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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 1450-63-1 1,1,4,4-TETRAPHENYL-1,3-BUTADIENE Manufacturer

Cas:1450-63-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1,1,4,4-Tetraphenylbutadiene

Cas:1450-63-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,1,4,4-Tetraphenyl-1,3-butadiene

Cas:1450-63-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

GMP Manufacturer CAS 1450-63-1 with competitive price

Cas:1450-63-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1,1,4,4-Tetraphenylbutadiene

Cas:1450-63-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE CAS:1450-63-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE CAS:1450-63-1

Cas:1450-63-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,1,4,4-Tetraphenylbutadiene

Cas:1450-63-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1,1,4,4-Tetraphenylbutadiene

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,1,4,4-Tetraphenylbutadiene

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,1,4,4-tetraphenyl-1,3-butadiene

Cas:1450-63-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply 1,1,4,4-Tetraphenyl-1,3-butadiene

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Other

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Henan Tianfu Chemical Co., Ltd.

TPB; 1,1,4,4-TETRAPHENYL-1,3-BUTADIENE; 1,1,4,4-TETRAPHENYLBUTADIENE; (1,4,4-Triphenyl-1,3-butadienyl)benzene; 1,1,4 , 4-tetraphenyl-3-butadiene; 1,1',1'',1'''-(1,3-butadiene-1,4-diylidene)tetrabenzene; 1,1,4,4-Tetraphenyl-1

1,1,4,4-Tetraphenyl-1,3-butadiene, 99%

Cas:1450-63-1

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

Cas:1450-63-1

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

Cas:1450-63-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

Cas:1450-63-1

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

Cas:1450-63-1

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

1,1,4,4-Tetraphenyl-1,3-Butadiene

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1,1,4,4-Tetraphenyl-1,3-butadiene

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,1,4,4-Tetraphenylbutadiene

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE Application:1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Other

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white to yellow powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as

1,1,4,4-Tetraphenyl-1,3-butadiene

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Fandachem Co.,Ltd

1,1,4,4-Tetraphenylbutadiene cas 1450-63-1Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1,1,4,4-Tetraphenylbutadiene cas 1450-63-1

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

1,1,4,4-TETRAPHENYL-1,3-BUTADIENEAppearance:white to slightly yellow needle-like crystals Storage:keep in dry and ventilated Package:As requested Application:1450-63-1 Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount.

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Other

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE Basic information

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

Cas:1450-63-1

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

inquiry

Yinghao Pharm Co.,Ltd.

Yinghao Pharm products include: leader molecule, heterocyclic compounds,chiral compounds, photoelectric materials, biochemical reagents etc. For example:benzene, pyrimidine, boricacid,pyridine, pyrazole, imidazole, pyrrole, fluorine and other derivat

1,1,4,4-TETRAPHENYL-1,3-BUTADIENE

Cas:1450-63-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1.Best service, high quality and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). ? 3. It's customers' right to choose the packing way for his products fro

Best price/ 1,1,4,4-Tetraphenyl-1,3-butadiene CAS NO.1450-63-1

Cas:1450-63-1

Min.Order:0

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Type:Trading Company

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Synthetic route

2-chloro-1,1-diphenylethene
4541-89-3

2-chloro-1,1-diphenylethene

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

Conditions
ConditionsYield
With 4-(3'-butyl-1'-imidazolio)-1-butanesulfonic acid hydrogen sulfate; aluminium In carbon dioxide at 45℃; under 116262 Torr; for 12h; Ullmann reaction; Supercritical conditions;98%
With carbon dioxide; aluminium; 1-butyl-3-methylimidazolium trifluoromethanesulfonimide at 45℃; under 116262 Torr; for 12h; Ullmann reaction;97%
tetraphenylbutatriene
1483-68-7

tetraphenylbutatriene

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

Conditions
ConditionsYield
With water; zinc(II) chloride; zinc In tetrahydrofuran for 6h; Heating; other substrate;95%
With water; zinc(II) chloride; zinc In tetrahydrofuran for 6h; Heating;95%
With i-Amyl alcohol; acetic acid; zinc
With phosphorus; hydrogen iodide
Multi-step reaction with 2 steps
1: 87 percent / sulfur / dimethylformamide / 125 °C
2: 52 percent / 1,8-diazabicyclo<5,4,0>undec-7-ene, / dimethylformamide / 10 h / Heating
View Scheme
1-bromo-2,2-diphenylethylene
13249-58-6

