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EAST CHEMSOURCES LIMITED

Acrolein dimethyl acetal Cas No.:6044-68-4 Molecular Structure: Acrolein dimethyl acetal 98% min. Synonyms: 3,3-dimethoxy-1-propene EINECS No.: 227-936-4 Molecular Formula: C5H10O2 M.W: 102.13 Properties: 1) Appearance: Colorless tra

Acrolein dimethyl acetal

Cas:6044-68-4

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

Acrolein Dimethyl Acetal

Cas:6044-68-4

Min.Order:1 Metric Ton

Negotiable

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Acrolein dimethylacetal

Cas:6044-68-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 6044-68-4 with competitive price

Cas:6044-68-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

Acrolein dimethyl acetal

Cas:6044-68-4

Min.Order:1 Kilogram

FOB Price: $7.0 / 9.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name: Acrolein dimethyl acetal Synonyms: 1-Propene, 3,3-dimethoxy-;3,3-dimethoxy-1-propen;3,3-Dimethoxypropene-1;3,3-DIMETHOXY-1-PROPENE;ACROLEIN DIMETHYL ACETAL;

Acrolein dimethyl acetal CAS: 6044-68-4

Cas:6044-68-4

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) reasonable & compet

Acrolein dimethyl acetal CAS NO.:6044-68-4

Cas:6044-68-4

Min.Order:1 Gram

FOB Price: $3.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

6044-68-4 Package:As per buy's request ISO/SGS/REACH Certificate Fast Delivery Appearance:CLEAR COLOURLESS LIQUID Package:1kg-200KG Drum With Pallet Port:China Main Port

6044-68-4

Cas:6044-68-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Acrolein dimethyl acetal 6044-68-4

Cas:6044-68-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

3,3-dimethoxy-1-propene

Cas:6044-68-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

Acrolein dimethyl acetal

Cas:6044-68-4

Min.Order:1 Kilogram

FOB Price: $30.0 / 50.0

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Lonwin Chemical Group Limited

Acrolein dimethyl acetal CAS:6044-68-4 Specification Acrolein dimethyl acetal 98% min. Synonyms: 3,3-dimethoxy-1-propene EINECS No.: 227-936-4 Molecular Formula: C5H10O2 M.W: 102.13 Properties: 1) Appearance: Colorless transparant liquid 2) B.P: 9

Factory supply Acrolein dimethyl acetal CAS 6044-68-4 in China

Cas:6044-68-4

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Acrolein dimethyl acetal

Cas:6044-68-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Acrolein Dimethyl Acetal

Cas:6044-68-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Acrolein Dimethyl Acetal

Cas:6044-68-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

ACROLEIN DIMETHYL ACETAL 6044-68-4

Cas:6044-68-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Acrolein dimethyl acetal

Cas:6044-68-4

Min.Order:0 Metric Ton

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Type:Other

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Hangzhou Lingrui Chemical Co.,Ltd.

advantage: 1. The best price, satisfactory quality; 2. customers have the right to choose the delivery of parcels (EMS, DHL, FedEx, UPS); 3. customers have the right to choose from the recent effective packaging methods of their products packaging

high quality Acrolein dimethyl acetal

Cas:6044-68-4

Min.Order:1 Gram

Negotiable

Type:Other

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Acrolein Dimethyl Acetal

Cas:6044-68-4

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: Acrolein Dimethyl Acetal CAS No.:6044-68-4 Molecule Formula:C5H10O2 Molecule Weight:102.13 Purity: 98.0% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard

Best Quality Acrolein Dimethyl Acetal

Cas:6044-68-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

Acrolein dimethyl acetal Chemical Properties Boiling point 89-90 °C(lit.) density 0.862 g/mL at 25 °C(lit.) refractive index n20/D 1.395(lit.) Fp 27 °F storage temp. 2-8°C BRN 1700037 CAS DataBase Reference

Acrolein Dimethyl Acetal

Cas:6044-68-4

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Acrolein Dimethyl Acetal

Cas:6044-68-4

Min.Order:1 Gram

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Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Acrolein Dimethyl Acetal

Cas:6044-68-4

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Acrolein dimethyl acetal

Cas:6044-68-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Acrolein dimethyl acetal Cas no.6044-68-4 98%

Cas:6044-68-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Acrolein Dimethyl Acetal

Cas:6044-68-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Acrolein dimethyl acetal

Cas:6044-68-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

3,3-dimethoxy-1-propene

Cas:6044-68-4

Min.Order:0

Negotiable

Type:Other

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Chemsigma International Co.,Ltd.

