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Wuhan Fortuna Chemical Co.,Ltd

High quality 1,5-Anhydro-D-glucitol CAS 154-58-5 with fast delivery Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed a

High quality 1,5-Anhydro-D-glucitol CAS 154-58-5 with fast delivery

Cas:154-58-5

Min.Order:10 Gram

FOB Price: $10.0

Type:Trading Company

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price API 99% 1,5-ANHYDRO-D-GLUCITOL 154-58-5 GMP Manufacturer

Cas:154-58-5

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine c

1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 154-58-5 with best quality

Cas:154-58-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

1,5-ANHYDRO-D-GLUCITOL CAS:154-58-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte

1,5-ANHYDRO-D-GLUCITOL CAS:154-58-5

Cas:154-58-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,5-ANHYDRO-D-GLUCITOL

Cas:154-58-5

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,5-anhydro-d-glucitol

Cas:154-58-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Product Name: 1,5-ANHYDRO-D-GLUCITOL Synonyms: 1-Deoxy-D-Glucose;1-Deoxyglucose;Polygalitol;(2R,3S,4R,5S)-2-(hydroxymethyl)oxane-3,4,5-triol;(2R,3S,4R,5S)-2-methyloltetrahydropyran-3,4,5-triol;Aceritol;1,5-Anhydro-D-sorbitol, (2

TIANFUCHEM--High purity 154-58-5 1,5-ANHYDRO-D-GLUCITOL

Cas:154-58-5

Min.Order:1 Metric Ton

FOB Price: $20.0

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

1,5-ANHYDRO-D-GLUCITOL

Cas:154-58-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd a comprehensive enterprise, is located in High-Tech Science Park,Changsha,Chia . Specializing in R&D, manufacture and marketing, we provide a wide range of products and the most professional services to meet the

Benzyl alpha-d-glucopyranoside

Cas:154-58-5

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:0

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Type:Lab/Research institutions

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Hangzhou Fandachem Co.,Ltd

1,5-Anhydro-D-glucitol cas 154-58-5Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1,5-Anhydro-D-glucitol cas 154-58-5

Cas:154-58-5

Min.Order:0

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Type:Other

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:20mg Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any por

1,5-Anhydro-D-Sorbitol Crystalline

Cas:154-58-5

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

154-58-5

Cas:154-58-5

Min.Order:0

Negotiable

Type:Trading Company

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Guangzhou Lanning Biotechnology Co., Ltd

Provide HPLC,HNMR,MS and COA. Package:Glass bottles Application:scientific research Transportation:by air

Amikacin Impurity 5

Cas:154-58-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:0

Negotiable

Type:Trading Company

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NUTROCHEM- MANUFACTURE PLACE

best seller Application:API

1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:0

Negotiable

Type:Trading Company

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

1,5-ANHYDRO-D-GLUCITOL

Cas:154-58-5

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

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HENAN SUNLAKE ENTERPRISE CORPORATION

Henan Sunlake Enterprise Corporation Our Advantages 1, Any inquiry about ch

1,5-ANHYDRO-D-GLUCITOL

Cas:154-58-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Cerametek Materials(ShenZhen)Co., Ltd.

Cerametek Materials (CMT) is your industrial and R&D supplier: 1. Semiconductor materials: Compounds of II, III, IV, V, VI groups such as Metal Sulfides, Selenides, Tellurides, Arsenide, Antimonide, Phosphide... 2. Advanced ceramic and crys

1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:0

Negotiable

Type:Other

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Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

1,5-Anhydro-D-glucitol

Cas:154-58-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Nanjing Chemlin Chemical Co., Ltd.

Nanjing Chemlin Chemical Industry Co., Ltd was established in Aug,1999, located in the industrial park of Nanjing University of Technology, It is a private enterprises in Jiangsu Province with 1200 square meters’ R&D center. Our R&D center has a well

154-58-5

Cas:154-58-5

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai Run-Biotech Co., Ltd.