1-bromo-2,2-diphenylethylene

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

Conditions
ConditionsYield
With dibromobis(triphenylphosphine)nickel(II); triphenylphosphine; zinc In N,N-dimethyl-formamide at 20℃; for 8h;90%
With potassium iodide; nickel dichloride; zinc In N,N,N,N,N,N-hexamethylphosphoric triamide at 40℃; for 7h; oth. solvent, oth. time, oth. temperature, presence of additive;78%
With potassium iodide; zinc; bis(triethylphosphine)nickel(II) chloride In various solvent(s) at 50℃; for 1h; Product distribution; other temperatrure, other time, other catalyst, other solvent;97 % Chromat.
With potassium iodide; zinc; bis(triethylphosphine)nickel(II) chloride In various solvent(s) at 50℃; for 1h;97 % Chromat.
1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

Conditions
ConditionsYield
Stage #1: 1,1-Diphenylethylene With Hg(II) trifluoroacetate In benzene at 0℃; for 0.25h; Substitution;
Stage #2: With triethylamine; palladium dichloride In benzene at 0℃; for 0.25h; Coupling reaction;
88%
With oxygen; copper diacetate; palladium diacetate; benzyl chloride In N,N-dimethyl-formamide at 110℃; under 760.051 Torr; for 10h;53%
2,2-diphenyl-1,3-dithiolane
6317-10-8

2,2-diphenyl-1,3-dithiolane

2,2-diphenylcyclopropyl magnesium bromide
123752-05-6

2,2-diphenylcyclopropyl magnesium bromide

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

B

C20H22
123751-94-0

C20H22

Conditions
ConditionsYield
bis(triphenylphosphine)nickel(II) chloride In toluene Heating;A 87%
B 31%
trans-1,1,4,4-tetraphenyl-2-butene-1,4-diol
59856-52-9

trans-1,1,4,4-tetraphenyl-2-butene-1,4-diol

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

Conditions
ConditionsYield
With lithium aluminium tetrahydride; titanium(III) chloride In tetrahydrofuran for 3h; Heating;83%
(4R,5R)-4,5-bis[chloro(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane
147700-73-0

(4R,5R)-4,5-bis[chloro(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

Conditions
ConditionsYield
With zinc chloride diethyl ether; phosphan at -196 - 90℃; under 9000.9 - 97509.8 Torr; for 37h; Inert atmosphere; Autoclave;80%
(1Z,3Z)-1,4-dibromo-1,4-diphenylbuta-1,3-diene
55373-68-7

(1Z,3Z)-1,4-dibromo-1,4-diphenylbuta-1,3-diene

phenylboronic acid
98-80-6

phenylboronic acid

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In methanol; toluene for 24h; Inert atmosphere; Reflux;75%
1-dimethyl(2-pyridyl)silyl-2,2-diphenylethene
270589-02-1

1-dimethyl(2-pyridyl)silyl-2,2-diphenylethene

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

Conditions
ConditionsYield
With copper(l) iodide; cesium fluoride In acetonitrile at 20℃; for 3h;58%
6,7-Dibenzhydrylidene-[1,2,3,4,5]pentathiepane
118091-25-1