bulk productiongoods in stockswe have the best competitive price in the marketmeantime,we are committed to service to our every customer Chemsigma International Co.,Ltd. is a chemical manufacturer, specialize in custom synthesis and organic chemical

Acrolein dimethyl acetal

Cas:6044-68-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Acrolein dimethyl acetal 6044-68-4

Cas:6044-68-4

Min.Order:0

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Type:Trading Company

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Synthetic route

methanol
67-56-1

methanol

acrolein
107-02-8

acrolein

A

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

B

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

Conditions
ConditionsYield
With oxygen; Pd5-Bi2-Fe1/(100)SiO2-MgO for 4h;A n/a
B 91.5%
methanol
67-56-1

methanol

allyl n-butyl ether
3739-64-8

allyl n-butyl ether

A

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

B

3-n-butyloxy-3-methoxy-1-propene
106521-18-0

3-n-butyloxy-3-methoxy-1-propene

Conditions
ConditionsYield
With tris (2,4-dibromophenyl)amine; sodium methylate; lithium perchlorate at 40℃; electrochem. oxidation;A 25%
B 37%
methanol
67-56-1

methanol

Allyl ether
557-40-4

Allyl ether

A

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

B

3-allyloxy-3-methoxy-1-propene
113443-66-6

3-allyloxy-3-methoxy-1-propene

Conditions
ConditionsYield
With tris (2,4-dibromophenyl)amine; sodium methylate; lithium perchlorate at 40℃; electrochem. oxidation;A 9%
B 35%
With tris (2,4-dibromophenyl)amine; sodium methylate; lithium perchlorate at 40℃; electrochem. oxidation;A 9%
B 35%
3-chloropropionaldehyde dimethyl acetal
35502-06-8

3-chloropropionaldehyde dimethyl acetal

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

Conditions
ConditionsYield
With potassium hydroxide
3-bromopropanal dimethyl acetal
36255-44-4

3-bromopropanal dimethyl acetal

sodium methylate
124-41-4

sodium methylate

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

1,1,3-trimethoxypropane
14315-97-0

1,1,3-trimethoxypropane

A

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

B

dimethoxypropene
78300-84-2

dimethoxypropene

Conditions
ConditionsYield
With quinoline; diisopropyl sulfate at 350℃;
With quinoline; diisopropyl sulfate at 350℃; entsteht ein Gemisch der stereoisomeren;
3-bromopropanal dimethyl acetal
36255-44-4

3-bromopropanal dimethyl acetal

sodium acetate
127-09-3

sodium acetate

acetic acid
64-19-7

acetic acid

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

methanol
67-56-1

methanol

acrolein
107-02-8

acrolein

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

Conditions
ConditionsYield
With toluene-4-sulfonic acid; Petroleum ether
With copper dichloride
methanol
67-56-1

methanol

Methoxyallene
13169-00-1

Methoxyallene

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

Conditions
ConditionsYield
With toluene-4-sulfonic acid In diethyl ether Heating;
acrolein
107-02-8

acrolein

trimethyl orthoformate
149-73-5

trimethyl orthoformate

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

Conditions
ConditionsYield
With ammonium nitrate In methanol
With ammonium nitrate In methanol for 5h; Ambient temperature;
With ammonium nitrite In methanol for 8h; Heating;
hydrogenchloride
7647-01-0

hydrogenchloride

methanol
67-56-1

methanol

acrolein
107-02-8

acrolein

A

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

B

3-methoxy-1-propanal
2806-84-0

3-methoxy-1-propanal

Conditions
ConditionsYield
at 25 - 40℃; Kinetics;
3-chloropropionaldehyde dimethyl acetal
35502-06-8

3-chloropropionaldehyde dimethyl acetal

potassium hydroxide

potassium hydroxide

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

Conditions
ConditionsYield
beim Destillieren;
quinoline
91-22-5

quinoline

diisopropyl sulfate
2973-10-6

diisopropyl sulfate

1,1,3-trimethoxypropane
14315-97-0

1,1,3-trimethoxypropane

A

methanol
67-56-1

methanol

B

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

C

acrolein
107-02-8

acrolein

D

1,3-dimethoxy-propene

1,3-dimethoxy-propene

Conditions
ConditionsYield
at 350℃; Pyrolyse des Dampfes.Pyrolysis;
1,1,3-trimethoxypropane
14315-97-0

