35 °C
4.1: hydrogenchloride; acetic anhydride / tert-butyl methyl ether / 10 h / -5 - 30 °C
4.2: 5 h / Reflux
5.1: methanol / 6 h / Reflux
View Scheme
2-tolylmethylnitrile
22364-68-7

2-tolylmethylnitrile

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: ethyl nitrite; sodium hydroxide / chlorobenzene / 1 h / 15 °C
2.1: sodium hydroxide / water / 0.5 h / 8 - 10 °C
3.1: sodium carbonate / water / 1.6 h / 80 - 85 °C
3.2: 6 °C
4.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
5.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
Multi-step reaction with 5 steps
1.1: isopentyl nitrite; potassium hydroxide / chlorobenzene / 1 h / 15 °C
2.1: sodium hydroxide / water / 0.5 h / 8 - 10 °C
3.1: sodium carbonate / water / 1.6 h / 80 - 85 °C
3.2: 6 °C
4.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
5.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
Multi-step reaction with 5 steps
1.1: sodium carbonate; n-propyl nitrite / dichloromethane / 1.5 h / 5 °C
2.1: sodium hydroxide / water / 0.5 h / 11 - 15 °C
3.1: sodium hydroxide / water / 2.5 h / 50 - 65 °C
3.2: 25 °C
4.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
5.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
2-methyl-α-methoxyiminophenylacetonitrile

2-methyl-α-methoxyiminophenylacetonitrile

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: sodium carbonate / water / 1.6 h / 80 - 85 °C
1.2: 6 °C
2.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
3.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
Multi-step reaction with 3 steps
1.1: sodium hydroxide / water / 2.5 h / 50 - 65 °C
1.2: 25 °C
2.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
3.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
Multi-step reaction with 3 steps
1.1: sodium hydroxide / water / 3 h / 70 - 75 °C
1.2: 5 - 10 °C
2.1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
3.1: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
methyl-(E)-2-(2-tolyl)-2-methoxyiminoacetate
120974-97-2

methyl-(E)-2-(2-tolyl)-2-methoxyiminoacetate

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: dibenzoyl peroxide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione / 1,2-dichloro-ethane / 4 h / 55 °C
2: copper(l) iodide / butanone / 4 h / Reflux
View Scheme
methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

(E)-methyl 2-(2-((4-iodo-2-methylphenoxy)methyl)phenyl)-2-(methoxyimino)acetate

(E)-methyl 2-(2-((4-iodo-2-methylphenoxy)methyl)phenyl)-2-(methoxyimino)acetate

Conditions
ConditionsYield
With Iodine monochloride In dichloromethane; acetic acid at 20℃; for 5h;95%
methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

(E)-2-methoxyimino-2-{[2-(2-tolyl)oxymethyl]phenyl}acetic acid
1007364-30-8

(E)-2-methoxyimino-2-{[2-(2-tolyl)oxymethyl]phenyl}acetic acid

Conditions
ConditionsYield
Stage #1: methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate With sodium hydroxide In water; toluene at 40 - 70℃; for 6h;
Stage #2: With hydrogenchloride In water; toluene at 10 - 15℃; pH=1.5;
93.75%
With water; sodium hydroxide In methanol for 3h; Reflux;92%
With sodium hydroxide In methanol at 65℃;86%
With sodium hydroxide; water In methanol Reflux;
methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

N-Methyl-E-2-methoxyimino-2-[(2-methylphenyloxymethyl)phenyl]-acetamide
156996-22-4

N-Methyl-E-2-methoxyimino-2-[(2-methylphenyloxymethyl)phenyl]-acetamide

Conditions
ConditionsYield
In methylamine
In methylamine
methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

(E)-tert-butyl 6-(4-((2-(2-methoxy-1-(methoxyimino)-2-oxoethyl)benzyl)oxy)-3-methylphenyl)hex-5-ynoate

(E)-tert-butyl 6-(4-((2-(2-methoxy-1-(methoxyimino)-2-oxoethyl)benzyl)oxy)-3-methylphenyl)hex-5-ynoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Iodine monochloride / dichloromethane; acetic acid / 5 h / 20 °C
2: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / N,N-dimethyl-formamide / 3 h / 20 °C / Inert atmosphere
View Scheme
methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