6,7-Dibenzhydrylidene-[1,2,3,4,5]pentathiepane

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

B

2-(2,2-Diphenyl-vinyl)-3-phenyl-benzo[b]thiophene
118091-34-2

2-(2,2-Diphenyl-vinyl)-3-phenyl-benzo[b]thiophene

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 10h; Heating;A 52%
B 12%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 10h; Heating;A 52%
B 12%
methyl 2-carbomethoxy-4-benzyl-4-(2,2-diphenylvinyl)-6,6-diphenyl-2,5-hexadienoate
325770-97-6

methyl 2-carbomethoxy-4-benzyl-4-(2,2-diphenylvinyl)-6,6-diphenyl-2,5-hexadienoate

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

B

1-benzyl-3,3,5,5-tetraphenyl-4-(2,2-dicarbomethoxyvinyl)-1-cyclopentene

1-benzyl-3,3,5,5-tetraphenyl-4-(2,2-dicarbomethoxyvinyl)-1-cyclopentene

trans-1,1-diphenyl-2-benzyl-2-(2,2-dicarbomethoxyvinyl)-3-(2,2-diphenylvinyl)cyclopropane

trans-1,1-diphenyl-2-benzyl-2-(2,2-dicarbomethoxyvinyl)-3-(2,2-diphenylvinyl)cyclopropane

cis-1,1-diphenyl-2-benzyl-2-(2,2-dicarbomethoxyvinyl)-3-(2,2-diphenylvinyl)cyclopropane

cis-1,1-diphenyl-2-benzyl-2-(2,2-dicarbomethoxyvinyl)-3-(2,2-diphenylvinyl)cyclopropane

Conditions
ConditionsYield
With acetophenone In benzene for 0.25h; Irradiation; Further byproducts given;A 12 mg
B 43%
C n/a
D n/a
1,1-dibromo-2,2-diphenylethylene
2592-73-6

1,1-dibromo-2,2-diphenylethylene

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

Triphenylethylene
58-72-0

Triphenylethylene

C

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

Conditions
ConditionsYield
With dibromobis(triphenylphosphine)nickel(II); tetraethylammonium iodide; zinc In tetrahydrofuran Ambient temperature;A 29%
B 21%
C 40%
tetraphenylbutatriene
1483-68-7

tetraphenylbutatriene

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

B

2-(2,2-Diphenyl-vinyl)-3-phenyl-benzo[b]selenophene
118091-31-9

2-(2,2-Diphenyl-vinyl)-3-phenyl-benzo[b]selenophene

Conditions
ConditionsYield
With selenium; 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 10h; Heating;A 38%
B 8%
1,1,3,5,5-pentaphenyl-1,4-pentadien-3-ol
114789-76-3

1,1,3,5,5-pentaphenyl-1,4-pentadien-3-ol

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

B

1,2,2,5,5-pentaphenyl-4-penten-1-one
57365-26-1

1,2,2,5,5-pentaphenyl-4-penten-1-one

cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane
114789-83-2

cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

trans-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane
114789-84-3

trans-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

Conditions
ConditionsYield
In acetonitrile for 5.2h; Irradiation;A 1.7%
B 1.7%
C 36.5%
D 14.4%
ethyl 2,4,4-triphenyl-2,3-butadienoate
36858-84-1

ethyl 2,4,4-triphenyl-2,3-butadienoate

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

B

3-ethoxy-2,4,4-triphenylcyclobut-2-enone

3-ethoxy-2,4,4-triphenylcyclobut-2-enone

Conditions
ConditionsYield
In hexane Ambient temperature; Irradiation;A n/a
B 35%
methyl 2-carbomethoxy-4-methyl-4-(2,2-diphenylvinyl)-6,6-diphenyl-2,5-hexadienoate
325770-96-5

methyl 2-carbomethoxy-4-methyl-4-(2,2-diphenylvinyl)-6,6-diphenyl-2,5-hexadienoate