1,1,3-trimethoxypropane

aluminium oxide

aluminium oxide

A

methanol
67-56-1

methanol

B

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

C

acrolein
107-02-8

acrolein

D

1,3-dimethoxy-propene

1,3-dimethoxy-propene

Conditions
ConditionsYield
at 228℃; Pyrolyse des Dampfes.Pyrolysis;
acrolein
107-02-8

acrolein

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

Conditions
ConditionsYield
With hydroquinone In methanol
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

1-[(4-chlorophenyl)methylene]-5,5-dimethyl-3-oxopyrazolidin-1-ium-2-ide
80414-54-6

1-[(4-chlorophenyl)methylene]-5,5-dimethyl-3-oxopyrazolidin-1-ium-2-ide

7-chloro-10-methoxy-3,3-dimethyl-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-1-one

7-chloro-10-methoxy-3,3-dimethyl-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-1-one

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; lithium acetate at 40℃; for 12h; Sealed tube; regioselective reaction;98%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

C36H42N2O7S

C36H42N2O7S

C39H48N2O9S

C39H48N2O9S

Conditions
ConditionsYield
With Hoveyda-Grubbs catalyst second generation In dichloromethane at 20℃; for 5h; Cross Metathesis; Inert atmosphere; chemoselective reaction;97%
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane at 20℃; for 5h; Inert atmosphere;97%
With Hoveyda-Grubbs catalyst second generation In dichloromethane at 20℃; for 5h; Inert atmosphere;
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

C12H13ClN2O

C12H13ClN2O

6-chloro-10-methoxy-3,3-dimethyl-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-1-one

6-chloro-10-methoxy-3,3-dimethyl-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-1-one

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; lithium acetate at 40℃; for 12h; Sealed tube; regioselective reaction;96%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

bis-(phenylthio)-dibutylstannane
14365-16-3

bis-(phenylthio)-dibutylstannane

(E,Z)-1-methoxy-3-phenylthio-1-propene
150748-90-6

(E,Z)-1-methoxy-3-phenylthio-1-propene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In toluene at -78℃; for 0.5h;93%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

1-benzylidene-5,5-dimethyl-3-oxopyrazolidin-1-ium-2-ide
42953-83-3

1-benzylidene-5,5-dimethyl-3-oxopyrazolidin-1-ium-2-ide

10-methoxy-3,3-dimethyl-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-1-one

10-methoxy-3,3-dimethyl-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-1-one

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; lithium acetate at 40℃; for 12h; Catalytic behavior; Mechanism; Kinetics; Solvent; Reagent/catalyst; Sealed tube; regioselective reaction;93%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

C14H17N3O2

C14H17N3O2

N-(10-methoxy-3,3-dimethyl-1-oxo-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-7-yl)acetamide

N-(10-methoxy-3,3-dimethyl-1-oxo-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-7-yl)acetamide

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; lithium acetate at 40℃; for 12h; Sealed tube; regioselective reaction;93%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

1-benzylidene-5,5-dimethyl-3-oxopyrazolidin-1-ium-2-ide
42953-83-3

1-benzylidene-5,5-dimethyl-3-oxopyrazolidin-1-ium-2-ide

C16H20N2O2

C16H20N2O2

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; lithium acetate at 40℃; for 12h; Catalytic behavior; Reagent/catalyst;93%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

benzyl chloroformate
501-53-1

benzyl chloroformate

((E)-3-methyloxy-allyl)-carbamic acid benzyl ester
1075689-61-0

((E)-3-methyloxy-allyl)-carbamic acid benzyl ester

Conditions
ConditionsYield
Stage #1: 3,3-dimethoxyprop-1-ene In benzene-d6 at 23℃;
Stage #2: benzyl chloroformate With potassium carbonate In tetrahydrofuran; benzene-d6 at 23℃; for 12h; Further stages.;
92%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

C13H14N2O3

C13H14N2O3

10-methoxy-6,6-dimethyl-4b,6,7,10,10a,11-hexahydro-8H-[1,3]dioxolo[4',5':5,6]indeno[1,2-c]pyrazolo[1,2-a]pyrazol-8-one

10-methoxy-6,6-dimethyl-4b,6,7,10,10a,11-hexahydro-8H-[1,3]dioxolo[4',5':5,6]indeno[1,2-c]pyrazolo[1,2-a]pyrazol-8-one

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; lithium acetate at 40℃; for 12h; Sealed tube; regioselective reaction;92%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

(1R,2S)-1-phenyl-2-benzyloxycarbonylamino-1-propanol
104863-92-5

(1R,2S)-1-phenyl-2-benzyloxycarbonylamino-1-propanol

(2S,4S,5R)-4-Methyl-5-phenyl-2-vinyl-oxazolidine-3-carboxylic acid benzyl ester
113323-06-1