Shanghai, Run-Biotech Co., Ltd is a leading domestic pharmaceutical, biopharmaceutical, and health care products R & D outsourcing services company. As an innovation-driven and customer-focused company, Run Biotech provides a broad and integrated por

1,5-ANHYDRO-D-GLUCITOL

Cas:154-58-5

Min.Order:0

Negotiable

Type:Trading Company

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Synthetic route

1,5-anhydro-2,3,4,6-tetra-O-allyl-D-glucitol
1338660-78-8

1,5-anhydro-2,3,4,6-tetra-O-allyl-D-glucitol

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With methanol; palladium dichloride at 60℃; for 8h;100%
1-deoxy-D-glucose tetraacetate
13137-69-4

1-deoxy-D-glucose tetraacetate

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With sodium methylate In methanol at 45℃; for 0.333333h;98%
With sodium methylate In methanol at 20℃; for 16h;92%
With methanol; potassium carbonate at 25℃; for 1.5h;90%
sucrose octakis(trimethylsilyl) ether
19159-25-2

sucrose octakis(trimethylsilyl) ether

A

mannitol
69-65-8

mannitol

B

D-sorbitol
50-70-4

D-sorbitol

C

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
Stage #1: sucrose octakis(trimethylsilyl) ether With bis(pentafluorophenyl)borinic acid; 1,1,3,3-tetramethyldisilazane In chloroform-d1 at 25℃; for 3h; Inert atmosphere; Glovebox;
Stage #2: In methanol Inert atmosphere; Glovebox;
A n/a
B n/a
C 90%
C32H72O6Si4

C32H72O6Si4

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With triethylsilane; tris(pentafluorophenyl)borate In dichloromethane at 20℃; for 48h; Reagent/catalyst;86%
1-deoxy-3,4,6-tri-O-benzyl-D-glucopyranose
152840-34-1

1-deoxy-3,4,6-tri-O-benzyl-D-glucopyranose

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With hydrogen; palladium dihydroxide In methanol under 2327.2 Torr; for 4h;81%
methyl 2,3,4,6-tetrakis-O-trimethylsilyl-α-D-glucopyranoside
2641-79-4

methyl 2,3,4,6-tetrakis-O-trimethylsilyl-α-D-glucopyranoside

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
Stage #1: methyl 2,3,4,6-tetrakis-O-trimethylsilyl-α-D-glucopyranoside With bis(pentafluorophenyl)borinic acid; 1,1,3,3-tetramethyldisilazane In chloroform-d1 at 25℃; for 1.5h; Inert atmosphere; Glovebox;
Stage #2: In methanol Inert atmosphere; Glovebox; regioselective reaction;
81%
(1R,2R,3S,4R,5R)-fluoro-2,3,4,6-tetra-O-(trimethylsilyl)-α-D-glucopyranoside

(1R,2R,3S,4R,5R)-fluoro-2,3,4,6-tetra-O-(trimethylsilyl)-α-D-glucopyranoside

A

D-sorbitol
50-70-4

D-sorbitol

B

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
Stage #1: (1R,2R,3S,4R,5R)-fluoro-2,3,4,6-tetra-O-(trimethylsilyl)-α-D-glucopyranoside With bis(pentafluorophenyl)borinic acid; 1,1,3,3-tetramethyldisilazane In chloroform-d1 at 25℃; for 0.3h; Inert atmosphere; Glovebox;
Stage #2: In methanol Inert atmosphere; Glovebox; regioselective reaction;
A 9%
B 76%
N,N-dimethyl β-D-glucopyranosyl dithiocarbamate
19200-26-1

N,N-dimethyl β-D-glucopyranosyl dithiocarbamate

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

A

methyl 3-(α-D-glucopyranosyl)propanoate

methyl 3-(α-D-glucopyranosyl)propanoate

B

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In water at 75℃; for 1.5h; Reagent/catalyst; Inert atmosphere; stereoselective reaction;A 72%
B 28%
D-sorbitol
50-70-4