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

B

1-methyl-3,3,5,5-tetraphenyl-4-(2,2-dicarbomethoxyvinyl)-1-cyclopentene

1-methyl-3,3,5,5-tetraphenyl-4-(2,2-dicarbomethoxyvinyl)-1-cyclopentene

C

cis-1,1-dicarbomethoxy-2-methyl-2,3-bis(2,2-diphenylvinyl)cyclopropane

cis-1,1-dicarbomethoxy-2-methyl-2,3-bis(2,2-diphenylvinyl)cyclopropane

D

cis-1,1-diphenyl-2-methyl-2-(2,2-diphenylvinyl)-3-(2,2-dicarbomethoxyvinyl)cyclopropane

cis-1,1-diphenyl-2-methyl-2-(2,2-diphenylvinyl)-3-(2,2-dicarbomethoxyvinyl)cyclopropane

Conditions
ConditionsYield
With acetophenone In benzene for 0.25h; Irradiation; Further byproducts given;A 15 mg
B 33%
C n/a
D n/a
1,1-dibromo-2,2-diphenylethylene
2592-73-6

1,1-dibromo-2,2-diphenylethylene

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

Triphenylethylene
58-72-0

Triphenylethylene

C

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

D

diphenyl acetylene
501-65-5

diphenyl acetylene

Conditions
ConditionsYield
With dibromobis(triphenylphosphine)nickel(II); zinc In tetrahydrofuran at 50℃;A 3%
B 28%
C 29%
D 1%
benzophenone
119-61-9

benzophenone

1,1-diphenyl-1-propene
778-66-5

1,1-diphenyl-1-propene

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

Conditions
ConditionsYield
With hydrogenchloride; n-butyllithium; acetic acid In tetrahydrofuran; hexane Product distribution; other substituted 1,1-diphenylpropenes, other phenones;25%
Yield given. Multistep reaction;
1,1,4,4-tetraphenyl-1,4-butanediol
63469-15-8

1,1,4,4-tetraphenyl-1,4-butanediol

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

Conditions
ConditionsYield
With Lawessons reagent In toluene for 0.5h; Heating;24%
With chloroform; bromine
With hydrogenchloride; acetic acid
cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane
114789-83-2

cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

B

1,2,2,5,5-pentaphenyl-4-penten-1-one
57365-26-1

1,2,2,5,5-pentaphenyl-4-penten-1-one

trans-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane
114789-84-3

trans-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

Conditions
ConditionsYield
With 4-(Dimethylamino)benzophenone In acetonitrile for 1.67h; Irradiation;A 4.9%
B 1.5%
C 22%
In acetonitrile for 2.3h; Irradiation;A 3.8%
B 1.3%
C 14.9%
2-(2,2-diphenylvinylidene)-4-butanolide
52217-17-1

2-(2,2-diphenylvinylidene)-4-butanolide

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

B

3-(2,2-diphenylvinyl)dihydrofuran-2(3H)-one

3-(2,2-diphenylvinyl)dihydrofuran-2(3H)-one

C

2-(1-ethoxyethyl)-2-(2,2-diphenylvinyl)-4-butanolide

2-(1-ethoxyethyl)-2-(2,2-diphenylvinyl)-4-butanolide

Conditions
ConditionsYield
In diethyl ether; hexane for 30h; Ambient temperature; Irradiation;A 3%
B 18%
C 21%
1,2,2,5,5-pentaphenyl-4-penten-1-one
57365-26-1

1,2,2,5,5-pentaphenyl-4-penten-1-one

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane
114789-83-2

cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

trans-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane
114789-84-3

trans-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

Conditions
ConditionsYield
In acetonitrile at 94℃; for 1.56667h; Irradiation;A 9.65%
B 21%
C 16.8%
In acetonitrile for 1.56667h; Irradiation;A 9.65%
B 21%
C 16.8%
In acetonitrile for 1.56667h; Irradiation;A 9.65%
B 21%
C 16.8%
1,1,3,5,5-pentaphenyl-1,4-pentadien-3-ol
114789-76-3