(E)-tert-butyl 6-(4-((2-(2-methoxy-1-(methoxyimino)-2-oxoethyl)benzyl)oxy)-3-methylphenyl)hexanoate

(E)-tert-butyl 6-(4-((2-(2-methoxy-1-(methoxyimino)-2-oxoethyl)benzyl)oxy)-3-methylphenyl)hexanoate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: Iodine monochloride / dichloromethane; acetic acid / 5 h / 20 °C
2: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / N,N-dimethyl-formamide / 3 h / 20 °C / Inert atmosphere
3: Wilkinson's catalyst; hydrogen / tetrahydrofuran / 16 h / 20 °C / 3040.2 Torr
View Scheme
methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

(E)-6-(4-((2-(2-methoxy-1-(methoxyimino)-2-oxoethyl)benzyl)oxy)-3-methylphenyl)hexanoic acid

(E)-6-(4-((2-(2-methoxy-1-(methoxyimino)-2-oxoethyl)benzyl)oxy)-3-methylphenyl)hexanoic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: Iodine monochloride / dichloromethane; acetic acid / 5 h / 20 °C
2: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / N,N-dimethyl-formamide / 3 h / 20 °C / Inert atmosphere
3: Wilkinson's catalyst; hydrogen / tetrahydrofuran / 16 h / 20 °C / 3040.2 Torr
4: formic acid / 3 h / 20 °C / Inert atmosphere
View Scheme
methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

(E)-tert-butyl 6-(2-(methoxyimino)-2-(2-((o-tolyloxy)methyl)phenyl)acetoxy)hexanoate

(E)-tert-butyl 6-(2-(methoxyimino)-2-(2-((o-tolyloxy)methyl)phenyl)acetoxy)hexanoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium hydroxide / methanol / 65 °C
2: potassium carbonate / N,N-dimethyl-formamide / 24 h / 20 °C / Inert atmosphere
View Scheme
methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

(E)-6-(2-(methoxyimino)-2-(2-((o-tolyloxy)methyl)phenyl)acetoxy)hexanoic acid

(E)-6-(2-(methoxyimino)-2-(2-((o-tolyloxy)methyl)phenyl)acetoxy)hexanoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: sodium hydroxide / methanol / 65 °C
2: potassium carbonate / N,N-dimethyl-formamide / 24 h / 20 °C / Inert atmosphere
3: formic acid / 3 h / 20 °C / Inert atmosphere
View Scheme
methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

C28H32N2O8

C28H32N2O8

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: Iodine monochloride / dichloromethane; acetic acid / 5 h / 20 °C
2: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / N,N-dimethyl-formamide / 3 h / 20 °C / Inert atmosphere
3: Wilkinson's catalyst; hydrogen / tetrahydrofuran / 16 h / 20 °C / 3040.2 Torr
4: formic acid / 3 h / 20 °C / Inert atmosphere
5: triethylamine / acetonitrile / 0 - 20 °C / Inert atmosphere
View Scheme
methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

C27H30N2O8

C27H30N2O8

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: sodium hydroxide / methanol / 65 °C
2: potassium carbonate / N,N-dimethyl-formamide / 24 h / 20 °C / Inert atmosphere
3: formic acid / 3 h / 20 °C / Inert atmosphere
4: triethylamine / acetonitrile / 0 - 20 °C / Inert atmosphere
View Scheme
methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

C23H28BrNO4

C23H28BrNO4

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium hydroxide; water / methanol / 3 h / Reflux
2: dicyclohexyl-carbodiimide; dmap / dichloromethane / 12 h / 20 °C / Reflux
View Scheme
methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate
143390-89-0

methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate

C41H43NO4P(1+)*Br(1-)

C41H43NO4P(1+)*Br(1-)

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: sodium hydroxide; water / methanol / 3 h / Reflux
2: dicyclohexyl-carbodiimide; dmap / dichloromethane / 12 h / 20 °C / Reflux
3: potassium iodide / acetonitrile / 24 h / Reflux
View Scheme
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