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inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
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inquiry(E)-A,SS-STYRENEDIBORONIC ACID BIS(PINACOL) ESTERCASAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
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Type:
inquiryphenylacetylene
bis(pinacol)diborane
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
With gold In toluene at 100℃; for 1.5h; Catalytic behavior; Reagent/catalyst; Solvent; Time; Concentration; Green chemistry; diastereoselective reaction; | 93% |
With atomically dispersed Pt on beta-cyclodextrin-containing polymer In toluene at 100℃; for 2h; Reagent/catalyst; Temperature; Solvent; | 93% |
With Pd(1,3,4,5-tetramethylimidazol-2-ylidene)2(diphenylacetylene) In benzene at 20℃; for 3h; stereoselective reaction; | 91% |
bis(pinacol)diborane
4,4,5,5-tetramethyl-2-phenylethynyl-[1,3,2]dioxaborolane
A
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
tetrakis(triphenylphosphine)platinum In toluene (N2); addn. of phenylethynylpinacolatoborane in react. mixt. of Pt(PPh3)4 and bis(pinacolato)diborane(4) in dry toluene; stirring overnight at 80°C; | A n/a B 0% |
phenylacetylene
bis(pinacol)diborane
A
4,4,5,5-tetramethyl-2-((E)-styryl)-[1,3,2]dioxaborolane
B
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
With triphenylphosphine In toluene at 160℃; under 1125.11 Torr; for 1.5h; Inert atmosphere; stereoselective reaction; | |
With Pt(075 wtpercent)/CeO2 In toluene at 160℃; under 1125.11 Torr; for 0.7h; Inert atmosphere; stereoselective reaction; |
phenylacetylene
A
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: HCl; (n-C4H9)Li / hexane; diethyl ether 2: tetrakis(triphenylphosphine)platinum / toluene View Scheme |
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
A
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: HCl; (n-C4H9)Li / hexane; diethyl ether 2: tetrakis(triphenylphosphine)platinum / toluene View Scheme |
phenylacetylene
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
A
4,4,5,5-tetramethyl-2-(1-phenylvinyl)-1,3,2-dioxaborolane
B
4,4,5,5-tetramethyl-2-styryl-[1,3,2]dioxaborolane
C
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; tert-butylisonitrile; carbon monoxide at 50℃; under 760.051 Torr; | A 26 %Spectr. B 15 %Spectr. C 51 %Spectr. |
iodobenzene
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Triphenylethylene
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium hydroxide In tetrahydrofuran; water at 70℃; for 4h; Suzuki-Miyaura Coupling; | 100% |
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
(E)-2-(2-bromo-1-phenylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Conditions | Yield |
---|---|
With copper(ll) bromide In tetrahydrofuran; water at 70℃; for 1h; | 98% |
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
(E)-2-(2-iodo-1-phenylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Conditions | Yield |
---|---|
With iodine; sodium hydroxide In diethyl ether at 0℃; for 0.5h; | 95% |
methanol
carbon monoxide
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
dimethyl 2-(phenyl)maleate
Conditions | Yield |
---|---|
With palladium diacetate; triphenylphosphine; p-benzoquinone at 20℃; under 760.051 Torr; for 24h; | 93% |
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
(R)-1-phenyl-1,2-ethanediol
Conditions | Yield |
---|---|
Stage #1: (E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) With hydrogen; di(norbornadiene)rhodium(I) tetrafluoroborate; (R)-1-[2-(2'-diphenylphosphinophenyl)-ferrocenyl]ethyldi[bis-(3,5-trifluoromethyl)phenyl]phosphine under 11400.8 Torr; Stage #2: With dihydrogen peroxide Product distribution / selectivity; | 86% |
Stage #1: (E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) With hydrogen; di(norbornadiene)rhodium(I) tetrafluoroborate; (R)-1-[2-(2'-diphenylphosphinophenyl)-ferrocenyl]ethyldi[bis-(3,5-trifluoromethyl)phenyl]phosphine under 11400.8 Torr; Stage #2: With sodium hydroxide; dihydrogen peroxide Product distribution / selectivity; | 86% |
2-iodo-benzo[1,2-b:4,3-b']dithiophene
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene for 8h; Suzuki coupling reaction; Heating; | 73% |
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
(E)-2-(2-chloro-1-phenylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Conditions | Yield |
---|---|
With copper dichloride In tetrahydrofuran; water at 70℃; for 1h; | 62% |
para-bromotoluene
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
(CH3)4C2O2BC(C6H5)CHC6H4CH3
Conditions | Yield |
---|---|
With K2CO3; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In dimethylformamide 80°C, 16 h; | 53% |
naphthalene-1,8-diamine
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
In toluene at 120℃; for 48h; Sealed tube; | 11% |
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
2,2'-(1-phenylethane-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
With bis(norbornadiene)rhodium(l)tetrafluoroborate; (R)-Walphos (W001); hydrogen In toluene under 15001.2 Torr; for 24h; | |
With hydrogen In toluene at 130℃; under 5250.53 Torr; for 13h; |
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
A
2-fluoroacetophenone
B
2,2-difluoro-1-phenylethanone
Conditions | Yield |
---|---|
Stage #1: (E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) With sodium hydroxide; Selectfluor In acetonitrile at 25℃; for 15h; Stage #2: With sodium hydroxide In acetonitrile |
cyclohexylamine
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
Stage #1: (E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) With sodium hydrogencarbonate; Selectfluor In acetonitrile at 20℃; for 15h; Stage #2: cyclohexylamine With montmorillonite K-10 In acetonitrile at 25℃; for 15h; Further stages.; | 19 % Spectr. |
N-butylamine
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
Stage #1: (E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) With sodium hydrogencarbonate; Selectfluor In acetonitrile at 20℃; for 15h; Stage #2: N-butylamine With montmorillonite K-10 In acetonitrile at 25℃; for 15h; Further stages.; | 33 % Spectr. |
isopropylamine
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
A
N-(2,2-difluoro-1-phenylethylidene)isopropylamine
B
2,2-difluoro-1-phenylethanone
Conditions | Yield |
---|---|
Stage #1: (E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) With sodium hydrogencarbonate; Selectfluor In acetonitrile at 20℃; for 15h; Stage #2: isopropylamine With montmorillonite K-10 In acetonitrile at 25℃; for 15h; Further stages.; | A 27 % Spectr. B 1 % Spectr. |
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
(2R)-2,2'-(1-phenylethane-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
With C32H12BF24(1-)*C56H70IrNO7P(1+); hydrogen In dichloromethane at 20℃; under 37503.8 Torr; for 2h; optical yield given as %ee; enantioselective reaction; |
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
(E)-1,2-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-phenylethene
Conditions | Yield |
---|---|
With tris[2-phenylpyridinato-C2,N]iridium(III) In acetonitrile for 16h; Sealed tube; Inert atmosphere; UV-irradiation; |
naphthalene-1,8-diamine
(E)-2,2′-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: toluene / 48 h / 120 °C / Sealed tube 2: 2-(2,6-iPr2−C6H3NCMe)-6-(C(Me)N-((S)-(CH(CH3)C(CH3)2CH2−))−(C5H3N)Co); hydrogen / benzene-d6 / 24 h / 23 °C / 3040.2 Torr / Sealed tube; Glovebox View Scheme |
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