1,1,3,5,5-pentaphenyl-1,4-pentadien-3-ol

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane
114789-83-2

cis-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

trans-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane
114789-84-3

trans-1-hydroxy-1,2,2-triphenyl-3-(2,2-diphenylvinyl)cyclopropane

Conditions
ConditionsYield
With 4-(Dimethylamino)benzophenone In acetonitrile for 0.666667h; Irradiation;A 4.65%
B 17.9%
C 1.56%
1,4-diphenyl-1,3-butadiyne
886-66-8

1,4-diphenyl-1,3-butadiyne

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

A

C28H22
1005197-76-1

C28H22

B

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

C

(1Z,3Z)-1,2,3,4-tetraphenylbuta-1,3-diene
1608-11-3

(1Z,3Z)-1,2,3,4-tetraphenylbuta-1,3-diene

Conditions
ConditionsYield
With water; acetic acid; bis-triphenylphosphine-palladium(II) chloride at 20℃; for 6h;A n/a
B n/a
C 15%
α-methyl-γ,γ-diphenylallenecarboxylic acid ethyl ester
5717-43-1

α-methyl-γ,γ-diphenylallenecarboxylic acid ethyl ester

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

B

ethyl 1-methyl-3-phenylindene-1-carboxylate

ethyl 1-methyl-3-phenylindene-1-carboxylate

Conditions
ConditionsYield
With dicobalt octacarbonyl In hexane for 16h; Ambient temperature; Irradiation;A 12%
B 4%
methyl 2-methyl-4,4-diphenyl-2,3-butadienoate
70582-44-4

methyl 2-methyl-4,4-diphenyl-2,3-butadienoate

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

B

3-Methoxy-2-methyl-4,4-diphenyl-cyclobut-2-enone

3-Methoxy-2-methyl-4,4-diphenyl-cyclobut-2-enone

Conditions
ConditionsYield
In hexane Ambient temperature; Irradiation;A n/a
B 5%
α-methyl-γ,γ-diphenylallenecarboxylic acid ethyl ester
5717-43-1

α-methyl-γ,γ-diphenylallenecarboxylic acid ethyl ester

A

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

B

3-Ethoxy-2-methyl-4,4-diphenyl-cyclobut-2-enone

3-Ethoxy-2-methyl-4,4-diphenyl-cyclobut-2-enone

Conditions
ConditionsYield
In hexane Ambient temperature; Irradiation;A n/a
B 5%
quinoline
91-22-5

quinoline

(α-acetoxy-benzhydryl)-benzhydrylidene-succinic acid
858807-12-2

(α-acetoxy-benzhydryl)-benzhydrylidene-succinic acid

copper diacetate
142-71-2

copper diacetate

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

diiodomethane
75-11-6

diiodomethane

1,1,4,4-tetraphenyl-but-2-enediyl dipotassium

1,1,4,4-tetraphenyl-but-2-enediyl dipotassium

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

diethyl ether
60-29-7

diethyl ether

3,3-diphenylacrylonitrile
3531-24-6

3,3-diphenylacrylonitrile

2,2-diphenyl-vinyl magnesium (1+); bromide

2,2-diphenyl-vinyl magnesium (1+); bromide

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

iodoxybenzene
696-33-3

iodoxybenzene

benzophenone
119-61-9

benzophenone

Conditions
ConditionsYield
With obj. of study: similarity in reactions to ozone, other olefins In nitrobenzene at 170℃; for 5h;78.5%
1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

2,2-diphenyl-3-(2,2-diphenylvinyl)oxirane
98760-59-9

2,2-diphenyl-3-(2,2-diphenylvinyl)oxirane

Conditions
ConditionsYield
With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid In chloroform at 0 - 20℃; for 26h;77%
1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

benzophenone
119-61-9

benzophenone

Conditions
ConditionsYield
With 1-hydroxy-pyrrolidine-2,5-dione; graphitic carbon nitride; oxygen In acetonitrile at 20℃; Inert atmosphere; Irradiation;68%
1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