D-sorbitol

A

2,5-anhydro-d-sorbitol
51607-79-5

2,5-anhydro-d-sorbitol

B

Isosorbide
652-67-5

Isosorbide

C

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With Amberlyst-15 at 120℃; under 7.50075 Torr; for 10h; Reagent/catalyst;A n/a
B 71%
C n/a
3,4,6-tri-O-tert-butyldimethylsilyl-1-deoxy-D-glucopyranose

3,4,6-tri-O-tert-butyldimethylsilyl-1-deoxy-D-glucopyranose

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With trifluoroacetic acid In methanol for 2.5h;70%
1-deoxy-2,3,4,6-tetra-O-benzyl-D-glucopyranose
78890-68-3

1-deoxy-2,3,4,6-tetra-O-benzyl-D-glucopyranose

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In ethanol for 29h;69%
With hydrogen; catalyst63%
With hydrogen; palladium on activated charcoal In ethanol for 24h; Ambient temperature;0.16 g
tri-O-allylcellulose

tri-O-allylcellulose

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
Stage #1: tri-O-allylcellulose With triethylsilane; trifluorormethanesulfonic acid; boron trifluoride diethyl etherate In dichloromethane at 0 - 20℃; for 12h;
Stage #2: With pyrographite; copper dichloride; palladium dichloride In methanol at 60℃; for 8h;
65%
N,N-dimethyl β-D-glucopyranosyl dithiocarbamate
19200-26-1

N,N-dimethyl β-D-glucopyranosyl dithiocarbamate

allyltributylstanane
24850-33-7

allyltributylstanane

A

(2R,3R,4R,5S,6R)-2-allyl-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol
106756-74-5

(2R,3R,4R,5S,6R)-2-allyl-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol

B

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In 1,4-dioxane at 75℃; for 2h; Inert atmosphere; stereoselective reaction;A 65%
B 35%
D-sorbitol
50-70-4

D-sorbitol

A

Isosorbide
652-67-5

Isosorbide

B

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With toluene-4-sulfonic acid; N,N,N-trimethyl-N-propylammonium bis(trifluoromethanesulfonyl)imide at 180℃; for 0.166667h; Reagent/catalyst; Temperature; Time; Microwave irradiation;A 61%
B 5%
With toluene-4-sulfonic acid; N,N,N-trimethyl-N-propylammonium bis(trifluoromethanesulfonyl)imide at 130℃; for 0.5h; Microwave irradiation; Ionic liquid;A 22%
B 26%
With N,N,N-trimethyl-N-propylammonium bis(trifluoromethanesulfonyl)imide at 180℃; for 0.166667h; Catalytic behavior; Reagent/catalyst; Microwave irradiation; chemoselective reaction;A 50 %Chromat.
B 18 %Chromat.
1,5-D-anhydrofructose
75414-43-6

1,5-D-anhydrofructose

A

1,5-anhydro-D-mannitol
492-93-3

1,5-anhydro-D-mannitol

B

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
Stage #1: 1,5-D-anhydrofructose In water at 20℃; for 24h; hydration;
Stage #2: With sodium tetrahydroborate In water at 0 - 20℃; for 2h; Reduction;
A n/a
B 60%
With hydrogen; palladium on activated charcoal In water at 50℃; under 2000000 Torr; for 120h; Catalytic hydrogenation;A 58%
B n/a
With sodium tetrahydroborate
1-O-methyl-2,3,4,6-tetra-O-trimethylsilyl-β-D-glucopyranoside
2296-40-4

1-O-methyl-2,3,4,6-tetra-O-trimethylsilyl-β-D-glucopyranoside

A

1,6-deoxyglucitol
205598-17-0

1,6-deoxyglucitol

B

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With triethylsilane; tris(pentafluorophenyl)borate In dichloromethane at 25℃; for 48h; Glovebox; Inert atmosphere;A 60%
B 34%
1,2,3,6,2',3',4',6'-octa-O-trimethylsilyl-β-cellobiose
33428-70-5