(2S,4S,5R)-4-Methyl-5-phenyl-2-vinyl-oxazolidine-3-carboxylic acid benzyl ester

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In benzene for 5h; Heating;91%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

phosphorous acid trimethyl ester
121-45-9

phosphorous acid trimethyl ester

dimethyl (1-methoxyprop-2-enyl)phosphonate
80986-52-3

dimethyl (1-methoxyprop-2-enyl)phosphonate

Conditions
ConditionsYield
Stage #1: 3,3-dimethoxyprop-1-ene With phosphorus trichloride for 0.25h; Inert atmosphere; Cooling;
Stage #2: phosphorous acid trimethyl ester at 20℃; for 1h; Inert atmosphere; Cooling;
91%
With phosphorus trichloride In toluene for 3h; Ambient temperature;82%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

(1Z)-5,5-dimethyl-1-[(4-nitrophenyl)methylidene]-3-oxopyrazolidin-1-ium-2-ide
77396-68-0

(1Z)-5,5-dimethyl-1-[(4-nitrophenyl)methylidene]-3-oxopyrazolidin-1-ium-2-ide

10-methoxy-3,3-dimethyl-7-nitro-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-1-one

10-methoxy-3,3-dimethyl-7-nitro-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-1-one

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; lithium acetate at 40℃; for 12h; Sealed tube; regioselective reaction;91%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

(1S,2R)-(+)-2-chloro-N-(2-hydroxy-1-methyl-2-phenylethyl)acetamide
16251-50-6

(1S,2R)-(+)-2-chloro-N-(2-hydroxy-1-methyl-2-phenylethyl)acetamide

2-Chloro-1-((2S,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-ethanone
137314-81-9

2-Chloro-1-((2S,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-ethanone

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In benzene for 10h; Heating;90%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

methylallylether
627-40-7

methylallylether

Conditions
ConditionsYield
With benzo[1,3,2]dioxaborole In benzene Ambient temperature;88%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

1-[(4-bromophenyl)methylene]-5,5-dimethyl-3-oxopyrazolidin-1-ium-2-ide
88740-94-7

1-[(4-bromophenyl)methylene]-5,5-dimethyl-3-oxopyrazolidin-1-ium-2-ide

7-bromo-10-methoxy-3,3-dimethyl-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-1-one

7-bromo-10-methoxy-3,3-dimethyl-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-1-one

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; lithium acetate at 40℃; for 12h; Sealed tube; regioselective reaction;88%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

(2R,3S,4R,5R,6S)-2-(hydroxymethyl)-6-phenyltetrahydro-2H-pyran-3,4,5-triol
5627-22-5, 6138-10-9, 6708-49-2, 20181-49-1, 29084-16-0, 54933-92-5, 63598-21-0, 95839-12-6, 95839-13-7

(2R,3S,4R,5R,6S)-2-(hydroxymethyl)-6-phenyltetrahydro-2H-pyran-3,4,5-triol

(R)-4,6-O-prop-2-enylidene-β-D-glucopyranosylbenzene
946411-12-7

(R)-4,6-O-prop-2-enylidene-β-D-glucopyranosylbenzene

Conditions
ConditionsYield
With camphor-10-sulfonic acid In N,N-dimethyl-formamide at 25℃; for 24h;87%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

ethyl 2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside
130539-43-4

ethyl 2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

ethyl 4,6-O-allylidene-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

ethyl 4,6-O-allylidene-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

Conditions
ConditionsYield
With toluene-4-sulfonic acid In N,N-dimethyl-formamide for 1.5h;86%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

C14H16N2O3

C14H16N2O3

methyl 10-methoxy-3,3-dimethyl-1-oxo-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazole-7-carboxylate

methyl 10-methoxy-3,3-dimethyl-1-oxo-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazole-7-carboxylate

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; lithium acetate at 40℃; for 12h; Sealed tube; regioselective reaction;86%
C31H40O11
943239-55-2

C31H40O11

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

C34H42O11
943239-56-3

C34H42O11

Conditions
ConditionsYield
With (1S)-10-camphorsulfonic acid In dichloromethane at 20℃; for 3.5h; Temperature; Reagent/catalyst;85.1%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

norephedrine ortho-bromobenzamide

norephedrine ortho-bromobenzamide

(2-Bromo-phenyl)-((2S,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-methanone

(2-Bromo-phenyl)-((2S,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-methanone