(E)-1,1,4,4-tetraphenylbut-2-ene-1,4-d2

(E)-1,1,4,4-tetraphenylbut-2-ene-1,4-d2

Conditions
ConditionsYield
With ethyl [2]alcohol; sodium In diethyl ether; mineral oil at 20℃; for 0.166667h; Inert atmosphere;62%
1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

[Ag2(1,1,4,4-tetraphenyl-1,3-butadiene)(CF3SO3)2]

[Ag2(1,1,4,4-tetraphenyl-1,3-butadiene)(CF3SO3)2]

Conditions
ConditionsYield
In 1,3,5-trimethyl-benzene under Ar atm. to soln. tphb in 1,3,5-trimethylbenzene was added Ag(CF3SO3); mixt. was filtered, filtrate was layered with n-hexane and left standing at room temp. for 2 weeks; elem. anal.;60%
4-Phenyl-1,2,4-triazolidine-3,5-dione
4233-33-4

4-Phenyl-1,2,4-triazolidine-3,5-dione

1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

2-Hendo-5-(2,2-diphenylvinyl)-N,N',6-triphenyl-3,4,9,10-tetraazatricyclo<6.2.2.02,7>dodeca-6,11-diene-3,4:9,10-bisdicarboximide

2-Hendo-5-(2,2-diphenylvinyl)-N,N',6-triphenyl-3,4,9,10-tetraazatricyclo<6.2.2.02,7>dodeca-6,11-diene-3,4:9,10-bisdicarboximide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 20h;49%
1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

silver perchlorate

silver perchlorate

[Ag2(1,1,4,4-tetraphenyl-1,3-butadiene)(ClO4)2]

[Ag2(1,1,4,4-tetraphenyl-1,3-butadiene)(ClO4)2]

Conditions
ConditionsYield
In 1,3,5-trimethyl-benzene under Ar atm. to soln. tphb in 1,3,5-trimethylbenzene was added AgClO4; mixt. was filtered, filtrate was layered with n-hexane and left standing at room temp. for 2 weeks; elem. anal.;47%
1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

ethyl acetoacetate
141-97-9

ethyl acetoacetate

A

phenyl-1,3,3-triphenyl-prop-2-enyl ketone
2491-41-0

phenyl-1,3,3-triphenyl-prop-2-enyl ketone

B

3-Ethoxycarbonyl-2-methyl-4-(2,2-diphenylethenyl)-5,5-diphenyl-4,5-dihydrofuran
134643-51-9

3-Ethoxycarbonyl-2-methyl-4-(2,2-diphenylethenyl)-5,5-diphenyl-4,5-dihydrofuran

Conditions
ConditionsYield
With manganese triacetate In acetic acid for 0.0833333h; Heating;A 12%
B 46%
1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

Tris(2,4-pentanedionato)cobalt(III)

Tris(2,4-pentanedionato)cobalt(III)

3-Acetyl-2-methyl-4-(2,2-diphenylethenyl)-5,5-diphenyl-4,5-dihydrofuran
134643-33-7

3-Acetyl-2-methyl-4-(2,2-diphenylethenyl)-5,5-diphenyl-4,5-dihydrofuran

Conditions
ConditionsYield
In acetic acid for 2h; Heating; other 1,3-dicarbonyl compound-manganese(III) acetate;42%
In acetic acid for 2h; Heating;42%
1,1,4,4-tetraphenyl-1,3-butadiene
1450-63-1

1,1,4,4-tetraphenyl-1,3-butadiene

phenyl-1,3,3-triphenyl-prop-2-enyl ketone
2491-41-0

phenyl-1,3,3-triphenyl-prop-2-enyl ketone

Conditions
ConditionsYield
With iodine tris(trifluoroacetate) In tetrachloromethane at 23℃; for 3h;37%
With 3-chloro-benzenecarboperoxoic acid
Multi-step reaction with 2 steps
1: 77 percent / sodium bicarbonate, m-chloroperbenzoic acid / CHCl3 / 26 h / 0 - 20 °C
2: TFA / CDCl3
View Scheme

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