1,2,3,6,2',3',4',6'-octa-O-trimethylsilyl-β-cellobiose

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
Stage #1: 1,2,3,6,2',3',4',6'-octa-O-trimethylsilyl-β-cellobiose With tris(pentafluorophenyl)borate In dichloromethane-d2 at 23℃; Inert atmosphere;
Stage #2: With methanol for 2h;
Stage #3: With water at 50℃; for 0.5h;
51%
sucrose octakis(trimethylsilyl) ether
19159-25-2

sucrose octakis(trimethylsilyl) ether

A

D-sorbitol
50-70-4

D-sorbitol

B

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

C

2,5-anhydro-D-glucitol
27826-73-9

2,5-anhydro-D-glucitol

Conditions
ConditionsYield
Stage #1: sucrose octakis(trimethylsilyl) ether With n-butylsilane; bis(pentafluorophenyl)borinic acid In chloroform-d1 at 40℃; for 24h; Inert atmosphere; Glovebox;
Stage #2: In methanol Inert atmosphere; Glovebox;
A 32%
B 20%
C 37%
1,2,3,6,2',3',4',6'-octa-O-trimethylsilyl-β-maltose

1,2,3,6,2',3',4',6'-octa-O-trimethylsilyl-β-maltose

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
Stage #1: 1,2,3,6,2',3',4',6'-octa-O-trimethylsilyl-β-maltose With tris(pentafluorophenyl)borate In dichloromethane-d2 at 23℃; Inert atmosphere;
Stage #2: With methanol for 2h;
Stage #3: With water at 50℃; for 0.5h;
36%
Conditions
ConditionsYield
With SBA-15-SO3H at 120℃; under 7.50075 Torr; for 10h; Reagent/catalyst; Temperature;A n/a
B n/a
C n/a
D 31%
E n/a
C19H46O6Si4

C19H46O6Si4

A

(2S,3S,4R,5S)-2-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol
194991-50-9

(2S,3S,4R,5S)-2-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol

B

6-deoxy-D-glucitol
71075-63-3

6-deoxy-D-glucitol

C

D-sorbitol
50-70-4

D-sorbitol

D

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
Stage #1: C19H46O6Si4 With bis(pentafluorophenyl)borinic acid; 1,1,3,3-tetramethyldisilazane In chloroform-d1 at 25℃; for 15h; Inert atmosphere; Glovebox;
Stage #2: In methanol Inert atmosphere; Glovebox; regioselective reaction;
A 31%
B n/a
C n/a
D 22%
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide
572-09-8

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; diethyl ether
With lithium aluminium tetrahydride In diethyl ether at 20℃; for 1h;
Multi-step reaction with 2 steps
1.1: Bu3SnH; 2,2'-azobis(isobutyronitrile) / diethyl ether / 20 °C
1.2: 3.30 g / KF / H2O / 0.33 h / 20 °C
2.1: 98 percent / NaOMe / methanol / 0.33 h / 45 °C
View Scheme
Multi-step reaction with 2 steps
1: 97 percent / Bu3SnH; AIBN / benzene / 1 h / 80 °C
2: NaOEt / ethanol / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: 80 percent / H2, Triethylamine / Raney nickel / ethyl acetate / 2 h / 50 °C / 51714.8 Torr
2: Triethylamine / methanol; H2O / 10 h
View Scheme
Conditions
ConditionsYield
With triethylsilane; trimethylsilyl trifluoromethanesulfonate; water 1.) acetonitrile, RT, overnight; Yield given. Multistep reaction. Yields of byproduct given;
Conditions
ConditionsYield
With triethylsilane; trimethylsilyl trifluoromethanesulfonate; water 1.) acetonitrile, RT, overnight; Yield given. Multistep reaction. Yields of byproduct given;
Tenuifoliside D
139726-38-8