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In benzene for 10h; Heating;85%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

2-(3,3-dimethoxypropyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
259526-19-7

2-(3,3-dimethoxypropyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With Wilkinson's catalyst In dichloromethane for 24h;85%
tris(triphenylphosphine)rhodium(I) chloride In dichloromethane stirred for 1 d; fractionated; elem. anal.;85%
With Wilkinson's catalyst In dichloromethane at 20℃; Addition; hydroboration;75%
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; bis-diphenylphosphinomethane In dichloromethane at 20℃; for 18h; Inert atmosphere; Sealed tube;29%
morpholine
110-91-8

morpholine

2-bromobutene
23074-36-4

2-bromobutene

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

4-((E)-2-Ethyl-5,5-dimethoxy-pent-2-enyl)-morpholine
76251-71-3

4-((E)-2-Ethyl-5,5-dimethoxy-pent-2-enyl)-morpholine

Conditions
ConditionsYield
palladium diacetate at 125℃; for 48h;84%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

(-)-N-cyanomethylphenylglycinol
111980-33-7

(-)-N-cyanomethylphenylglycinol

(-)-(2R,4R)-2-(methoxyethyl)-N-cyanomethyl-4-phenyl-1,3-oxazolidine
132609-60-0

(-)-(2R,4R)-2-(methoxyethyl)-N-cyanomethyl-4-phenyl-1,3-oxazolidine

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 1h; Heating;83%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

1,5-anhydro-D-glucitol
154-58-5

1,5-anhydro-D-glucitol

1,5-anhydro-(R)-4,6-O-prop-2-enylidene-D-glucitol
946411-14-9

1,5-anhydro-(R)-4,6-O-prop-2-enylidene-D-glucitol

Conditions
ConditionsYield
With camphor-10-sulfonic acid In N,N-dimethyl-formamide at 25℃; for 24h;83%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

norefedrine α-chloropropionamide
137314-75-1, 137431-00-6, 143060-09-7

norefedrine α-chloropropionamide

A

2-Chloro-1-((2S,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-propan-1-one
137314-76-2, 137314-82-0, 142955-00-8

2-Chloro-1-((2S,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-propan-1-one

B

2-Chloro-1-((2R,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-propan-1-one
137314-76-2, 137314-82-0, 142955-00-8

2-Chloro-1-((2R,4S,5R)-4-methyl-5-phenyl-2-vinyl-oxazolidin-3-yl)-propan-1-one

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In benzene for 14h; Heating;A 82.8%
B 7.2%
With pyridinium p-toluenesulfonate In benzene Heating; 4 Angstroem mol. sieves; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

1-nitrohexane
646-14-0

1-nitrohexane

5-Dimethoxymethyl-3-pentyl-4,5-dihydro-isoxazole
88911-41-5

5-Dimethoxymethyl-3-pentyl-4,5-dihydro-isoxazole

Conditions
ConditionsYield
82%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

N-allyl-N-hydroxybenzamide
154491-53-9

N-allyl-N-hydroxybenzamide

N-allyl-N-(1-methoxy-allyloxy)-benzamide
639512-99-5

N-allyl-N-(1-methoxy-allyloxy)-benzamide

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In benzene at 80℃;82%
(Z)-5,5-dimethyl-1-(4-methylphenylmethylidene)-3-oxopyrazolidin-1-ium-2-ide
924663-44-5

(Z)-5,5-dimethyl-1-(4-methylphenylmethylidene)-3-oxopyrazolidin-1-ium-2-ide

3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

10-methoxy-3,3,7-trimethyl-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-1-one

10-methoxy-3,3,7-trimethyl-2,3,4a,9,9a,10-hexahydro-1H-indeno[1,2-c]pyrazolo[1,2-a]pyrazol-1-one

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; lithium acetate at 40℃; for 12h; Sealed tube; regioselective reaction;82%
3,3-dimethoxyprop-1-ene
6044-68-4

3,3-dimethoxyprop-1-ene

3-Phenylpropenol
104-54-1

3-Phenylpropenol

4-phenyl-1,5-hexadien-3-ol

4-phenyl-1,5-hexadien-3-ol

Conditions
ConditionsYield
Stage #1: 3-Phenylpropenol With C20H17ClPdSe2; water; toluene-4-sulfonic acid; bis(pinacol)diborane In methanol; dimethyl sulfoxide at 50℃; for 16h;
Stage #2: 3,3-dimethoxyprop-1-ene In methanol; dimethyl sulfoxide at 50℃; for 20h;
81%

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