Tenuifoliside D

A

methyl 3,4,5-trimethoxycinnamate
20329-96-8

methyl 3,4,5-trimethoxycinnamate

B

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With potassium carbonate In methanol; water for 0.333333h; Ambient temperature;A 27 mg
B n/a
1,3,4,5,6-Penta-O-acetyl-2-desoxy-L-gulo-S-phenyl-hemithioacetal
137396-22-6, 137396-23-7

1,3,4,5,6-Penta-O-acetyl-2-desoxy-L-gulo-S-phenyl-hemithioacetal

A

(2S,3S,4R,5S)-2-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol
194991-50-9

(2S,3S,4R,5S)-2-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol

B

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With diisobutylaluminium hydride In hexane; dichloromethane at -78℃; for 1h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
alpha cyclodextrin
10016-20-3

alpha cyclodextrin

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With triethylsilane; trimethylsilyl trifluoromethanesulfonate Product distribution; determined structure after trifluoroacetylation by g.l.c.-E.I.m.s.;
Conditions
ConditionsYield
Product distribution; other glycosides and sugars; var. silyl protecting group, var. catalysts;
(4-O-β-D-glucopyranosyl)-1,5-anhydro-D-glucitol
51260-20-9

(4-O-β-D-glucopyranosyl)-1,5-anhydro-D-glucitol

A

D-Glucose
2280-44-6

D-Glucose

B

(4S,5S)-4,5-Dihydroxy-5,6-dihydro-4H-pyran-2-carbaldehyde

(4S,5S)-4,5-Dihydroxy-5,6-dihydro-4H-pyran-2-carbaldehyde

C

(+)-(2R,3R)-3,5-dihydroxy-2-hydroxymethyl-2,3-dihydro-4H-pyran-4-one
158715-81-2

(+)-(2R,3R)-3,5-dihydroxy-2-hydroxymethyl-2,3-dihydro-4H-pyran-4-one

D

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With oxygen In water Mechanism; Quantum yield; investigation on the effect of copper and chromate ions on the iron catalysis of the degradation by oxygen or hydrogen peroxide; various temperatures and circumstances;
methyl 2,3,4,6-tetra-O-methyl-β-D-glucopyranoside
3149-65-3

methyl 2,3,4,6-tetra-O-methyl-β-D-glucopyranoside

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

Conditions
ConditionsYield
With dimethylsulfide borane complex; Trichlorbutylstannan In dichloromethane for 3h; Product distribution; Ambient temperature; reductive cleavage of permethylated mono- and polysaccharides with borane-dimethyl sulfide complex and butyltin trichloride; time-course of reductive cleavage;
acetic anhydride
108-24-7

acetic anhydride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1-deoxy-D-glucose tetraacetate
13137-69-4

1-deoxy-D-glucose tetraacetate

Conditions
ConditionsYield
With pyridine; dmap at 20℃;100%
With sodium acetate
With pyridine
acetic anhydride
108-24-7

acetic anhydride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1-deoxy-2,3,4,6-tetraacetyl-D-glucopyranoside-d5
1239971-75-5

1-deoxy-2,3,4,6-tetraacetyl-D-glucopyranoside-d5

Conditions
ConditionsYield
Stage #1: 1,5-anhydro-D-glucitol With palladium 10% on activated carbon; hydrogen; water-d2 at 80℃; for 24h;
Stage #2: acetic anhydride With pyridine at 20℃; for 24h; regioselective reaction;
100%
1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-D-fructose
109212-90-0

1,5-anhydro-D-fructose

Conditions
ConditionsYield
With pyranose 2-oxidase; catalase In water at 22℃; for 9h;98%
p-(benzyloxy)benzoic acid
1486-51-7

p-(benzyloxy)benzoic acid

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-2,3,4,6-tetrakis-O-(3'-benzyloxybenzoyl)-D-glucitol

1,5-anhydro-2,3,4,6-tetrakis-O-(3'-benzyloxybenzoyl)-D-glucitol

Conditions
ConditionsYield
With dmap; 2-chloro-1-methyl-pyridinium iodide; triethylamine In dichloromethane at 20℃; for 48h;98%
docosanoyl chloride
21132-76-3

docosanoyl chloride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-D-glucitol-2,3,4,6-O-tetrabehenate

1,5-anhydro-D-glucitol-2,3,4,6-O-tetrabehenate

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide; toluene at 50 - 90℃; for 5h; Inert atmosphere;96%
3,4,5-tribenzyloxybenzoic acid
1486-48-2

3,4,5-tribenzyloxybenzoic acid

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1-deoxy-D-glucopyranose-2,3,4,6-tetrakis[3,4,5-tris(phenylmethoxy)benzoate]

1-deoxy-D-glucopyranose-2,3,4,6-tetrakis[3,4,5-tris(phenylmethoxy)benzoate]

Conditions
ConditionsYield
With dmap; 2-chloro-1-methyl-pyridinium iodide; triethylamine In dichloromethane at 20℃; for 48h;92%
With dmap; dicyclohexyl-carbodiimide In dichloromethane for 18h; Steglich esterification; Heating;31.3%
With N-(3-dimethylaminopropyl)-N-ethylcarbodiimide In 1,2-dichloro-ethane at 75℃; for 12h; Inert atmosphere;
3-benzyloxybenzoic acid
69026-14-8

3-benzyloxybenzoic acid

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-2,3,4,6-tetrakis-O-(3'-benzyloxybenzoyl)-D-glucitol

1,5-anhydro-2,3,4,6-tetrakis-O-(3'-benzyloxybenzoyl)-D-glucitol

Conditions
ConditionsYield
With dmap; 2-chloro-1-methyl-pyridinium iodide; triethylamine In dichloromethane at 20℃; for 48h;92%
benzoyl chloride
98-88-4

benzoyl chloride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-tetra-O-benzoyl-D-glucitol
14218-10-1

1,5-anhydro-tetra-O-benzoyl-D-glucitol

Conditions
ConditionsYield
In pyridine91%
With pyridine
(diethoxymethyl)benzene
774-48-1

(diethoxymethyl)benzene

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-4,6-O-(R)-benzylidene-D-glucitol
65391-44-8

1,5-anhydro-4,6-O-(R)-benzylidene-D-glucitol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In N,N-dimethyl-formamide at 20℃; for 96h;91%
1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

n-hexadecanoyl chloride
112-67-4

n-hexadecanoyl chloride

1,5-anhydro-D-glucitol-2,3,4,6-O-tetrapalmitate

1,5-anhydro-D-glucitol-2,3,4,6-O-tetrapalmitate

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 50 - 90℃; for 5h; Inert atmosphere;90%
n-tridecanoyl chloride
17746-06-4

n-tridecanoyl chloride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-D-glucitol-2,3,4,6-O-tetratridecanoate

1,5-anhydro-D-glucitol-2,3,4,6-O-tetratridecanoate

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 50 - 90℃; for 4h; Inert atmosphere;89%
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-D-glucitol-2,3,4,6-O-tetralaurate

1,5-anhydro-D-glucitol-2,3,4,6-O-tetralaurate

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 50 - 90℃; for 5h; Inert atmosphere;88%
pentadecanoyl chloride
17746-08-6

pentadecanoyl chloride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-D-glucitol-2,3,4,6-O-tetrapentadecanoate

1,5-anhydro-D-glucitol-2,3,4,6-O-tetrapentadecanoate

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 50 - 90℃; for 4h; Inert atmosphere;88%
heptadecanoyl chloride
40480-10-2

heptadecanoyl chloride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-D-glucitol-2,3,4,6-O-tetraheptadecanoate

1,5-anhydro-D-glucitol-2,3,4,6-O-tetraheptadecanoate

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 50 - 90℃; for 5h; Inert atmosphere;88%
benzaldehyde dimethyl acetal
1125-88-8

benzaldehyde dimethyl acetal

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

(4aR,7S,8R,8aS)-2-phenylhexahydropyrano[3,2-d][1,3]dioxine-7,8-diol
65190-39-8

(4aR,7S,8R,8aS)-2-phenylhexahydropyrano[3,2-d][1,3]dioxine-7,8-diol

Conditions
ConditionsYield
With camphor-10-sulfonic acid In N,N-dimethyl-formamide for 0.5h; pH=4; Inert atmosphere;87%
With toluene-4-sulfonic acid In N,N-dimethyl-formamide11%
Stearoyl chloride
112-76-5

Stearoyl chloride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-D-glucitol-2,3,4,6-O-tetrastearate

1,5-anhydro-D-glucitol-2,3,4,6-O-tetrastearate

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 50 - 90℃; for 6h; Inert atmosphere;86%
p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-6-O-toluene-p-sulfonyl-D-glucitol
85906-16-7, 102419-15-8

1,5-anhydro-6-O-toluene-p-sulfonyl-D-glucitol

Conditions
ConditionsYield
With pyridine at 25℃; for 24h;85%
With pyridine at 0 - 20℃; for 5h;
n-decanoyl chloride
112-13-0

n-decanoyl chloride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-D-glucitol-2,3,4,6-O-tetradecanoate

1,5-anhydro-D-glucitol-2,3,4,6-O-tetradecanoate

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 50 - 90℃; for 6h; Inert atmosphere;84%
benzyl bromide
100-39-0

benzyl bromide

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1-deoxy-2,3,4,6-tetra-O-benzyl-D-glucopyranose
78890-68-3

1-deoxy-2,3,4,6-tetra-O-benzyl-D-glucopyranose

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 20℃; for 16h;83%
With sodium hydride In N,N-dimethyl-formamide at 20℃; for 3h;1.473 g
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-(R)-4,6-O-prop-2-enylidene-D-glucitol
946411-14-9

1,5-anhydro-(R)-4,6-O-prop-2-enylidene-D-glucitol

Conditions
ConditionsYield
With camphor-10-sulfonic acid In N,N-dimethyl-formamide at 25℃; for 24h;83%
benzaldehyde dimethyl acetal
1125-88-8

benzaldehyde dimethyl acetal

pivaloyl chloride
3282-30-2

pivaloyl chloride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-2,3-dipivaloyl-4,6-O-benzylidene-D-glucitol
221278-39-3

1,5-anhydro-2,3-dipivaloyl-4,6-O-benzylidene-D-glucitol

Conditions
ConditionsYield
Stage #1: benzaldehyde dimethyl acetal; 1,5-anhydro-D-glucitol With sulfuric acid In N,N-dimethyl-formamide Inert atmosphere;
Stage #2: pivaloyl chloride With pyridine at 0 - 20℃; for 24h;
83%
undecanoyl chloride
17746-05-3

undecanoyl chloride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-D-glucitol-2,3,4,6-O-tetraundecanoate

1,5-anhydro-D-glucitol-2,3,4,6-O-tetraundecanoate

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 50 - 90℃; for 6h; Inert atmosphere;82%
1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

methylating agent

methylating agent

1,5-anhydro-2,3,4,6-tetra-O-methyl-D-glucitol
81874-02-4

1,5-anhydro-2,3,4,6-tetra-O-methyl-D-glucitol

Conditions
ConditionsYield
79%
tetradecanoyl chloride
112-64-1

tetradecanoyl chloride

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-D-glucitol-2,3,4,6-O-tetramyristate

1,5-anhydro-D-glucitol-2,3,4,6-O-tetramyristate

Conditions
ConditionsYield
With pyridine In N,N-dimethyl-formamide at 50 - 90℃; for 6h; Inert atmosphere;78%

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